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公开(公告)号:US20160101642A1
公开(公告)日:2016-04-14
申请号:US14891528
申请日:2014-05-16
Applicant: BASF SE
Inventor: Michelle RICHERT , Oliver SEEGER , Nikolay A. GRIGORENKO
IPC: B42D25/29 , C08K3/08 , B42D25/328 , B42D25/364 , B42D25/373 , C09D101/18 , B41M3/14
CPC classification number: B42D25/29 , B41M3/14 , B41M3/148 , B42D25/328 , B42D25/364 , B42D25/373 , C08K3/08 , C08K2003/0806 , C09D5/00 , C09D5/29 , C09D101/18
Abstract: The present invention relates to complex security elements based on liquid crystal coatings which are subsequently coated with specific metallic nano-shaped metal particles, a method for their manufacture, in particular on a glass, paper or on a plastic substrate and a security product obtainable using the security element. The security element may contain additionally an embossed surface relief microstructure, especially an optically variable image (an optically variable device, OVD), such as a hologram. A further aspect of the invention is the use of such a security element for the prevention of counterfeit or reproduction of a document of value.
Abstract translation: 本发明涉及基于液晶涂层的复杂安全元件,其随后涂覆有特定的金属纳米金属颗粒,其制造方法,特别是在玻璃,纸或塑料基材上的方法,以及可使用 安全元素。 安全元件还可另外包含压花表面浮雕微结构,特别是光学可变图像(光学可变器件,OVD),例如全息图。 本发明的另一方面是使用这种安全元件来防止伪造或复制有价值的文件。
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公开(公告)号:US20150137504A1
公开(公告)日:2015-05-21
申请号:US14578657
申请日:2014-12-22
Applicant: BASF SE
Inventor: Michelle RICHERT , Thomas BOLLE , Roland FLEURY
IPC: B42D25/405 , B05D3/06 , B42D25/30
CPC classification number: B42D25/405 , B05D3/067 , B41M1/24 , B41M3/06 , B41M3/148 , B41M7/00 , B41M7/0081 , B42D25/21 , B42D25/23 , B42D25/24 , B42D25/29 , B42D25/30 , B42D25/324 , B42D25/328 , B42D25/373 , B42D25/42 , B42D25/425 , B42D2033/10 , B42D2033/30 , G03H1/028 , G03H2001/185 , G03H2250/36 , G03H2270/12
Abstract: A method and an apparatus for forming a surface relief microstructure, especially an optically variable image on a paper substrate are provided, the method comprising the steps of: A) applying a curable composition to at least a portion of the frontside of the paper substrate; B) contacting at least a portion of the curable composition with surface relief microstructure, especially optically variable image forming means; C) curing the composition by using at least one UV lamp (1, 2, 3) which is arranged on the backside of the paper substrate; D) optionally depositing a layer of a transparent high refractive index material and/or a metallic layer on at least a portion of the cured composition, wherein the lamp (1, 2, 3) having emission peak(s) in the UV-A and near VIS range and the curable composition comprises at least a photoinitiator which absorbs in the UV-A region and preferably in the near VIS range. A paper product obtainable uses the method and an apparatus for forming a surface relief microstructure on a paper substrate. Surface relief microstructures, such as holograms may be replicated rapidly and with accuracy on a paper substrate by using the method and the apparatus.
Abstract translation: 提供一种用于形成表面浮雕微结构,特别是在纸基材上的光学可变图像的方法和装置,所述方法包括以下步骤:A)将可固化组合物施加到纸基材的前侧的至少一部分; B)使可固化组合物的至少一部分与表面浮雕微结构接触,特别是光学上可变的成像装置; C)通过使用布置在纸基材的背面上的至少一个UV灯(1,2,3)来固化组合物; D)任选地在所述固化组合物的至少一部分上沉积透明高折射率材料和/或金属层的层,其中在所述UV-A中具有发射峰的灯(1,2,3) 并且接近VIS范围,并且可固化组合物至少包含在UV-A区域中吸收的光引发剂,优选在接近VIS范围内。 可获得的纸制品使用在纸基材上形成表面浮雕微结构的方法和装置。 通过使用该方法和装置,诸如全息图之类的表面浮雕微结构可以在纸基材上快速且准确地复制。
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公开(公告)号:US20220088957A1
公开(公告)日:2022-03-24
申请号:US17424607
申请日:2020-01-20
Applicant: BASF SE
Inventor: Nikolay A. GRIGORENKO , Michelle RICHERT
IPC: B42D25/373 , B42D25/382 , B42D25/45 , C09D11/037 , C09D11/033 , C09D11/14
Abstract: The present invention relates to security elements, comprising (a) a substrate, (b) on at least part of the substrate surface a metal layer, (c) optionally on at least part of the metal layer a dielectric layer, (d) on at least part of the metal layer, or the dielectric layer, a layer obtained by overcoating the metal layer, or the dielectric layer with a composition, comprising (i) silver nanoparticles, (ii) a solvent, (iii) (surface) stabilizing agent(s) and (iv) optionally a binder, and (e) a protective layer on top of layer (d). The maximum absorption wavelength of the silver nanoparticles in layer (d) is controlled by the amount of (surface) stabilizing agent(s) and optionally binder relative to the amount of silver nanoparticles to be preferably in the range of 700 to 1600 nm.
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公开(公告)号:US20210171786A1
公开(公告)日:2021-06-10
申请号:US16613714
申请日:2018-05-07
Applicant: BASF SE
Inventor: Nikolay A GRIGORENKO , Michelle RICHERT
IPC: C09D5/36 , C09D7/40 , C09D7/61 , C09D161/12 , C09D7/20 , C09D11/50 , C09D11/037 , C09D11/103 , C09D11/101 , C09D11/033 , B42D25/373 , B42D25/378 , B44F1/08 , B22F1/00 , B22F9/24 , B41M3/14 , B41M7/00
Abstract: The present invention relates to a process for the preparation of thin silver nanoparticle layers, which are produced directly on a substrate as part of a coating or printing process. The layers show different colours in transmittance and reflectance. The layers do not show the typical conductivity of metallic layers, since the particles are essentially discrete particles which are not sintered. The invention further relates to decorative and security elements. When the layers are applied over a security element, such as a hologram, the obtained products show also different colours in reflection and transmission, an extremely bright optically variable image (OVD image) and high purity and contrast. Depending on the thickness of the layer a more or less intensive metallic aspect appears.
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公开(公告)号:US20190232711A1
公开(公告)日:2019-08-01
申请号:US16376756
申请日:2019-04-05
Applicant: BASF SE
Inventor: Michelle RICHERT , Thomas BOLLE , Roland FLEURY
IPC: B42D25/405 , B42D25/24 , B42D25/21 , B41M7/00 , B41M3/14 , G03H1/02 , B42D25/30 , B05D3/06 , B42D25/42 , B42D25/373 , B42D25/23 , B42D25/328 , B42D25/29 , B42D25/425
CPC classification number: B42D25/405 , B05D3/067 , B41M1/24 , B41M3/06 , B41M3/148 , B41M7/00 , B41M7/0081 , B42D25/21 , B42D25/23 , B42D25/24 , B42D25/29 , B42D25/30 , B42D25/324 , B42D25/328 , B42D25/373 , B42D25/42 , B42D25/425 , B42D2033/10 , B42D2033/30 , G03H1/028 , G03H2001/185 , G03H2250/36 , G03H2270/12
Abstract: Disclosed herein is a method for forming a surface relief microstructure, including the steps of A) applying a curable composition to at least a portion of the frontside of the paper substrate, B) contacting at least a portion of the curable composition with surface relief microstructure, C) curing the composition by using at least one UV lamp which is arranged on the backside of the paper substrate, and D) depositing a metallic layer, and optionally a layer of a transparent high refractive index material, on at least a portion of the cured composition, wherein the UV lamp has an emission peak in a UV-A range of 320 nm to 400 nm and additionally in a near VIS range of 400 nm to 450 nm, the curable composition comprises a photoinitiator which absorbs in the UV-A range and also in the near VIS range.
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16.
公开(公告)号:US20170028764A1
公开(公告)日:2017-02-02
申请号:US15292889
申请日:2016-10-13
Applicant: BASF SE
Inventor: Michelle RICHERT , Roland FLEURY , Nikolay A. GRIGORENKO
IPC: B42D25/405 , B42D25/328 , B41F17/00 , C09D7/12 , G03H1/02 , G03H1/04 , C09D5/38 , C09D5/29 , B42D25/29 , G03H1/00
CPC classification number: B42D25/405 , B29C35/0888 , B29C35/10 , B29C59/046 , B29C2035/0827 , B29C2059/023 , B41F17/00 , B41M1/24 , B41M3/003 , B41M3/006 , B41M3/14 , B41M3/148 , B42D25/29 , B42D25/30 , B42D25/324 , B42D25/328 , B42D25/351 , B42D25/36 , B42D25/42 , B42D25/425 , B42D2035/20 , C09D5/29 , C09D5/36 , C09D5/38 , C09D7/67 , C09D7/68 , C09D7/70 , G03H1/0011 , G03H1/0244 , G03H1/028 , G03H1/04 , G03H2250/43 , G03H2270/32
Abstract: The present invention relates to a method for forming a surface relief microstructure, especially an optically variable image (an optically variable device) on a transparent or translucent substrate and a product obtainable using the method. A further aspect of the invention is the use for the prevention of counterfeit or reproduction of a document of value and a method of forming a coating showing an angle dependent color change.
Abstract translation: 本发明涉及一种用于形成表面浮雕微结构的方法,特别是在透明或半透明基底上的光学可变图像(光学可变装置)和可使用该方法获得的产品。 本发明的另一方面是用于防止有价值的文件的伪造或再现的用途以及形成依赖于角度的颜色变化的涂层的方法。
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公开(公告)号:US20160230339A1
公开(公告)日:2016-08-11
申请号:US15022107
申请日:2014-10-01
Applicant: BASF SE
Inventor: Michelle RICHERT , Thomas BOLLE , Roland FLEURY
CPC classification number: D21H19/16 , C23C14/22 , D21H19/06 , D21H19/08 , D21H19/20 , D21H19/22 , D21H19/82 , D21H25/04 , D21H27/26
Abstract: The instant invention pertains to a method for the production of brilliant glossy metal coatings on paper substrates. Further aspects of the invention are a paper product obtainable using the method and the use of such a paper for decorative or packaging purposes.
Abstract translation: 本发明涉及在纸基材上生产光亮金属涂层的方法。 本发明的其它方面是使用该方法可获得的纸制品以及用于装饰或包装目的的这种纸的使用。
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