摘要:
The present invention relates to a composition containing silico-organic nanohybrid and/or microhybrid capsules for scratch-resistant and/or abrasion-resistant coatings, wherein the silico-organic nanohybrid and/or microhybrid system includes one or more small metal oxide cores A and a substantially complete, silico-organic shell B, and the composition can be obtained by a reaction performed in situ, in a synthetic resin or in a synthetic-resin precursor compound, between metal oxide particles (KA-O) and at least one organofunctional silicon compound which contains an organofunctional group and at least one hydrolyzable group or at least one hydroxy group. The present invention also relates to the use of such compositions as the base for lacquers for producing a scratch-resistant and abrasion-resistant coating on a substrate as well as articles provided with corresponding scratch-resistant as well as abrasion-resistant coatings.
摘要:
Organosilicon nano/microhybrid systems or microhybrid systems having nanoscale and/or microscale oxide particles (KA—O), and an organosilicon shell with at least one organosilicon constituent of the general formula Ia wherein the organosilicon constituent of the shell B is attached to the oxide particles via one or more covalent linkages of formula Ib A process for preparing a composition comprising organosilicon nano/microhybrid systems or microhybrid systems directly in a synthetic resin composition allows in situ preparation of a curable resin. The compositions may be used as coating materials for producing scratch resistant and abrasion resistant coatings.
摘要:
A composition which retains a flash point of more than 21° C. even on storage and is obtainable by mixing and reacting (i) from 50 to 70% by weight of at least one alkyltrialkoxysilane, (ii) from 10 to 25% by weight of at least one alkoxysiloxane and/or at least one tetraalkoxysilane, (iii) from 15 to 25% by weight of at least one aqueous silica sol, (iv) from 0.1 to 5% by weight of at least one acid, and (v) from 0.1 to 60% by weight of at least one alcohol and/or glycol, the sum of the above components being not more than 100% by weight, by introducing components (i) and (ii) and also, if desired, a fraction of component (v) as an initial charge, adding component (iii), adjusting the mixture to a temperature in the range from −5 to 10° C., and subsequently adding component (iv), then allowing the mixture to continue reacting, thereafter distilling off hydrolysis alcohol under reduced pressure, and replacing it by adding component (v); which composition is useful for producing a coating on surfaces and also as a base material for paints; a process for preparing such a composition; and coatings and articles obtainable by applying such a composition.
摘要:
The present invention provides a composition based on the reaction at least of the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having an SiO2 content of >20% by weight, (iii) an organic acid hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, a process for its preparation, and the use thereof, particularly as a composition for scratch resistant coatings, and also provides articles thus coated.
摘要:
The present invention relates to an air-drying silane coating composition containing an epoxy or acrylic resin, an optional silicic ester or alkyl silicate, an aminoalkylsilane component, an optional organoalkyoxysilane, and possible auxiliaries; methods of use thereof, and articles and substrates coated accordingly.
摘要:
Organosilane-based composition for producing a barrier layer for gases, comprising (i) at least one organoalkoxysilane whose organofunctionality displays at least one unsaturated hydrocarbon group, (ii) at least one aminoalkylalkoxysilane, (iii) at least one polyol, (iv) optionally, another alkoxysilane or alkoxysiloxane, and (v) optionally, at least one nano- or microscale semimetal oxide or metal oxide, semimetal oxide hydroxide or metal oxide hydroxide, or sernimetal hydroxide or metal hydroxide, and/or (vi) at least one cocondensate composed of the components (i), (ii), (iii), and, optionally, (iv), and also, optionally, (v), and/or (vii) reaction products produced under hydrolysis conditions from the components (i), (ii), (iii), and, optionally, (iv), and also, optionally, (v) (viii) and organic solvent, with the proviso that there is a molar ratio (i):(ii):(iii) where (i)=1 and (ii)=from 0.5 to 1.5, and (iii)=from 0.3 to 1.1. The invention also relates to a process for producing, and the use of, the composition, and to packaging materials produced using the composition.
摘要:
The present invention provides a polymerizable organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle comprising at least one oxide or mixed oxide, KA-O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R (Ia) wherein R is a vinyl or allyl group; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA-O)—, SiO— or —Z; wherein remaining free valences of Si′ are each independently (KA-O)—, SiO—, —R, or —Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attached thereto.
摘要:
The present invention relates to mixtures of catenate and cyclic siloxane oligomers of the formulae I and II where the substituents R consist of (i) aminopropyl-functional groups of the formula —(CH2)3—NH2 or —(CH2)3—NHR′ or —(CH2)3—NH(CH2)2—NH2 or —(CH2)3—NH(CH2)2—NH(CH2)2—NH2,in which R′ is a linear, branched or cyclic alkyl group of 1 to 18 carbon atoms or an aryl group of 6 to 12 carbon atoms, and (ii) methoxy, ethoxy, 2-methoxyethoxy and/or propoxy groups, and (iii) if desired, alkyl, alkenyl, isoalkyl or cycloalkyl groups of 1 to 18 carbon atoms and/or aryl groups of 6 to 12 carbon atoms, and where not more than one aminopropyl-functional group is attached to one silicon atom and the degree of oligomerization of compounds of the formula I is within the range 2
摘要:
The residual halogen content in alkoxysilanes and in alkoxysilane-based compositions is reduced by a process comprising, treating the alkoxysilane or the alkoxysilane-based composition with activated carbon.
摘要:
A composite material, useful in producing wood-based materials, comprises (a) at least one cellulose- or lignocellulose-containing material and (b) at least one aminoalkylsilane, or at least one cocondensate of the at least one aminoalkylsilane and at least one further functional silane, or an aqueous solution which contains the at least one aminoalkylsilane or the at least one cocondensate of the at least one aminoalkylsilane and the at least one further functional silane.