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公开(公告)号：US20090036300A1
公开(公告)日：2009-02-05
申请号：US11915317
申请日：2006-06-02
申请人： Satoshi Matsueda , Mareo Kimura , Akimasa Hirai , Keiichi Narita , Hirohisa Tanaka , Mari Uenishi , Isao Tan , Masashi Taniguchi
发明人： Satoshi Matsueda , Mareo Kimura , Akimasa Hirai , Keiichi Narita , Hirohisa Tanaka , Mari Uenishi , Isao Tan , Masashi Taniguchi
IPC分类号： B01J23/10
CPC分类号： B01J23/63 , B01D53/9445 , B01D53/945 , B01D2255/10 , B01D2255/204 , B01D2255/206 , B01D2255/20715 , B01J23/002 , B01J23/10 , B01J35/002 , B01J35/1014 , B01J37/0009 , B01J37/0205 , B01J37/03 , B01J37/08 , B01J2523/00 , F01N3/10 , Y02T10/22 , B01J2523/25 , B01J2523/36 , B01J2523/3712 , B01J2523/48 , B01J2523/828 , B01J2523/3706 , B01J2523/3725
摘要： An exhaust gas-purifying catalyst (1) contains a rare-earth element, an alkaline-earth element, zirconium and a precious metal, wherein an atomic ratio of the alkaline-earth element with respect to a sum of the rare-earth element and the zirconium is 10 atomic % or more, a part of the rare-earth element and a part of zirconium form a composite oxide with at least a part of the alkaline-earth element, and the composite oxide and a part of the precious metal form a solid solution.
摘要翻译： 废气净化催化剂（1）含有稀土元素，碱土金属元素，锆和贵金属，其中碱土元素相对于稀土元素和 锆为10原子％以上，部分稀土元素和锆的一部分与至少一部分碱土元素形成复合氧化物，复合氧化物和贵金属的一部分形式 一个坚实的解决方案。
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公开(公告)号：US07795170B2
公开(公告)日：2010-09-14
申请号：US12227858
申请日：2007-04-23
申请人： Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi , Mareo Kimura , Satoshi Matsueda , Akimasa Hirai , Keiichi Narita
发明人： Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi , Mareo Kimura , Satoshi Matsueda , Akimasa Hirai , Keiichi Narita
IPC分类号： B01J23/10
CPC分类号： B01J23/002 , B01D2255/402 , B01J23/10 , B01J23/63 , B01J23/894 , B01J37/0215 , B01J37/0242 , B01J37/0244 , B01J37/0248 , B01J37/033 , B01J2523/00 , B01J2523/3706 , B01J2523/824 , B01J2523/842 , B01J2523/3712 , B01J2523/3725 , B01J2523/48 , B01J2523/822 , B01J2523/36 , B01J2523/23 , B01J2523/828
摘要： Provided is a catalyst with a noble metal efficiently supported on the surfacemost thereof. A composite oxide-containing layer is formed on a catalyst carrier so as to contain a perovskite-type composite oxide represented by the following general formula (1) and an other composite oxide, and a noble metal layer is further formed on the catalyst carrier so as to be supported on the surfacemost of the catalyst carrier by immersing the catalyst carrier formed with the composite oxide-containing layer in an aqueous noble metal salt solution to impregnate the catalyst carrier with the aqueous noble metal salt solution: AxByO3±δ (1) (wherein A represents at least one element selected from rare earth elements and alkaline earth metals; B represents at least one element selected from transition elements (excluding rare earth elements); x represents an atomic ratio of less than 1; y represents an atomic ratio of 1.0; and δ represents an oxygen excess or an oxygen deficiency.)
摘要翻译： 提供一种贵金属的催化剂，其有效地支撑在其表面的最表面上。 在催化剂载体上形成复合氧化物层，以含有由以下通式（1）表示的钙钛矿型复合氧化物和其它复合氧化物，并且在催化剂载体上进一步形成贵金属层 通过将形成有复合氧化物的层的催化剂载体浸渍在贵金属盐水溶液中以使贵金属盐水溶液浸渍催化剂载体：AxByO3±δ（1）来担载在催化剂载体的最表面上， （其中A表示选自稀土元素和碱土金属中的至少一种元素; B表示选自过渡元素（不包括稀土元素）中的至少一种元素; x表示小于1的原子比; y表示原子比 为1.0;δ表示氧过量或缺氧。）
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公开(公告)号：US08993475B2
公开(公告)日：2015-03-31
申请号：US12307571
申请日：2007-06-22
申请人： Mareo Kimura , Keiichi Narita , Akimasa Hirai , Akiya Chiba , Naoto Miyoshi , Kazunobu Ishibashi , Takaaki Kanazawa , Takeru Yoshida , Hirohisa Tanaka , Mari Uenishi , Isao Tan , Masashi Taniguchi
发明人： Mareo Kimura , Keiichi Narita , Akimasa Hirai , Akiya Chiba , Naoto Miyoshi , Kazunobu Ishibashi , Takaaki Kanazawa , Takeru Yoshida , Hirohisa Tanaka , Mari Uenishi , Isao Tan , Masashi Taniguchi
CPC分类号： C01G25/02 , B01D53/02 , B01D2253/112 , B01D2255/407 , B01D2256/12 , B01D2259/4525 , B01J23/002 , B01J23/63 , B01J2523/00 , C01P2002/72 , C01P2002/85 , C01P2004/82 , C01P2006/12 , Y10S502/526 , B01J2523/25 , B01J2523/3712 , B01J2523/48 , B01J2523/36
摘要： An excellent oxygen storage capacity is achieved even in the case used for a long period of time under high temperature conditions. An oxygen storage material contains a first particle made of a composite oxide of cerium and zirconium or a composite oxide of cerium, a rare-earth element other than cerium and zirconium, a second particle including a composite oxide of a rare-earth element, an alkaline-earth element and zirconium, and a precious metal. A part of the precious metal forms a solid solution with the composite oxide included in the second particle.
摘要翻译： 即使在高温条件下长时间使用的情况下也能实现极好的储氧能力。 储氧材料包含由铈和锆的复合氧化物制成的第一颗粒或铈，铈和锆以外的稀土元素的复合氧化物，包含稀土元素的复合氧化物的第二颗粒， 碱土元素和锆，以及贵金属。 贵金属的一部分与第二颗粒中包含的复合氧化物形成固溶体。
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公开(公告)号：US20090253574A1
公开(公告)日：2009-10-08
申请号：US12227858
申请日：2007-04-23
申请人： Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi , Mareo Kimura , Satoshi Matsueda , Akimasa Hirai , Keiichi Narita
发明人： Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi , Mareo Kimura , Satoshi Matsueda , Akimasa Hirai , Keiichi Narita
IPC分类号： B01J23/10
CPC分类号： B01J23/002 , B01D2255/402 , B01J23/10 , B01J23/63 , B01J23/894 , B01J37/0215 , B01J37/0242 , B01J37/0244 , B01J37/0248 , B01J37/033 , B01J2523/00 , B01J2523/3706 , B01J2523/824 , B01J2523/842 , B01J2523/3712 , B01J2523/3725 , B01J2523/48 , B01J2523/822 , B01J2523/36 , B01J2523/23 , B01J2523/828
摘要： Provided is a catalyst with a noble metal efficiently supported on the surfacemost thereof. A composite oxide-containing layer is formed on a catalyst carrier so as to contain a perovskite-type composite oxide represented by the following general formula (1) and an other composite oxide, and a noble metal layer is further formed on the catalyst carrier so as to be supported on the surfacemost of the catalyst carrier by immersing the catalyst carrier formed with the composite oxide-containing layer in an aqueous noble metal salt solution to impregnate the catalyst carrier with the aqueous noble metal salt solution: AxByO3±δ (1) (wherein A represents at least one element selected from rare earth elements and alkaline earth metals; B represents at least one element selected from transition elements (excluding rare earth elements); x represents an atomic ratio of less than 1; y represents an atomic ratio of 1.0; and δ represents an oxygen excess or an oxygen deficiency.)
摘要翻译： 提供一种贵金属的催化剂，其有效地支撑在其表面的最表面上。 在催化剂载体上形成复合氧化物层，以含有由以下通式（1）表示的钙钛矿型复合氧化物和其它复合氧化物，并且在催化剂载体上进一步形成贵金属层 通过将形成有复合氧化物的层的催化剂载体浸渍在贵金属盐水溶液中以用贵金属盐水溶液浸渍催化剂载体：AxByO3±δ（1）来支撑在催化剂载体的表面上， （其中A表示选自稀土元素和碱土金属中的至少一种元素; B表示选自过渡元素（不包括稀土元素）中的至少一种元素; x表示小于1的原子比; y表示原子比 为1.0;并且δ表示氧过量或缺氧。）
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公开(公告)号：US07625836B2
公开(公告)日：2009-12-01
申请号：US11792832
申请日：2005-12-13
申请人： Satoshi Matsueda , Mareo Kimura , Naoto Miyoshi , Yoshinori Ishii , Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi
发明人： Satoshi Matsueda , Mareo Kimura , Naoto Miyoshi , Yoshinori Ishii , Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi
IPC分类号： B01J21/00 , B01J21/02 , B01J21/06 , B01J21/10 , B01J23/00 , B01J23/02 , B01J23/10 , B01J23/38 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/54 , B01J23/56 , B01J23/58 , B01J23/63 , B01J37/08 , C01F3/00 , C01F5/00 , C01F7/00 , C01F11/00 , C01F17/00 , C01G25/00 , C01G25/02 , C01G55/00 , C01G57/00
CPC分类号： C01G25/006 , B01J23/002 , B01J23/63 , B01J2523/00 , C01P2002/52 , C01P2006/37 , C04B35/486 , C04B2235/3205 , C04B2235/3213 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3289 , C04B2235/3418 , C04B2235/441 , C04B2235/443 , C04B2235/444 , F01N3/2803 , F01N2370/02 , B01J2523/36 , B01J2523/48 , B01J2523/822 , B01J2523/3706 , B01J2523/3712 , B01J2523/37
摘要： To provide a heat-resistant oxide which is excellent in heat resistance and durability at high temperature and has high activity, a heat-resistant oxide which has an oxide crystal structure and in which a rate of a solid solution of a noble metal in the oxide crystal structure is 50% or more is obtained by heat-treating (secondarily baking) a precursor composition comprising zirconia, at least one coordinative element selected from the group consisting of rare earth elements, alkaline earth elements, aluminum and silicon, and at least one noble metal selected from the group consisting of platinum, rhodium and palladium at 650° C. or higher.
摘要翻译： 为了提供耐热性和耐高温性优异且活性高的耐热氧化物，具有氧化物结晶结构的耐热氧化物，其中贵金属在氧化物中的固溶率 通过对包含氧化锆的前体组合物进行热处理（二次焙烧），至少一种选自稀土元素，碱土金属元素，铝和硅的配位元素和至少一种配位元素获得的晶体结构为50％以上 选自铂，铑和钯在650℃以上的贵金属。
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公开(公告)号：US20090131251A1
公开(公告)日：2009-05-21
申请号：US12343451
申请日：2008-12-23
申请人： Satoshi Matsueda , Mareo Kimura , Akimasa Hirai , Keiichi Narita , Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi
发明人： Satoshi Matsueda , Mareo Kimura , Akimasa Hirai , Keiichi Narita , Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi
CPC分类号： B01D53/945 , B01D2255/102 , B01D2255/402 , B01D2255/405 , B01J21/10 , B01J23/002 , B01J23/02 , B01J23/58 , B01J23/894 , B01J23/8946 , B01J35/0006 , B01J35/1009 , B01J35/1014 , B01J37/0009 , B01J37/03 , B01J37/033 , B01J2523/00 , Y02T10/22 , B01J2523/23 , B01J2523/47 , B01J2523/822 , B01J2523/3706 , B01J2523/824 , B01J2523/842
摘要： An exhaust gas-purifying catalyst is less prone to cause a decrease in its activity even when used in a high temperature atmosphere containing oxygen at a high concentration. The exhaust gas-purifying catalyst includes a composite oxide and Pd or a second solid solution of a composite and Rh and/or Pt. The first and second solid solutions have perovskite structure and are represented by ABO3 and CDO3, respectively. The composite oxide catalyst is supported by a composite oxide support including a composite oxide of spinel structure represented by EF2O4 or a composite oxide represented by GAl12O19. A and B represent a rare-earth element and a transition element, respectively. C and G represent an alkaline-earth element. D represents one or more of Ti, Zr, Hf and Ce. E represents an alkaline-earth element and/or a transition element. F represents one or more of Al, Mg and transition elements.
摘要翻译： 废气净化催化剂即使在高浓度氧气的高温气氛中使用也不易引起其活性降低。 废气净化催化剂包括复合氧化物和Pd或复合材料和Rh和/或Pt的第二固溶体。 第一和第二固溶体具有钙钛矿结构，分别由ABO 3和CDO 3表示。 复合氧化物催化剂由包含由EF 2 O 4表示的尖晶石结构的复合氧化物或由GA122019表示的复合氧化物的复合氧化物载体负载。 A和B分别表示稀土元素和过渡元素。 C和G表示碱土元素。 D表示Ti，Zr，Hf和Ce中的一种或多种。 E表示碱土元素和/或过渡元素。 F表示Al，Mg和过渡元素中的一种或多种。
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公开(公告)号：US20070297971A1
公开(公告)日：2007-12-27
申请号：US11792832
申请日：2005-12-13
申请人： Satoshi Matsueda , Mareo Kimura , Naoto Miyoshi , Yoshinori Ishii , Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi
发明人： Satoshi Matsueda , Mareo Kimura , Naoto Miyoshi , Yoshinori Ishii , Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi
IPC分类号： C01G25/02
CPC分类号： C01G25/006 , B01J23/002 , B01J23/63 , B01J2523/00 , C01P2002/52 , C01P2006/37 , C04B35/486 , C04B2235/3205 , C04B2235/3213 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3289 , C04B2235/3418 , C04B2235/441 , C04B2235/443 , C04B2235/444 , F01N3/2803 , F01N2370/02 , B01J2523/36 , B01J2523/48 , B01J2523/822 , B01J2523/3706 , B01J2523/3712 , B01J2523/37
摘要： To provide a heat-resistant oxide which is excellent in heat resistance and durability at high temperature and has high activity, a heat-resistant oxide which has an oxide crystal structure and in which a rate of a solid solution of a noble metal in the oxide crystal structure is 50% or more is obtained by heat-treating (secondarily baking) a precursor composition comprising zirconia, at least one coordinative element selected from the group consisting of rare earth elements, alkaline earth elements, aluminum and silicon, and at least one noble metal selected from the group consisting of platinum, rhodium and palladium at 650° C. or higher.
摘要翻译： 为了提供耐热性和耐高温性优异且活性高的耐热氧化物，具有氧化物结晶结构的耐热氧化物，其中贵金属在氧化物中的固溶率 通过对包含氧化锆的前体组合物进行热处理（二次焙烧），至少一种选自稀土元素，碱土金属元素，铝和硅的配位元素和至少一种配位元素获得的晶体结构为50％以上 选自铂，铑和钯在650℃以上的贵金属。
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公开(公告)号：US20070249497A1
公开(公告)日：2007-10-25
申请号：US10583153
申请日：2004-12-15
申请人： Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi
发明人： Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi
CPC分类号： B01D53/945 , B01D2255/402 , B01J23/002 , B01J23/58 , B01J23/63 , B01J23/8946 , B01J35/002 , B01J35/1009 , B01J35/1014 , B01J2523/00 , B82Y30/00 , C01G55/002 , C01P2002/34 , C01P2002/72 , C01P2004/03 , C01P2004/04 , C01P2004/64 , C01P2006/12 , Y02T10/22 , B01J2523/25 , B01J2523/47 , B01J2523/822 , B01J2523/24 , B01J2523/31 , B01J2523/828 , B01J2523/23 , B01J2523/48 , B01J2523/821 , B01J2523/842 , B01J2523/3706 , B01J2523/22
摘要： A catalyst composition which prevents deterioration due to grain growth of Rh and/or Pt, includes a perovskite-type composite oxide represented by the following general formula (1): A1−xA′xB1−(y+z)B′yNzO3 (1) wherein A represents at least one element selected from alkaline earth metals; A′ represents at least one element selected from rare earth elements; B represents at least one element selected from Ti, Zr, and Hf; B′ represents at least one element selected from transition elements (excluding rare earth elements, Ti, Zr, Hf, Rh, and Pt) and Al; N represents at least one element selected from Rh and Pt; x represents an atomic ratio satisfying the following condition: 0≦x≦0.4; y represents an atomic ratio satisfying the following condition: 0≦y
摘要翻译： 防止由Rh和/或Pt的晶粒生长引起的劣化的催化剂组合物包括由以下通式（1）表示的钙钛矿型复合氧化物：<？在线配方说明=“在线配方”末端 =“铅”→A 1-x A''x B 1-（y + z）B'y 其中A表示至少 一种选自碱土金属的元素; A'表示选自稀土元素中的至少一种元素; B表示选自Ti，Zr和Hf中的至少一种元素; B'表示选自过渡元素（不包括稀土元素，Ti，Zr，Hf，Rh和Pt）和Al的至少一种元素; N表示选自Rh和Pt中的至少一种元素; x表示满足以下条件的原子比：0 <= x <= 0.4; y表示满足以下条件的原子比：0 <= y <0.5; z表示满足以下条件的原子比：0
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公开(公告)号：US08133839B2
公开(公告)日：2012-03-13
申请号：US11915317
申请日：2006-06-02
申请人： Satoshi Matsueda , Mareo Kimura , Akimasa Hirai , Keiichi Narita , Hirohisa Tanaka , Mari Uenishi , Isao Tan , Masashi Taniguchi
发明人： Satoshi Matsueda , Mareo Kimura , Akimasa Hirai , Keiichi Narita , Hirohisa Tanaka , Mari Uenishi , Isao Tan , Masashi Taniguchi
IPC分类号： B01J23/00
CPC分类号： B01J23/63 , B01D53/9445 , B01D53/945 , B01D2255/10 , B01D2255/204 , B01D2255/206 , B01D2255/20715 , B01J23/002 , B01J23/10 , B01J35/002 , B01J35/1014 , B01J37/0009 , B01J37/0205 , B01J37/03 , B01J37/08 , B01J2523/00 , F01N3/10 , Y02T10/22 , B01J2523/25 , B01J2523/36 , B01J2523/3712 , B01J2523/48 , B01J2523/828 , B01J2523/3706 , B01J2523/3725
摘要： An exhaust gas-purifying catalyst (1) contains a rare-earth element, an alkaline-earth element, zirconium and a precious metal, wherein an atomic ratio of the alkaline-earth element with respect to a sum of the rare-earth element and the zirconium is 10 atomic % or more, a part of the rare-earth element and a part of zirconium form a composite oxide with at least a part of the alkaline-earth element, and the composite oxide and a part of the precious metal form a solid solution.
摘要翻译： 废气净化催化剂（1）含有稀土元素，碱土金属元素，锆和贵金属，其中碱土元素相对于稀土元素和 锆为10原子％以上，部分稀土元素和锆的一部分与至少一部分碱土元素形成复合氧化物，复合氧化物和贵金属的一部分形式 一个坚实的解决方案。
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公开(公告)号：US20100227759A1
公开(公告)日：2010-09-09
申请号：US12225418
申请日：2007-03-08
申请人： Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi , Mareo Kimura , Satoshi Matsueda
发明人： Hirohisa Tanaka , Isao Tan , Mari Uenishi , Masashi Taniguchi , Mareo Kimura , Satoshi Matsueda
CPC分类号： B01D53/945 , B01D53/94 , B01D2255/1025 , B01D2255/204 , B01D2255/2047 , B01D2255/20738 , B01D2255/2092 , B01J23/002 , B01J23/58 , B01J23/8946 , B01J37/0201 , B01J37/031 , B01J2523/00 , Y02A50/2324 , Y02T10/22 , B01J2523/31 , B01J2523/3718 , B01J2523/822 , B01J2523/24 , B01J2523/842 , B01J2523/22 , B01J2523/47
摘要： Provided is a catalyst composition capable of preventing decrease in catalytic activity due to grain growth of noble metal under high temperature or under change in oxidation reduction or further for long term use, and of achieving excellent catalytic activity over a long time.The catalyst composition containing a composite oxide represented by the following general formula (1): AO.x(B2-yCyO3-α) (1) (wherein A represents an element selected from monovalent elements, divalent elements and lanthanides; B represents a trivalent element; and C represents a noble metal; x represents an integer of 1 to 6; y represents an atomic ratio satisfying the following relation: 0
摘要翻译： 提供一种催化剂组合物，其能够防止贵金属在高温下或氧化还原或长期使用的变化下由于贵金属的晶粒生长而导致的催化活性降低，并且能够长期获得优异的催化活性。 含有由以下通式（1）表示的复合氧化物的催化剂组合物：AO.x（B2-yCyO3-α）（1）（其中A表示选自一价元素，二价元素和镧系元素的元素; B表示三价 元素; C表示贵金属; x表示1〜6的整数; y表示满足以下关系的原子比：0
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