Syndiotactic rich polyolefins
    111.
    发明申请
    Syndiotactic rich polyolefins 有权
    间同立构聚烯烃

    公开(公告)号:US20060020067A1

    公开(公告)日:2006-01-26

    申请号:US11220114

    申请日:2005-09-06

    IPC分类号: C08K5/17

    摘要: Disclosed herein is a polymer comprising an amorphous syndiotactic rich polyolefin comprising greater than about 50 wt % C3-C40 alpha olefins and having about 50% to less than about 80% r dyads, based on the total number of r and m dyads present in the polymer; a heat of fusion of 10 joules/g or less according to the procedure described in ASTM E 794-85; and an ash content of 1 wt % or less. A functionalized amorphous syndiotactic rich polyolefin is also disclosed, along with methods to produce and a method to use the inventive polymer.

    摘要翻译: 本文公开了一种聚合物,其包含无定形间同立构聚烯烃,其包含大于约50重量%的C 3 -C 40α-烯烃,并且具有约50%至小于约80% 基于聚合物中存在的r和m二重峰的总数; 根据ASTM E 794-85中描述的程序,10焦耳/克或更小的熔化热; 灰分含量为1重量%以下。 还公开了官能化的无定形间同立构聚烯烃,以及制备方法和使用本发明聚合物的方法。

    Hyperbranched polymers by coordination polymerization
    113.
    发明授权
    Hyperbranched polymers by coordination polymerization 有权
    超支化聚合物通过配位聚合

    公开(公告)号:US06294631B1

    公开(公告)日:2001-09-25

    申请号:US09211644

    申请日:1998-12-15

    申请人: Patrick Brant

    发明人: Patrick Brant

    IPC分类号: C08F1234

    摘要: Hyperbranched copolymers comprising at least one C2-C20 &agr;-monoolefin monomers and 0.2 to 20 mole % of at least one &agr;,&ohgr;-non-conjugated diene monomers having 5 to 18 carbon atoms are prepared by coordination (metallocene) copolymerization of the monomers and quenching the reaction prior to the formation of a gelled product. The building blocks of the products are characterized by a number average molecular weight less than 5 times the entanglement molecular weight of a homopolymer prepared using the same catalyst but in the absence of the diene component.

    摘要翻译: 包含至少一种C 2 -C 20α-单烯烃单体和0.2至20摩尔%至少一种具有5至18个碳原子的α,ω-非共轭二烯单体的超支化共聚物通过单体的配位(茂金属)共聚和 在形成凝胶产物之前淬灭反应。 产物的结构单元的特征在于数均分子量小于使用相同催化剂制备但不存在二烯组分的均聚物的缠结分子量的5倍。

    Fullerene-polymer compositions
    118.
    发明授权
    Fullerene-polymer compositions 失效
    富勒烯聚合物组合物

    公开(公告)号:US5281653A

    公开(公告)日:1994-01-25

    申请号:US797525

    申请日:1991-11-25

    CPC分类号: C08K3/04 Y10S977/753

    摘要: The present invention relates to novel compositions of matter comprising fullerenes and polymers, wherein the fullerenes are combined with the polymer in an amount sufficient to result in a change or modification in the viscoelastic properties of the resulting composition from that of the unmodified polymer typically within the range of from about 0.01 wt. % to about 85 wt. %. Also included in the present invention is the process for making the novel fullerene-polymer compositions and the products produced by the process disclosed therein. The novel compositions show changes in the viscoelastic properties in comparison to the unmodified polymer, and hence, have utility in any application in which the unmodified polymer may be used, but wherein the application would benefit from the resulting change in the viscoelastic properties.

    摘要翻译: 本发明涉及包含富勒烯和聚合物的新型物质组合物,其中富勒烯与聚合物结合的量足以导致所得组合物的粘弹性性质与未改性聚合物的粘弹性性质的改变或改性, 范围为约0.01重量% %至约85重量% %。 本发明还包括制备新型富勒烯聚合物组合物和通过其中公开的方法制备的产品的方法。 与未改性的聚合物相比,该新型组合物显示出粘弹性性能的变化,因此在可以使用未改性聚合物的任何应用中具有实用性,但是其应用将受益于所得到的粘弹性质的变化。

    Narrow molecular weight distribution ethylene-acrylate cling layer in
stretch/cling films
    119.
    发明授权
    Narrow molecular weight distribution ethylene-acrylate cling layer in stretch/cling films 失效
    拉伸/粘贴膜中窄分子量分布乙烯 - 丙烯酸酯粘合层

    公开(公告)号:US5173343A

    公开(公告)日:1992-12-22

    申请号:US633509

    申请日:1990-12-28

    IPC分类号: B32B27/08 B32B27/32

    摘要: A thermoplastic film is provided which is especially suited for use in stretch/cling applications such as, for example, the bundling, packaging and unitizing of foods and other goods. The film comprises a cling layer comprising a polymer of at least ethylene and 2-40 wt % acrylate having a ratio of M.sub.w /M.sub.n less than about 3.5, a ratio of M.sub.z /M.sub.w less than about 3, a melt index of about 0.1-30 dg/min, and a melt index swell ratio less than about 1.6, preferably without a tackifying additive. The film may further comprise a non-cling layer comprising a thermoplastic preferably essentially free of anticling (slip and/or antiblock) additive. Preferred thermoplastic materials include polyethylene and polypropylene.

    摘要翻译: 提供了一种热塑性薄膜,其特别适用于拉伸/粘贴应用,例如食品和其他物品的捆扎,包装和组合。 该薄膜包括一层粘合层,该粘结层包含至少为乙烯和2-40wt%丙烯酸酯的聚合物,其Mw / Mn比小于约3.5,Mz / Mw小于约3,熔体指数为约0.1 30dg / min,熔体指数溶胀比小于约1.6,优选不含增粘剂。 膜可以进一步包括非粘附层,其包含优选基本上不含抗皱(滑动和/或抗粘连)添加剂的热塑性塑料。 优选的热塑性材料包括聚乙烯和聚丙烯。

    Tackified ethylene-acrylate cling layers in stretch/cling films
    120.
    发明授权
    Tackified ethylene-acrylate cling layers in stretch/cling films 失效
    拉伸/粘贴膜中的乙烯 - 丙烯酸酯粘合层的增强

    公开(公告)号:US5154981A

    公开(公告)日:1992-10-13

    申请号:US633524

    申请日:1990-12-28

    IPC分类号: B32B27/08 B32B27/32

    摘要: A thermoplastic film is provided which is especially suited for use in stretch/cling applications such as, for example, the bundling, packaging and unitizing of foods and other goods. The film comprises a cling layer comprising (i) a polymer of at least ethylene and acrylate or vinyl acetate, blended with (ii) a compatible, non-migratory tackifier. The film may further comprise a non-cling layer comprising a thermoplastic material essentially free of tackifier, with or without an anticling (slip and/or antiblock) additive. Preferred thermoplastic materials include linear low density polyethylene and polypropylene.

    摘要翻译: 提供了一种热塑性薄膜,其特别适用于拉伸/粘贴应用,例如食品和其他物品的捆扎,包装和组合。 该膜包括粘合层,其包含(i)至少乙烯和丙烯酸酯或乙酸乙烯酯的聚合物,与(ii)相容的非迁移性增粘剂共混。 膜可以进一步包含非粘附层,其包含基本上不含增粘剂的热塑性材料,具有或不具有抗皱(滑移和/或抗粘连)添加剂。 优选的热塑性材料包括线性低密度聚乙烯和聚丙烯。