公开(公告)号：US08603937B2

公开(公告)日：2013-12-10

申请号：US13470867

申请日：2012-05-14

Applicant: Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

Inventor： Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

IPC: B01J23/00

CPC classification number: B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/50 ,  B01J23/688 ,  B01J27/138 ,  B01J35/002 ,  C07C29/106 ,  C07D301/10 ,  Y02P20/142 ,  C07C31/20

Abstract: A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.

公开(公告)号：US07741499B2

公开(公告)日：2010-06-22

申请号：US11746236

申请日：2007-05-09

Applicant: John Robert Lockemeyer

Inventor： John Robert Lockemeyer

IPC: C07D301/10

CPC classification number: B01J23/66 ,  B01J21/04 ,  B01J23/50 ,  B01J23/58 ,  B01J23/688 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1076 ,  B01J37/06 ,  C07D301/10

Abstract: There is provided a catalyst carrier comprising a refractory inorganic material having a sodium solubilization rate no greater than 5 ppmw/5 minutes. There is further a catalyst comprising a refractory inorganic material carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and one or more catalytically reactive metals deposited on said carrier. There is also provided a catalyst suitable for the vapor phase production of alkylene oxide from olefins and oxygen comprising an alumina-based carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and catalytically reactive silver deposited on said carrier.

Abstract translation: 提供了一种催化剂载体，其包含钠溶解速率不大于5ppmw / 5分钟的耐火无机材料。 还有一种催化剂，其包含钠溶解速率不大于5ppmw / 5分钟的耐火无机材料载体; 和沉积在所述载体上的一种或多种催化活性金属。 还提供了一种适用于从烯烃和氧气中气相生产环氧烷的催化剂，其包含钠增溶速率不大于5ppmw / 5分钟的氧化铝基载体; 和沉积在所述载体上的催化反应性银。

公开(公告)号：US07560411B2

公开(公告)日：2009-07-14

申请号：US11215267

申请日：2005-08-30

Applicant: Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

Inventor： Randall Clayton Yeates ,  John Robert Lockemeyer ,  Marek Matusz

IPC: B01J23/68

CPC classification number: C07C29/106 ,  B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/24 ,  B01J23/50 ,  B01J23/688 ,  B01J23/755 ,  B01J27/138 ,  B01J35/1042 ,  B01J37/26 ,  C07D301/10 ,  Y02P20/142 ,  C07C31/20

Abstract: A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.

Abstract translation: 提供了一种制备载体的方法，该方法包括在载体制备的任何阶段在载体中引入强度增强添加剂。 还提供了其中结合有强度增强添加剂的所得载体和包含载体的催化剂。 还提供了使用该催化剂对烯烃进行环氧化的方法。 还提供了使用如此制备的用于制备1,2-二醇，1,2-二醇醚或链烷醇胺的烯烃氧化物的方法。

公开(公告)号：US07232786B2

公开(公告)日：2007-06-19

申请号：US10936248

申请日：2004-09-08

Applicant: John Robert Lockemeyer

Inventor： John Robert Lockemeyer

IPC: B01J21/02 ,  B01J27/02 ,  B01J23/00 ,  B01J23/70 ,  B01J23/50

CPC classification number: B01J23/66 ,  B01J21/04 ,  B01J23/50 ,  B01J23/58 ,  B01J23/688 ,  B01J35/002 ,  B01J35/1009 ,  B01J35/1038 ,  B01J35/1076 ,  B01J37/06 ,  B01J37/30 ,  C07D301/10

Abstract: There is provided a catalyst carrier comprising a refractory inorganic material having a sodium solubilization rate no greater than 5 ppmw/5 minutes. There is further a catalyst comprising a refractory inorganic material carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and one or more catalytically reactive metals deposited on said carrier. There is also provided a catalyst suitable for the vapor phase production of alkylene oxide from olefins and oxygen comprising an alumina-based carrier having a sodium solubilization rate no greater than 5 ppmw/5 minutes; and catalytically reactive silver deposited on said carrier.

公开(公告)号：US5786293A

公开(公告)日：1998-07-28

申请号：US668039

申请日：1996-06-17

Applicant: John Robert Lockemeyer

Inventor： John Robert Lockemeyer

IPC: B01J27/19 ,  B01J23/85 ,  B01J29/08 ,  B01J37/20 ,  C10G45/08 ,  C10G49/02 ,  B01J27/02

CPC classification number: B01J37/20

Abstract: The present invention relates to a process for presulfiding hydrocarbon processing catalysts by impregnating the catalyst with an inorganic polysulfide solution such that at least a portion of said sulfide or sulfur is incorporated in the pores of said catalyst, and thereafter heating the sulfur-incorporated catalyst under non-oxidizing conditions to fix the incorporated sulfur onto the catalyst.

Abstract translation: 本发明涉及一种通过用无机多硫化物溶液浸渍催化剂来预硫化烃加工催化剂的方法，使得至少一部分所述硫化物或硫被加入到所述催化剂的孔中，然后加热下面的含硫催化剂 非氧化条件将引入的硫固定在催化剂上。

公开(公告)号：US08937031B2

公开(公告)日：2015-01-20

申请号：US13581641

申请日：2011-02-24

Applicant: John Robert Lockemeyer ,  Marek Matusz ,  Randall Clayton Yeates

Inventor： John Robert Lockemeyer ,  Marek Matusz ,  Randall Clayton Yeates

IPC: B01J21/00 ,  B01J23/00 ,  B01J25/00 ,  B01J29/00 ,  B01J31/00 ,  B01J27/047 ,  C07C213/04 ,  B01J27/051 ,  B01J27/188 ,  B01J27/19 ,  B01J35/10 ,  B01J37/02 ,  C07D301/10

CPC classification number: B01J27/051 ,  B01J27/047 ,  B01J27/188 ,  B01J27/19 ,  B01J35/108 ,  B01J35/1095 ,  B01J37/0201 ,  C07C213/04 ,  C07D301/10 ,  Y02P20/142 ,  C07C215/08

Abstract: A catalyst for the epoxidation of an olefin comprising a carrier and, deposited thereon, silver, a rhenium promoter, a first co-promoter, and a second co-promoter; wherein the quantity of the rhenium promoter deposited on the carrier is greater than 1 mmole/kg, relative to the weight of the catalyst; the first co-promoter is selected from sulfur, phosphorus, boron, and mixtures thereof; the second co-promoter is selected from tungsten, molybdenum, chromium, and mixtures thereof; the total quantity of the first co-promoter and the second co-promoter deposited on the carrier is at most 5.0 mmole/kg, relative to the weight of the catalyst; and wherein the carrier has a monomodal, bimodal or multimodal pore size distribution, a pore diameter of 0.01-200 μm, a specific surface area of 0.03-10 m2/g, a pore volume of 0.2-0.7 cm3/g, wherein the median pore diameter is 0.1-100 μm, and a water absorption of 10-80%.

Abstract translation: 一种用于环氧化包含载体并在其上沉积有银，铼助催化剂，第一共助催化剂和第二共助催化剂的烯烃的催化剂; 其中沉积在载体上的铼助催化剂的量相对于催化剂的重量大于1mmol / kg; 第一共助催化剂选自硫，磷，硼及其混合物; 第二共助催化剂选自钨，钼，铬及其混合物; 沉积在载体上的第一助催化剂和第二助催化剂的总量相对于催化剂的重量为至多5.0mmol / kg; 并且其中所述载体具有单峰，双峰或多峰孔径分布，孔径为0.01-200μm，比表面积为0.03-10m 2 / g，孔体积为0.2-0.7cm 3 / g，其中中值 孔径为0.1〜100μm，吸水率为10-80％。

公开(公告)号：US20090275764A1

公开(公告)日：2009-11-05

申请号：US12502850

申请日：2009-07-14

Applicant: Randall Clayton YEATES ,  John Robert Lockemeyer ,  Marek Matusz

Inventor： Randall Clayton YEATES ,  John Robert Lockemeyer ,  Marek Matusz

IPC: C07D301/03 ,  B01J23/10 ,  C07C41/02 ,  C07C29/10

CPC classification number: B01J21/04 ,  B01J23/02 ,  B01J23/10 ,  B01J23/50 ,  B01J23/688 ,  B01J27/138 ,  B01J35/002 ,  C07C29/106 ,  C07D301/10 ,  Y02P20/142 ,  C07C31/20

Abstract: A process is provided for preparing a carrier which process comprises incorporating into the carrier at any stage of the carrier preparation a strength-enhancing additive. Also provided is the resultant carrier having incorporated therein a strength-enhancing additive and a catalyst comprising the carrier. Also provided is a process for the epoxidation of an olefin employing the catalyst. Also provided is a method of using the olefin oxide so produced for making a 1,2-diol, a 1,2-diol ether or an alkanolamine.

Abstract translation: 提供了一种制备载体的方法，该方法包括在载体制备的任何阶段在载体中引入强度增强添加剂。 还提供了其中结合有强度增强添加剂的所得载体和包含载体的催化剂。 还提供了使用该催化剂对烯烃进行环氧化的方法。 还提供了使用如此制备的用于制备1,2-二醇，1,2-二醇醚或链烷醇胺的烯烃氧化物的方法。

公开(公告)号：US07538235B2

公开(公告)日：2009-05-26

申请号：US11096117

申请日：2005-03-31

Applicant: John Robert Lockemeyer

Inventor： John Robert Lockemeyer

IPC: C07D301/10 ,  C07D301/03 ,  C07D27/00 ,  C07D31/00

CPC classification number: B01J23/50 ,  B01J21/04 ,  B01J23/66 ,  B01J23/683 ,  B01J23/688 ,  B01J37/0203 ,  B01J37/0207 ,  C07C29/106 ,  C07C41/03 ,  C07C213/04 ,  C07D301/10 ,  Y02P20/52 ,  C07C31/202 ,  C07C43/13

Abstract: A process for preparing an epoxidation catalyst comprising silver and a high-selectivity dopant on a support, which process comprises depositing a base having a pKb of at most 3.5 when measured in water at 25° C., on the support prior to depositing silver on the support, and depositing silver and a high-selectivity dopant on the support; the epoxidation catalyst; and a process for preparing an olefin oxide by reacting an olefin with oxygen in the presence of the epoxidation catalyst.

Abstract translation: 一种在载体上制备包含银和高选择性掺杂剂的环氧化催化剂的方法，该方法包括在将银沉积在载体上之前，在25℃的水中测量时，沉积具有至多3.5的pKb的碱 载体和在载体上沉积银和高选择性掺杂剂; 环氧化催化剂; 以及在环氧化催化剂存在下使烯烃与氧反应制备烯烃氧化物的方法。

公开(公告)号：US20080154052A1

公开(公告)日：2008-06-26

申请号：US11613763

申请日：2006-12-20

Applicant: Jeroen Willem Bolk ,  Alouisius Nicolaas Renee Bos ,  Wayne Errol Evans ,  John Robert Lockemeyer ,  Paul Michael McAllister ,  Bernardus Franciscus Josef Marie Ramakers ,  Dominicus Maria Rekers ,  Mathias Jozef Paul Slapak

Inventor： Jeroen Willem Bolk ,  Alouisius Nicolaas Renee Bos ,  Wayne Errol Evans ,  John Robert Lockemeyer ,  Paul Michael McAllister ,  Bernardus Franciscus Josef Marie Ramakers ,  Dominicus Maria Rekers ,  Mathias Jozef Paul Slapak

IPC: C07D301/06 ,  C07D301/10

CPC classification number: C07D301/06 ,  C07D301/10

Abstract: The present invention relates to an improved epoxidation process and an improved epoxidation reactor. The present invention makes use of a reactor which comprises a plurality of microchannels. Such process microchannels may be adapted such that the epoxidation and optionally other processes can take place in the microchannels and that they are in a heat exchange relation with channels adapted to contain a heat exchange fluid. A reactor comprising such process microchannels is referred to as a “microchannel reactor”. The invention also provides a method of installing an epoxidation catalyst in a microchannel reactor. The invention also provides a method of preparing an epoxidation catalyst. The invention also provides an epoxidation catalyst. The invention also provides a certain process for the epoxidation of an olefin and a process for the preparation of a chemical derivable from an olefin oxide. The invention also provides a microchannel reactor.

Abstract translation: 本发明涉及改进的环氧化方法和改进的环氧化反应器。 本发明利用包括多个微通道的反应器。 这种工艺微通道可以适于使得环氧化和任选的其它方法可以在微通道中发生，并且它们与适于容纳热交换流体的通道处于热交换关系。 将包含这种工艺微通道的反应器称为“微通道反应器”。 本发明还提供了一种在微通道反应器中安装环氧化催化剂的方法。 本发明还提供了制备环氧化催化剂的方法。 本发明还提供一种环氧化催化剂。 本发明还提供了烯烃环氧化的一定方法以及制备可衍生自烯烃氧化物的化学品的方法。 本发明还提供一种微通道反应器。

公开(公告)号：US20080125610A1

公开(公告)日：2008-05-29

申请号：US11940968

申请日：2007-11-15

Applicant: John Robert Lockemeyer ,  Randall Clayton Yeates

Inventor： John Robert Lockemeyer ,  Randall Clayton Yeates

IPC: B01J23/50 ,  B01J32/00 ,  B01J27/02 ,  B01J27/14 ,  B01J27/24 ,  B01J27/25 ,  B01J21/02 ,  B01J27/06 ,  B01J23/02 ,  B01J23/28 ,  B01J23/34 ,  B01J23/10 ,  B01J23/14 ,  C07B41/00 ,  C07C29/15 ,  C07C41/01 ,  C07C213/08

CPC classification number: B01J23/688 ,  B01J23/50 ,  B01J32/00 ,  B01J37/06 ,  C07C29/00 ,  C07C41/02 ,  C07C213/00 ,  C07D301/04 ,  C07D301/10

Abstract: A process for treating a carrier, or a precursor thereof, to at least partly remove impurities comprising contacting the carrier, or the precursor thereof, with a treatment solution comprising a salt; a process for preparing a catalyst; the catalyst; a process for preparing an olefin oxide by reacting an olefin with oxygen in the presence of the catalyst; and a process for preparing a 1,2-diol, a 1,2-diol ether or an alkanolamine.

Abstract translation: 一种处理载体或其前体以至少部分除去杂质的方法，包括使载体或其前体与包含盐的处理溶液接触; 一种制备催化剂的方法; 催化剂; 一种在催化剂存在下使烯烃与氧反应制备烯烃氧化物的方法; 和1,2-二醇，1,2-二醇醚或链烷醇胺的制备方法。