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91.发明公开公开(公告)号：US20240307861A1
公开(公告)日：2024-09-19
申请号：US18601509
申请日：2024-03-11
申请人： TIANJIN UNIVERSITY
发明人： Jinlong GONG , Wei Wang , Sai Chen , Chunlei Pei , Zhijian Zhao
IPC分类号： B01J37/02 , B01J21/04 , B01J21/06 , B01J21/08 , B01J23/06 , B01J23/08 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/847 , B01J29/076 , B01J37/00 , B01J37/08 , C07C5/32
CPC分类号： B01J37/024 , B01J21/04 , B01J21/063 , B01J21/08 , B01J23/06 , B01J23/08 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/8472 , B01J29/076 , B01J37/009 , B01J37/0236 , B01J37/088 , C07C5/324 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/06 , C07C2523/08 , C07C2523/22 , C07C2523/26 , C07C2523/34 , C07C2523/745 , C07C2523/847 , C07C2529/076
摘要： The present disclosure discloses a supported polymetallic oxide tandem catalyst, preparation method and application thereof, a surface of the support is supported with an oxide of metal A and then with metal vanadate nano-particles; and the oxide of metal A serves as a direct dehydrogenation catalytic site, and the metal vanadate nano-particles serve as a selective hydrogen combustion site. In the application of the tandem catalyst, dehydrogenation site and selective hydrogen combustion site are coupled at the nano-scale, and this coupling mechanism shifts the reaction equilibrium to the alkenes through the selective combustion of byproduct hydrogen, which effectively surpasses the thermodynamic limit; and meanwhile, the combustion of hydrogen releases chemical energy, and provides heat energy through direct heating, enabling the self-heating operation of the reaction. The present disclosure has the outstanding advantages of high single-pass conversion rate of light alkanes and high selectivity towards target product alkenes.
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公开(公告)号：US20240131503A1
公开(公告)日：2024-04-25
申请号：US18547178
申请日：2021-09-22
发明人： Metta CHAREONPANICH , Waleeporn DONPHAI , Pariyawalee SANGTEANTONG , Yutthana WONGNONGWA , Siriporn JUNGSUTTIWONG , Sitthiphong PENGPANICH , Kaew-arpha THAVORNPRASERT
CPC分类号： B01J37/0244 , B01J23/08 , B01J23/62 , B01J29/44 , B01J37/0236 , B01J37/08 , B01J37/346 , C07C5/417 , B01J2229/20 , C07C2523/62
摘要： The present invention relates to a catalyst for aromatization of alkanes having 4 to 7 carbon atoms, especially alkanes having carbon atoms. Said catalyst has the efficacy in the aromatics production with high conversion and high selectivity of aromatics or high yield of aromatics, wherein said catalyst comprises zeolite, at least 1 transition metal from group VIII transition metal in a range of 0.1 to 2% by weight based on the total weight of the catalyst, and at least 1 metal from group IIIA metal in a range of 0.1 to 5% by weight based on the total weight of the catalyst. Said catalyst is treated and dried with a microwave at a power in a range from 400 to 1,000 watts after step of contacting with a solution comprising at least 1 transition metal salt from group VIII transition metal and after step of contacting with a solution comprising at least 1 group IIIA metal salt. Moreover, this invention also relates to a process for preparing said catalyst and a process of aromatics preparation using said catalyst.
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公开(公告)号：US11845063B2
公开(公告)日：2023-12-19
申请号：US17805914
申请日：2022-06-08
发明人： Qinghe Zheng , Jing Lu , Michael Howard
IPC分类号： B01J21/04 , B01J21/06 , B01J23/02 , B01J23/04 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/12 , B01J23/16 , B01J23/42 , B01J23/46 , B01J23/63 , B01J23/72 , B01J23/74 , B01J23/76 , B01J23/78 , B01J23/80 , B01J23/83 , B01J23/84 , B01J23/89 , B01J37/02 , B01J37/22 , B01J37/08 , B01J35/00 , B01J35/04 , F01N3/10 , F01N3/28
CPC分类号： B01J23/42 , B01J21/04 , B01J23/10 , B01J23/464 , F01N3/101 , F01N2570/10 , F01N2570/12 , F01N2570/14
摘要： A method of manufacturing a catalyst article, the method comprising: providing a complex of a polyphenol and a PGM, the PGM comprising rhodium and/or platinum, the polyphenol comprising an ester functional group; providing a support material; applying the complex to the support material to form a loaded support material; disposing the loaded support material on a substrate; and heating the loaded support material to form nanoparticles of the PGM on the support material.
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94.发明授权公开(公告)号：US11642657B2
公开(公告)日：2023-05-09
申请号：US17942824
申请日：2022-09-12
发明人： Carlos Rene Klotz Rabello , Alexandre Gaspar De Barros , Luciano Honorato Chagas , Lucia Gorenstin Appel , Priscila Da Costa Zonetti , Michelly Távora Rodrigues
CPC分类号： B01J23/08 , B01J21/066 , B01J21/08 , B01J23/06 , B01J37/024 , B01J37/0205 , B01J37/0236 , B01J37/088 , C07C1/22 , C07C2521/06 , C07C2521/08 , C07C2523/06 , C07C2523/08
摘要： The present invention relates to a process for the production of butadiene by condensation of ethanol using a catalyst containing sillica-supported elements from group 3A and group 4B of the periodic table. The catalyst of the present invention has high activity and selectivity to butadiene in the synthesis reaction of said olefin from ethanol.
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公开(公告)号：US20230133426A1
公开(公告)日：2023-05-04
申请号：US17884424
申请日：2022-08-09
申请人： UOP LLC
摘要： A fluidized catalytic reactor decouples the catalyst regenerator temperature from the catalyst reactor residence time. Regenerated catalyst is cooled before it contacts reactant feed. The regenerated catalyst may be cooled by heat exchange with oxygen supply gas, spent catalyst or other materials. The process and apparatus are especially useful for fluidized endothermic catalytic reactions.
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公开(公告)号：US20220305483A1
公开(公告)日：2022-09-29
申请号：US17705175
申请日：2022-03-25
发明人： Jude Kelley , Eric Morgan , Roderick Russell Kunz
摘要： Methods, systems, and compositions related to the recycling and/or recovery of activating materials from activated aluminum are disclosed. In one embodiment, an aqueous solution's composition may be controlled to maintain aluminum ions dissolved in solution during reaction of an activated aluminum. In another embodiment, aluminum hydroxide containing the activating materials may be dissolved into an aqueous solution to isolate the activating materials.
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97.发明授权公开(公告)号：US11420911B2
公开(公告)日：2022-08-23
申请号：US16963030
申请日：2019-01-28
发明人： Xiulian Pan , Feng Jiao , Xinhe Bao , Yuxiang Chen
IPC分类号： C07C1/04 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/18 , B01J23/26 , B01J23/34 , B01J23/745 , B01J23/75 , B01J29/18 , B01J29/24 , B01J29/26 , B01J35/10
摘要： A catalyst containing LF-type B acid preparing ethylene using direct conversion of syngas is a composite catalyst and formed by compounding component A and component B in a mechanical mixing mode. The active ingredient of the component A is a metal oxide; the component B is a zeolite of MOR topology; and a weight ratio of the active ingredients in the component A to the component B is 0.1-20. The reaction process has an extremely high product yield and selectivity, with the selectivity for light olefin reaching 80-90%, wherein ethylene has high space time yield and can reach selectivity of 75-80%. Meanwhile, the selectivity for a methane side product is extremely low (
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98.发明申请公开(公告)号：US20220088574A1
公开(公告)日：2022-03-24
申请号：US17417955
申请日：2019-12-16
发明人： Alexey Kirilin , Adam Chojecki , Glenn Pollefeyt , Davy L.S. Nieskens , Kyle C. Andrews , Vera P. Santos Castro , Joseph F. DeWilde , David F. Yancey , Andrzej Malek
摘要： A method for preparing C2 to C5 paraffins includes introducing a feed stream including hydrogen gas and a carbon-containing gas selected from carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor. Converting the feed stream into a product stream including C2 to C5 paraffins in the presence of a hybrid catalyst. The hybrid catalyst includes a microporous catalyst component; and a metal oxide catalyst component selected from (A) a bulk material consisting of gallium oxide, (B) gallium oxide present on a titanium dioxide support material, and (C) a mixture of gallium oxide and at least one promoter present on a support material selected from Group 4 of the IUPAC periodic table of elements.
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99.发明申请公开(公告)号：US20220080392A1
公开(公告)日：2022-03-17
申请号：US17417846
申请日：2019-12-16
发明人： Adam Chojecki , Alexey Kirilin , Andrzej Malek , Joseph F. DeWilde , Vera P. Santos Castro , David F. Yancey , Kyle C. Andrews
IPC分类号： B01J23/08 , B01J23/00 , B01J29/85 , B01J37/04 , B01J37/02 , B01J35/00 , B01J35/10 , C07C1/04
摘要： A process for preparing C2 to C4 olefins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor. The feed stream is converted into a product stream including C2 to C4 olefins in the reaction zone in the presence of the hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component comprising gallium oxide and phase pure zirconia, and a microporous catalyst component.
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100.发明申请公开(公告)号：US20210402377A1
公开(公告)日：2021-12-30
申请号：US17035144
申请日：2020-09-28
申请人： Hyundai Motor Company , Kia Motors Corporation , Research & Business Foundation Sungkyunkwan University
发明人： Chae Hwan Hong , Jin Woo Choung , Jong Wook Bae , Tae Yeol Goag
摘要： Disclosed are a catalyst used for converting carbon dioxide to methanol by hydrogenation and a method preparing the sane. The caratlys may include: a mesoporous indium oxide; and a catalyst supported on the mesoporous indium oxide. Preferably, a porous structure of the mesoporous indium oxide may have Ia3d symmetry and may include mesopores and micropores interconnecting the mesopores.
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