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公开(公告)号：US07902103B2
公开(公告)日：2011-03-08
申请号：US12459307
申请日：2009-06-30
申请人： Jean W. Beeckman , Glenn R. Sweeten , Arthur W. Chester , John P. McWilliams , Dominick N. Mazzone
发明人： Jean W. Beeckman , Glenn R. Sweeten , Arthur W. Chester , John P. McWilliams , Dominick N. Mazzone
CPC分类号： B01J37/0018 , B01J20/183 , B01J29/041 , B01J29/084 , B01J29/40 , B01J29/65 , B01J37/0009 , B01J2229/42 , C04B35/18 , C04B38/0022 , C04B2111/00793 , C08L83/04 , C10G45/04 , C10G49/02 , C04B38/0006 , C04B38/0054 , C08L2666/54 , C08L2666/58
摘要： The invention relates to the use of particulate silicone resins in the absence of added organic solvents with particulate inorganic materials to form structured bodies and in particular molecular sieve containing structured bodies. The silicone resin is used in the form of a particulate with an average particle size of less than 700 um. Upon calcining, the silicone resin is converted to silica which acts as a binder.
摘要翻译： 本发明涉及在没有添加的有机溶剂与颗粒状无机材料形成结构体的情况下使用颗粒状有机硅树脂，特别是分子筛含结构体的用途。 有机硅树脂以平均粒径小于700μm的颗粒形式使用。 煅烧后，将有机硅树脂转化为二氧化硅作为粘合剂。
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公开(公告)号：US20090270246A1
公开(公告)日：2009-10-29
申请号：US12459307
申请日：2009-06-30
申请人： Jean W. Beeckman , Glenn R. Sweeten , Arthur W. Chester , John P. McWilliams , Dominick N. Mazzone
发明人： Jean W. Beeckman , Glenn R. Sweeten , Arthur W. Chester , John P. McWilliams , Dominick N. Mazzone
IPC分类号： B01J29/04
CPC分类号： B01J37/0018 , B01J20/183 , B01J29/041 , B01J29/084 , B01J29/40 , B01J29/65 , B01J37/0009 , B01J2229/42 , C04B35/18 , C04B38/0022 , C04B2111/00793 , C08L83/04 , C10G45/04 , C10G49/02 , C04B38/0006 , C04B38/0054 , C08L2666/54 , C08L2666/58
摘要： The invention relates to the use of particulate silicone resins in the absence of added organic solvents with particulate inorganic materials to form structured bodies and in particular molecular sieve containing structured bodies. The silicone resin is used in the form of a particulate with an average particle size of less than 700 um. Upon calcining, the silicone resin is converted to silica which acts as a binder.
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公开(公告)号：US10307751B2
公开(公告)日：2019-06-04
申请号：US15013035
申请日：2016-02-02
申请人： Jean W. Beeckman , Natalie A. Fassbender , Theodore E. Datz , Chuansheng Bai , Adrienne J. Thornburg , Tilman W. Beutel
发明人： Jean W. Beeckman , Natalie A. Fassbender , Theodore E. Datz , Chuansheng Bai , Adrienne J. Thornburg , Tilman W. Beutel
摘要： Disclosed herein are an apparatus and a method for mixing and/or mulling a sample, the apparatus comprising at least one container made of a flexible material and containing a sample, means for holding the container, and means for impacting the container, wherein the means for holding and the means for impacting are movable relative to each other, and wherein the means for holding, the means for impacting, and the container are arranged such that the means for impacting and the container can repeatedly collide, whereby an energy of collision can be imparted to the sample, thereby mixing and/or mulling the sample. Also disclosed is an assembly for performing high throughput experiments including the apparatus for mixing and/or mulling a sample and an extruder configured to receive a sample weighing less than 100 grams.
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公开(公告)号：US08546286B2
公开(公告)日：2013-10-01
申请号：US12653511
申请日：2009-12-15
CPC分类号： B01J37/0205 , B01J23/42 , B01J23/44 , B01J29/0325 , B01J29/043 , B01J29/068 , B01J37/0201 , B01J37/0207 , B01J37/088 , B01J37/10 , B01J37/18 , B01J37/28 , B01J2229/18 , B01J2229/186 , B01J2229/20 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C10G45/54 , C10G2300/1096
摘要： In a process for producing a metal containing catalyst composition suitable for effecting hydrocarbon hydrogenation and/or dehydrogenation reactions, a catalyst support comprising a porous crystalline material combined with an amorphous binder is treated with an anchoring material capable of bonding to the surface of the support and to a metal component. In addition, a precursor to the metal component is deposited on the surface of the catalyst support and then the treated catalyst support having the precursor deposited thereon is subjected to conditions effective to convert the precursor to the metal component and to cause the anchoring material to bond to the surface of the support and to the metal component.
摘要翻译： 在适用于进行烃氢化和/或脱氢反应的含金属催化剂组合物的制备方法中，将包含与无定形粘合剂结合的多孔结晶材料的催化剂载体用能够粘合到载体表面的锚定材料进行处理， 到金属部件。 另外，金属组分的前体沉积在催化剂载体的表面上，然后将其上沉积有前体的经处理的催化剂载体进行有效地将前体转化为金属组分并使锚定材料结合 到支撑体的表面和金属部件。
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公开(公告)号：US20090182183A1
公开(公告)日：2009-07-16
申请号：US12014406
申请日：2008-01-15
申请人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
发明人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
IPC分类号： C07C2/24
CPC分类号： C07C2/10 , C07C2521/06 , C07C2523/30 , Y02P20/52
摘要： A process for the oligomerization of propylene is disclosed wherein a tungstated zirconia catalyst prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms useful for preparing neo acids.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中在反应蒸馏区中在温度和压力条件下使用制备为蒸馏结构的钨酸氧化锆催化剂，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性，以用于制备新酸的优选异构形式。
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16.发明申请公开(公告)号：US20080128329A1
公开(公告)日：2008-06-05
申请号：US11633971
申请日：2006-12-05
申请人： Stephen H. Brown , Jose G. Santiesteban , Bryson J. Sundberg , Terry E. Helton , Daria N. Lissy , Jean W. Beeckman , Arthur P. Werner
发明人： Stephen H. Brown , Jose G. Santiesteban , Bryson J. Sundberg , Terry E. Helton , Daria N. Lissy , Jean W. Beeckman , Arthur P. Werner
IPC分类号： C10G25/03
CPC分类号： C10G29/02 , B01J29/7007 , B01J29/7038 , B01J35/023 , B01J35/026 , C10G2300/1096 , C10G2300/4018
摘要： A process for reducing the Bromine Index of a hydrocarbon feed containing bromine-reactive contaminants that has improved cycle length and utilizes a crystalline molecular sieve catalyst. The process is carried out by contacting the hydrocarbon feed under conversion conditions with a catalyst shaped in the form of an elongated aggregate comprising a crystalline molecular sieve having a MWW or *BEA framework type. The shortest cross-sectional dimension of the elongated aggregate is less about 1/10 inch (2.54 millimeters).
摘要翻译： 一种降低含溴反应性污染物的烃进料的溴指数的方法，其具有改善的循环长度并且使用结晶分子筛催化剂。 该方法通过在转化条件下使烃进料与包含具有MWW或* BEA骨架类型的结晶分子筛的细长骨料形式的催化剂接触来进行。 细长骨料的最短横截面尺寸较小约为1/10英寸（2.54毫米）。
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公开(公告)号：US20150158786A1
公开(公告)日：2015-06-11
申请号：US14233203
申请日：2012-06-14
申请人： Machteld M. W. Mertens , Geraldine Tosin , Jean W. Beeckman , Hans K. T. Goris , George M. K. Mathys
发明人： Machteld M. W. Mertens , Geraldine Tosin , Jean W. Beeckman , Hans K. T. Goris , George M. K. Mathys
IPC分类号： C07C2/12
CPC分类号： C07C2/12 , B01J20/08 , B01J20/12 , B01J20/28019 , B01J20/28061 , B01J20/28071 , B01J21/04 , B01J29/7042 , B01J2229/42 , C07C2521/04 , C07C2529/70 , Y02P20/52 , C07C11/02
摘要： The invention relates to an olefin oligomerization process comprising the steps of: i) contacting a feed comprising olefins and nitriles with a guard bed comprising eta alumina; and ii) contacting the feed obtained in step i) with an oligomerization catalyst under conditions suitable to oligomerize the olefins in the feed. It also relates to the use of a guard bed comprising eta-alumina for reducing the content of basic organic compounds in a hydrocarbon feed.
摘要翻译： 本发明涉及烯烃低聚方法，其包括以下步骤：i）使包含烯烃和腈的进料与包含等离子体氧化铝的保护床接触; 和ii）在适于使进料中的烯烃低聚的条件下，使步骤i）中获得的进料与低聚催化剂接触。 它还涉及使用包含等离子体 - 氧化铝的保护床来降低烃进料中的碱性有机化合物的含量。
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公开(公告)号：US07407909B2
公开(公告)日：2008-08-05
申请号：US11228366
申请日：2005-09-16
CPC分类号： B01J29/0325 , B01J23/40 , B01J29/043 , B01J29/064 , B01J35/0013 , B01J35/002 , B01J35/0066 , B01J37/06 , B01J37/14 , B01J37/18 , B01J37/20
摘要： A method of ex-situ activation and dry passivation of supported noble metal catalysts including the steps of reducing in the presence of hydrogen and dry passivation by cooling in an inert atmosphere and exposing to air or by filling the pores of the catalyst with a low sulfur oil before exposing to air.
摘要翻译： 一种负载型贵金属催化剂的原位活化和干法钝化的方法，包括以下步骤：在惰性气氛中冷却并通过在惰性气氛中冷却并且暴露于空气或通过用低硫填充催化剂的孔来减少氢气和干燥钝化 油在暴露于空气之前。
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19.发明申请Catalyst composition, the method of manufacturing and the process of use thereof in aromatics alkylation 有权催化剂组合物，其制备方法及其在芳烃烷基化中的应用方法公开(公告)号：US20080154080A1
公开(公告)日：2008-06-26
申请号：US11643530
申请日：2006-12-21
IPC分类号： C07C6/12
CPC分类号： B01J29/7038 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J35/10 , B01J37/0009 , B01J2229/42 , C07C2/66 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/65 , C07C2529/70 , C07C2529/80 , Y02P20/52 , C07C15/085
摘要： A catalyst composition comprises a crystalline MCM-22 family molecular sieve and a binder, wherein the catalyst composition is characterized by an extra-molecular sieve porosity greater than or equal to 0.122 ml/g for pores having a pore diameter ranging from about 2 nm to about 8 nm, wherein the porosity is measured by N2 porosimetry. The catalyst composition may be used for the process of alkylation or transalkylation of an alkylatable aromatic compound with an alkylating agent. The molecular sieve may have a Constraint Index of less than 12, e.g., less than 2. Examples of molecular sieve useful for this disclosure are a MCM-22 family molecular sieve, zeolite Y, and zeolite Beta
摘要翻译： 一种催化剂组合物包括结晶MCM-22族分子筛和粘合剂，其中该催化剂组合物的特征在于具有大于或等于0.122ml / g的分子量以上孔隙，孔隙范围为约2nm至 约8nm，其中通过N 2孔隙率法测量孔隙度。 催化剂组合物可用于烷基化芳族化合物与烷基化剂的烷基化或烷基转移过程。 分子筛可以具有小于12，例如小于2的约束指数。可用于本公开的分子筛的实例是MCM-22族分子筛，沸石Y和沸石β
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公开(公告)号：US5137855A
公开(公告)日：1992-08-11
申请号：US410762
申请日：1989-09-21
申请人： Louis Hegedus , Jean W. Beeckman , Wie-Hin Pan , Jeffrey P. Solar
发明人： Louis Hegedus , Jean W. Beeckman , Wie-Hin Pan , Jeffrey P. Solar
CPC分类号： B01J21/063 , B01D53/8628 , B01J35/0026 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1038 , B01J35/1066 , B01J37/0009
摘要： Catalysts for the selective catalytic reduction of NOx by ammonia are made from porous formed supports having a certain fraction of the pores with pore diameters larger than 600 Angstrom units. Thus macropores can be introduced in a formed TiO.sub.2 support by adding burnout materials prior to forming the titania into the formed support. Then conventional DeNOx catalytic metals are added. Barium sulfate can be added to the surface of the porous inorganic oxide to make an improved support.
摘要翻译： 用于由氨选择性催化还原NOx的催化剂由具有孔径大于600埃单位的孔的一定部分的多孔成形载体制成。 因此，在将二氧化钛形成到形成的载体之前，通过添加烧制材料，可以在形成的TiO 2载体中引入大孔。 然后加入常规的DeNOx催化金属。 可以将硫酸钡加入到多孔无机氧化物的表面以形成改进的载体。
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