公开(公告)号：US20120052314A1

公开(公告)日：2012-03-01

申请号：US13285301

申请日：2011-10-31

Applicant: Himanshu Asthana ,  Safwat Tadros ,  Paul Sybert ,  Christopher L. Hein ,  Edward Kung ,  David Rosendale ,  Xiangyang Li ,  Luca Saggese ,  Erich O. Teutsch ,  Glen Tryson ,  Hua Wang ,  Hongyi Zhou ,  Chris Hartshorn ,  Axel Grimm ,  Theodorus J.M. Timmerman ,  Jeroen Vervoort ,  Hendrik Cornelus Jacobus de Nooijer ,  Gert Boven ,  Beth Brister ,  Enamul Haque

Inventor： Himanshu Asthana ,  Safwat Tadros ,  Paul Sybert ,  Christopher L. Hein ,  Edward Kung ,  David Rosendale ,  Xiangyang Li ,  Luca Saggese ,  Erich O. Teutsch ,  Glen Tryson ,  Hua Wang ,  Hongyi Zhou ,  Chris Hartshorn ,  Axel Grimm ,  Theodorus J.M. Timmerman ,  Jeroen Vervoort ,  Hendrik Cornelus Jacobus de Nooijer ,  Gert Boven ,  Beth Brister ,  Enamul Haque

IPC: B32B27/18 ,  B29C47/06 ,  B32B27/36 ,  B29C51/14 ,  B29C65/02 ,  B29C35/08 ,  B29C45/14 ,  C09J5/06

CPC classification number: B32B27/36 ,  B29C45/14811 ,  B29C48/0017 ,  B29C48/08 ,  B29C48/21 ,  B29C48/30 ,  B29C48/307 ,  B29C48/49 ,  B29C51/002 ,  B29C51/02 ,  B29C51/082 ,  B29C2791/001 ,  B29K2033/04 ,  B29K2633/08 ,  B29K2705/00 ,  B29K2713/00 ,  B29K2995/0055 ,  B29K2995/0058 ,  B29L2031/30 ,  B29L2031/3008 ,  B32B27/06 ,  B32B37/153 ,  B32B38/0008 ,  B32B38/12 ,  B32B2038/0016 ,  B32B2310/0445 ,  B32B2310/14 ,  B32B2605/08 ,  Y10T428/24942 ,  Y10T428/31507 ,  Y10T428/31565 ,  Y10T428/3158 ,  Y10T428/31587 ,  Y10T428/31681 ,  Y10T428/31786

Abstract: Multilayer articles comprising a coating layer comprising resorcinol arylate chain members bound to a support substrate via an optional intermediate tie layer. Adhesion between the layers of the multilayer article is enhanced by modifying at least a part of a surface of at least one of the layers in the multilayer article by a technique selected from at least one of: surface adhesive treatment, surface corona treatment, flame treatment, plasma surface treatment, vacuum deposition treatment, ionization radiation, chemical surface treatment, surface abrasion treatment, and surface texturing treating.

Abstract translation: 包含包含间苯二酚芳基化物链成员的涂层的多层制品通过任选的中间粘结层结合到支撑基底上。 通过选自以下技术中的一种技术来修饰多层制品中的至少一层的至少一部分表面的多层制品层之间的粘合性：表面粘合剂处理，表面电晕处理，火焰处理 ，等离子体表面处理，真空沉积处理，电离辐射，化学表面处理，表面磨损处理和表面纹理处理。

公开(公告)号：US20070129492A1

公开(公告)日：2007-06-07

申请号：US11537154

申请日：2006-09-29

Applicant: Robert Colborn ,  Gary Davis ,  Jianbo Di ,  Constantin Donea ,  Irene Dris ,  Katherine Jackson ,  Brian Mullen ,  Laura Schultz ,  Moitreyee Sinha ,  Paul Sybert

Inventor： Robert Colborn ,  Gary Davis ,  Jianbo Di ,  Constantin Donea ,  Irene Dris ,  Katherine Jackson ,  Brian Mullen ,  Laura Schultz ,  Moitreyee Sinha ,  Paul Sybert

IPC: C08L83/10

CPC classification number: C08G63/64 ,  B64C1/1492 ,  C08G63/19 ,  C08G63/605 ,  C08G63/6956 ,  C08L83/10 ,  Y10T428/31663

Abstract: A polysiloxane copolymer composition comprises: a polysiloxane unit comprising 4 to 50 siloxane units, and a polyester-polycarbonate unit consisting of 50 to 100 mole percent of arylate ester units, less than 50 mole percent aromatic carbonate units, less than 30 mole percent resorcinol carbonate units, and less than 35 mole percent bisphenol carbonate units, wherein the siloxane units are present in the polysiloxane unit in an amount of 0.2 to 10 wt % of the total weight of the polysiloxane copolymer composition, and wherein the polysiloxane copolymer composition has a 2 minute integrated heat release rate of less than or equal to 65 kilowatt-minutes per square meter (kW-min/m2) and a peak heat release rate of less than 65 kilowatts per square meter (kW/m2) as measured using the method of FAR F25.4, in accordance with Federal Aviation Regulation FAR 25.853 (d). A window article for an aircraft, comprising the polysiloxane copolymer composition, is also disclosed.

Abstract translation: 聚硅氧烷共聚物组合物包括：包含4至50个硅氧烷单元的聚硅氧烷单元和由50至100摩尔％的芳基酯单元，小于50摩尔％的芳族碳酸酯单元，小于30摩尔％的间苯二酚碳酸酯组成的聚酯 - 聚碳酸酯单元 单体和小于35摩尔％的双酚碳酸酯单元，其中硅氧烷单元以聚硅氧烷共聚物组合物总重量的0.2-10重量％的量存在于聚硅氧烷单元中，并且其中聚硅氧烷共聚物组合物具有2 小于或等于65千瓦 - 分钟/平方米（kW-min / m 2）的每分钟集成放热速率和小于65千瓦/平方米的峰值放热率（kW / 根据FAR F25.4的方法，根据联邦航空法规FAR 25.853（d）测量。 还公开了一种包含聚硅氧烷共聚物组合物的飞机用窗构件。

公开(公告)号：US20060142527A1

公开(公告)日：2006-06-29

申请号：US11025249

申请日：2004-12-29

Applicant: Katherine Glasgow ,  Brian Mullen ,  Paul Sybert

Inventor： Katherine Glasgow ,  Brian Mullen ,  Paul Sybert

IPC: C08G77/04 ,  C08G77/06 ,  C08L83/04

CPC classification number: C08L83/10 ,  C08G63/64 ,  C08G77/445 ,  C08G77/448

Abstract: A thermoplastic composition is disclosed, comprising the reaction product of: a polyester polycarbonate comprising a polyester unit and a polycarbonate unit; a polysiloxane polycarbonate copolymer having a haze of 30% or less, comprising a polycarbonate unit and a polysiloxane unit; and a transesterification catalyst. The resulting thermoplastic composition has a haze of 30% or less as measured according to ASTM D1003-00 at a thickness of 3.2 millimeters. A method of forming the composition and articles formed from the composition are also disclosed.

Abstract translation: 公开了一种热塑性组合物，其包含以下反应产物：包含聚酯单元和聚碳酸酯单元的聚酯聚碳酸酯; 具有30％以下的雾度的聚硅氧烷聚碳酸酯共聚物，其包含聚碳酸酯单元和聚硅氧烷单元; 和酯交换催化剂。 所得热塑性组合物的雾度为30％以下，根据ASTM D1003-00测定，厚度为3.2毫米。 还公开了形成由组合物形成的组合物和制品的方法。

公开(公告)号：US20060004152A1

公开(公告)日：2006-01-05

申请号：US10881957

申请日：2004-06-28

Applicant: Ali Acar ,  Paul Sybert ,  Xiangyang Li ,  Karthik Balakrishnan ,  Gregory O'Neil

Inventor： Ali Acar ,  Paul Sybert ,  Xiangyang Li ,  Karthik Balakrishnan ,  Gregory O'Neil

IPC: C08L69/00 ,  B32B27/00

CPC classification number: C08L67/03 ,  C08L69/00 ,  C08L69/005 ,  C08L101/00 ,  Y10T428/31507 ,  C08L2666/02 ,  C08L2666/18

Abstract: The present invention relates to a polymer composition comprising a transparent polymer blend. The polymer blend comprises a first resin and a second resin. The first resin comprises polyarylate structural units of formula I, wherein R1 is independently at each occurrence a C1-C12 alkyl group, or a halogen atom, and p is 0 to 3. The second resin is selected from the group consisting of polycarbonates, polyarylates and copolyestercarbonates. The first resin and the second resin are further characterized by a difference in polyarylate structural unit conte

Abstract translation: 本发明涉及包含透明聚合物共混物的聚合物组合物。 聚合物共混物包括第一树脂和第二树脂。 第一树脂包括式I的多芳基化合物结构单元，其中R 1在每次出现时独立地为C 1 -C 12烷基，或 卤素原子，p为0〜3。第二树脂选自聚碳酸酯，聚芳酯和共聚酯碳酸酯。 第一树脂和第二树脂的特征还在于多芳基化合物结构单元的差异 TIF”alt =“文本丢失或难以辨认

公开(公告)号：US20050159577A1

公开(公告)日：2005-07-21

申请号：US11025635

申请日：2004-12-29

Applicant: Gary Davis ,  Brian Mullen ,  Paul Sybert

Inventor： Gary Davis ,  Brian Mullen ,  Paul Sybert

IPC: B32B27/06 ,  B32B27/08 ,  B32B27/18 ,  C08G63/19 ,  C08G63/64 ,  C08G63/676 ,  C08G63/695 ,  C08G63/79 ,  C08J7/04 ,  C09D167/03 ,  F02B61/04 ,  C08G64/00

CPC classification number: B32B27/365 ,  B32B27/06 ,  B32B27/08 ,  B32B27/20 ,  B32B27/283 ,  B32B27/36 ,  B32B2307/584 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2419/00 ,  B32B2605/00 ,  C08F293/00 ,  C08G63/19 ,  C08G63/64 ,  C08G63/676 ,  C08G63/6956 ,  C08G63/79 ,  C08J7/047 ,  C08J2467/00 ,  C08J2469/00 ,  C08L53/00 ,  C08L2666/02 ,  C09D153/00 ,  C09D167/03 ,  C09J153/00 ,  F02B61/045 ,  Y10T428/31504 ,  Y10T428/31507

Abstract: A copolymer composition comprises an arylate polyester unit, an aromatic carbonate unit, and a soft-block moiety, wherein individual occurrences of the soft block moiety are linked by a spacer unit comprising one or more of the arylate polyester units, one or more of the aromatic carbonate units, or a combination comprising each of these. In one embodiment, a soft block moiety comprises a polysiloxane unit. A film of the composition has a percent transmittance of greater than or equal to 60% as determined according to ASTM D1003-00. A method of forming a copolymer composition is disclosed, comprising substantially forming the bis-haloformates of a dihydroxy compound comprising an arylate polyester unit, and a dihydroxy compound comprising a soft-block moiety, and reacting the bis haloformates with a dihydroxy aromatic compound.

Abstract translation: 共聚物组合物包含芳基化聚酯单元，芳族碳酸酯单元和软嵌段部分，其中软嵌段部分的单独出现由包含一个或多个芳基化聚酯单元的间隔单元连接，一个或多个 芳族碳酸酯单元，或包含这些中的每一个的组合。 在一个实施方案中，软嵌段部分包含聚硅氧烷单元。 根据ASTM D1003-00测定，该组合物的透光率百分比大于或等于60％。 公开了一种形成共聚物组合物的方法，其包括基本上形成包含芳基化聚酯单元的二羟基化合物的双卤代甲酸酯和包含软嵌段部分的二羟基化合物，并使双卤代甲酸酯与二羟基芳族化合物反应。

公开(公告)号：US20050070643A1

公开(公告)日：2005-03-31

申请号：US10676892

申请日：2003-09-30

Applicant: Glen Merfeld ,  Rainer Koeniger ,  Ali Acar ,  Paul Sybert ,  Zhaohui Su

Inventor： Glen Merfeld ,  Rainer Koeniger ,  Ali Acar ,  Paul Sybert ,  Zhaohui Su

IPC: C08G63/78 ,  C08J3/00 ,  C08K5/09 ,  C08K5/10 ,  C08K5/1515 ,  C08K5/17 ,  C08K5/29 ,  C08L61/24 ,  C08L61/28 ,  C08L101/00 ,  C09D167/00 ,  C09D167/03

CPC classification number: C08G63/78 ,  C08K5/09 ,  C08K5/10 ,  C08K5/1515 ,  C08K5/17 ,  C08K5/29 ,  C08L61/24 ,  C08L61/28 ,  C08L101/00 ,  C09D167/03 ,  Y10T428/31507 ,  Y10T428/31786 ,  Y10T428/31942 ,  C08L2666/16

Abstract: A coating composition comprising components A, B and optionally C, wherein component A comprises at least one hydroxy-terminated polyarylate. Component B is an organic species which can react with the hydroxy terminal groups of component A, and component C is a catalyst or mixture of catalysts. The hydroxy-terminated polyarylates are prepared by a solution polymerization method.

Abstract translation: 包含组分A，B和任选C的涂料组合物，其中组分A包含至少一种羟基封端的多芳基化合物。 组分B是可以与组分A的羟基端基反应的有机物，组分C是催化剂或催化剂的混合物。 羟基封端的聚芳酯通过溶液聚合法制备。

公开(公告)号：US20050049369A1

公开(公告)日：2005-03-03

申请号：US10639998

申请日：2003-08-12

Applicant: Gregory O'Neil ,  Ali Acar ,  Paul Sybert ,  Pratima Rangarajan ,  Hongyi Zhou ,  Joseph Suriano

Inventor： Gregory O'Neil ,  Ali Acar ,  Paul Sybert ,  Pratima Rangarajan ,  Hongyi Zhou ,  Joseph Suriano

IPC: C08F20/00 ,  C08G63/19 ,  C08G63/193 ,  C08G63/40 ,  C08G63/64

CPC classification number: C08G63/64

Abstract: A method of preparing block copolyestercarbonates wherein at least one dihydroxy-substituted aromatic hydrocarbon moiety and at least one aromatic diacid chloride are reacted under interfacial conditions to give a hydroxy-terminated polyester intermediate. The dihydroxy-substituted aromatic compound is used in about 10 mole to about 125 mole percent excess relative to the diacid chloride. Enhanced control of hydroxy-terminated polyester intermediate molecular weight is achieved by limiting the amount of water present to provide a final salt level of greater than 30 percent. The final salt level is a theoretical value but is readily calculable. The hydroxy-terminated polyester intermediate is then converted to a block copolyestercarbonate by reaction with a carbonate precursor such as phosgene.

Abstract translation: 制备嵌段共聚酯碳酸酯的方法，其中至少一种二羟基取代的芳族烃部分和至少一种芳族二酰氯在界面条件下反应得到羟基封端的聚酯中间体。 二羟基取代的芳族化合物以相对于二酰氯为约10摩尔至约125摩尔％的过量使用。 羟基封端的聚酯中间体分子量的增强控制是通过限制存在的水量提供大于30％的最终盐水平来实现的。 最终的盐水平是理论值，但容易计算。 然后通过与诸如光气的碳酸酯前体反应将羟基封端的聚酯中间体转化成嵌段共聚酯碳酸酯。