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2.发明公开HALOGEN-FREE FLAME RETARDANT TYPE RESIN COMPOSITION 审中-公开HALOGENFREIE FLAMMHEMMENDE HARZZUSAMMENSETZUNG
公开(公告)号：EP3112422A1
公开(公告)日：2017-01-04
申请号：EP15755556.6
申请日：2015-02-11
发明人： XI, Long , HE, Yueshan , WANG, Biwu
IPC分类号： C08L79/04 , C08L79/08 , C08L63/00 , C08K13/02 , C08K5/523 , C08K5/521 , C08K5/5399 , B32B27/04 , B32B15/08 , H05K1/03
CPC分类号： C08L79/04 , B32B15/08 , B32B15/092 , B32B27/16 , B32B27/18 , B32B27/20 , B32B27/38 , B32B27/42 , B32B2264/102 , B32B2307/3065 , B32B2307/558 , B32B2457/08 , C08J5/24 , C08J2379/04 , C08J2463/00 , C08J2479/04 , C08J2479/08 , C08K3/22 , C08K3/36 , C08K5/3445 , C08K5/521 , C08K5/5399 , C08L61/06 , C08L61/34 , C08L63/00 , C08L79/085 , C08L2201/02 , C08L2201/08 , C08L2201/22 , C08L2203/20 , C08L2205/03 , H05K1/0326 , H05K1/0366 , H05K1/0373 , H05K2201/012
摘要： The present invention relates to a halogen-free flame-retardant resin composition, based on the weight parts of organic solids, comprising (A) from 1 to 10 parts by weight of bismaleimide resin, (B) from 30 to 60 parts by weight of benzoxazine resin, (C) from 10 to 40 parts by weight of polyepoxy compound, (D) from 5 to 25 parts by weight of phosphorous-containing flame retardant, and (E) from 1 to 25 parts by weight of curing agent, which is amine curing agent and/or phenolic resin curing agent. The present invention further provides prepregs, laminates, laminates for printed circuits prepared from said resin composition.
摘要翻译： 本发明涉及一种基于有机固体重量份的无卤阻燃树脂组合物，其包含（A）1至10重量份的双马来酰亚胺树脂，（B）30至60重量份的 苯并恶嗪树脂，（C）10〜40重量份聚环氧化合物，（D）5〜25重量份含磷阻燃剂，（E）1〜25重量份固化剂， 是胺固化剂和/或酚醛树脂固化剂。 本发明还提供由所述树脂组合物制备的用于印刷电路的预浸料，层压材料，层压材料。
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公开(公告)号：EP2933293A1
公开(公告)日：2015-10-21
申请号：EP13863595.8
申请日：2013-02-07
发明人： HE, Yueshan , SU, Shiguo
IPC分类号： C08L63/00 , C08L63/02 , C08L61/06 , C08K13/02 , C08K5/5399 , C08K5/357 , C08G59/50 , B32B27/06 , B32B27/38 , B32B15/092 , H05K1/03
CPC分类号： C08L63/00 , B32B15/092 , B32B15/16 , B32B27/20 , B32B2260/025 , B32B2260/046 , B32B2264/102 , B32B2264/104 , B32B2307/306 , B32B2457/08 , C08G59/50 , C08G59/621 , C08J5/24 , C08J2361/06 , C08J2363/00 , C08K5/357 , C08K5/5399 , C08L61/06 , C08L71/00 , H05K1/0353 , H05K1/0366 , H05K1/0373 , H05K3/022 , H05K2201/012 , H05K2201/0209 , C08L79/04 , C08L85/02
摘要： The present invention relates to a halogen-free flame retardant resin composition, according to parts by weight, the resin composition comprises:(A) a mixture of phenoxyphosphazene compound (A 1 ) and compound (A 2 ) having dihydrobenzoxazine ring: 45-90 parts by weight, and the weight ratio of the phenoxyphosphazene compound (A 1 ) and the compound(A 2 ) having dihydrobenzoxazine ring is between 1:25-1:2; (B) an epoxy resin with epoxy equivalent of 500 -2000: 10-45 parts by weight; (C) a phenolic resin: 10-25 parts by weight, and (D) an amine curing agent: 0.5-10 parts by weight. The prepreg, laminate, metal-clad laminate for printed circuit prepared using the halogen-free flame retardant resin composition, have the advantages of high glass transition temperature (Tg), high thermal resistance, low dielectric dissipation factor, low water absorption as well as low C.T.E.
摘要翻译： 本发明涉及无卤阻燃树脂组合物，根据重量份，树脂组合物包含：（A）苯氧基磷腈化合物（A 1）和具有二氢苯并恶嗪环的化合物（A 2）的混合物：45-90 （A 1）和具有二氢苯并恶嗪环的化合物（A 2）的重量比为1:25-1:2; （B）环氧当量为500-2000：10-45重量份的环氧树脂; （C）酚醛树脂：10-25重量份，（D）胺固化剂：0.5-10重量份。 使用无卤阻燃树脂组合物制备的印刷电路用预浸料，层压板，覆金属层压板具有玻璃化转变温度（Tg）高，耐热性高，介电损耗因数低，吸水率低的优点 低CTE
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公开(公告)号：EP2769975A1
公开(公告)日：2014-08-27
申请号：EP11874158.6
申请日：2011-10-18
发明人： SU, Shiguo , HE, Yueshan
IPC分类号： C07D265/12
CPC分类号： C07D265/12
摘要： The present invention relates to a benzoxazine intermediate and a preparation method thereof. The structural formula of the benzoxazine intermediate is shown by formula (1), R 1 in formula represents O, C=O, S, SO 2 , alicyclic hydrocarbon with 3 to 30 carbon atoms and derivatives thereof, aliphatic hydrocarbon with 1 to 20 carbon atoms and derivatives thereof, or unsaturated aliphatic hydrocarbon with 2 to 20 carbon atoms and derivatives thereof; R 2 is alicyclic hydrocarbon with 3 to 20 carbon atoms and derivatives thereof, aliphatic hydrocarbon with 1 to 20 carbon atoms and derivatives thereof, or unsaturated aliphatic hydrocarbon with 2 to 20 carbon atoms and derivatives thereof. The benzoxazine intermediate of the present invention contains a naphthalene ring structure segment, has desirable heat resistance performance and flame retarding performance, and can be widely applied in composite materials.
摘要翻译： 苯并恶嗪中间体及其制备方法本发明涉及苯并恶嗪中间体及其制备方法。 式（1）表示苯并恶嗪中间体的结构式，式中的R 1表示O，C = O，S，SO 2，具有3至30个碳原子的脂环烃及其衍生物，具有1至20个碳原子的脂族烃和 其衍生物或具有2至20个碳原子的不饱和脂族烃及其衍生物; R2为具有3至20个碳原子的脂环烃及其衍生物，具有1至20个碳原子的脂族烃及其衍生物或具有2至20个碳原子的不饱和脂族烃及其衍生物。 本发明的苯并恶嗪中间体含有萘环结构链段，具有理想的耐热性能和阻燃性能，可广泛应用于复合材料中。
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公开(公告)号：EP3053963B1
公开(公告)日：2018-09-19
申请号：EP14888197.2
申请日：2014-07-17
发明人： YOU, Jiang , HE, Yueshan
IPC分类号： C08L63/00 , C08K5/3437 , C08K5/50
CPC分类号： C08L63/00 , C08G59/4215 , C08G59/4276 , C08G59/686 , C08J5/24 , C08J2363/00 , C08J2379/04 , C08J2463/00 , C08J2479/04 , C08K5/3437 , C08K5/50 , C08L79/04 , C08L2201/02 , C08L2201/08 , C09D163/00 , C09D179/04 , C09J163/00 , C08K3/36 , C08K5/5313 , C08L67/00
摘要： Disclosed is a halogen-free resin composition. The halogen-free resin composition comprises: (A) 10-60 parts by weight of dicyclopentadiene benzoxazine resin, (B) an epoxy resin, (C) an active ester curing agent and (D) a phosphorus-containing flame retardant, based on 100 parts by weight of the total amount of total organic solid matters of (A), (B), (C) and (D). A prepreg and a laminate which are prepared using the halogen-free resin composition have low dielectric constant, low dielectric loss factor, low water absorption, high dimensional stability, high thermal resistance and good flame retardancy, processability and chemical resistance.
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公开(公告)号：EP2933293B1
公开(公告)日：2018-05-30
申请号：EP13863595.8
申请日：2013-02-07
发明人： HE, Yueshan , SU, Shiguo
IPC分类号： C08L63/00 , C08L63/02 , C08L61/06 , C08K13/02 , C08K5/5399 , C08K5/357 , C08G59/50 , B32B27/06 , B32B27/38 , B32B15/092 , H05K1/03 , C08G59/62
CPC分类号： C08L63/00 , B32B15/092 , B32B15/16 , B32B27/20 , B32B2260/025 , B32B2260/046 , B32B2264/102 , B32B2264/104 , B32B2307/306 , B32B2457/08 , C08G59/50 , C08G59/621 , C08J5/24 , C08J2361/06 , C08J2363/00 , C08K5/357 , C08K5/5399 , C08L61/06 , C08L71/00 , H05K1/0353 , H05K1/0366 , H05K1/0373 , H05K3/022 , H05K2201/012 , H05K2201/0209 , C08L79/04 , C08L85/02
摘要： The present invention relates to a halogen-free flame retardant resin composition, according to parts by weight, the resin composition comprises:(A) a mixture of phenoxyphosphazene compound (A 1 ) and compound (A 2 ) having dihydrobenzoxazine ring: 45-90 parts by weight, and the weight ratio of the phenoxyphosphazene compound (A 1 ) and the compound(A 2 ) having dihydrobenzoxazine ring is between 1:25-1:2; (B) an epoxy resin with epoxy equivalent of 500 -2000: 10-45 parts by weight; (C) a phenolic resin: 10-25 parts by weight, and (D) an amine curing agent: 0.5-10 parts by weight. The prepreg, laminate, metal-clad laminate for printed circuit prepared using the halogen-free flame retardant resin composition, have the advantages of high glass transition temperature (Tg), high thermal resistance, low dielectric dissipation factor, low water absorption as well as low C.T.E.
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公开(公告)号：EP2769975B1
公开(公告)日：2017-05-31
申请号：EP11874158.6
申请日：2011-10-18
发明人： SU, Shiguo , HE, Yueshan
IPC分类号： C07D265/12
CPC分类号： C07D265/12
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8.发明授权
公开(公告)号：EP2752449B1
公开(公告)日：2019-07-03
申请号：EP11871425.2
申请日：2011-09-02
发明人： HE, Yueshan
IPC分类号： B32B15/14 , B32B15/20 , B32B37/10 , B32B38/08 , C08K5/00 , C08K5/5399 , C09D143/02 , C09D145/00 , C09D163/10 , C09D171/12 , H05K1/03 , H05K1/02 , H05K3/02
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10.发明公开SILOXANE-MODIFIED CYCLOTRIPHOSPHAZENE HALOGEN-FREE FLAME RETARDANT, PREPARATION PROCESS AND USE THEREOF 审中-公开硅氧烷改性的环三卤代无卤阻燃剂，其制备方法及其用途
公开(公告)号：EP3312186A1
公开(公告)日：2018-04-25
申请号：EP17163189.8
申请日：2017-03-28
发明人： WANG, Yongzhen , HE, Yueshan , YANG, Zhongqiang , XU, Yongjing
IPC分类号： C07F9/659 , C08K5/5399 , D06M15/673 , C08L27/02
CPC分类号： C09K21/12 , B32B15/092 , B32B27/20 , B32B37/06 , B32B2305/076 , B32B2307/3065 , B32B2383/00 , C07F9/659 , C08J5/24 , C08J2363/00 , C08J2363/04 , C08K3/22 , C08K3/36 , C08K5/5399 , C08K5/5406 , C08K5/5442 , C08K2003/2206 , C08K2003/2227 , C08L27/02 , C08L2201/02 , D06M15/673 , C08L63/00
摘要： The present invention provides a siloxane-modified cyclotriphosphazene halogen-free flame retardant, and a preparation method and a use thereof. The siloxane-modified cyclotriphosphazene halogen-free flame retardant has the structural formula as shown in Formula I. In the siloxane-modified cyclotriphosphazene halogen-free flame retardant of the present invention, three kinds of structures of siloxane, aryl phosphorus oxygen compound and cyclotriphosphazene are built in one molecular formula, which combines the advantages of three structures, improves the compatibility between the flame retardant and resins, has a high flame retardant efficiency and a better char formation and can greatly increase the flame retardancy and stability of resin cured products.
摘要翻译： 本发明提供了一种硅氧烷改性的环三磷腈无卤阻燃剂及其制备方法和用途。 硅氧烷改性的环三磷腈无卤阻燃剂具有如式I所示的结构式。本发明的硅氧烷改性的环三磷腈卤素阻燃剂中，硅氧烷，芳基磷氧化合物和环三磷腈三种结构为 结合了三种结构的优点，提高了阻燃剂与树脂的相容性，阻燃效率高，成炭好，可大大提高树脂固化产品的阻燃性和稳定性。
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