Abstract:
The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor based on molybdenum (Mo), in its monomeric or dimeric form, having at least one Mo═O or Mo—OR bond or at least one Mo═S or Mo—SR bond where [R═CxHy where x≧1 and (x−1)≦y≦(2x+1) or R═Si(OR′)3 or R═Si(R′)3 where R′═Cx′Hy′ where x′≧1 and (x′−1)≦y′≦(2x′+1)], and optionally from at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst being dried at a temperature of less than 200° C. then advantageously being sulphurized before being deployed in said process.
Abstract:
The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and silicon, said elements being incorporated into said matrix by means of at least two precursors of which at least one precursor contains molybdenum and at least one precursor contains silicon.
Abstract:
The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and aluminium, said elements being incorporated into said matrix by means of at least one precursor comprising molybdenum and aluminium.
Abstract:
The invention concerns a process for the preparation of a catalyst based on tungsten intended for hydrotreatment or hydrocracking processes.The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor compound based on tungsten (W), in its monomeric or dimeric form, having at least one W═O or W—OR bond or at least one W═S or W—SR bond where [R═CxHy where x≧1 and (x−1)≦y≦(2x+1) or R═Si(OR′)3 or R═Si(R′)3 where R′═Cx′Hy′ where x′≧1 and (x′−1)≦y′≦(2×t+1)], optionally at least one Mo precursor and optionally at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst advantageously being sulphurized before being deployed in said process.
Abstract:
The invention relates to a process of hydrodesulphuration of at least one gasoil cut implementing a catalyst containing, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, said polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size within the range 1.5 to 50 nm and having amorphous walls of thickness within the range 1 to 30 nm, the said catalyst being sulphured before being implemented in the said process.
Abstract:
A subject matter of the invention is a catalyst comprising a support and an active phase consisting of nickel, molybdenum and tungsten, and phosphorus, the nickel content, measured in the NiO form, is between 3% and 4% by weight; the molybdenum content, measured in the MoO3 form, is between 2% and 4% by weight; the tungsten content, measured in the WO3 form, is between 34% and 40% by weight; the phosphorus content, measured in the P2O5 form, is between 3% and 4% by weight, with respect to the total weight of the catalyst; the WO3/MoO3 molar ratio is between 5.3 and 12.4 mol/mol, the NiO/(WO3 + MoO3) molar ratio is between 0.20 and 0.33 mol/mol and the P2O5/(WO3 + MoO3) molar ratio is between 0.21 and 0.34 mol/mol. The invention also relates to its method of preparation and to its use in hydrotreating and/or hydrocracking.
Abstract:
The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and silicon, said elements being incorporated into said matrix by means of at least one precursor comprising molybdenum and silicon and having at least one sequence of Si—O—Mo bonds.
Abstract:
The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and aluminium, said elements being incorporated into said matrix by means of at least two precursors of which at least one precursor contains molybdenum and at least one precursor contains aluminium.