公开(公告)号：US09162218B2

公开(公告)日：2015-10-20

申请号：US14598809

申请日：2015-01-16

Applicant: BASF Corporation

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/06 ,  B01J29/80 ,  B01D53/94 ,  B01J23/42 ,  B01J23/89 ,  B01J29/072 ,  B01J29/72 ,  B01J29/76 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  B01J29/74 ,  B01D53/86 ,  C01B39/46

CPC classification number: B01J29/723 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9431 ,  B01D53/9477 ,  B01D2251/206 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9032 ,  B01D2255/904 ,  B01D2255/9155 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2258/012 ,  B01J23/42 ,  B01J23/8926 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0246 ,  B01J2029/062 ,  C01B39/46 ,  Y02T10/24 ,  Y10T428/24149

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

公开(公告)号：US20130195731A1

公开(公告)日：2013-08-01

申请号：US13790973

申请日：2013-03-08

Applicant: BASF Corporation

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/72 ,  B01D53/94

CPC classification number: B01J29/723 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9431 ,  B01D53/9477 ,  B01D2251/206 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9032 ,  B01D2255/904 ,  B01D2255/9155 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2258/012 ,  B01J23/42 ,  B01J23/8926 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0246 ,  B01J2029/062 ,  C01B39/46 ,  Y02T10/24 ,  Y10T428/24149

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25: 1 to about 1:1.

公开(公告)号：US20240226862A9

公开(公告)日：2024-07-11

申请号：US18277908

申请日：2022-02-18

Applicant: BASF CORPORATION

Inventor： Jia Di Zhang ,  Wen-Mei Xue ,  Xiaofan Yang ,  Weiyong Tang ,  Burcu Bayram ,  Yu Fen Hao

IPC: B01J29/76 ,  B01D53/94 ,  B01J23/42 ,  B01J29/90 ,  B01J35/57 ,  B01J35/61 ,  B01J35/77 ,  B01J37/00 ,  B01J37/02 ,  B01J38/12 ,  F01N3/20 ,  F01N3/28

CPC classification number: B01J29/763 ,  B01D53/9418 ,  B01D53/944 ,  B01J23/42 ,  B01J29/90 ,  B01J35/57 ,  B01J35/612 ,  B01J35/77 ,  B01J37/0036 ,  B01J37/0215 ,  B01J38/12 ,  F01N3/2066 ,  F01N3/2803 ,  B01D2255/1021 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9155 ,  B01D2257/404 ,  B01D2258/012 ,  B01J2229/186 ,  F01N2370/04

Abstract: The present invention relates to a SCR catalytic article, comprising —a substrate and —a copper-containing small pore zeolite, having a crystal structure characterized by a decrease of unit cell volume upon sulfurization and desulfurization of less than Å3 as determined by an X-ray powder diffraction, wherein the sulfurization and desulfurization are carried out in accordance with the processes as described in the specification, and to an exhaust treatment system comprising the same. The present invention also relates to a method for determining whether a metal-promoted small pore zeolite is resistant to irreversible sulfur poisoning and a method for evaluating whether a metal-promoted small pore zeolite is qualified for resistance to irreversible sulfur poisoning.

公开(公告)号：US20240131498A1

公开(公告)日：2024-04-25

申请号：US18277908

申请日：2022-02-18

Applicant: BASF CORPORATION

Inventor： Jia Di Zhang ,  Wen-Mei Xue ,  Xiaofan Yang ,  Weiyong Tang ,  Burcu Bayram ,  Yu Fen Hao

IPC: B01J29/76 ,  B01D53/94 ,  B01J23/42 ,  B01J29/90 ,  B01J35/57 ,  B01J35/61 ,  B01J35/77 ,  B01J37/00 ,  B01J37/02 ,  B01J38/12 ,  F01N3/20 ,  F01N3/28

CPC classification number: B01J29/763 ,  B01D53/9418 ,  B01D53/944 ,  B01J23/42 ,  B01J29/90 ,  B01J35/57 ,  B01J35/612 ,  B01J35/77 ,  B01J37/0036 ,  B01J37/0215 ,  B01J38/12 ,  F01N3/2066 ,  F01N3/2803 ,  B01D2255/1021 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9155 ,  B01D2257/404 ,  B01D2258/012 ,  B01J2229/186 ,  F01N2370/04

Abstract: The present invention relates to a SCR catalytic article, comprising —a substrate and —a copper-containing small pore zeolite, having a crystal structure characterized by a decrease of unit cell volume upon sulfurization and desulfurization of less than Å3 as determined by an X-ray powder diffraction, wherein the sulfurization and desulfurization are carried out in accordance with the processes as described in the specification, and to an exhaust treatment system comprising the same. The present invention also relates to a method for determining whether a metal-promoted small pore zeolite is resistant to irreversible sulfur poisoning and a method for evaluating whether a metal-promoted small pore zeolite is qualified for resistance to irreversible sulfur poisoning.

公开(公告)号：US20240091751A1

公开(公告)日：2024-03-21

申请号：US18513785

申请日：2023-11-20

Applicant: BASF Corporation

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/72 ,  B01D53/56 ,  B01D53/86 ,  B01D53/94 ,  B01J23/42 ,  B01J23/89 ,  B01J29/06 ,  B01J29/068 ,  B01J29/072 ,  B01J29/74 ,  B01J29/76 ,  B01J29/80 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  C01B39/46

CPC classification number: B01J29/723 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9431 ,  B01D53/9477 ,  B01J23/42 ,  B01J23/8926 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0246 ,  C01B39/46 ,  B01D2251/206 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/903 ,  B01D2255/9032 ,  B01D2255/904 ,  B01D2255/9155 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2258/012 ,  B01J2029/062 ,  Y02C20/10 ,  Y02T10/12 ,  Y10T428/24149

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stability at high-reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica-to-alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

公开(公告)号：US11845067B2

公开(公告)日：2023-12-19

申请号：US18055708

申请日：2022-11-15

Applicant: BASF Corporation

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/72 ,  B01J29/068 ,  B01D53/56 ,  B01D53/94 ,  B01J23/42 ,  B01J23/89 ,  B01J29/072 ,  B01J29/76 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  B01J29/74 ,  B01D53/86 ,  B01J29/06 ,  B01J29/80 ,  C01B39/46

CPC classification number: B01J29/723 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9431 ,  B01D53/9477 ,  B01J23/42 ,  B01J23/8926 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0246 ,  C01B39/46 ,  B01D2251/206 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/903 ,  B01D2255/904 ,  B01D2255/9032 ,  B01D2255/9155 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2258/012 ,  B01J2029/062 ,  Y02C20/10 ,  Y02T10/12 ,  Y10T428/24149

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

公开(公告)号：US10450918B2

公开(公告)日：2019-10-22

申请号：US15735509

申请日：2016-06-10

Applicant: BASF Corporation

Inventor： Wen-Mei Xue ,  John K. Hochmuth

IPC: F01N3/10 ,  F01N3/20 ,  B01J23/44 ,  F01N13/00

Abstract: Described are exhaust gas treatment systems for treatment of a gasoline engine exhaust gas stream. The exhaust gas treatment systems comprise an ammonia generating and hydrocarbon oxidation catalyst, a TWC catalyst, and an ammonia selective catalytic reduction (SCR) catalyst downstream of the TWC catalyst. The ammonia generating and hydrocarbon oxidation catalyst comprises a refractory metal oxide support, a platinum component, and a palladium component. The ammonia generating and hydrocarbon oxidation catalyst is substantially free of ceria and substantially free of NOx storage components. The platinum and palladium components are present in a platinum to palladium ratio of greater than about 1 to 1.

公开(公告)号：US20180163597A1

公开(公告)日：2018-06-14

申请号：US15735491

申请日：2016-06-10

Applicant: BASF Corporation

Inventor： Wen-Mei Xue ,  John K. Hochmuth

IPC: F01N3/28 ,  F01N3/20 ,  F01N3/08 ,  C01C1/02 ,  B01J23/42 ,  B01J23/44 ,  B01J35/04 ,  B01J23/02 ,  B01D53/94

CPC classification number: F01N3/2803 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/945 ,  B01D53/9472 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2042 ,  B01D2255/9032 ,  B01D2255/91 ,  B01D2255/9155 ,  B01J23/02 ,  B01J23/42 ,  B01J23/44 ,  B01J35/04 ,  C01C1/02 ,  F01N3/0814 ,  F01N3/0842 ,  F01N3/2066 ,  F01N3/2073 ,  F01N2240/25 ,  F01N2510/0682 ,  F01N2510/0684 ,  F01N2570/14 ,  F01N2610/02 ,  Y02T10/24

Abstract: Described are exhaust gas treatment systems for treatment of a gasoline engine exhaust gas stream. The exhaust gas treatment systems comprise an ammonia generating catalyst and an ammonia selective catalytic reduction (SCR) catalyst downstream of the ammonia generating catalyst. The ammonia generating catalyst comprises a NOx storage component, a refractory metal oxide support, a platinum component, and a palladium component. The ammonia generating catalyst is substantially free of ceria. The platinum and palladium components are present in a platinum to palladium ratio of greater than about 1 to 1.

公开(公告)号：US20180038252A1

公开(公告)日：2018-02-08

申请号：US15555117

申请日：2016-03-24

Applicant: BASF CORPORATION

Inventor： Xiaofan Yang ,  Wen-Mei Xue ,  John K. Hochmuth ,  Matthew J. Schladt ,  Yuejin Li

IPC: F01N3/08 ,  B01J23/46 ,  B01J29/76 ,  B01J35/00 ,  F01N13/00 ,  B01D53/94 ,  F01N3/10 ,  F01N3/20 ,  F01N3/035 ,  B01J23/44 ,  B01J35/04

CPC classification number: F01N3/0814 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/944 ,  B01D53/9445 ,  B01D53/945 ,  B01D53/9463 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/904 ,  B01D2255/9155 ,  B01D2258/014 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J29/04 ,  B01J29/072 ,  B01J29/763 ,  B01J35/0006 ,  B01J35/04 ,  F01N3/035 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/101 ,  F01N3/2066 ,  F01N13/0093 ,  F01N13/0097 ,  F01N2370/02 ,  Y02T10/22 ,  Y02T10/24

Abstract: Described are exhaust gas treatment systems for treatment of a gasoline engine exhaust gas stream containing NOx, particulate matter, and sulfur. The exhaust gas treatment system comprises: one or more catalytic articles selected from a three-way conversion catalyst (TWC), a lean NOx trap (LNT), and an integrated LNT-TWC; a platinum-containing catalytic article downstream from the one or more catalytic articles; and one or more selective catalytic reduction (SCR) catalytic articles immediately downstream from the platinum-containing catalytic article, the one or more SCR catalytic articles including a molecular sieve. The system stabilizes the SCR catalytic article from poisoning by sulfur.

公开(公告)号：US20150266014A1

公开(公告)日：2015-09-24

申请号：US14658486

申请日：2015-03-16

Applicant: BASF Corporation

Inventor： Wen-Mei Xue ,  Attilio Siani ,  John K. Hochmuth ,  Markus Kinne ,  Stefan Kielbassa

IPC: B01J35/00 ,  B01J23/63 ,  B01J23/40 ,  F01N13/00 ,  B01J23/46 ,  B01J23/652 ,  B01J37/02 ,  B01D53/94 ,  B01J23/44

CPC classification number: B01J35/0006 ,  B01D53/9422 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2042 ,  B01D2255/2047 ,  B01D2255/2065 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/908 ,  B01D2255/91 ,  B01D2258/012 ,  B01J21/04 ,  B01J21/066 ,  B01J23/63 ,  B01J35/002 ,  B01J35/04 ,  B01J37/0244 ,  B01J37/0248 ,  F01N3/0842 ,  F01N3/2828 ,  F01N2510/0684 ,  Y02T10/22 ,  Y02T10/24

Abstract: A layered catalyst composite for the treatment of exhaust gas emissions, effective to provide lean NOx trap functionality and three-way conversion functionality is described. Layered catalyst composites can comprise catalytic material on a substrate, the catalytic material comprising at least two layers. The first layer comprising rare earth oxide-high surface area refractory metal oxide particles, an alkaline earth metal supported on the rare earth oxide-high surface area refractory metal oxide particles, and at least one first platinum group metal component supported on the rare earth oxide-high surface area refractory metal oxide particles. The second layer comprising a second platinum group metal component supported on a first oxygen storage component (OSC) and/or a first refractory metal oxide support and, optionally, a third platinum group metal supported on a second refractory metal oxide support or a second oxygen storage component.

Abstract translation: 描述了用于处理废气排放的层状催化剂复合材料，其有效提供贫NOx捕集功能和三向转化功能。 层状催化剂复合材料可以在基材上包含催化材料，催化材料包含至少两层。 第一层包括稀土氧化物高表面积难熔金属氧化物颗粒，负载在稀土氧化物高表面积难熔金属氧化物颗粒上的碱土金属和负载在稀土氧化物上的至少一种第一铂族金属组分 - 高表面积难熔金属氧化物颗粒。 第二层包括负载在第一储氧组分（OSC）和/或第一难熔金属氧化物载体上的第二铂族金属组分和任选地载于第二难熔金属氧化物载体上的第三铂族金属或第二氧 存储组件。