公开(公告)号：US5952532A

公开(公告)日：1999-09-14

申请号：US904168

申请日：1997-07-31

申请人： Vincent A. Durante ,  Tilak P. Wijesekera ,  Swati Karmakar

发明人： Vincent A. Durante ,  Tilak P. Wijesekera ,  Swati Karmakar

IPC分类号： C07B41/02 ,  C07C37/58 ,  C07L37/00

CPC分类号： C07C37/58 ,  B01J21/063 ,  B01J23/20 ,  B01J23/22 ,  B01J23/50 ,  B01J23/70 ,  B01J23/8472 ,  B01J23/8926 ,  B01J29/064 ,  B01J29/072 ,  B01J29/076 ,  B01J29/89 ,  B01J37/0205 ,  B01J37/031 ,  C07B41/02 ,  Y02P20/52 ,  Y02P20/588

摘要： A process is disclosed for the catalytic hydroxylation of aromatic hydrocarbons which comprises contacting aromatic feedstock with oxidant comprising molecular oxygen, under suitable reaction conditions, in the presence of a catalyst comprising three essential components: a support; transition metal selected from the group consisting of vanadium, niobium, copper, palladium, nickel and silver, or combinations thereof, and a promoter comprising a multidentate chelating, binucleating ligand. The catalysts may further comprise additional metal ions. The process is particularly suited, for example, to the one-step conversion of benzene to phenol.

摘要翻译： 公开了用于芳烃的催化羟基化的方法，其包括在合适的反应条件下，在包含三种必需成分的催化剂的存在下使芳族原料与包含分子氧的氧化剂接触：载体; 选自钒，铌，铜，钯，镍和银的过渡金属或其组合，以及包含多齿螯合双核配体的启动子。 催化剂还可以包含另外的金属离子。 该方法特别适用于例如苯到苯的一步转化。

公开(公告)号：US5512529A

公开(公告)日：1996-04-30

申请号：US71250

申请日：1993-06-04

申请人： Klaus Deller ,  Bertrand Despeyroux ,  Erik Peldszus ,  Beate Kleinwaechter

发明人： Klaus Deller ,  Bertrand Despeyroux ,  Erik Peldszus ,  Beate Kleinwaechter

IPC分类号： B01J21/18 ,  B01J23/42 ,  B01J23/89 ,  C07B61/00 ,  C07C209/36 ,  C07C211/52 ,  B01J23/72

CPC分类号： B01J23/8926 ,  C07C209/365

摘要： A modified supported noble metal catalyst is disclosed for the selective hydrogenation of aromatic halonitro compounds to form aromatic haloamines. The support consists of active carbon. The active component is platinum modified with copper. The new catalyst is distinguished by good selectivity and a high yield.

摘要翻译： 公开了用于选择性氢化芳族卤代硝基化合物以形成芳族卤代胺的改性负载型贵金属催化剂。 载体由活性炭组成。 活性组分是用铜改性的铂。 新催化剂的选择性好，产率高。

公开(公告)号：US5334782A

公开(公告)日：1994-08-02

申请号：US960423

申请日：1992-12-23

申请人： Shinsuke Morikawa ,  Masaru Yoshitake ,  Shin Tatematsu

发明人： Shinsuke Morikawa ,  Masaru Yoshitake ,  Shin Tatematsu

IPC分类号： B01J23/48 ,  B01J23/89 ,  C07C17/00 ,  C07C17/24 ,  C07C19/02 ,  C07C19/04

CPC分类号： C07C17/23 ,  B01J23/48 ,  B01J23/8926

摘要： The present invention relates to a method for producing a hydrogen-containing chloromethane such as chloroform at high selectivity in good yield by reducing a polychloromethane such as carbon tetrachloride in the presence of a reduction catalyst.In the present invention, it is important to conduct the reduction reaction in a liquid phase, whereby formation of impurities such as polymers which deactivate the catalyst, can effectively be suppressed, and the high selectivity and high activity of the reduction catalyst can adequately be obtained.As the reduction catalyst, at least one member selected from elements of Groups 8, 9 and 10, such as ruthenium, rhodium, palladium and platinum, may suitably be employed. Also a catalyst comprising, as the main component, such an element and having at least one member of Group 11 elements such as copper, silver and gold added thereto, may also suitably be employed.In a case where the liquid phase reduction reaction is conducted continuously, it is preferred to adopt a fixed bed system, particularly a trickle bed system.The method of the present invention is valuable also as a method for converting carbon tetrachloride which is regulated from the standpoint of global environmental protection, to chloroform which is useful as raw material for various fluorine-containing compounds.

摘要翻译： PCT No.PCT / JP92 / 00522 Sec。 371日期1992年12月23日 102（e）日期1992年12月23日PCT 1991年4月23日提交PCT公布。 第WO92 / 18447号公报 本发明涉及通过在还原催化剂的存在下还原多氯甲烷如四氯化碳，以高选择性以高产率生产含氢氯甲烷如氯仿的方法。 在本发明中，重要的是在液相中进行还原反应，从而可以有效地抑制催化剂失活的诸如聚合物等杂质的形成，能够充分获得还原催化剂的高选择性和高活性 。 作为还原催化剂，可以适当选择选自元素8,9和10中的至少一种，例如钌，铑，钯和铂。 还可以适当地使用包含作为主要成分的这种元素并且具有添加到其中的至少一种第11族元素​​如铜，银和金的元素的催化剂。 在连续进行液相还原反应的情况下，优选采用固定床系统，特别是滴流床系统。 本发明的方法作为从全球环境保护的角度将四氯化碳转化为可用作各种含氟化合物的原料的氯仿的方法也是有价值的。

公开(公告)号：US5302622A

公开(公告)日：1994-04-12

申请号：US57604

申请日：1993-05-05

申请人： Patrick Chaumette ,  Catherine Verdon ,  Daniel Cruypelinck

发明人： Patrick Chaumette ,  Catherine Verdon ,  Daniel Cruypelinck

IPC分类号： B01J23/89 ,  B01J37/03 ,  C07C1/04 ,  C10G2/00 ,  C07C27/00 ,  C07C1/00

CPC分类号： C10G2/333 ,  B01J23/8926 ,  B01J37/036 ,  C07C1/0445 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/06 ,  C07C2523/14 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/75 ,  C07C2523/89

摘要： The invention relates to a process for the conversion of synthesis gases into a mixture of essentially linear and saturated hydrocarbons, characterized by the use of a catalyst prepared by a gelling procedure, incorporating cobalt, copper and ruthenium, the cobalt, copper and ruthenium being dispersed on a support having at least one oxide of a metal chosen from within the group formed by silica and alumina, the cobalt content, expressed by cobalt weight based on the catalyst weight, being between 1 and 60% by weight, the ruthenium content, expressed by ruthenium weight based on the cobalt weight, being between 0.1 and 20%, and the copper weight, expressed by copper weight based on the cobalt weight, being between 0.1 and 10%.

摘要翻译： 本发明涉及将合成气转化为基本上线性和饱和烃的混合物的方法，其特征在于使用通过凝胶化方法制备的催化剂，其结合钴，铜和钌，分散的钴，铜和钌 在具有选自由二氧化硅和氧化铝形成的组中的至少一种金属氧化物的载体上，基于催化剂重量由钴重量表示的钴含量在1至60重量％之间，钌含量表示为 基于钴重量的钌重量为0.1％至20％，铜重量（以铜重量计，基于钴重量计）为0.1-10％。

公开(公告)号：US5292916A

公开(公告)日：1994-03-08

申请号：US859294

申请日：1992-05-22

申请人： Tokuo Matsuzaki ,  Tuneo Shimamura ,  Satoru Fujitsu ,  Yoshinobu Toriyahara

发明人： Tokuo Matsuzaki ,  Tuneo Shimamura ,  Satoru Fujitsu ,  Yoshinobu Toriyahara

IPC分类号： B01J21/18 ,  B01J23/89 ,  C07C68/00 ,  C07C69/96

CPC分类号： B01J23/8993 ,  B01J23/8926 ,  C07C68/00 ,  B01J21/18

摘要： A carbonic acid diester is stably and safely produced at a high selectivity and at a high yield by catalytically reacting carbon monoxide with a nitrous acid ester in a gas phase in the presence of a solid catalyst comprising a catalytic solid material carried on a solid carrier and comprising:(a) a platinum group metal and/or a compound thereof,(b) a compound of Fe, Cu, Bi, Co, Ni and/or Sn, and(c) a vanadium compound, molybdenum compound, tungsten compound, sulfuric acid and/or phosphoric acid.

摘要翻译： PCT No.PCT / JP91 / 01313 Sec。 371日期：1992年5月22日 102（e）日期1992年5月22日PCT 1991年9月30日PCT PCT。 出版物WO92 / 06066 日期：1992年4月16日。在包含催化剂固体的固体催化剂存在下，通过在气相中将一氧化碳与亚硝酸酯催化反应，以高选择性和高产率稳定和安全地生产碳酸二酯 载体在固体载体上的材料，包括：（a）铂族金属和/或其化合物，（b）Fe，Cu，Bi，Co，Ni和/或Sn的化合物，和（c）钒化合物 ，钼化合物，钨化合物，硫酸和/或磷酸。

公开(公告)号：US5182088A

公开(公告)日：1993-01-26

申请号：US579316

申请日：1990-09-07

申请人： Paul Leondaridis ,  Albert S. Vendel ,  Tarranum Akthar

发明人： Paul Leondaridis ,  Albert S. Vendel ,  Tarranum Akthar

IPC分类号： B01D53/86 ,  B01J23/80 ,  B01J23/86 ,  B01J23/88 ,  B01J23/89

CPC分类号： B01J23/8926 ,  B01D53/8671 ,  B01J23/80

摘要： A metallic oxide catalyst, containing cupric oxide and an amount of one or more of AgO, HgO or CdO effective for enhancing the ability of the catalyst for removing gaseous hydrides from a gas stream.

公开(公告)号：US4970128A

公开(公告)日：1990-11-13

申请号：US399125

申请日：1989-08-28

申请人： Takashi Itoh ,  Katsuaki Kato

发明人： Takashi Itoh ,  Katsuaki Kato

IPC分类号： B01J23/89 ,  C22C1/00 ,  C22C5/04 ,  H01M4/86 ,  H01M4/88 ,  H01M4/90 ,  H01M4/92 ,  H01M4/96

CPC分类号： H01M4/926 ,  B01J23/8926 ,  H01M4/92 ,  H01M4/96 ,  H01M2004/8689 ,  H01M2300/0005 ,  H01M2300/0008 ,  H01M2300/0011

摘要： A supported platinum alloy electrocatalyst for an acid electrolyte fuel cell, said electrocatalyst consisting essentially of an electrically conductive powdery carbon carrier and dispersed in, and deposited on, the carrier, an ordered platinum-iron-copper ternary alloy comprising 40 to 60 atomic percent of platinum, 13 to 40 atomic percent of iron and 13 to 40 atomic percent of copper. The electrocatalyst has much better initial activity and lifetime than conventional platinum alone or multi-components alloy electrocatalysts. A process for producing the supported platinum alloy electrocatalyst which comprises depositing copper on a previously formed platinum-iron supported binary ordered alloy, again subjecting the product to an alloying treatment, or depositing iron on the platinum-copper supported binary alloy and then again subjecting the product to an alloying treatment. An electrode for an acid electrolyte fuel cell having an excellent output performance and a long operating life is also provided which comprises the above supported platinum alloy electrocatalyst and a water-repellent binder which are bonded to an electrically conductive and acid-resistant supporting member.

公开(公告)号：US4797382A

公开(公告)日：1989-01-10

申请号：US126065

申请日：1987-11-27

申请人： Waldo De Thomas ,  Paul D. Taylor

发明人： Waldo De Thomas ,  Paul D. Taylor

IPC分类号： B01J23/89 ,  C07C27/00 ,  C07C29/10 ,  C07C29/145 ,  C07C29/149 ,  C07C31/20 ,  C07C67/00 ,  B01J23/58 ,  B01J23/64 ,  B01J23/72

CPC分类号： C07C29/149 ,  B01J23/8926 ,  B01J23/8946

摘要： The invention relates to a novel supported catalyst comprising (a) copper, (b) a metal having an atomic weight greater than 100 and selected from Groups VIIB and VIII of the Periodic Table and (c) an alkali metal in a weight ratio of about 8-40:0.05-5:1.5-10 and to the use of the catalyst in the hydrogenation of butyrolactone to 1,4-butanediol.

公开(公告)号：US4492770A

公开(公告)日：1985-01-08

申请号：US330007

申请日：1981-12-11

申请人： Gilbert Blanchard ,  Jean-Pierre Brunelle ,  Michel Prigent

发明人： Gilbert Blanchard ,  Jean-Pierre Brunelle ,  Michel Prigent

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J23/89 ,  B01J37/02 ,  B01J23/10 ,  B01J23/42 ,  B01J23/44 ,  B01J23/72

CPC分类号： B01D53/945 ,  B01J23/8926 ,  B01J23/894 ,  B01J37/024 ,  Y02T10/22

摘要： Provided is an improved catalyst and a process employing same in the treatment of exhaust gases generated by internal combustion engines. The catalyst comprises a support and an active phase comprising copper, cerium and/or iron, at least one metal selected from the group consisting of platinum and palladium, and at least one metal selected from the group consisting of iridium and rhodium. The catalyst is particularly active in the removal of carbon monoxide, unburned hydrocarbons and nitrogen oxides generally present in the exhaust gases of an internal combustion engine.

摘要翻译： 提供了一种改进的催化剂及其在处理由内燃机产生的废气中使用的催化剂和方法。 催化剂包括载体和包含铜，铈和/或铁的活性相，选自铂和钯的至少一种金属和选自铱和铑的至少一种金属。 催化剂在通常存在于内燃机的排气中的一氧化碳，未燃烧的烃和氮氧化物的除去方面特别有活性。

公开(公告)号：US4483998A

公开(公告)日：1984-11-20

申请号：US484058

申请日：1983-04-11

申请人： John R. Sanderson ,  Edward T. Marquis ,  Jiang-Jen Lin

发明人： John R. Sanderson ,  Edward T. Marquis ,  Jiang-Jen Lin

IPC分类号： B01J23/89 ,  C07C51/235 ,  C07D301/06 ,  C07D303/04

CPC分类号： B01J23/8926 ,  C07C51/235 ,  C07D301/06 ,  C07D303/04

摘要： A process for simultaneously producing an epoxide and a carboxylic acid from an olefin and an aldehyde, respectively, by co-oxidation over a catalyst in the presence of oxygen is described. The catalyst is made by precipitating silver oxide in the presence of copper(II) oxide, copper(II) borate or a mixture thereof. These novel heterogeneous catalysts provide higher selectivities to the epoxide than those obtainable with commercial catalysts.

摘要翻译： 描述了通过在氧气存在下通过催化剂共氧化同时由烯烃和醛生成环氧化物和羧酸的方法。 催化剂通过在氧化铜（II），硼酸铜（II）或其混合物的存在下沉淀氧化银来制备。 这些新型的非均相催化剂提供了比用商业催化剂获得的更高的选择性。