公开(公告)号：US09745478B2

公开(公告)日：2017-08-29

申请号：US15264659

申请日：2016-09-14

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Jihui Guo ,  Kevin J. Henderson ,  Ericka Lynn Killian ,  John J. Rabasco ,  Daniel A. Saucy ,  Jordan Stracke

IPC: C08L3/00 ,  C09D7/00 ,  C09D7/12 ,  C09D133/08 ,  C09D133/12 ,  C09D5/02 ,  C09D151/00 ,  C08K9/04 ,  C08L75/04 ,  C08K3/22

CPC classification number: C09D7/002 ,  C08G18/227 ,  C08G18/2825 ,  C08G18/4812 ,  C08G18/4833 ,  C08G18/73 ,  C08G18/758 ,  C08K9/04 ,  C08K9/08 ,  C08K2003/2241 ,  C08L75/04 ,  C09D5/024 ,  C09D5/028 ,  C09D7/40 ,  C09D7/43 ,  C09D7/44 ,  C09D7/62 ,  C09D133/08 ,  C09D133/12 ,  C09D143/02 ,  C09D151/003 ,  C09D151/06

Abstract: The present invention relates to a composition comprising an aqueous dispersion of an associative thickener having a hydrophobic portion with a calculated log P in the range of from 2.7 to 5.0; and composite particles comprising phosphorus acid functionalized polymer particles adsorbed to the surfaces of TiO2 particles; wherein the phosphorus acid functionalized polymer particles have a core-shell morphology wherein the core protuberates from the shell. The composition of the present invention provides formulators with flexibility in their use of low and mid shear rate thickeners to balance paint performance properties.

公开(公告)号：US20170145219A1

公开(公告)日：2017-05-25

申请号：US15422925

申请日：2017-02-02

Applicant: The Regents of the University of California ,  Dow Chemical Technologies LLC ,  Rohm and Haas Company

Inventor： Joseph Jankolovits ,  Alexander S. Katz ,  Oz M. Gazit ,  James C. Bohling ,  John A. Roper, III

IPC: C09C1/36 ,  C08B11/20 ,  C09D101/28 ,  C09C1/40 ,  C09D105/00 ,  C08B37/00 ,  C09C1/30

CPC classification number: C08B37/0024 ,  B01J20/3204 ,  B01J20/3272 ,  B01J20/3274 ,  B01J20/3278 ,  B01J20/3289 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/04 ,  C08B11/20 ,  C09C1/3054 ,  C09C1/3072 ,  C09C1/3081 ,  C09C1/309 ,  C09C1/3661 ,  C09C1/3676 ,  C09C1/3684 ,  C09C1/3692 ,  C09C1/407 ,  C09C3/10 ,  C09D101/28 ,  C09D105/00

Abstract: The present invention is a multilayered composite comprising porous metal oxide particles that are covalently bonded by way of inorganic ether groups to one or more sites of a first polyhydroxyl-functionalized polymer. This first polymer is in turn covalently bonded by way of inorganic ether groups to one or more sites of a second polyhydroxyl-functionalized polymer. The multilayered composites can be prepared by contacting porous inorganic-oxide particles with a sufficient amount of OH-reactive crosslinking agent to form metal oxide particles imbibed with the crosslinking agent, and then contacting the inorganic-oxide particles with a solution of polyhydroxyl-functionalized polymer under reactive conditions.

公开(公告)号：US09469760B2

公开(公告)日：2016-10-18

申请号：US15019262

申请日：2016-02-09

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Catherine A. Finegan

IPC: C08L33/08 ,  C08L43/02 ,  C08F220/18 ,  C08F265/04 ,  C08K3/22 ,  C09D143/02 ,  C08F228/00 ,  C08F230/02 ,  C08K5/42 ,  C08K5/521 ,  C08F275/00

CPC classification number: C08L43/02 ,  C08F220/18 ,  C08F228/00 ,  C08F230/02 ,  C08F265/04 ,  C08F275/00 ,  C08K3/22 ,  C08K5/42 ,  C08K5/521 ,  C08K2003/2241 ,  C08L33/08 ,  C08L2201/54 ,  C09D143/02 ,  C08F212/14 ,  C08F220/34

Abstract: The present invention is a process for preparing a multistage polymer by contacting under emulsion polymerization conditions an acrylic monomer, a sulfur acid monomer, and a phosphorous acid monomer as described herein. The multistage polymer is useful as a binder for coatings compositions.

Abstract translation: 本发明是一种通过在乳液聚合条件下与本文所述的丙烯酸类单体，硫酸单体和亚磷酸单体接触来制备多级聚合物的方法。 多级聚合物可用作涂料组合物的粘合剂。

公开(公告)号：US09469758B2

公开(公告)日：2016-10-18

申请号：US14321911

申请日：2014-07-02

Applicant: Dow Global Technologies, LLC ,  Rohm and Haas Company

Inventor： James C. Bohling ,  Beth Cooper ,  Melinda H. Keefe ,  Margo Schaefer

IPC: C08F265/06 ,  C08L33/08 ,  C09D7/12 ,  C09D151/00

CPC classification number: C08L33/08 ,  C08F265/06 ,  C08L2207/53 ,  C09D7/65 ,  C09D7/68 ,  C09D151/003 ,  C08F220/06 ,  C08F220/18 ,  C08F2220/1825 ,  C08F220/34

Abstract: The present invention relates to a composition comprising a stable aqueous dispersion of large acrylic based polymer particles and small acrylic based polymer particles wherein the large polymer particles comprise structural units of a phosphorus acid monomer or a salt thereof; and wherein the small polymer particles comprise a substantial absence of structural units of any phosphorus acid monomer and salts thereof. The bimodal dispersion of the present invention provides a way of making a high solids adsorbing latex with high hiding efficiency.

Abstract translation: 本发明涉及包含大型丙烯酸类聚合物颗粒和小型丙烯酸类聚合物颗粒的稳定水分散体的组合物，其中大聚合物颗粒包含磷酸单体或其盐的结构单元; 并且其中所述小聚合物颗粒包含基本上没有任何磷酸单体及其盐的结构单元。 本发明的双峰分散体提供了制备具有高掩蔽效率的高固体吸附胶乳的方法。

公开(公告)号：US09464205B2

公开(公告)日：2016-10-11

申请号：US14565914

申请日：2014-12-10

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Kevin J. Henderson

IPC: C09D135/02 ,  C09D4/00 ,  C09D5/00 ,  C09D133/14

CPC classification number: C09D135/02 ,  C08K2003/2241 ,  C09D1/00 ,  C09D4/00 ,  C09D5/00 ,  C09D133/14

Abstract: The present invention is a composition comprising a) a stable aqueous dispersion of polymer particles functionalized with structural units of itaconic acid or a salt thereof and; b) a water-soluble polymer functionalized with structural units of a sulfonic acid monomer or a salt thereof as well as a method comprising mixing the stable aqueous dispersion of the itaconic acid functionalized polymer particles with the sulfonic acid functionalized polymer, and TiO2. The composition of the present invention is useful a coatings formulation that provides surprisingly good hiding.

Abstract translation: 本发明是一种组合物，其包含：a）用衣康酸或其盐的结构单元官能化的聚合物颗粒的稳定水性分散体; b）用磺酸单体或其盐的结构单元官能化的水溶性聚合物以及包含将所述衣康酸官能化聚合物颗粒的稳定水分散体与磺酸官能化聚合物和TiO 2混合的方法。 本发明的组合物可用于提供惊人的良好隐藏的涂料制剂。

公开(公告)号：US09464204B2

公开(公告)日：2016-10-11

申请号：US14649638

申请日：2013-11-26

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Muhunthan Sathiosatham

IPC: C08K3/22 ,  C09D133/08 ,  C08F220/18 ,  C08F265/06 ,  C09D143/02 ,  C09D151/00 ,  C08F220/14 ,  C08F228/02 ,  C08F230/02

CPC classification number: C09D133/08 ,  C08F220/14 ,  C08F220/18 ,  C08F228/02 ,  C08F230/02 ,  C08F265/06 ,  C08K3/22 ,  C08K2003/2241 ,  C09D143/02 ,  C09D151/003 ,  C08F2220/1825 ,  C08F220/36 ,  C08F212/14 ,  C08F220/06 ,  C08F220/40

Abstract: The present invention is a composition comprising a stable aqueous dispersion of polymer particles comprising structural units of a nonionic monoethylenically unsaturated monomer; 2-(methacryloyloxy)ethyl phosphonic acid (MEP) or a salt thereof; and a sulfur acid monomer or carboxylic acid monomer or a combination thereof or a salt thereof, as well as a composite comprising the polymer particles adsorbed to the surface of a pigment particle such as TiO2. The composition and composite are prepared using the phosphorus acid monomer MEP, which can be prepared in high purity with low residual non-polymerizable phosphorus acid, thereby reducing the load of neutralizing agent required to achieve the targeted pH as compared with phophoethyl methacrylate (PEM).

Abstract translation: 本发明是一种组合物，其包含稳定的包含非离子单烯属不饱和单体的结构单元的聚合物颗粒的水分散体; 2-（甲基丙烯酰氧基）乙基膦酸（MEP）或其盐; 和硫酸单体或羧酸单体或其组合或其盐，以及包含吸附在颜料颗粒如TiO 2表面上的聚合物颗粒的复合物。 使用磷酸单体MEP制备组合物和复合材料，其可以用低残留的非可聚合磷酸制备高纯度，从而降低与甲基丙烯酸磷酸乙酯（PEM）相比达到目标pH所需的中和剂的负载量， 。

公开(公告)号：US20150191589A1

公开(公告)日：2015-07-09

申请号：US14418099

申请日：2012-08-02

Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

Inventor： Qiaoqiao Cai ,  Junyu Chen ,  Xiangting Dong ,  Tingke Zhang ,  James C. Bohling

IPC: C08L33/14 ,  C08K3/22

CPC classification number: C08L33/14 ,  C08F220/10 ,  C08F230/02 ,  C08K3/22 ,  C08K2003/2241 ,  C08L31/02 ,  C08L31/04 ,  C08L33/02 ,  C08L33/08 ,  C08L43/02 ,  C08L2201/54 ,  C09D143/02

Abstract: The present invention relates to a composition of a stable aqueous dispersion of polymer particles comprising structural units of a) vinyl acetate; b) a vinyl ester of a branched carboxylic acid monomer; and c) a phosphorus acid monomer. The composition of the present invention provides vinyl ester/phosphorus acid based polymer particles that improve hiding efficiency in pigmented coatings formulations.

Abstract translation: 本发明涉及包含a）乙酸乙烯酯的结构单元的聚合物颗粒的稳定水分散体的组合物; b）支链羧酸单体的乙烯基酯; 和c）磷酸单体。 本发明的组合物提供了改善着色涂料制剂隐藏效率的乙烯基酯/磷酸基聚合物颗粒。

公开(公告)号：US20150011695A1

公开(公告)日：2015-01-08

申请号：US14321911

申请日：2014-07-02

Applicant: Dow Global Technologies, LLC ,  Rohm and Haas Company

Inventor： James C. Bohling ,  Beth Cooper ,  Melinda H. Keefe ,  Margo Schaefer

IPC: C08L33/08 ,  C09D7/12

CPC classification number: C08L33/08 ,  C08F265/06 ,  C08L2207/53 ,  C09D7/65 ,  C09D7/68 ,  C09D151/003 ,  C08F220/06 ,  C08F220/18 ,  C08F2220/1825 ,  C08F220/34

Abstract: The present invention relates to a composition comprising a stable aqueous dispersion of large acrylic based polymer particles and small acrylic based polymer particles wherein the large polymer particles comprise structural units of a phosphorus acid monomer or a salt thereof; and wherein the small polymer particles comprise a substantial absence of structural units of any phosphorus acid monomer and salts thereof. The bimodal dispersion of the present invention provides a way of making a high solids adsorbing latex with high hiding efficiency.

Abstract translation: 本发明涉及包含大型丙烯酸类聚合物颗粒和小型丙烯酸类聚合物颗粒的稳定水分散体的组合物，其中大聚合物颗粒包含磷酸单体或其盐的结构单元; 并且其中所述小聚合物颗粒包含基本上没有任何磷酸单体及其盐的结构单元。 本发明的双峰分散体提供了制备具有高掩蔽效率的高固体吸附胶乳的方法。

公开(公告)号：US20150005446A1

公开(公告)日：2015-01-01

申请号：US14375186

申请日：2013-01-30

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Yogesh Tiwary

IPC: C08L33/08

CPC classification number: C08L51/003 ,  C08F2/001 ,  C08F2/24 ,  C08F265/04 ,  C08K3/22 ,  C08K2003/2241 ,  C08L33/04 ,  C08L33/08 ,  C08L2201/54 ,  C09D133/14 ,  C09D143/02 ,  C08F220/18 ,  C08F212/08 ,  C08F220/06 ,  C08F212/14 ,  C08F230/08

Abstract: The present invention relates to a process comprising contacting a stable aqueous dispersion of pre-formed polymer particles with a monomer emulsion under emulsion polymerization conditions to form a stable aqueous dispersion of pre-formed particles protuberating from polymer particles arising from the polymerization of the monomer emulsion; these multistage polymer particles show exceptional compatibility with pigment particles. In another aspect, the present invention is a composition relating to the pre-formed particles.

Abstract translation: 本发明涉及一种方法，其包括在乳液聚合条件下使稳定的预形成聚合物颗粒的水分散体与单体乳液接触，以形成由单体乳液聚合产生的聚合物颗粒突出的预形成颗粒的稳定的水分散体 ; 这些多级聚合物颗粒与颜料颗粒显示出卓越的相容性。 另一方面，本发明是与预成型颗粒相关的组合物。