摘要:
A process for the synthesis of linear paraffinic hydrocarbons from a feed of carbon monoxide and dihydrogen in the presence of a catalyst of a mesoporous oxide matrix and a content by weight of the element cobalt of 0.5% to 60%, wherein the catalyst is prepared by a) mixing, in an aqueous or hydro-organic solvent, a molecular precursor containing cobalt and a molecular precursor of the mesoporous oxide matrix containing element X of silicon, aluminium, titanium, zirconium and or cerium; b) aerosol spray drying the mixture to form spherical liquid droplets; c) drying to obtain solid particles at a temperature of 10° C. to 300° C.; d) activation by a reduction treatment to form nanoparticles of cobalt with an oxidation state of 0.
摘要:
This invention has as its object a process for simultaneous dehydration and skeletal isomerization of a feedstock that comprises at least one C4 monoalcohol and that contains between 0.5 and 50% water, for the purpose of producing C4 alkenes, with said process operating at a temperature of between 250 and 550° C., under a pressure of between 0.1 and 1 MPa, with an hourly volumetric flow rate of between 0.1 and 10 h-1, characterized in that it uses a catalyst that comprises at least one mesostructured material that comprises silicon and at least one element X that is selected from among aluminum, boron, gallium, indium, and germanium.
摘要:
The invention relates to a process of hydrodesulphuration of at least one gasoil cut implementing a catalyst containing, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, said polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size within the range 1.5 to 50 nm and having amorphous walls of thickness within the range 1 to 30 nm, the said catalyst being sulphured before being implemented in the said process.
摘要:
The invention relates to a method for hydroprocessing a hydrocarbon feed, operated at a temperature of between 180° C. and 450° C., in the presence of a catalyst comprising i) a composite material comprising a compound based on at least one crystalline aluminium solid and carbon, the deposited carbon content being between 1 and 25 wt. % of the total mass of the composite material, and ii) at least one element of group VIB and at least one element of group VIII, in the sulfide form thereof, said catalyst being produced by a method comprising at least: a) a step of bringing a carbon precursor into contact with a compound based on at least one crystalline aluminium solid, b) a step of thermally treating the solid produced by step a), c) repeating steps a) and b) until the desired deposited carbon content is reached, d) depositing at least one element of group VIB and at least one element of group VIII on the surface of the solid produced by step c), and e) a step of sulfidisation of the solid produced in step d).
摘要:
A process for the synthesis of linear paraffinic hydrocarbons from a feed comprising carbon monoxide and dihydrogen in the presence of a mesoporous oxide matrix and cobalt prepared by mixing, at least one molecular precursor of cobalt and at least one colloidal precursor of mesoporous oxide matrix and by silicon, aluminium, titanium, zirconium, cerium or mixtures thereof, dissolved in aqueous or hydro-organic solvent; spray drying the mixture obtained to form spherical liquid droplets; drying the droplets to obtain solid particles activating the solid particles by reduction to form nanoparticles of cobalt with an oxidation state of 0.
摘要:
The invention relates to a catalyst that comprises a mesoporous oxide matrix, with said matrix comprising at least one oxide of an element X that is selected from among silicon and titanium, taken by itself or in a mixture, with said catalyst comprising at least the tantalum element and the niobium element, with the tantalum mass representing between 0.1 to 30% by weight of the mass of the mesoporous oxide matrix, the niobium mass representing between 0.02 to 6% by weight of the mass of the mesoporous oxide matrix, the content by mass of the tantalum element being greater than or equal to the content by mass of the niobium element. The invention also relates to the use of this catalyst in a method for the production of 1,3-butadiene from a feedstock that comprises at least ethanol.
摘要:
The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and silicon, said elements being incorporated into said matrix by means of at least two precursors of which at least one precursor contains molybdenum and at least one precursor contains silicon.
摘要:
The invention concerns a catalyst comprising at least the element tantalum, and at least one mesoporous oxide matrix that has undergone an acid wash comprising at least 90% by weight of silica before washing, the mass of the element tantalum being in the range 0.1% to 30% of the mass of said mesoporous oxide matrix.
摘要:
The invention relates to a catalyst that comprises at least the tantalum element, at least an aldolizing element and at least a mesoporous oxide matrix, with the tantalum mass being between 0.1 and 30% of the mesoporous oxide matrix mass, the mass of the at least one aldolizing element being between 0.02 and 4% of the mesoporous oxide matrix mass, and use thereof.
摘要:
The present invention relates to a process for obtaining a dialkyl phthalate and a reusable target PVC plastic from a PVC feedstock containing at least one phthalate, including:
a) a solid-liquid extraction of said PVC feedstock in the form of particles by placing said particles of the PVC feedstock in contact with a solvent including at least one alcohol CnH2n+1OH with n 8, to produce a liquid phase enriched in said phthalate and a solid phase including PVC plastic depleted in said phthalate; b) transformation of said phthalate of said liquid phase into dialkyl phthalate of formula C6H4(COOCnH2n+1)2 by transesterification using said alcohol; c) a solid-liquid separation between the solid phase and the liquid phase to produce at least one solid stream including the PVC plastic depleted in said phthalate so as to obtain said target PVC plastic; d) a liquid-liquid separation of the liquid phase, to produce at least a first liquid effluent including said dialkyl phthalate and a second liquid effluent comprising said solvent.