公开(公告)号：US09481807B2

公开(公告)日：2016-11-01

申请号：US14653014

申请日：2013-12-12

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Jeffrey J. Sobczak ,  Diane M. Vaessen ,  Mark D. Westmeyer ,  William J. Fabiny

IPC: C09D133/12 ,  C08K3/00 ,  C08K5/00 ,  B05D3/02 ,  C08J3/02 ,  C08J3/03 ,  C08F2/22 ,  C08J3/12 ,  C08J3/16 ,  C08F265/06 ,  C04B26/06 ,  C08F2/00 ,  C08F220/18 ,  C09D151/00 ,  C04B103/00 ,  C04B111/00 ,  C04B111/10

CPC classification number: C09D133/12 ,  C04B26/06 ,  C04B2103/0057 ,  C04B2103/0058 ,  C04B2103/0065 ,  C04B2111/00482 ,  C04B2111/1037 ,  C08F2/001 ,  C08F2/22 ,  C08F220/18 ,  C08F265/06 ,  C08J3/02 ,  C08J3/03 ,  C08J3/12 ,  C08J3/126 ,  C08J3/16 ,  C08K3/014 ,  C08K5/005 ,  C08K5/0083 ,  C09D151/003 ,  C04B14/06 ,  C04B14/102 ,  C04B14/28 ,  C04B20/0048 ,  C04B20/0076 ,  C04B22/16 ,  C04B24/32 ,  C04B24/383 ,  C04B40/0608 ,  C04B2103/50 ,  C04B2103/54 ,  C08F220/40 ,  C08F2230/085 ,  C08F2222/1013 ,  C08F2220/283 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06 ,  C08F220/28

Abstract: The present invention provides a water redispersible polymer powder (RDP) for use in the preparation of non-cementitious exterior finishing compositions such as textured paint formulations. Also provided are non-cementitious exterior finishing compositions comprising such RDPs and a method of coating a surface with such a finishing composition. When the RDP of the invention is incorporated into an exterior finishing composition such as a topcoat formulation of an external insulation finishing system (EIFS), the resultant composition provides improved dirt pickup resistance without a loss in wet abrasion resistance over conventional textured paint formulations comprising acrylic latex powders and, preferably, acrylic latexes.

Abstract translation: 本发明提供了一种用于制备非水泥外墙饰面组合物例如纹理漆制剂的水可再分散聚合物粉末（RDP）。 还提供了包含这种RDP的非水泥外涂层组合物和用这种精整组合物涂覆表面的方法。 当本发明的RDP结合到诸如外部绝缘整理系统（EIFS）的面漆配方的外部整理组合物中时，所得组合物提供改进的耐污物拾取阻力，而不会比含有丙烯酸酯的常规织构涂料配方损失耐湿磨损性 胶乳粉末，优选丙烯酸胶乳。

公开(公告)号：US20230145320A1

公开(公告)日：2023-05-11

申请号：US17919797

申请日：2021-04-12

Applicant: Rohm and Haas Company

Inventor： Juan F. Callejas ,  Melinda L. Einsla ,  Jeffrey J. Sobczak ,  Mark D. Westmeyer

IPC: C09D133/04 ,  C09D7/80 ,  C09D7/65 ,  C09D7/61

CPC classification number: C09D133/04 ,  C09D7/80 ,  C09D7/65 ,  C09D7/61

Abstract: The present invention relates to a process for preparing a blend of comprising an aqueous dispersion of polymer particles, a PMHS, an opacifying pigment, and an extender. The blend of the present invention is useful in exterior paint applications, especially where retention of color in the painted substrate is important.

公开(公告)号：US20220154010A1

公开(公告)日：2022-05-19

申请号：US17440439

申请日：2020-03-16

Applicant: Rohm and Haas Company

Inventor： Mark D. Westmeyer ,  Charles J. Rand ,  C. Damien Rodowski ,  Jeffrey J. Sobczak

IPC: C09D5/02 ,  C09D133/04 ,  C09D7/63 ,  C09D7/61

Abstract: The present disclosure provides for a coating formulation that includes a pigment, an organic aqueous emulsion and an organophosphonic acid of the formula: where R is a saturated or unsaturated alkyl having 2 to 10 carbon atoms or a substituted or unsubstituted aryl having 5 to 10 carbon atoms. The coating formulation can be used in forming a topcoat in an exterior insulation and finish system (EIFS). The present disclosure also provides for a method of forming a topcoat on a surface of the EIFS that helps to protect the underlayment of the EIFS against both weathering and moisture while helping to maintain color retention.

公开(公告)号：US20150337158A1

公开(公告)日：2015-11-26

申请号：US14653014

申请日：2013-12-12

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： Jeffrey J. Sobczak ,  Diane M. Vaessen ,  Mark D. Westmeyer ,  William J. Fabiny

IPC: C09D133/12 ,  C08K5/00 ,  C08K3/00

CPC classification number: C09D133/12 ,  C04B26/06 ,  C04B2103/0057 ,  C04B2103/0058 ,  C04B2103/0065 ,  C04B2111/00482 ,  C04B2111/1037 ,  C08F2/001 ,  C08F2/22 ,  C08F220/18 ,  C08F265/06 ,  C08J3/02 ,  C08J3/03 ,  C08J3/12 ,  C08J3/126 ,  C08J3/16 ,  C08K3/014 ,  C08K5/005 ,  C08K5/0083 ,  C09D151/003 ,  C04B14/06 ,  C04B14/102 ,  C04B14/28 ,  C04B20/0048 ,  C04B20/0076 ,  C04B22/16 ,  C04B24/32 ,  C04B24/383 ,  C04B40/0608 ,  C04B2103/50 ,  C04B2103/54 ,  C08F220/40 ,  C08F2230/085 ,  C08F2222/1013 ,  C08F2220/283 ,  C08F2220/1825 ,  C08F220/14 ,  C08F220/06 ,  C08F220/28

Abstract: The present invention provides a water redispersible polymer powder (RDP) for use in the preparation of non-cementitious exterior finishing compositions such as textured paint formulations. Also provided are non-cementitious exterior finishing compositions comprising such RDPs and a method of coating a surface with such a finishing composition. When the RDP of the invention is incorporated into an exterior finishing composition such as a topcoat formulation of an external insulation finishing system (EIFS), the resultant composition provides improved dirt pickup resistance without a loss in wet abrasion resistance over conventional textured paint formulations comprising acrylic latex powders and, preferably, acrylic latexes.

Abstract translation: 本发明提供了一种用于制备非水泥外墙饰面组合物例如纹理漆制剂的水可再分散聚合物粉末（RDP）。 还提供了包含这种RDP的非水泥外涂层组合物和用这种精整组合物涂覆表面的方法。 当本发明的RDP结合到诸如外部绝缘整理系统（EIFS）的面漆配方的外部整理组合物中时，所得组合物提供改进的耐污物拾取阻力，而不会比包含丙烯酸酯的常规织构涂料配方减少耐湿磨损性 胶乳粉末，优选丙烯酸胶乳。

公开(公告)号：US09284444B2

公开(公告)日：2016-03-15

申请号：US14563030

申请日：2014-12-08

Applicant: Rohm and Haas Company

Inventor： Jeffrey J. Sobczak ,  Mark D. Westmeyer

IPC: C08L33/08 ,  C08F265/06 ,  C08F8/44 ,  C08L51/06 ,  B29B9/12 ,  C04B24/26 ,  B29K33/04 ,  B29L31/00

CPC classification number: C08L33/08 ,  B29B9/12 ,  B29K2033/04 ,  B29L2031/00 ,  C04B24/2641 ,  C04B40/0042 ,  C04B40/0608 ,  C04B2103/0057 ,  C08F8/44 ,  C08F265/06 ,  C08L51/06 ,  C08F2/22 ,  C08L33/04 ,  C04B24/2623 ,  C04B24/32 ,  C04B2103/0051 ,  C04B28/02 ,  C04B22/064

Abstract: The present invention provides dry mix compositions and dry compositions of calcium methacrylate salt containing multistage acrylic copolymer RDP and dry anionic associative thickeners for use in the dry mix compositions so that when wet to make cement, mortar or trowellable compositions for use in Exterior Insulation Finishing Systems (EIFS), the compositions exhibit improved workability in both cementitious and non-cementitious dry mixes.

Abstract translation: 本发明提供干混合物组合物和含有多级丙烯酸共聚物RDP和干阴离子缔合增稠剂的甲基丙烯酸钙盐的干组合物，用于干混合组合物中，使得当湿润以制备用于外部绝缘整理系统的水泥，砂浆或可洗脱组合物 （EIFS），该组合物在水泥质和非水泥质混合物中表现出改进的可加工性。

公开(公告)号：US20150159006A1

公开(公告)日：2015-06-11

申请号：US14563030

申请日：2014-12-08

Applicant: ROHM AND HAAS COMPANY

Inventor： Jeffrey J. Sobczak ,  Mark D. Westmeyer

IPC: C08L33/08 ,  B29B9/12 ,  C04B24/26

CPC classification number: C08L33/08 ,  B29B9/12 ,  B29K2033/04 ,  B29L2031/00 ,  C04B24/2641 ,  C04B40/0042 ,  C04B40/0608 ,  C04B2103/0057 ,  C08F8/44 ,  C08F265/06 ,  C08L51/06 ,  C08F2/22 ,  C08L33/04 ,  C04B24/2623 ,  C04B24/32 ,  C04B2103/0051 ,  C04B28/02 ,  C04B22/064

Abstract: The present invention provides dry mix compositions and dry compositions of calcium methacrylate salt containing multistage acrylic copolymer RDP and dry anionic associative thickeners for use in the dry mix compositions so that when wet to make cement, mortar or trowellable compositions for use in Exterior Insulation Finishing Systems (EIFS), the compositions exhibit improved workability in both cementitious and non-cementitious dry mixes.

Abstract translation: 本发明提供干混合物组合物和含有多级丙烯酸共聚物RDP和干阴离子缔合增稠剂的甲基丙烯酸钙盐的干组合物，用于干混合组合物中，使得当湿润以制备用于外部绝缘整理系统的水泥，砂浆或可洗脱组合物 （EIFS），该组合物在水泥质和非水泥质混合物中表现出改进的可加工性。

公开(公告)号：US09499690B2

公开(公告)日：2016-11-22

申请号：US14563055

申请日：2014-12-08

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Margarita Perello ,  Jeffrey J. Sobczak ,  Mark D. Westmeyer

IPC: C08L33/02 ,  C08L33/12 ,  C09D133/12 ,  B01J2/04 ,  C09D133/02 ,  C04B26/06 ,  C08J3/12 ,  C08K3/00 ,  C08K3/36 ,  C04B103/00 ,  C04B111/00 ,  C04B111/10

CPC classification number: C08L33/12 ,  B01J2/04 ,  C04B26/06 ,  C04B2103/0058 ,  C04B2103/0065 ,  C04B2111/00517 ,  C04B2111/1037 ,  C08J3/122 ,  C08J3/126 ,  C08J2333/12 ,  C08J2429/04 ,  C08K3/013 ,  C08K3/36 ,  C08L33/02 ,  C08L2207/53 ,  C08L2666/04 ,  C08L2666/58 ,  C08L2666/72 ,  C08L2666/74 ,  C09D133/02 ,  C09D133/12 ,  C04B14/06 ,  C04B22/064 ,  C04B24/023 ,  C04B24/2623 ,  C04B40/0608 ,  C04B2103/54 ,  C04B24/045 ,  C04B24/08 ,  C04B14/10 ,  C04B14/28 ,  C04B14/305 ,  C04B14/42 ,  C04B20/0076 ,  C04B24/383 ,  C04B2103/50

Abstract: The present invention provides shelf-stable, non-cementitious dry mix compositions of inorganic non-cementious materials, such as sand, and water redispersible polymer powder (RDP) containing particles of a multi-stage acrylic copolymer having a calcium methacrylate salt group containing alkali-soluble resin outer stage and one or more inner stage, the particles further containing each of one or more nucleating agent having a boiling point of 150° C. to 500° C. and a water solubility of 3.5% or less, and one or more colloidal stabilizer, wherein the colloidal stabilizer and the multi-stage acrylic copolymer are contained in the same RDP particle.

Abstract translation: 本发明提供了诸如砂的无机非水泥材料，含有含有含有甲基丙烯酸钙盐的碱的多级丙烯酸共聚物颗粒的水可再分散聚合物粉末（RDP）的搁置稳定的非水泥质干混组合物， 所述颗粒进一步含有一种或多种沸点为150℃至500℃，水溶解度为3.5％以下的成核剂，以及一种或多种其中一种或多种 更多的胶体稳定剂，其中胶体稳定剂和多级丙烯酸共聚物包含在相同的RDP颗粒中。

公开(公告)号：US20150159008A1

公开(公告)日：2015-06-11

申请号：US14563055

申请日：2014-12-08

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Margarita Perello ,  Jeffrey J. Sobczak ,  Mark D. Westmeyer

IPC: C08L33/12 ,  B01J2/04 ,  C09D133/12

CPC classification number: C08L33/12 ,  B01J2/04 ,  C04B26/06 ,  C04B2103/0058 ,  C04B2103/0065 ,  C04B2111/00517 ,  C04B2111/1037 ,  C08J3/122 ,  C08J3/126 ,  C08J2333/12 ,  C08J2429/04 ,  C08K3/013 ,  C08K3/36 ,  C08L33/02 ,  C08L2207/53 ,  C08L2666/04 ,  C08L2666/58 ,  C08L2666/72 ,  C08L2666/74 ,  C09D133/02 ,  C09D133/12 ,  C04B14/06 ,  C04B22/064 ,  C04B24/023 ,  C04B24/2623 ,  C04B40/0608 ,  C04B2103/54 ,  C04B24/045 ,  C04B24/08 ,  C04B14/10 ,  C04B14/28 ,  C04B14/305 ,  C04B14/42 ,  C04B20/0076 ,  C04B24/383 ,  C04B2103/50

Abstract: The present invention provides shelf-stable, non-cementitious dry mix compositions of inorganic non-cementious materials, such as sand, and water redispersible polymer powder (RDP) containing particles of a multi-stage acrylic copolymer having a calcium methacrylate salt group containing alkali-soluble resin outer stage and one or more inner stage, the particles further containing each of one or more nucleating agent having a boiling point of 150° C. to 500° C. and a water solubility of 3.5% or less, and one or more colloidal stabilizer, wherein the colloidal stabilizer and the multi-stage acrylic copolymer are contained in the same RDP particle.

Abstract translation: 本发明提供了诸如砂的无机非水泥材料，含有含有含有甲基丙烯酸钙盐的碱的多级丙烯酸共聚物颗粒的水可再分散聚合物粉末（RDP）的搁置稳定的非水泥质干混组合物， 所述颗粒进一步含有一种或多种沸点为150℃至500℃，水溶解度为3.5％以下的成核剂，以及一种或多种其中一种或多种 更多的胶体稳定剂，其中胶体稳定剂和多级丙烯酸共聚物包含在相同的RDP颗粒中。