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公开(公告)号：US11369951B2
公开(公告)日：2022-06-28
申请号：US16963181
申请日：2019-01-28
Inventor： Xiulian Pan , Feng Jiao , Xinhe Bao , Na Li
IPC: B01J35/00 , B01J21/04 , B01J21/06 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/18 , B01J23/26 , B01J23/34 , B01J23/745 , B01J23/75 , B01J29/70 , B01J29/76 , B01J29/83 , B01J29/84 , B01J29/85 , B01J29/87 , B01J35/10 , C07C1/04
Abstract: A catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A weight ratio of the active ingredients in the component I to the component II is 0.1-20. The reaction process has high product yield and selectivity, wherein the sum of the selectivity of the propylene and butylene reaches 40-75%; and the sum of the selectivity of light olefin comprising ethylene, propylene and butylene can reach 50-90%. Meanwhile, the selectivity of a methane side product is less than 15%.
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2.发明授权公开(公告)号：US10532961B2
公开(公告)日：2020-01-14
申请号：US15740653
申请日：2015-10-16
Inventor： Xiulian Pan , Jinjing Li , Feng Jiao , Xinhe Bao
Abstract: The present invention discloses catalyst and method for producing light olefins directly from synthesis gas by a one-step process, and particularly relates to method and catalyst for directly converting synthesis gas into light olefins by a one-step process. The provided catalysts are composite materials formed of multicomponent metal oxide composites and inorganic solid acids with hierarchical pore structures. The inorganic solid acids have a hierarchical pore structure having micropores, mesopores and macropores. The metal composites can be mixed with or dispersed on surfaces or in pore channels of the inorganic solid acid and can catalyze the synthesis gas conversion to a C2-C4 light hydrocarbon product containing two to four carbon atoms. The single pass conversion of CO is 10%-60%. The selectivity of light hydrocarbon in all hydrocarbon products can be up to 60%-95%, wherein the selectivity of light olefins (C2═—C4═) is 50%-85%.
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公开(公告)号：US11420911B2
公开(公告)日：2022-08-23
申请号：US16963030
申请日：2019-01-28
Inventor： Xiulian Pan , Feng Jiao , Xinhe Bao , Yuxiang Chen
IPC: C07C1/04 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/18 , B01J23/26 , B01J23/34 , B01J23/745 , B01J23/75 , B01J29/18 , B01J29/24 , B01J29/26 , B01J35/10
Abstract: A catalyst containing LF-type B acid preparing ethylene using direct conversion of syngas is a composite catalyst and formed by compounding component A and component B in a mechanical mixing mode. The active ingredient of the component A is a metal oxide; the component B is a zeolite of MOR topology; and a weight ratio of the active ingredients in the component A to the component B is 0.1-20. The reaction process has an extremely high product yield and selectivity, with the selectivity for light olefin reaching 80-90%, wherein ethylene has high space time yield and can reach selectivity of 75-80%. Meanwhile, the selectivity for a methane side product is extremely low (
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公开(公告)号：US11365165B2
公开(公告)日：2022-06-21
申请号：US16963070
申请日：2019-01-28
Inventor： Xiulian Pan , Feng Jiao , Xinhe Bao
IPC: B01J29/06 , C07C1/04 , B01J29/24 , B01J29/26 , B01J35/10 , B01J23/26 , B01J23/16 , B01J23/75 , B01J23/22 , B01J23/34 , B01J23/745 , B01J29/18 , B01J29/22 , B01J37/08 , C07C11/04 , C07C11/06
Abstract: An organic base modified composite catalyst for producing ethylene by hydrogenation of carbon monoxide is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of the component I is a metal oxide; the component II is an organic base modified zeolite of MOR topology; and a weight ratio of the active ingredients in the component I to the component II is 0.1-20, and preferably 0.3-8. The reaction process has an extremely high product yield and selectivity. The selectivity of C2-C3 olefins is as high as 78-87%; the selectivity of hydrocarbon products with more than 4 C atoms is less than 10%; the selectivity of a methane side product is extremely low (
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公开(公告)号：US10661239B2
公开(公告)日：2020-05-26
申请号：US16300188
申请日：2017-03-22
Inventor： Xinhe Bao , Xiaoguang Guo , Guangzong Fang , Xiulian Pan , Jingheng Meng , Qinqin Yu , Dali Tan
IPC: B01J7/00 , C07C2/84 , B01J15/00 , B01J12/00 , B01J10/00 , B01J19/00 , B01J19/02 , B01J19/24 , C07C2/76 , C23C16/40
Abstract: A reactor configuration comprises an inlet section I, a preheating section II, a transition section III, a reaction section IV and an outlet section V; except for the preheating section II and the reaction section IV, the existence of the inlet section I, the transition section III and the outlet section V depends on reaction conditions; and the process realizes no coke deposition synthesis of methane and high selectivity synthesis of ethylene. The methane conversion rate is 20-90%; ethylene selectivity is 65-95%; propylene and butylene selectivity is 5-25%; aromatic hydrocarbon selectivity is 0-30%; and coke deposition is zero.
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Patent Agency Ranking
公开(公告)号：US11999910B2
公开(公告)日：2024-06-04
申请号：US17287084
申请日：2019-12-10
Inventor： Feng Jiao , Na Li , Xiulian Pan , Xinhe Bao
CPC classification number: C10G2/334 , B01J29/703 , B01J29/7042 , B01J29/7046 , B01J29/7261 , B01J29/7284 , B01J29/7292 , B01J29/7661 , B01J29/7684 , B01J29/7692 , B01J29/7861 , B01J29/7884 , B01J29/7892 , B01J35/612 , B01J35/613 , B01J35/615 , B01J37/0018 , B01J2229/18 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/30
Abstract: A method for preparing liquid fuel by direct conversion of syngas uses the syngas as reaction raw material and conducts a catalytic conversion reaction on a fixed bed or a moving bed. The catalyst is a composite catalyst formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of the component I is a metal oxide, and the component II is at least one of zeolites with one-dimensional ten-membered ring porous channels; and a weight ratio of the active ingredient in the component I to that in the component II is 0.1-20. The reaction process has high product yield and selectivity. The selectivity for liquid fuel composed of C5-C11 can reach 50-80%. The selectivity for aromatic hydrocarbon is less than 40% in C5-C11, while the selectivity for methane side product is less than 15%.
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7.发明授权公开(公告)号：US11459279B2
公开(公告)日：2022-10-04
申请号：US16963172
申请日：2019-01-28
Inventor： Xiulian Pan , Feng Jiao , Xinhe Bao , Gen Li
IPC: C07C1/04 , B01J21/04 , B01J21/06 , B01J21/08 , B01J21/10 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/18 , B01J23/26 , B01J23/34 , B01J29/78 , B01J35/00 , B01J35/10 , B01J37/04
Abstract: A supported catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is a supported zeolite. A carrier is one or more than one of hierarchical pores Al2O3, SiO2, TiO2, ZrO2, CeO2, MgO and Ga2O3; the zeolite is one or more than one of CHA and AEI structures; and the load of the zeolite is 4%-45% wt. A weight ratio of the active ingredients in the component I to the component II is 0.1-20. The reaction process has an extremely high light olefin selectivity; the sum of the selectivity of the light olefin comprising ethylene, propylene and butylene can reach 50-90%, while the selectivity of a methane side product is less than 7%.
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公开(公告)号：US10960387B2
公开(公告)日：2021-03-30
申请号：US16463142
申请日：2017-12-04
Inventor： Xinhe Bao , Feng Jiao , Xiulian Pan , Minzheng Ding
IPC: B01J29/74 , B01J29/78 , B01J29/70 , B01J35/00 , B01J37/00 , B01J37/04 , C07C1/04 , C07C9/04 , C07C11/04 , C07C11/06 , B01J29/87 , B01J29/85 , B01J29/83 , B01J29/82 , B01J29/84 , B01J29/89 , B01J23/00 , B01J23/06 , B01J37/28 , B01J37/30 , B01J23/26 , B01J23/16 , B01J23/64 , B01J23/54 , B01J23/34 , C07C11/08 , B01J23/652 , C07C1/10 , C07C11/09
Abstract: Direct conversion of syngas to light olefins is carried out in a fixed bed or a moving bed reactor with a composite catalyst A+B. The active ingredient of catalyst A is active metal oxide; and catalyst B is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A spacing between geometric centers of the active metal oxide of the catalyst A and the particle of the catalyst B is 5 μm-40 mm. A spacing between axes of the particles is preferably 100 μm-5 mm, and more preferably 200 μm-4 mm. A weight ratio of the active ingredients in the catalyst A and the catalyst B is within a range of 0.1-20 times, and preferably 0.3-5.
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公开(公告)号：US11999671B2
公开(公告)日：2024-06-04
申请号：US17286903
申请日：2019-12-10
Inventor： Feng Jiao , Gen Li , Xiulian Pan , Xinhe Bao
IPC: C07C1/04 , B01J8/02 , B01J8/24 , B01J19/14 , B01J21/04 , B01J21/06 , B01J23/00 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/18 , B01J23/26 , B01J23/34 , B01J23/745 , B01J23/75 , B01J29/85 , B01J35/00 , B01J35/61 , B01J37/00 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/10 , B01J37/18
CPC classification number: C07C1/044 , B01J8/02 , B01J8/24 , B01J19/14 , B01J21/04 , B01J21/066 , B01J23/002 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/18 , B01J23/26 , B01J23/34 , B01J23/745 , B01J23/75 , B01J29/85 , B01J35/19 , B01J35/613 , B01J35/615 , B01J37/0036 , B01J37/009 , B01J37/0201 , B01J37/031 , B01J37/04 , B01J37/06 , B01J37/082 , B01J37/10 , B01J37/18 , C07C1/0435 , B01J2229/18 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/18 , C07C2523/26 , C07C2523/34 , C07C2523/745 , C07C2523/75
Abstract: A composite catalyst containing heteroatom-doped zeolite for preparing light olefin using direct conversion of syngas is formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide, and the component II is a heteroatom-doped zeolite. The zeolite topology is CHA or AEI, and the skeleton atoms include Al—P—O or Si—Al—P—O; the heteroatoms is at least one of divalent metal Mg, Ca, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sr, Zr, Mo, Cd, Ba and Ce, trivalent metal Ti and Ga, and tetravalent metal Ge. A weight ratio of the active ingredient in the component I to the component II is 0.1-20. The reaction process has high light olefin selectivity; the sum selectivity of the light olefin including ethylene, propylene and butylene can reach 50-90%, while the selectivity of a methane side product is less than 7%.
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10.发明授权公开(公告)号：US11097253B2
公开(公告)日：2021-08-24
申请号：US16618749
申请日：2018-08-02
Inventor： Xinhe Bao , Feng Jiao , Xiulian Pan
IPC: B01J23/06 , B01J23/00 , B01J23/10 , B01J23/26 , B01J23/34 , B01J29/40 , B01J29/48 , B01J37/04 , C10G2/00
Abstract: Direct conversion of syngas produces liquid fuels and light olefins. The catalytic reaction is conducted on a fixed bed or a moving bed. The catalyst comprises A and B components. The component A is composed of active metal oxides, and the active ingredients of the component B are zeolites with a MEL structure. The distance between the geometric centers of catalyst A and catalyst B particles is 2 nm-10 mm; a weight ratio of the catalyst A to the catalyst B is 0.1-20. The pressure of the syngas is 0.1-10 MPa; reaction temperature is 300-600° C.; and space velocity is 300-10000 h−1. The reaction mainly produces gasoline with high octane number, and co-generates light olefins. Meanwhile, the selectivity for a methane byproduct is low (less than 10%).
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