公开(公告)号：US07829652B2

公开(公告)日：2010-11-09

申请号：US12183488

申请日：2008-07-31

申请人： Joyce Hung ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  David Roger Moore ,  Joshua James Stone ,  Hongyi Zhou ,  Joseph Anthony Suriano

发明人： Joyce Hung ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  David Roger Moore ,  Joshua James Stone ,  Hongyi Zhou ,  Joseph Anthony Suriano

IPC分类号： C08G2/00

CPC分类号： C08F283/08 ,  C08F283/06 ,  C08G65/4075 ,  C08G65/48 ,  C08G75/23 ,  C08G81/00 ,  C08G2650/40 ,  C08J5/2256 ,  C08J2371/12 ,  C08J2381/06 ,  C08J2387/00 ,  C08L51/08 ,  C08L53/00 ,  C08L71/00 ,  C08L81/06 ,  C08L2205/05 ,  H01M8/1025 ,  H01M8/1027 ,  H01M2300/0082 ,  C08L2666/02 ,  C08L81/00 ,  C08L2666/22

摘要： A composition including a polyarylether copolymer is provided. The copolymer includes a polyarylether backbone; and a sulfonated oligomeric group bonded to the polyarylether suitable for use as a cation conducting membrane. Method of bonding a sulfonated oligomeric group to the polyarylether backbone to form a polyarylether copolymer. The membrane may be formed from the polyarylether copolymer composition. The chain length of the sulfonated oligomeric group may be controlled to affect or control the ion conductivity of the membrane.

摘要翻译： 提供了包含聚芳醚基共聚物的组合物。 共聚物包括聚芳醚基骨架; 和与适合用作阳离子导电膜的聚芳醚结合的磺化低聚基团。 将磺化低聚基团键合到聚芳醚基骨架以形成聚芳醚基共聚物的方法。 膜可以由聚芳醚醚共聚物组合物形成。 可以控制磺化低聚基团的链长度以影响或控制膜的离子传导性。

公开(公告)号：US20100029864A1

公开(公告)日：2010-02-04

申请号：US12183488

申请日：2008-07-31

申请人： Joyce Hung ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  David Roger Moore ,  Joshua James Stone ,  Hongyi Zhou ,  Joseph Anthony Suriano

发明人： Joyce Hung ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  David Roger Moore ,  Joshua James Stone ,  Hongyi Zhou ,  Joseph Anthony Suriano

IPC分类号： C08F283/06

CPC分类号： C08F283/08 ,  C08F283/06 ,  C08G65/4075 ,  C08G65/48 ,  C08G75/23 ,  C08G81/00 ,  C08G2650/40 ,  C08J5/2256 ,  C08J2371/12 ,  C08J2381/06 ,  C08J2387/00 ,  C08L51/08 ,  C08L53/00 ,  C08L71/00 ,  C08L81/06 ,  C08L2205/05 ,  H01M8/1025 ,  H01M8/1027 ,  H01M2300/0082 ,  C08L2666/02 ,  C08L81/00 ,  C08L2666/22

摘要： A composition including a polyarylether copolymer is provided. The copolymer includes a polyarylether backbone; and a sulfonated oligomeric group bonded to the polyarylether suitable for use as a cation conducting membrane. Method of bonding a sulfonated oligomeric group to the polyarylether backbone to form a polyarylether copolymer. The membrane may be formed from the polyarylether copolymer composition. The chain length of the sulfonated oligomeric group may be controlled to affect or control the ion conductivity of the membrane.

摘要翻译： 提供了包含聚芳醚基共聚物的组合物。 共聚物包括聚芳醚基骨架; 和与适合用作阳离子导电膜的聚芳醚结合的磺化低聚基团。 将磺化低聚基团键合到聚芳醚基骨架以形成聚芳醚基共聚物的方法。 膜可以由聚芳醚醚共聚物组合物形成。 可以控制磺化低聚基团的链长度以影响或控制膜的离子传导性。

公开(公告)号：US06306507B1

公开(公告)日：2001-10-23

申请号：US09368706

申请日：1999-08-05

申请人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Tiberiu Mircea Siclovan ,  James Edward Pickett

发明人： Daniel Joseph Brunelle ,  Joseph Anthony Suriano ,  Tiberiu Mircea Siclovan ,  James Edward Pickett

IPC分类号： B32B2708

CPC分类号： B32B27/08 ,  B32B27/06 ,  B32B27/18 ,  B32B27/20 ,  B32B27/36 ,  B32B27/365 ,  B32B2307/4026 ,  B32B2367/00 ,  B32B2369/00 ,  B32B2605/00 ,  C08G63/19 ,  C08G63/64 ,  C08G63/676 ,  C08G63/6956 ,  C08G63/79 ,  C08G63/85 ,  C08J7/047 ,  C08J2467/00 ,  C09D167/03 ,  F02B61/045 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/2942 ,  Y10T428/31507 ,  Y10T428/31565 ,  Y10T428/31786

摘要： Thermally stable polymers comprising resorcinol arylate chain members are prepared using an interfacial method comprising the steps of: (a) combining at least one resorcinol moiety and at least one catalyst in a mixture of water and at least one organic solvent substantially immiscible with water; and (b) adding to the mixture from (a) at least one dicarboxylic acid dichloride while maintaining the pH between 3 and 8.5 through the presence of an acid acceptor, wherein the total molar amount of acid chloride groups is stoichiometrically deficient relative to the total molar amount of phenolic groups.

摘要翻译： 包含间苯二酚芳基化物链成员的热稳定聚合物使用界面方法制备，包括以下步骤：（a）将至少一种间苯二酚部分和至少一种与水和至少一种与水不混溶的有机溶剂的混合物的催化剂混合; 和（b）通过酸受体的存在，将（a）至少一种二羧酸二氯化物同时保持pH在3至8.5之间来加入到混合物中，其中酰氯基团的总摩尔量相对于总计的化学计量缺乏 酚基摩尔量。

公开(公告)号：US20090163692A1

公开(公告)日：2009-06-25

申请号：US11962627

申请日：2007-12-21

申请人： David Roger Moore ,  Gary William Yeager ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  Joyce Hung ,  Joseph Anthony Suriano ,  Hongyi Zhou

发明人： David Roger Moore ,  Gary William Yeager ,  Daniel Joseph Brunelle ,  Marianne Elisabeth Harmon ,  Joyce Hung ,  Joseph Anthony Suriano ,  Hongyi Zhou

IPC分类号： C08G75/02

CPC分类号： C08G65/40 ,  C07C317/14 ,  C07C317/22 ,  C07C317/44 ,  C08G65/4006 ,  C08G75/23

摘要： An aromatic polyether comprising structural units derived from a halosulfone sulfonate having structure (I): wherein R1 is a C3-C25 aromatic radical, a C3-C25 cycloaliphatic radical, or a C1-C10 aliphatic radical; M is hydrogen or a charge balancing cation; Y1 is independently at each occurrence a halogen; “t” is an integer having a value of 1 or 2; “s” is an integer having a value 0 to 3, “b” is an integer having a value 1 to 4; and “c” is an integer having a value 1 to 20. Also provided are methods of preparing the aromatic polyethers, and compositions including the aromatic polyethers.

摘要翻译： 包含衍生自具有结构（I）的卤代磺酸盐的结构单元的芳族聚醚：其中R1是C3-C25芳族基团，C3-C25脂环族基团或C1-C10脂族基团; M是氢或电荷平衡阳离子; Y1在每次出现时独立地为卤素; “t”是1或2的整数; “s”为0〜3的整数，b为1〜4的整数， “c”是1至20的整数。还提供了制备芳族聚醚的方法和包括芳族聚醚的组合物。

公开(公告)号：US06559270B1

公开(公告)日：2003-05-06

申请号：US09416529

申请日：1999-10-12

申请人： Tiberiu Mircea Siclovan ,  Jimmy Lynn Webb ,  Sterling Bruce Brown ,  Donald Joseph Buckley, Jr. ,  James Edward Pickett ,  Joseph Anthony Suriano ,  Paul Dean Sybert ,  Daniel Joseph Brunelle ,  Margaret Louise Blohm ,  Hongyi Zhou ,  Georgia Dris Fishburn

发明人： Tiberiu Mircea Siclovan ,  Jimmy Lynn Webb ,  Sterling Bruce Brown ,  Donald Joseph Buckley, Jr. ,  James Edward Pickett ,  Joseph Anthony Suriano ,  Paul Dean Sybert ,  Daniel Joseph Brunelle ,  Margaret Louise Blohm ,  Hongyi Zhou ,  Georgia Dris Fishburn

IPC分类号： C08G6401

CPC分类号： C08L67/00 ,  C08G63/64 ,  C08G63/78 ,  C08G64/18 ,  C08G2261/126 ,  C08K3/013 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L69/005 ,  C08L79/08 ,  F02B61/045

摘要： Block copolyestercarbonates may be prepared by first conducting a reaction between at least one of resorcinol or an alkyl- or haloresorcinol and at least one aromatic dicarboxylic acid dichloride, preferably isophthaloyl dichloride, terephthaloyl dichloride or a mixture thereof, to produce a hydroxy-terminated polyester intermediate, and then conducting a reaction of the intermediate with a carbonate precursor, preferably in the presence of a dihydroxy compound such as bisphenol A. The products have excellent physical properties, including a high degree of weatherability. They may be blended with other polymers such as polycarbonates, poly(alkylene carboxylates), polyarylates, polyetherimides, and addition polymers to improve the weatherability thereof.

摘要翻译： 嵌段共聚酯碳酸酯可以通过首先在间苯二酚或烷基 - 或卤代间苯二酚和至少一种芳族二羧酸二氯化物，优选间苯二酰氯，对苯二甲酰氯或其混合物中的至少一种之间进行反应来制备，以产生羟基封端的聚酯中间体 ，然后进行中间体与碳酸酯前体的反应，优选在二羟基化合物如双酚A的存在下进行。产物具有优异的物理性能，包括高度的耐候性。 它们可以与其他聚合物如聚碳酸酯，聚（亚烷基羧酸酯），聚芳酯，聚醚酰亚胺和加成聚合物共混以改善其耐候性。

公开(公告)号：US06462168B1

公开(公告)日：2002-10-08

申请号：US09842616

申请日：2001-04-25

申请人： Tiberiu Mircea Siclovan ,  Daniel Joseph Brunelle ,  James Edward Pickett ,  Joseph Anthony Suriano

发明人： Tiberiu Mircea Siclovan ,  Daniel Joseph Brunelle ,  James Edward Pickett ,  Joseph Anthony Suriano

IPC分类号： C08G6400

CPC分类号： C08G64/12

摘要： In one embodiment the present invention is a polycarbonate comprising structural units derived from at least one dihydric phenol, a carbonate precursor, and at least one member selected from the group consisting of an oxanilide-comprising compound, an oxamate-comprising compound, and mixtures thereof. In another embodiment the present invention is a method for making a polycarbonate comprising structural units derived from at least one dihydric phenol and at least one member selected from the group consisting of an oxanilide-comprising compound, an oxamate-comprising compound, and mixtures thereof, which comprises the step of contacting under reactive conditions at least one dihydric phenol, a carbonate precursor, and at least one member selected from the group consisting of an oxanilide-comprising compound, an oxamate-comprising compound, and mixtures thereof. In still another embodiment the present invention is an article comprising a polycarbonate comprising oxanilide structural units. In still another embodiment the present invention is a method for making a symmetrical or unsymmetrical oxanilide-comprising dihydric phenol which comprises the step of contacting at least one aromatic amine bearing a hydroxy group with a diaryl oxalate or a dialkyl oxalate bearing alkyl groups each substituted with at least one electron-withdrawing group. In still another embodiment the present invention is a method for making an oxamate-comprising monohydric phenol which comprises the step of contacting an aromatic amine bearing a hydroxy group with a diaryl oxalate or a dialkyl oxalate bearing alkyl groups each substituted with at least one electron-withdrawing group.

摘要翻译： 在一个实施方案中，本发明是包含衍生自至少一种二元酚，碳酸酯前体和至少一种选自由含草酰替苯的化合物，含草酸酯化合物及其混合物组成的组中的至少一种的结构单元的聚碳酸酯 。 在另一个实施方案中，本发明是一种制备聚碳酸酯的方法，该聚碳酸酯包含衍生自至少一种二元酚的结构单元和至少一种选自由含草酰替苯的化合物，含草酸酯化合物及其混合物组成的组， 其包括在反应条件下使至少一种二元酚，碳酸酯前体和选自由含草酰替苯的化合物，含草酸酯化合物及其混合物中的至少一种接触的步骤。 在另一个实施方案中，本发明是包含含有草酰替苯胺结构单元的聚碳酸酯的制品。 在另一个实施方案中，本发明是一种制备包含对称或不对称的草酰替苯胺的二元酚的方法，其包括使至少一种带有羟基的芳族胺与草酸二芳基酯或带有烷基的二烷基酯的烷基基团接触的步骤， 至少一个吸电子基团。 在另一个实施方案中，本发明是一种制备含草酸羟基的一元酚的方法，其包括使带有羟基的芳族胺与草酸二芳基酯或带有烷基的草酸二烷基酯接触的步骤，每个烷基取代有至少一个电子 - 退出组。

公开(公告)号：US5977265A

公开(公告)日：1999-11-02

申请号：US922105

申请日：1997-09-02

申请人： Patrick Joseph McCloskey ,  Gary Charles Davis ,  David Michel Dardaris ,  Daniel Joseph Brunelle ,  Robert Russell Gallucci ,  Mahari Tjahjadi ,  David Whalen ,  Kevin Mitchell Snow

发明人： Patrick Joseph McCloskey ,  Gary Charles Davis ,  David Michel Dardaris ,  Daniel Joseph Brunelle ,  Robert Russell Gallucci ,  Mahari Tjahjadi ,  David Whalen ,  Kevin Mitchell Snow

IPC分类号： C08L23/00 ,  C08G64/10 ,  C08G64/42 ,  C08L33/06 ,  C08L67/00 ,  C08L69/00 ,  H01R13/46 ,  H01R13/73 ,  C08C19/22

CPC分类号： C08G64/42 ,  C08G64/10

摘要： High flow brominated polycarbonates, useful as flame retardant additives for other polymers such as polyesters, are obtained by equilibration of a brominated aromatic polycarbonate such as a tetrabromobisphenol A homo- or copolycarbonate with a di- or polyhydroxy aromatic compound such as bisphenol A, or a diaryl carbonate, and an equilibration catalyst, under conditions such that the weight average molecular weight of the brominated polycarbonate is reduced by at least 35%. Preferred equilibration catalysts are Group I metal carboxylates, such as sodium stearate, and hexaalkylguanidinium salts.

摘要翻译： 通过将溴代芳族聚碳酸酯例如四溴双酚A均聚物或共聚碳酸酯与二羟基芳族化合物或多羟基芳族化合物如双酚A或其混合物平衡，可获得用作其它聚合物如聚酯的阻燃添加剂的高流动溴化聚碳酸酯， 碳酸二芳酯和平衡催化剂，使得溴化聚碳酸酯的重均分子量降低至少35％的条件下进行。 优选的平衡催化剂是I族金属羧酸盐，例如硬脂酸钠和六烷基胍盐。

公开(公告)号：US07705190B2

公开(公告)日：2010-04-27

申请号：US11651167

申请日：2007-01-09

申请人： Daniel Joseph Brunelle

发明人： Daniel Joseph Brunelle

IPC分类号： C07C41/00

CPC分类号： B01J31/0239 ,  B01J31/0265 ,  B01J31/0268 ,  B01J2231/14 ,  B01J2231/40 ,  B01J2531/98 ,  C07C41/16 ,  C07C315/04 ,  C07F9/067 ,  C08G65/4087 ,  C08G79/025 ,  C07C317/22 ,  C07C43/29

摘要： A method for carrying out a chemical reaction between at least two reactants occupying separate phases within a multiphase reaction mixture has been discovered in which at least one phosphazenium salt is employed as a phase transfer catalyst. The remarkable utility of phosphazenium salts as phase transfer catalysts is illustrated by the preparation of aromatic ethers. The phosphazenium salt phase transfer catalysts are shown to be especially useful in the preparation of aromatic polyethers such as polyether sulfones.

摘要翻译： 已经发现在多相反应混合物中在至少两种占据分离相的反应物之间进行化学反应的方法，其中使用至少一种磷氮烯基鏻盐作为相转移催化剂。 通过制备芳族醚来说明磷氮烯基鏻盐作为相转移催化剂的显着效用。 显示磷氮烯基鏻盐相转移催化剂特别可用于制备芳族聚醚如聚醚砜。

公开(公告)号：US20080269396A1

公开(公告)日：2008-10-30

申请号：US11966051

申请日：2007-12-28

申请人： Sreepdaraj Karanam ,  Robert Lee Sherman ,  Ganesh Kannan ,  Steven James Montgomery ,  Daniel Joseph Brunelle ,  Enrico Binassi

发明人： Sreepdaraj Karanam ,  Robert Lee Sherman ,  Ganesh Kannan ,  Steven James Montgomery ,  Daniel Joseph Brunelle ,  Enrico Binassi

IPC分类号： C08K3/34

CPC分类号： C08L69/00 ,  C08K3/346 ,  C08K9/04 ,  C08L21/00 ,  C08L51/00 ,  C08L55/02 ,  C08L67/02 ,  C08L2666/02

摘要： A composition comprises, based on the total weight of the composition, from 30 to 50 weight percent of an ionomeric telechelic polyalkylene ester comprising from 0.05 to 5 mole percent of sulfonate end groups; from 50 to 70 weight percent of a polycarbonate; from 0.1 to 10 weight percent of an organoclay; and from 2 to 12 weight percent of an impact modifier.

摘要翻译： 组合物基于组合物的总重量包含30至50重量％的包含0.05至5摩尔％磺酸酯端基的离聚物遥爪聚亚烷基酯; 50-70重量％的聚碳酸酯; 0.1至10重量％的有机粘土; 和2至12重量％的抗冲改性剂。

公开(公告)号：US07381331B2

公开(公告)日：2008-06-03

申请号：US11241227

申请日：2005-09-30

申请人： Hieu Minh Duong ,  Hongyi Zhou ,  Rainer Koeniger ,  Daniel Joseph Brunelle ,  Daniel Robert Olson ,  Karmin Lorraine Olson

发明人： Hieu Minh Duong ,  Hongyi Zhou ,  Rainer Koeniger ,  Daniel Joseph Brunelle ,  Daniel Robert Olson ,  Karmin Lorraine Olson

IPC分类号： B01D39/00 ,  B01D39/14 ,  B01D71/14 ,  B01D29/00 ,  B01D63/00

CPC分类号： B01D67/0088 ,  B01D67/0093 ,  B01D71/36 ,  B01D71/38 ,  B01D71/44 ,  B01D2323/02 ,  B01D2323/30 ,  B01D2323/32 ,  B01D2325/36 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1053 ,  H01M8/1058 ,  H01M8/1081 ,  H01M10/0565 ,  H01M2300/0082 ,  Y02P70/56

摘要： A membrane is provided, which may include a microporous base membrane; and a cross-linkable coating disposed on a surface of the membrane. The coating may include polyvinyl nucleophilic polymer and a urethane or a blocked isocyanate. The coating may be cross-linked. Also provided is a method of making the membrane.

摘要翻译： 提供膜，其可以包括微孔基膜; 以及设置在膜的表面上的可交联涂层。 涂层可以包括聚乙烯基亲核聚合物和聚氨酯或封端的异氰酸酯。 涂层可以是交联的。 还提供了制造膜的方法。