摘要:
Water-insoluble, water swellable polymer compositions are disclosed. In one embodiment, the polymer composition comprises a copolymer of styrene and meleic anhydride and a multi arm block copolymer of styrene and ethylene oxide. In a preferred embodiment, the maleic anhydride groups of the anhydride-containing copolymer are treated with a strong base to further enhance absorption capacity.
摘要:
The invention relates to a thermoplastic moulding compound consisting of:A. at least 95% (wt) of a copolymer consisting of1. 50-95 moles % styrene and/or .alpha.-methylstyrene2. 50-55 moles % unsaturated dicarboxylic anhydrideB. at most 5% (wt) of an phosphite with the general formula of ##STR1## where R represents hydrogen or the residue of an alkyl, cycloalkyl, aryl, alkaryl or aralkyl, while the R substituents need not to be the same and may contain heteroatoms.It has been found that additions of these phosphites to SMA-containing moulding compounds checks the decomposition of SMA, prevents the moulding compound from getting stuck to the processing equipment and consequently reduces corrosion to a high degree.
摘要:
Described herein are novel bismaleimides and prepregable resin compositions comprising these bismaleimides and one or more liquid coreactants and optionally, one or more other additives. The novel bismaleimides, such as alpha, alpha-bis-(4-maleimidophenyl)-meta-diisopropylbenzene, are characterized by the presence of three aromatic rings in the molecular structure and in some respects optimize the desirable characteristics of the one or two and four aromatic ring-containing bismaleimides in resins prepared therefrom.
摘要:
Water-insoluble, water swellable polymer compositions are disclosed. In one embodiment, the polymer composition comprises a copolymer of styrene and maleic anhydride and a multi arm block copolymer of styrene and ethylene oxide. In a preferred embodiment, the maleic anhydride groups of the anhydride-containing copolymer are treated with a strong base to further enhance absorption capacity.
摘要:
A dispersion of water soluble or water swellable polymer in water immiscible liquid is made by reverse phase polymerization utilizing a dispersing system comprising a polymerization stabilizer and the resulting dispersion, optionally after dehydration, may be distributed into water utilizing a distributing system. The dispersing system or the distributing system, or both, includes at least one non-ionic compound selected from C.sub.6-12 alkanols, C.sub.4-12 alkylene glycol monoethers and their C.sub.1-4 alkanoates, C.sub.6-12 polyalkylene glycol monoethers and their C.sub.1-4 alkanoates and benzyl alcohol. Novel dispersions are made by reverse phase polymerization and, in particular, include a non-ionic compound selected from C.sub.4-12 alkylene glycol monoethers, their C.sub.1-4 alkanoates and C.sub.6-12 polyalkylene glycol monoethers and their C.sub.1-4 alkanoates. When the polymer is water soluble a solution of it in water can be made by distributing the dispersion into water.
摘要:
A thickening composition is made by blending (a) a liquid emulsion polymer made from (i) an addition polymerizable acid, (ii) an addition polymerizable nonionic vinyl monomer, and (iii) a nonionic vinyl surfactant ester; and (b) a urethane polymer having at least three hydrophobic groups, at least two of which are terminal hydrophobic groups, the hydrophobic groups being linked by hydrophilic groups. The thickening compositions of the invention have an excellent combination of properties including leveling, lack of sagging, and lack of syneresis.
摘要:
A moldable polyblend comprising a physical mixture of from about 99 to about 1% by weight poly(arylene sulfide) with from about 1 to about 99% by weight of a copolymer containing recurring units of a vinyl aromatic monomer and recurring units of a maleimide monomer is disclosed.
摘要:
The tendency to crosslink of polymer compositions comprising polymer units derived from acrylonitrile and maleic anhydride is controlled by the use of boron compounds selected from boron oxide, boron acids and esters of boron acids.
摘要:
The tendency of high temperatures to decompose polymer compositions comprising polymer units derived from maleic anhydride is controlled by the use of a tetrahalogenated aromatic dicarboxylic acid or anhydride thereof.
摘要:
A water-absorbing rubber composition comprising (A) a 1,3-diene rubber with a crystal or glass region content as measured at an ordinary temperature of 5-50% and (B) a highly water-absorbing resin dispersed in the said rubber, the said highly water-absorbing resin being a product of crosslinking of a polymer which contains as monomer component thereof at least 40 mole percent of an .alpha.,.beta.-unsaturated compound containing 1 or 2 groups each selected from the class consisting of a carboxyl group and a group convertible to a carboxyl group with at least one crosslinking agent selected from the class consisting of a polyfunctional epoxy compound and a polyamine, the resin being in the form of a powder capable of passing through a 20-mesh Tyler screen and absorbing 20-500 times its own weight of distilled water. The composition can absorb water rapidly and produce a high swelling pressure, and has good durability in the swollen state.