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公开(公告)号：US20140213670A1
公开(公告)日：2014-07-31
申请号：US13750089
申请日：2013-01-25
Applicant: Kandaswamy Jothimurugesan , Robert James Saxton
Inventor： Kandaswamy Jothimurugesan , Robert James Saxton
CPC classification number: C07C1/0435 , B01J29/7661 , B01J37/0009 , B01J37/0203 , B01J2229/20 , B01J2229/42 , C07C9/00 , C10G2/332 , C10G2/333 , C10G2/334 , C10G2300/1022
Abstract: Disclosed are hybrid Fischer-Tropsch catalysts containing cobalt and ZSM-48 zeolite. The hybrid Fischer-Tropsch catalysts can contain cobalt deposited on ZSM-48 extrudate supports. Alternatively, the Fischer-Tropsch catalysts can contain cobalt deposited on supports mixed with ZSM-48 particles. It has surprisingly been found that the use of hybrid Fischer-Tropsch catalysts containing ZSM-48 zeolite in synthesis gas conversion reactions results in improved C5+ productivity and catalyst activity, as well as a desirable product distribution including low formation of methane and C21+.
Abstract translation: 公开了含有钴和ZSM-48沸石的混合费 - 托催化剂。 混合费 - 托催化剂可以含有沉积在ZSM-48挤出物载体上的钴。 或者，费 - 托催化剂可以含有沉积在与ZSM-48颗粒混合的载体上的钴。 令人惊奇地发现，在合成气转化反应中使用含有ZSM-48沸石的混合费 - 托催化剂导致提高的C5 +生产率和催化剂活性，以及包括低甲烷和C21 +形成的理想产物分布。
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公开(公告)号：US20130253079A1
公开(公告)日：2013-09-26
申请号：US13603743
申请日：2012-09-05
Applicant: Kandaswamy Jothimurugesan , Robert James Saxton
Inventor： Kandaswamy Jothimurugesan , Robert James Saxton
CPC classification number: C10G2/334 , B01J23/8913 , B01J29/7669 , B01J29/80 , B01J35/006 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0009 , B01J37/0201 , B01J37/04 , C10G2/332
Abstract: Disclosed are hybrid Fischer-Tropsch catalysts containing cobalt deposited on hybrid supports. The hybrid supports contain an acidic zeolite component and a silica-containing material. It has been found that the use of the hybrid Fischer-Tropsch catalysts in synthesis gas conversion reactions results in high C5+ productivity, high CO conversion rates and low olefin formation.
Abstract translation: 公开了含有沉积在混合载体上的钴的混合费 - 托催化剂。 杂化载体含有酸性沸石组分和含二氧化硅的材料。 已经发现，在合成气转化反应中使用混合费 - 托催化剂导致高的C5 +生产率，高CO转化率和低烯烃形成。
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13.发明申请INTEGRAL SYNTHESIS GAS CONVERSION CATALYST EXTRUDATES AND METHODS FOR PREPARING AND USING SAME 审中-公开一体化合成气转化催化剂挤出物及其制备方法和使用方法公开(公告)号：US20130158138A1
公开(公告)日：2013-06-20
申请号：US13327184
申请日：2011-12-15
Applicant: Kandaswamy Jothimurugesan , Robert J. Saxton , Howard S. Lacheen , Tapan Das
Inventor： Kandaswamy Jothimurugesan , Robert J. Saxton , Howard S. Lacheen , Tapan Das
IPC: C07C27/00 , B01J37/00 , B01J29/072 , B01J29/076 , B01J29/06 , B01J29/70
CPC classification number: B01J29/7669 , B01J23/8913 , B01J29/043 , B01J29/044 , B01J29/045 , B01J29/7469 , B01J35/0006 , B01J37/0009 , B01J37/035 , B01J2229/186 , B01J2229/42 , C10G2/334 , C10G2/341 , Y02E60/324
Abstract: Methods for preparing integral synthesis gas conversion catalyst extrudates including an oxide of a Fischer-Tropsch (FT) metal component and a zeolite component are disclosed. The oxide of the FT metal component is precipitated from a solution into crystallites having a particle size between about 2 nm and about 30 nm. The oxide of the FT metal component is combined with a zeolite powder and a binder material, and the combination is extruded to form integral catalyst extrudates. The oxide of the FT metal component in the resulting catalyst is in the form of reduced crystallites located outside the zeolite channels. No appreciable ion exchange of FT metal occurs within the zeolite channels. The acid site density of the integral catalyst extrudate is at least about 80% of the zeolite acid site density.
Abstract translation: 公开了制备包含费 - 托（FT）金属组分和沸石组分的氧化物的整体合成气转化催化剂挤出物的方法。 FT金属成分的氧化物从溶液中沉淀成粒径在约2nm至约30nm之间的微晶。 将FT金属成分的氧化物与沸石粉末和粘合剂材料组合，将其组合挤出成一体的催化剂挤出物。 所得催化剂中FT金属组分的氧化物为位于沸石通道外部的微晶形式。 在沸石通道内不发生明显的FT金属离子交换。 整体催化剂挤出物的酸性位点密度为沸石酸性位点密度的至少约80％。
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公开(公告)号：US08377996B2
公开(公告)日：2013-02-19
申请号：US13031341
申请日：2011-02-21
Applicant: Charles L. Kibby , Kandaswamy Jothimurugesan
Inventor： Charles L. Kibby , Kandaswamy Jothimurugesan
IPC: C07C27/00
CPC classification number: B01J37/16 , B01J29/068 , B01J29/072 , B01J29/44 , B01J29/46 , B01J37/0009 , B01J37/0203 , B01J37/12 , B01J37/14 , B01J37/18 , B01J2229/20 , B01J2229/42 , C10G2/332 , C10G2/334 , C10G2300/703
Abstract: A method for forming a catalyst for synthesis gas conversion comprises impregnating a zeolite extrudate using a solution, for example, a substantially non-aqueous solution, comprising a cobalt salt to provide an impregnated zeolite extrudate and activating the impregnated zeolite extrudate by a reduction-oxidation-reduction cycle.
Abstract translation: 形成合成气转化催化剂的方法包括使用包含钴盐的溶液例如基本上非水溶液浸渍沸石挤出物，以提供浸渍的沸石挤出物，并通过还原氧化活化浸渍的沸石挤出物 - 减少周期。
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15.发明授权Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using 有权稳定的勃姆石衍生的催化剂载体，催化剂，制备和使用方法公开(公告)号：US07449496B2
公开(公告)日：2008-11-11
申请号：US11875484
申请日：2007-10-19
Applicant: Yaming Jin , Kandaswamy Jothimurugesan , Kristi A. Fjare , J. Dale Ortego, Jr. , Beatrice C. Ortego , Rafael L. Espinoza
Inventor： Yaming Jin , Kandaswamy Jothimurugesan , Kristi A. Fjare , J. Dale Ortego, Jr. , Beatrice C. Ortego , Rafael L. Espinoza
CPC classification number: B01J37/0207 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/8913 , B01J32/00 , B01J35/006 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B82Y30/00 , C01F7/442 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C10G2/33 , C10G2/332 , C10G2300/70
Abstract: A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.
Abstract translation: 具有改进的水热稳定性的稳定的催化剂载体，由其制备的催化剂，以及使用所述催化剂从合成气生产烃的方法。 稳定的载体通过包括处理与至少一种结构稳定剂或其化合物接触的结晶含水氧化铝前体的方法制备。 结晶含水氧化铝前体优选包括平均微晶尺寸，其选自由期望的耐热热性和所需孔隙率限定的最佳范围。 结晶含水氧化铝前体优选包括平均微晶尺寸不同至少约1nm的氧化铝氢氧化物，例如结晶勃姆石，结晶三羟铝石或其多个。 结晶含水氧化铝前体可以在与结构稳定剂或其化合物接触之前或之后成型。 处理包括在450℃或更高温度下煅烧。 优选的结构稳定剂可包括钴，镁，锰，锰，锆，硼，铝，钡，硅，镧，氧化物或其组合。
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Patent Agency Ranking
公开(公告)号：US07341976B2
公开(公告)日：2008-03-11
申请号：US11114804
申请日：2005-04-26
Applicant: Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Dale Ortego, Jr. , Kristi A. Fjare , Beatrice C. Ortego
Inventor： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Dale Ortego, Jr. , Kristi A. Fjare , Beatrice C. Ortego
CPC classification number: B01J37/0207 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/8913 , B01J32/00 , B01J35/006 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B82Y30/00 , C01F7/442 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C10G2/33 , C10G2/332 , C10G2300/70
Abstract: A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.
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公开(公告)号：US20080039539A1
公开(公告)日：2008-02-14
申请号：US11875484
申请日：2007-10-19
Applicant: Rafael Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Ortego , Kristi Fjare , Beatrice Ortego
Inventor： Rafael Espinoza , Kandaswamy Jothimurugesan , Yaming Jin , J. Ortego , Kristi Fjare , Beatrice Ortego
CPC classification number: B01J37/0207 , B01J21/04 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/8913 , B01J32/00 , B01J35/006 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B82Y30/00 , C01F7/442 , C01P2002/60 , C01P2002/72 , C01P2004/64 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C10G2/33 , C10G2/332 , C10G2300/70
Abstract: A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450° C. or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.
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公开(公告)号：US07323100B2
公开(公告)日：2008-01-29
申请号：US11180089
申请日：2005-07-13
Applicant: Rafael L. Espinoza , Keith H. Lawson , Kandaswamy Jothimurugesan
Inventor： Rafael L. Espinoza , Keith H. Lawson , Kandaswamy Jothimurugesan
CPC classification number: B01J37/036 , B01J21/12 , B01J23/24 , B01J23/40 , B01J23/42 , B01J23/652 , B01J23/85 , B01J23/89 , B01J35/0006 , B01J35/002 , B01J35/0066 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/04 , C10G2/32 , C10G47/02 , C10G47/04 , C10G47/12 , C10G47/14
Abstract: An amorphous support, methods for making the same and methods of using, particularly in hydrocracking. A method of making may comprise mixing a first amorphous material and a second amorphous material of different acidities to form a mixture, and treating by either separately treating the first and second amorphous materials before mixing or treating the mixture, so as to form an amorphous catalyst support. Treating preferably includes calcining. The acidity of the amorphous support may be modified by the different acidities of the precursor amorphous materials, their proportions in the mixture, and/or the order of the mixing and treating steps. A method of use may comprise reacting a hydrocarbon fraction with hydrogen over a hydrocracking catalyst comprising the amorphous catalyst support to form a hydrocracked product. Further embodiments include the first and second amorphous materials comprising silica-alumina, and/or differing in Brönsted acidity, Lewis acidity, or acidity index.
Abstract translation: 无定形支撑物，制备方法和使用方法，特别是在加氢裂化中。 制备方法可以包括混合不同酸度的第一无定形材料和第二无定形材料以形成混合物，并且在混合或处理混合物之前单独处理第一和第二非晶材料进行处理，以形成无定形催化剂 支持。 处理优选包括煅烧。 无定形载体的酸度可以通过前体无定形材料的不同酸度，它们在混合物中的比例和/或混合和处理步骤的顺序来改变。 使用的方法可以包括使烃馏分与氢气在包含无定形催化剂载体的加氢裂化催化剂上反应以形成加氢裂化产物。 另外的实施方案包括包含二氧化硅 - 氧化铝的第一和第二无定形材料和/或布朗斯台德酸度，路易斯酸度或酸度指数不同。
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19.发明授权Attrition resistant bulk iron catalysts and processes for preparing and using same 有权耐磨散体铁催化剂及其制备和使用方法公开(公告)号：US07259286B2
公开(公告)日：2007-08-21
申请号：US10344896
申请日：2001-08-28
Applicant: Kandaswamy Jothimurugesan , James G. Goodwin, Jr. , Santosh K. Gangwal
Inventor： Kandaswamy Jothimurugesan , James G. Goodwin, Jr. , Santosh K. Gangwal
CPC classification number: C10G2/332 , B01J21/08 , B01J23/745 , B01J23/78 , B01J27/22 , B01J35/002 , B01J35/0026 , B01J35/08 , B01J35/1014 , B01J35/1019 , B01J37/0009 , B01J37/0045 , B01J37/03 , B01J37/08 , C01B3/16 , C01B2203/0283 , C01B2203/1047 , Y02P20/52
Abstract: An attrition resistant precipitated bulk iron catalyst is prepared from iron oxide precursor and a binder by spray drying. The catalysts are preferably used in carbon monoxide hydrogenation processes such as Fischer-Tropsch synthesis. These catalysts are suitable for use in fluidized-bed reactors, transport reactors and, especially, slurry bubble column reactors.
Abstract translation: 通过喷雾干燥由氧化铁前体和粘合剂制备耐磨耗的沉淀体铁催化剂。 催化剂优选用于一氧化碳氢化方法如费 - 托合成。 这些催化剂适用于流化床反应器，运输反应器，特别是浆液鼓泡塔反应器。
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20.发明授权公开(公告)号：US07176160B2
公开(公告)日：2007-02-13
申请号：US10688412
申请日：2003-10-16
Applicant: Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin
Inventor： Rafael L. Espinoza , Kandaswamy Jothimurugesan , Yaming Jin
CPC classification number: C10G2/332 , B01J21/04 , B01J23/74 , B01J23/75 , B01J23/8913 , B01J37/0045 , B01J37/0201 , B01J37/0205 , B01J37/0207
Abstract: A method is provided for forming a highly active Fischer-Tropsch catalyst using boehmite having a particular crystallite size. In this method, a support material comprising boehmite is contacted with a catalytic metal-containing compound to form a catalyst precursor. The boehmite is selected to have an average crystallite size in the range of from about 6 nanometers (nm) to about 30 nm. An alternate embodiment uses a mixture of boehmites with various average crystallite sizes in the range of from about 4 nm to about 30 nm, differing by at least by 1 nm. Subsequently, the catalyst precursor is calcined to convert the boehmite to a stabilized aluminum oxide structure, thereby forming a catalyst support having a good attrition resistance and a relatively high hydrothermal stability.
Abstract translation: 提供了使用具有特定微晶尺寸的勃姆石形成高活性费 - 托催化剂的方法。 在该方法中，将包含勃姆石的载体材料与含催化金属的化合物接触以形成催化剂前体。 勃姆石被选择为具有在约6纳米（nm）至约30nm范围内的平均微晶尺寸。 替代实施例使用具有在约4nm至约30nm范围内的各种平均微晶尺寸的勃氏混合物，至少不同于1nm。 随后，将催化剂前体煅烧以将勃姆石转化为稳定的氧化铝结构，从而形成具有良好耐磨性和较高水热稳定性的催化剂载体。
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