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156 条记录 (耗时 0.032 秒)

    Graft polymers
    111.
    发明授权
    Graft polymers 失效
    接枝聚合物

    公开(公告)号：US4755564A

    公开(公告)日：1988-07-05

    申请号：US798893

    申请日：1985-11-18

    申请人： Christian Lindner ,  Ludwig Trabert ,  Herbert Bartl ,  Karl-Heinz Ott

    发明人： Christian Lindner ,  Ludwig Trabert ,  Herbert Bartl ,  Karl-Heinz Ott

    IPC分类号： C08F291/00 ,  C08F255/02 ,  C08F265/04 ,  C08F279/02 ,  C08F291/02 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08L77/00 ,  C08L101/00 ,  C08F27/00

    CPC分类号： C08F279/02 ,  C08F255/02 ,  C08F265/04 ,  C08F291/02

    摘要： This invention relates to graft polymers produced from:(1) an elastomer component having glass transition temperatures below 0.degree. C. as the graft base; and(2) graft monomers corresponding to the following general formula: ##STR1## wherein R.sup.1 represents H or a C.sub.1 -C.sub.4 alkyl radical;R.sup.3 represents H, phenyl or a C.sub.1 -C.sub.8 alkyl radical;R.sup.2 represents H, a C.sub.1 -C.sub.10 alkyl or C.sub.6 -C.sub.12 aryl radical or --OR.sup.4 ; andR.sup.4 represents C.sub.1 -C.sub.8 alkyl or C.sub.6 -C.sub.12 aryl optionally substituted by alkyl groups, O-containing or N-containing groups;X represents a single bond, a C.sub.1 -C.sub.10 alkylene or C.sub.6 -C.sub.12 arylene radical, ##STR2## Y represents --O--Z--, --NH--Z--; and Z represents a C.sub.1 -C.sub.10 alkylene or C.sub.6 -C.sub.12 arylene radical; and, optionally, other olefinically unsaturated monomers.

    摘要翻译： 本发明涉及由以下物质制备的接枝聚合物：（1）玻璃化转变温度低于0℃的弹性体组分作为接枝基质; 和（2）对应于以下通式的接枝单体：其中R 1表示H或C 1 -C 4烷基; R3表示H，苯基或C1-C8烷基; R2表示H，C1-C10烷基或C6-C12芳基或-OR4; 且R 4表示任选被烷基，含O或N基团取代的C 1 -C 8烷基或C 6 -C 12芳基; X表示单键，C1-C10亚烷基或C6-C12亚芳基，Y表示-O-Z-，-NH-Z-; Z表示C1-C10亚烷基或C6-C12亚芳基; 和任选的其它烯属不饱和单体。

    Rubber powders
    118.
    发明授权
    Rubber powders 失效
    橡胶粉

    公开(公告)号：US4456734A

    公开(公告)日：1984-06-26

    申请号：US337064

    申请日：1982-01-04

    申请人： Christian Lindner ,  Karl-Heinz Ott

    发明人： Christian Lindner ,  Karl-Heinz Ott

    IPC分类号： C08F2/18 ,  C08F285/00 ,  C08J3/12 ,  C08F265/06

    CPC分类号： C08F285/00

    摘要： Free-flowing rubber powders of particles having an average diameter of from 0.01 to 10 mm which contain a grafted-on shell of the polymer or copolymer of one or more vinyl monomers in a quantity of from 2 to 20% by weight, based on the rubber, which rubber is a latex polymer of which the latex particles consist essentially of from 99 to 80% by weight of acrylate rubber having glass transition temperatures below 0.degree. C. and from 1 to 20% by weight of polymer having glass transition temperatures above 0.degree. C. grafted thereon, and a process for their production, wherein the latex of the rubber is completely broken to form an aqueous suspension of the rubber, after which from 2 to 20% by weight, based on the rubber, of one or more vinyl monomers which form polymers having glass transition temperatures above 25.degree. C. are introduced into the suspension and the monomer(s) is/are polymerized, optionally after the addition of a radical-forming catalyst.

    摘要翻译： 平均直径为0.01至10mm的颗粒的自由流动的橡胶粉末，其含有2-20重量％的2-20重量％的聚合物或共聚物的接枝壳，基于 橡胶，其是胶乳聚合物，其中胶乳颗粒基本上由99至80重量％的玻璃化转变温度低于0℃的丙烯酸酯橡胶和1至20重量％的具有玻璃化转变温度的聚合物组成 接枝在其上的0℃及其制备方法，其中橡胶的胶乳被完全破碎以形成橡胶的水性悬浮液，之后，基于橡胶的2至20重量％的橡胶为1或 将形成玻璃化转变温度高于25℃的聚合物的更多的乙烯基单体引入悬浮液中，任选地在加入自由基形成催化剂之后将单体聚合。

    High-notched-impact core-shell polymers having improved weather resistance
    119.
    发明授权
    High-notched-impact core-shell polymers having improved weather resistance 失效
    具有改进的耐候性的高切口冲击的核 - 壳聚合物

    公开(公告)号：US4393172A

    公开(公告)日：1983-07-12

    申请号：US309569

    申请日：1981-10-08

    申请人： Christian Lindner ,  Karl-Heinz Ott ,  Alfred Pischtschan

    发明人： Christian Lindner ,  Karl-Heinz Ott ,  Alfred Pischtschan

    IPC分类号： C08F279/00 ,  C08F279/02 ,  C08F285/00 ,  C08L51/04 ,  C08F265/04

    CPC分类号： C08F279/02 ,  Y10S525/902

    摘要： A particulate graft polymer comprising (a) a core formed by a crosslinked homopolymer of a conjugated diene or a copolymer thereof with up to 10% by weight of styrene or acrylonitrile; (b) a first shell formed by a crosslinked homopolymer of an acrylic acid alkyl ester or a copolymer thereof with up to 30% by weight of vinyl monomers; (c) a second shell formed by a polymer of resin-forming monomers, a process for manufacturing these graft polymers by means of a multi-stage emulsion polymerization, and their application as molding compositions, optionally together with rigid thermoplastic resins.

    摘要翻译： 一种颗粒状接枝聚合物，其包含（a）由共轭二烯的交联均聚物或其共聚物与至多10重量％的苯乙烯或丙烯腈的交联均聚物形成的芯; （b）由丙烯酸烷基酯的交联均聚物或其共聚物与至多30重量％的乙烯基单体形成的第一壳; （c）由树脂形成单体的聚合物形成的第二壳，通过多阶段乳液聚合制造这些接枝聚合物的方法，以及它们作为模塑组合物，任选地与刚性热塑性树脂一起使用。