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11.发明申请公开(公告)号：US20100028679A1
公开(公告)日：2010-02-04
申请号：US12576062
申请日：2009-10-08
申请人： Machteld M. Mertens , An Verberckmoes , Marcel J. Janssen , Yun Feng Chang , Luc R.M. Martens , Stephen Nell Vaughn , Kenneth Ray Clem , Wilfried J. Mortier
发明人： Machteld M. Mertens , An Verberckmoes , Marcel J. Janssen , Yun Feng Chang , Luc R.M. Martens , Stephen Nell Vaughn , Kenneth Ray Clem , Wilfried J. Mortier
CPC分类号： B01J29/85 , C01B39/54 , C07C1/20 , C07C2529/70 , C07C2529/85 , Y02P30/20 , Y02P30/42 , Y10S423/30 , Y10T428/2982 , C07C11/02
摘要： A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.
摘要翻译： 公开了一种硅铝磷酸盐分子筛，其包含CHA骨架型和AEI骨架型的第一和第二共生相，其中所述第一共生相的AEI / CHA比为约5/95至约40/60，如通过DIFFaX 分析中，第二共生相具有通过DIFFaX分析确定的约30/70至约的AEI / CHA比，并且所述分子筛具有约0.13至约0.24的二氧化硅与氧化铝的摩尔比（Si / Al 2）。
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12.发明授权Crystalline intergrowth material, its synthesis and its use in the conversion of oxygenates to olefins 有权结晶共生材料，其合成及其在含氧化合物转化为烯烃的应用公开(公告)号：US07622624B2
公开(公告)日：2009-11-24
申请号：US11072830
申请日：2005-03-04
申请人： Machteld M. Mertens , An Verberckmoes , Marcel J. Janssen , Yun Feng Chang , Luc R. M. Martens , Stephen Neil Vaughn , Kenneth Ray Clem , Wilfried J. Mortier
发明人： Machteld M. Mertens , An Verberckmoes , Marcel J. Janssen , Yun Feng Chang , Luc R. M. Martens , Stephen Neil Vaughn , Kenneth Ray Clem , Wilfried J. Mortier
CPC分类号： B01J29/85 , C01B39/54 , C07C1/20 , C07C2529/70 , C07C2529/85 , Y02P30/20 , Y02P30/42 , Y10S423/30 , Y10T428/2982 , C07C11/02
摘要： A silicoaluminophosphate molecular sieve is disclosed that comprises first and second intergrown phases of a CHA framework type and an AEI framework type, wherein said first intergrown phase has an AEI/CHA ratio of from about 5/95 to about 40/60 as determined by DIFFaX analysis, the second intergrown phase has an AEI/CHA ratio of about 30/70 to about 55/45 as determined by DIFFaX analysis and said molecular sieve has a silica to alumina molar ratio (Si/Al2) from about 0.13 to about 0.24.
摘要翻译： 公开了一种硅铝磷酸盐分子筛，其包含CHA骨架型和AEI骨架型的第一和第二共生相，其中所述第一共生相的AEI / CHA比为约5/95至约40/60，如通过DIFFaX 分析表明，第二共生相具有通过DIFFaX分析确定的约30/70至约55/45的AEI / CHA比，并且所述分子筛具有约0.13至约0.24的二氧化硅与氧化铝的摩尔比（Si / Al 2）。
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公开(公告)号：US06953767B2
公开(公告)日：2005-10-11
申请号：US10092792
申请日：2002-03-07
申请人： Marcel J. G. Janssen , An Verberckmoes , Machteld M. Mertens , Antonie Jan Bons , Wilfried J. Mortier
发明人： Marcel J. G. Janssen , An Verberckmoes , Machteld M. Mertens , Antonie Jan Bons , Wilfried J. Mortier
IPC分类号： B01J29/83 , B01J29/00 , B01J29/85 , B01J37/00 , B01J37/04 , B01J37/08 , C01B37/08 , C01B39/54 , C07B61/00 , C07C1/20 , C07C1/207 , C07C1/213 , C10G3/00 , C01B33/26 , B01J27/182 , C07C1/247
CPC分类号： B01J29/005 , B01J29/85 , B01J37/0009 , C01B37/08 , C01B39/54 , C07C1/20 , C10G3/49 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： The present invention relates to a silicoaluminophosphate molecular sieve comprising at least one intergrown phase of molecular sieves having AEI and CHA framework types, wherein said intergrown phase has an AEI/CHA ratio of from about 5/95 to 40/60 as determined by DIFFaX analysis, using the powder X-ray diffraction pattern of a calcined sample of said silicoaluminophosphate molecular sieve. It also relates to methods for its preparation and to its use in the catalytic conversion of methanol to olefins.
摘要翻译： 本发明涉及包含具有AEI和CHA骨架类型的分子筛的至少一个共生相的硅铝磷酸盐分子筛，其中所述共生相具有通过DIFFaX分析测定的约5/95至40/60的AEI / CHA比 ，使用所述硅铝磷酸盐分子筛的煅烧样品的粉末X射线衍射图。 它还涉及其制备方法及其在将甲醇催化转化成烯烃中的用途。
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公开(公告)号：US06008426A
公开(公告)日：1999-12-28
申请号：US89276
申请日：1998-06-02
CPC分类号： C07C5/2775 , B01J29/06 , B01J29/084 , B01J29/7007 , B01J29/85 , C07C2/08 , C07C2529/08 , C07C2529/40 , C07C2529/70 , C07C2529/85
摘要： The conversion of n-olefins, particularly n-butene, by skeletal isomerization, or by dimerization optionally with cracking, may be selectively carried out using as a catalyst a molecular sieve, such as a zeolite or silica/alumina phosphate, which has been ion exchanged with a cation to provide a Lewis acid site. No steam activation of the molecular sieve is required.
摘要翻译： 通过骨架异构化或通过任选裂化的二聚转化正烯烃，特别是正丁烯的转化可以使用已经离子的分子筛（例如沸石或二氧化硅/氧化铝/磷酸铝）作为催化剂选择性地进行 与阳离子交换以提供路易斯酸位点。 不需要分子筛的蒸汽活化。
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公开(公告)号：US20090023972A1
公开(公告)日：2009-01-22
申请号：US12163393
申请日：2008-06-27
申请人： Helge Jaensch , Wilfried J. Mortier
发明人： Helge Jaensch , Wilfried J. Mortier
CPC分类号： C07C5/48 , B01J23/34 , B01J23/688 , B01J35/002 , B01J37/03 , B01J37/30 , C01G45/00 , C01G45/02 , C01P2002/08 , C01P2002/72 , C01P2002/85 , C07B33/00 , C07C45/33 , C07C51/215 , C07C51/252 , C07C2523/34 , Y02P20/582 , C07C11/02 , C07C57/04
摘要： Catalytic structures are provided comprising octahedral tunnel lattice manganese oxides ion-exchanged with metal cations or mixtures thereof. The structures are useful as catalysts for the oxidation of alkanes and may be prepared by treating layered manganese oxide under highly acidic conditions, optionally drying the treated product, and subjecting it to ion exchange.
摘要翻译： 提供催化结构，其包括与金属阳离子或其混合物离子交换的八面体隧道晶格锰氧化物。 该结构可用作烷烃氧化的催化剂，并且可以通过在高度酸性条件下处理层状氧化锰，任选地干燥处理过的产品并进行离子交换来制备。
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公开(公告)号：US06979756B2
公开(公告)日：2005-12-27
申请号：US10281645
申请日：2002-10-28
申请人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert Edward Schweizer , Cornelius W. M. Van Oorschot , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
发明人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert Edward Schweizer , Cornelius W. M. Van Oorschot , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
CPC分类号： C01B39/02 , B01J29/04 , B01J29/85 , B01J37/084 , B01J2229/14 , B01J2229/24 , B01J2229/40 , B01J2229/42 , C01B37/00 , C07C1/20 , C07C2529/85 , C07C11/02
摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.
摘要翻译： 公开了分子筛热处理方法。 该方法包括提供含模板的分子筛，在有效从分子筛除去一部分模板的条件下加热分子筛，并冷却加热的分子筛，留下一定量的模板，以有效地覆盖分子内的催化位点 筛。 还提供了一种催化剂组合物，其包括具有微孔结构和粘合剂的分子筛，其中10至90体积％的微孔结构被材料占据，所述材料包含模板或模板的碳质残余物，以及 催化剂组合物的Davison指数不大于30。
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公开(公告)号：US06812372B2
公开(公告)日：2004-11-02
申请号：US09924016
申请日：2001-08-07
申请人： Marcel J. G. Janssen , An Verberckmoes , Machteld M. Mertens , Antonie Jan Bons , Wilfried J. Mortier
发明人： Marcel J. G. Janssen , An Verberckmoes , Machteld M. Mertens , Antonie Jan Bons , Wilfried J. Mortier
IPC分类号： B01J27182
CPC分类号： C01B39/54 , B01J29/005 , B01J29/85 , B01J37/0009 , C01B37/08 , C07C1/20 , C10G3/49 , C10G2400/20 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a silicoaluminophosphate molecular sieve comprising at least one intergrown phase of molecular sieves having AEI and CHA framework types, wherein said intergrown phase has an AEI/CHA ratio of from about 5/95 to 40/60 as determined by DIFFaX analysis, using the powder X-ray diffraction pattern of a calcined sample of said silicoaluminophosphate molecular sieve. It also relates to methods for its preparation and to its use in the catalytic conversion of methanol to olefins.
摘要翻译： 本发明涉及包含具有AEI和CHA骨架类型的分子筛的至少一个共生相的硅铝磷酸盐分子筛，其中所述共生相具有通过DIFFaX分析测定的约5/95至40/60的AEI / CHA比 ，使用所述硅铝磷酸盐分子筛的煅烧样品的粉末X射线衍射图。 它还涉及其制备方法及其在将甲醇催化转化成烯烃中的用途。
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公开(公告)号：US06797852B2
公开(公告)日：2004-09-28
申请号：US10206574
申请日：2002-07-26
申请人： Marcel J. G. Janssen , Cornelius W. M. Van Oorschot , Shun C. Fung , Luc R. M. Martens , Wilfried J. Mortier , Ronald G. Searle , Machteld M. Mertens , Stephen N. Vaughn
发明人： Marcel J. G. Janssen , Cornelius W. M. Van Oorschot , Shun C. Fung , Luc R. M. Martens , Wilfried J. Mortier , Ronald G. Searle , Machteld M. Mertens , Stephen N. Vaughn
IPC分类号： C07C100
CPC分类号： B01J29/85 , B01J37/08 , B01J2229/24 , B01J2229/40 , B23K1/002 , B23K2101/06 , C07C1/20 , C07C2529/85 , Y02P30/20 , Y10S502/514 , Y10S585/906 , C07C11/02
摘要： This invention is directed to a method of making an olefin product from an oxygenate feedstock and a method of protecting catalytic activity of a silicoaluminophosphate molecular sieve. The methods comprise providing a silicoaluminophosphate molecular sieve having catalytic sites within the molecular sieve; shielding the catalytic sites to protect from loss of catalytic activity; and contacting the protected sieve in its activated state with an oxygenate feedstock under conditions effective to produce an olefin product before undesirable loss of catalytic activity. Undesirable loss in catalytic activity occurs when activated molecular sieve contacting the oxygenate feedstock has a methanol uptake index of at least 0.15.
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公开(公告)号：US06395674B1
公开(公告)日：2002-05-28
申请号：US09399675
申请日：1999-09-21
申请人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert E. Schweizer , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
发明人： Shun C. Fung , Marcel J. G. Janssen , Stephen N. Vaughn , Machteld M. Mertens , Albert E. Schweizer , Luc R. M. Martens , Richard B. Hall , Wilfried J. Mortier , Ronald G. Searle , Yi-Gang Xiong
IPC分类号： B01J27182
CPC分类号： C01B39/02 , B01J29/04 , B01J29/85 , B01J37/084 , B01J2229/14 , B01J2229/24 , B01J2229/40 , B01J2229/42 , C01B37/00 , C07C1/20 , C07C2529/85 , C07C11/02
摘要： Disclosed is a method of heat treating a molecular sieve. The method comprises providing a template-containing molecular sieve, heating the molecular sieve under conditions effective to remove a portion of the template from the molecular sieve, and cooling the heated molecular sieve to leave an amount of template effective to cover catalytic sites within the molecular sieve. A catalyst composition is also provided which comprises a molecular sieve having a microporous structure and a binder, wherein between 10 and 90 vol % of the microporous structure is occupied by a material, the material comprising a template or a carbonaceous residue of a template, and the catalyst composition exhibits a Davison Index of not greater than 30.
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公开(公告)号：US20090042723A1
公开(公告)日：2009-02-12
申请号：US12012693
申请日：2008-02-05
CPC分类号： B01J27/0576 , B01J23/002 , B01J23/28 , B01J35/002 , B01J37/0236 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C57/04 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68
摘要： A process for preparing a mixed metal oxide catalyst. The process includes the steps of admixing metal compounds, at least one of which is an oxygen containing compound, and at least one solvent to form a solution, removing the solvent from the solution to obtain a catalyst precursor, calcining the catalyst precursor at a temperature from about 350° C. to about 850° C. under a gaseous atmosphere comprising CO2, and forming a mixed-metal oxide catalyst. A process for reducing the formation of tellurium metal in a mixed metal oxide catalyst including tellurium is also provided.
摘要翻译： 一种制备混合金属氧化物催化剂的方法。 该方法包括以下步骤：将金属化合物（其中至少一种是含氧化合物）和至少一种溶剂混合以形成溶液，从溶液中除去溶剂以获得催化剂前体，在温度下煅烧催化剂前体 在约350℃至约850℃的CO 2气氛下，形成混合金属氧化物催化剂。 还提供了一种减少包含碲的混合金属氧化物催化剂中碲金属形成的方法。
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