摘要:
The present invention relates to a unit cell for a solid-oxide fuel cell and to a solid-oxide fuel cell using same, and, more specifically, relates to: a unit cell for a solid-oxide fuel cell, wherein a fuel charging-and-discharging part and an air charging-and-discharging part are provided perpendicularly to a cathode comprised in the solid-oxide fuel cell; and a solid-oxide fuel cell using same.
摘要:
Disclosed herein is a method of manufacturing an anode for in-situ sintering for a molten carbonate fuel cell, in which an anode green sheet is prepared using a slurry, and then a reinforcing layer is placed on the anode green sheet and then pressed, thereby improving the mechanical stability of a fuel cell stack and the long term stability of an anode, and an anode manufactured using the method.
摘要:
Disclosed is a molten carbonate fuel cell comprising a reinforced lithium aluminate matrix, a cathode, an anode, a cathode frame channel and an anode frame channel, wherein at least one of the cathode frame channel and the anode frame channel is filled with a lithium source. Disclosed also are a method for producing the same, and a method for supplying a lithium source. The molten carbonate fuel cell in which a lithium source is supplied to an electrode has high mechanical strength and maintains stability of electrolyte to allow long-term operation.
摘要:
A high-performance carbonate electrolyte for use in a molten carbonate fuel cell comprising a cathode electrode, an anode electrode, an electrolyte matrix and at least a cathode current collector abutting said cathode electrode, the high-performance carbonate electrolyte comprising: a first carbonate electrolyte stored in at least the cathode electrode of the molten carbonate fuel cell comprising a mixture of eutectic Li/Na carbonate electrolyte doped with one or more additive materials and one or more lithium precursors, wherein the additive materials include one or more of Rb2CO3, Cs2CO3, BaCO3, La2O3, Bi2O3, Ta2O5 and mixtures thereof, and a second carbonate electrolyte stored in at least the cathode current collector, the second carbonate electrolyte having a composition that is the same or different from the first carbonate electrolyte.
摘要翻译:一种用于熔融碳酸盐燃料电池的高性能碳酸盐电解质,包括阴极电极,阳极电极,电解质基质和与所述阴极接触的至少阴极集电体,所述高性能碳酸盐电解质包括:第一碳酸盐电解质 存储在熔融碳酸盐燃料电池的至少阴极中,其包含掺杂有一种或多种添加剂材料的共晶Li / Na碳酸盐电解质和一种或多种锂前体的混合物,其中所述添加剂材料包括一种或多种Rb 2 CO 3,Cs 2 CO 3, BaCO 3,La 2 O 3,Bi 2 O 3,Ta 2 O 5及其混合物,以及存储在至少阴极集电体中的第二碳酸酯电解质,所述第二碳酸酯电解质具有与所述第一碳酸酯电解质相同或不同的组成。
摘要:
Disclosed herein is a method of manufacturing the electrolyte-filled cathode of a molten carbonate fuel cell. The method includes the steps of a) manufacturing an air electrode through a sintering process; b) dispersing electrolyte powder throughout one surface of the air electrode according to a composition of eutectics; c) attaching the electrolyte powder, uniformly dispersed throughout the one surface of the air electrode, to the air electrode using pressure by pressing the electrolyte powder on the air electrode at a predetermined pressure; and d) filling the air electrode with the electrolyte powder, attached to the air electrode, through heat treatment.
摘要:
An apparatus and method in which a delayed carbonate electrolyte is stored in the storage areas of a non-electrolyte matrix fuel cell component and is of a preselected content so as to obtain a delayed time release of the electrolyte in the storage areas in the operating temperature range of the fuel cell.
摘要:
A direct carbon fuel cell having an anode electrode of carbon particles pre-wetted with carbonate, a cathode electrode, and an electrolyte layer disposed between the anode electrode and the cathode electrode and containing a molten carbonate. The fuel cell includes a wicking feature whereby excess carbonate produced during the operation of the fuel cell is removed. The use of carbonate pre-wetted carbon particles as the anode provides a network of empty voids, facilitating the removal of CO2 gas from the cell, thereby enhancing fuel cell performance.
摘要:
Disclosed is a reinforced matrix for a molten carbonate fuel cell comprising a porous aluminum support and a lithium aluminate tape-cast on the porous aluminum support. Further, disclosed is a method for preparing the molten carbonate fuel cell comprising the reinforced matrix comprising steps of tape-casting a lithium aluminate on a porous aluminum support so as to prepare a reinforced matrix (S1), making a unit cell or a stack of the unit cells using the reinforced matrix (S2) and heat treating the unit cell or the stack so as to oxidize aluminum in the support into lithium aluminate (S3). According to the present invention, the method is simple and economic, and the mass production of the matrix is easy, and strength of the matrix can be increased effectively and therefore there is no worry about fracture or crack.
摘要:
Disclosed is a molten carbonate fuel cell capable of preventing the leakage of a fuel gas due to deterioration of material by suppressing a high temperature generated at a hot section within a unit cell, thereby improving the reliability thereof. The present invention provides a molten carbonate fuel cell including a plurality of stacked unit cells 8, and separator plates 3 interposed between the adjacent unit cells, the respective unit cells having porous fuel electrode plates 9a and 9b, air electrode plates 11a and 11b, and electrolyte plates 10 interposed between these electrode plates; wherein the separator plate 3 forming a body 1 of the unit cell 8 is provided with at a center thereof intake internal manifolds 12a and 13a arranged at regular intervals for taking in fuel gas R and oxidant gas O towards a center of the body, and at both sides thereof exhaust internal manifolds 12b, 12c, 13b and 13c for exhausting the reacted fuel gas R and the reacted oxidant gas O, as well as forming passages for the fuel gas R ad the oxidant gas O at both sides thereof.
摘要:
According to one embodiment of the invention, an intermediate binding layer and a metal layer can be deposited on a silicon electrode that has been configured with a flow field for a fuel cell. The metal provides high conductivity for the electrode and can also prevent degradation of the silicon. The intermediate binding layer allows the metal to be coupled with the silicon. As one example, tantalum can be used as the intermediate layer and gold can be used as the covering layer.