公开(公告)号：US4837000A

公开(公告)日：1989-06-06

申请号：US940578

申请日：1986-12-11

申请人： Kozo Takatsu ,  Noboru Kawata

发明人： Kozo Takatsu ,  Noboru Kawata

IPC分类号： C01B39/04 ,  B01J29/00 ,  B01J29/70 ,  C01B39/48 ,  C07C1/20

CPC分类号： B01J29/70 ,  C01B33/2869 ,  C01B39/48 ,  C07C1/20 ,  C07C2529/06 ,  Y02P30/42 ,  Y10S423/36

摘要： Crystalline silicates and processes for the production thereof are described. These crystalline silicates are of new crystalline structure, which, as determined after calcination in the air at 550.degree. C., have a composition represented by the general formula (I): pM.sub.2/n O.Al.sub.2 O.sub.3.qSiO.sub.2 (the symbols are as defined in the appended claims) and give a X-ray diffraction pattern as shown in Table 2. They are superior in heat resistance and acid resistance, and can be used as catalysts for the conversion of various organic compounds, absorbents, or as catalysts for various reactions. They are produced by reacting an aqueous mixture comprising (a) a silica source, (b) an alumina source, (c) an alkali metal and/or alkaline earth metal source, and monoethanolamine at a temperature of 100.degree. to 300.degree. C. until the desired crystalline silicates are formed. Although monoethanolamine does not remain in the crystalline silicates, it plays an important role in the formation of the desired crystalline structure in the course of the production thereof.

公开(公告)号：US4657750A

公开(公告)日：1987-04-14

申请号：US713086

申请日：1985-03-18

申请人： Kozo Takatsu ,  Noboru Kawata

发明人： Kozo Takatsu ,  Noboru Kawata

IPC分类号： C01B39/04 ,  B01J29/00 ,  B01J29/70 ,  C01B39/48 ,  C07C1/20 ,  C01B33/28

CPC分类号： B01J29/70 ,  C01B33/2869 ,  C01B39/48 ,  C07C1/20 ,  C07C2529/06 ,  Y02P30/42 ,  Y10S423/36

摘要： Crystalline silicates and processes for the production thereof are described. These crystalline silicates are of new crystalline structure, which, as determined after calcination in the air at 550.degree. C., have a composition represented by the general formula (I): pM.sub.2/n O.Al.sub.2 O.sub.3.qSiO.sub.2 (the symbols are as defined in the appended claims) and give a X-ray diffraction pattern as shown in Table 2. They are superior in heat resistance and acid resistance, and can be used as catalysts for the conversion of various organic compounds, absorbents, or as catalysts for various reactions. They are produced by reacting an aqueous mixture comprising (a) a silica source, (b) an alumina source, (c) an alkali metal and/or alkaline earth metal source, and (d) ethylene glycol or (e) monoethanolamine at a temperature of 100.degree. to 300.degree. C. till the desired crystalline silicates are formed. Although ethylene glycol and monoethanolamine do not remain in the crystalline silicates, they play important roles in the formation of the desired crystalline structure in the course of the production thereof.

摘要翻译： 描述了结晶硅酸盐及其生产方法。 这些结晶硅酸盐具有新的结晶结构，其在550℃下在空气中煅烧后测定，具有由通式（I）表示的组成：pM2 / nO.Al2O3.qSiO2（符号如 所附权利要求书），得到如表2所示的X射线衍射图案。它们的耐热性和耐酸性优异，可用作各种有机化合物，吸收剂或用于各种反应的催化剂的转化催化剂 。 它们是通过使含有（a）二氧化硅源，（b）氧化铝源，（c）碱金属和/或碱土金属源，（d）乙二醇或（e）单乙醇胺的二氧化硅源， 温度在100℃至300℃直到形成所需的结晶硅酸盐。 尽管乙二醇和单乙醇胺不残留在结晶硅酸盐中，但是在制备期望的晶体结构的形成中起重要作用。

公开(公告)号：US08444945B2

公开(公告)日：2013-05-21

申请号：US10540881

申请日：2003-12-24

申请人： Kozo Takatsu ,  Gakuji Takegoshi

发明人： Kozo Takatsu ,  Gakuji Takegoshi

IPC分类号： B01D53/48

CPC分类号： C10L3/102 ,  B01D53/04 ,  B01D2253/10 ,  B01D2253/108 ,  B01D2253/112 ,  B01D2256/16 ,  B01D2257/30 ,  B01D2257/304 ,  B01D2259/4009 ,  B01J20/186 ,  B01J21/12 ,  B01J23/72 ,  B01J23/755 ,  B01J29/06 ,  B01J35/0006 ,  C01B3/38 ,  C01B2203/1258 ,  C01B2203/127 ,  C10L3/00 ,  C10L3/10 ,  H01M8/0662 ,  Y02P20/52

摘要： A method for removing sulfur compounds from a hydrocarbon-containing gas wherein the gas is fed to a desulfurizing bed comprising a desulfurizing agent A comprising zeolite and a desulfurizing agent B comprising at least one selected from the group consisting of a metal element, a metal oxide and a metal component-carried oxide, is provided. Hydrogen for a fuel cell is produced by a method, wherein the gas obtained by the described desulfurization method is contacted with a partial oxidation reforming catalyst, an autothermal reforming catalyst or a steam reforming catalyst.

摘要翻译： 一种从含烃气体中除去硫化合物的方法，其中将气体供给到包含沸石的脱硫剂A和脱硫剂B的脱硫床，脱硫剂B包含选自金属元素，金属氧化物 和金属成分负载氧化物。 通过一种方法制备用于燃料电池的氢，其中通过所述脱硫方法获得的气体与部分氧化重整催化剂，自热重整催化剂或蒸汽重整催化剂接触。

公开(公告)号：US08088708B2

公开(公告)日：2012-01-03

申请号：US12594983

申请日：2008-04-02

申请人： Kozo Takatsu ,  Yoshimi Kawashima ,  Satoshi Nakai

发明人： Kozo Takatsu ,  Yoshimi Kawashima ,  Satoshi Nakai

IPC分类号： B01J23/00 ,  B01J23/60 ,  B01J23/72 ,  B01J23/02 ,  B01J23/06 ,  B01J23/70 ,  H01M8/22 ,  H01M8/06 ,  C01B31/20 ,  C01B3/16 ,  C01B3/18 ,  C10G25/00 ,  C10G45/04 ,  C10G45/60 ,  C10G29/00

CPC分类号： B01J35/006 ,  B01J23/80 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/03 ,  C01B3/16 ,  C01B3/326 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/066 ,  C01B2203/1076 ,  C01B2203/1223 ,  C01B2203/1288 ,  H01M8/0618 ,  H01M8/0668 ,  Y02P20/52

摘要： The present invention provides a catalyst precursor substance containing copper, zinc, and aluminum and exhibiting an X-ray diffraction pattern having a broad peak at a specific interplanar spacing d (Å). The present invention also provides a method for producing the catalyst precursor substance by mixing a solution containing a copper salt, a zinc salt, and an aluminum salt with a solution containing an alkali metal hydroxide or an alkaline earth metal hydroxide, thereby forming a precipitate. In the present invention, a catalyst is prepared through calcining of the catalyst precursor; the catalyst is employed for water gas shift reaction; and carbon monoxide conversion is carried out by use of the catalyst. Thus, the present invention also provides a catalyst useful for water gas shift reaction, which exhibits high activity and durability and which, even when applied to a fuel cell, can be used for a long period of time with reduction in activity being suppressed; a carbon monoxide conversion method employing the catalyst; and a fuel cell system employing hydrogen produced through the carbon monoxide conversion method.

摘要翻译： 本发明提供了含有铜，锌和铝的催化剂前体物质，并且具有在特定的晶面间距d（）下具有宽峰的X射线衍射图。 本发明还提供了通过将含有铜盐，锌盐和铝盐的溶液与含有碱金属氢氧化物或碱土金属氢氧化物的溶液混合从而形成沉淀物来制备催化剂前体物质的方法。 在本发明中，通过煅烧催化剂前体制备催化剂; 催化剂用于水煤气变换反应; 并且通过使用催化剂进行一氧化碳转化。 因此，本发明还提供了可用于水煤气变换反应的催化剂，其具有高活性和耐久性，并且甚至当应用于燃料电池时可以长时间使用，同时抑制活性的降低; 使用该催化剂的一氧化碳转化方法; 以及使用通过一氧化碳转化法生产的氢的燃料电池系统。

公开(公告)号：US07776785B2

公开(公告)日：2010-08-17

申请号：US12445389

申请日：2007-10-10

申请人： Kozo Takatsu ,  Yoshimi Kawashima ,  Satoshi Nakai ,  Takashi Umeki

发明人： Kozo Takatsu ,  Yoshimi Kawashima ,  Satoshi Nakai ,  Takashi Umeki

IPC分类号： B01J23/06

CPC分类号： B01J23/80 ,  B01J23/002 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/03 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/31 ,  C01B3/16 ,  C01B3/38 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/066 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1258 ,  H01M8/0618 ,  Y02P20/52 ,  Y02P70/56

摘要： The invention provides a catalyst for carbon monoxide conversion, comprising from 10 to 90% by mass of a copper oxide ingredient, from 5 to 50% by mass of a zinc oxide ingredient and from 10 to 50% by mass of an aluminum oxide ingredient, and having a specific surface area of from 100 to 300 m2/g, a carbon monoxide adsorption of from 20 to 80 μmol/g, and a copper oxide crystallite diameter of at most 200 angstroms, as a catalyst suitable for carbon monoxide conversion for fully reducing carbon monoxide in the hydrogen gas obtained through reforming of a starting hydrocarbon material, for the purpose of enabling stable long-term operation of a fuel cell which uses hydrogen gas as a fuel and which is frequently and repeatedly started and stopped.

摘要翻译： 本发明提供一氧化碳转化用催化剂，其含有10〜90质量％的氧化铜成分，5〜50质量％的氧化锌成分和10〜50质量％的氧化铝成分， 比表面积为100〜300m2 / g，一氧化碳吸附量为20〜80μmol/ g，氧化铜微晶直径为200以下，作为适用于全部一氧化碳转化的催化剂 为了能够使使用氢气作为燃料的燃料电池能够稳定地长期运行并且频繁且反复地开始和停止的目的，减少通过原料烃材料的重整获得的氢气中的一氧化碳。

公开(公告)号：US20100112397A1

公开(公告)日：2010-05-06

申请号：US12594983

申请日：2008-04-02

申请人： Kozo Takatsu ,  Yoshimi Kawashima ,  Satoshi Nakai

发明人： Kozo Takatsu ,  Yoshimi Kawashima ,  Satoshi Nakai

IPC分类号： B01J23/06 ,  B01D53/62 ,  H01M8/06 ,  B01J23/72

CPC分类号： B01J35/006 ,  B01J23/80 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/03 ,  C01B3/16 ,  C01B3/326 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/066 ,  C01B2203/1076 ,  C01B2203/1223 ,  C01B2203/1288 ,  H01M8/0618 ,  H01M8/0668 ,  Y02P20/52

摘要： The present invention provides a catalyst precursor substance containing copper, zinc, and aluminum and exhibiting an X-ray diffraction pattern having a broad peak at a specific interplanar spacing d (Å). The present invention also provides a method for producing the catalyst precursor substance by mixing a solution containing a copper salt, a zinc salt, and an aluminum salt with a solution containing an alkali metal hydroxide or an alkaline earth metal hydroxide, thereby forming a precipitate. In the present invention, a catalyst is prepared through calcining of the catalyst precursor; the catalyst is employed for water gas shift reaction; and carbon monoxide conversion is carried out by use of the catalyst. Thus, the present invention also provides a catalyst useful for water gas shift reaction, which exhibits high activity and durability and which, even when applied to a fuel cell, can be used for a long period of time with reduction in activity being suppressed; a carbon monoxide conversion method employing the catalyst; and a fuel cell system employing hydrogen produced through the carbon monoxide conversion method.

摘要翻译： 本发明提供了含有铜，锌和铝的催化剂前体物质，并且具有在特定的晶面间距d（）下具有宽峰的X射线衍射图。 本发明还提供了通过将含有铜盐，锌盐和铝盐的溶液与含有碱金属氢氧化物或碱土金属氢氧化物的溶液混合从而形成沉淀物来制备催化剂前体物质的方法。 在本发明中，通过煅烧催化剂前体制备催化剂; 催化剂用于水煤气变换反应; 并且通过使用催化剂进行一氧化碳转化。 因此，本发明还提供了可用于水煤气变换反应的催化剂，其具有高活性和耐久性，并且甚至当应用于燃料电池时可以长时间使用，同时抑制活性的降低; 使用该催化剂的一氧化碳转化方法; 以及使用通过一氧化碳转化法生产的氢的燃料电池系统。

公开(公告)号：US07531361B2

公开(公告)日：2009-05-12

申请号：US11659965

申请日：2005-08-05

申请人： Kozo Takatsu ,  Gakuji Takegoshi

发明人： Kozo Takatsu ,  Gakuji Takegoshi

IPC分类号： G01N31/22

CPC分类号： G01N31/22 ,  H01M8/04089 ,  H01M8/0618 ,  H01M8/0675 ,  Y10T436/18 ,  Y10T436/182 ,  Y10T436/196666 ,  Y10T436/200833

摘要： Provided are a coloration agent for carbonyl sulfide which contains a metal oxide, and at least one metal component selected from among a cerium component, a silver component, a copper component, a nickel component, and an iron component, the metal component being supported on the metal oxide, or which contains at least one metal oxide selected from among a cerium oxide, a silver oxide, a copper oxide, a nickel oxide, and an iron oxide; carbonyl sulfide detection means including the coloration agent for carbonyl sulfide; and a fuel cell system including the detection means. The coloration agent for carbonyl sulfide has the ability to develop a color in the presence of carbonyl sulfide even at ambient temperature, exhibits excellent performance in detecting carbonyl sulfide contained in a hydrocarbon fuel, and enables the service life of a desulfurizing agent to be determined through visual observation.

摘要翻译： 提供了含有金属氧化物的硫化氢着色剂和选自铈成分，银成分，铜成分，镍成分和铁成分中的至少一种金属成分，金属成分被负载在 金属氧化物，或者含有选自氧化铈，氧化银，氧化铜，氧化镍和氧化铁中的至少一种金属氧化物; 包括硫化碳着色剂的羰基硫化物检测手段; 以及包括检测装置的燃料电池系统。 硫化钴着色剂即使在环境温度下也具有在硫化羰存在下显色的能力，在检测碳氢化合物燃料中所含羰基硫化物方面表现出优异的性能，并且可以通过以下方式确定脱硫剂的使用寿命： 目视观察。

公开(公告)号：US07892417B2

公开(公告)日：2011-02-22

申请号：US12104802

申请日：2008-04-17

申请人： Tetsuya Fukunaga ,  Tomoki Yanagino ,  Kozo Takatsu ,  Takashi Umeki

发明人： Tetsuya Fukunaga ,  Tomoki Yanagino ,  Kozo Takatsu ,  Takashi Umeki

IPC分类号： C07C1/00

CPC分类号： B01J37/0207 ,  B01J21/04 ,  B01J23/6562 ,  B01J23/8892 ,  B01J23/8913 ,  B01J23/892 ,  B01J23/894 ,  B01J23/8946 ,  B01J23/8986 ,  B01J37/0205 ,  B01J37/0236 ,  B01J37/08 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1082 ,  Y02P20/52

摘要： The present invention relates to a catalyst for reforming a hydrocarbon comprising a carrier containing manganese oxide and carried thereon (a) at least one component selected from a ruthenium component, a platinum component, a rhodium component, a palladium component, an iridium component and a nickel component and a process for producing the same and to a process for reforming a hydrocarbon (steam reforming, self thermal reforming, partial oxidation reforming and carbon dioxide reforming) using the above catalyst. Provided are a catalyst for reforming a hydrocarbon which comprises ruthenium, platinum, rhodium, palladium, iridium or nickel as an active component and in which a reforming activity is elevated, a process for producing the same, and a steam reforming process, a self thermal reforming process, a partial oxidation reforming process and a carbon dioxide reforming process for a hydrocarbon using the above catalyst.

摘要翻译： 本发明涉及一种用于重整烃的催化剂，其包含含有氧化锰的载体，并在其上载持（a）至少一种选自钌组分，铂组分，铑组分，钯组分，铱组分和 镍成分及其制造方法以及使用上述催化剂的碳氢化合物的重整方法（蒸汽重整，自热重整，部分氧化重整和二氧化碳重整）。 提供一种用于重整烃的催化剂，其包含钌，铂，铑，钯，铱或镍作为活性组分，其中重整活性升高，其制备方法和蒸汽重整过程，自热 重整过程，部分氧化重整过程和使用上述催化剂的烃的二氧化碳重整过程。

公开(公告)号：US20100015023A1

公开(公告)日：2010-01-21

申请号：US12445389

申请日：2007-10-10

申请人： Kozo Takatsu ,  Yoshimi Kawashima ,  Satoshi Nakai ,  Takashi Umeki

发明人： Kozo Takatsu ,  Yoshimi Kawashima ,  Satoshi Nakai ,  Takashi Umeki

IPC分类号： B01D53/62 ,  B01J23/80

CPC分类号： B01J23/80 ,  B01J23/002 ,  B01J35/002 ,  B01J35/006 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/03 ,  B01J2523/17 ,  B01J2523/27 ,  B01J2523/31 ,  C01B3/16 ,  C01B3/38 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/066 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1258 ,  H01M8/0618 ,  Y02P20/52 ,  Y02P70/56

摘要： The invention provides a catalyst for carbon monoxide conversion, comprising from 10 to 90% by mass of a copper oxide ingredient, from 5 to 50% by mass of a zinc oxide ingredient and from 10 to 50% by mass of an aluminum oxide ingredient, and having a specific surface area of from 100 to 300 m2/g, a carbon monoxide adsorption of from 20 to 80 μmol/g, and a copper oxide crystallite diameter of at most 200 angstroms, as a catalyst suitable for carbon monoxide conversion for fully reducing carbon monoxide in the hydrogen gas obtained through reforming of a starting hydrocarbon material, for the purpose of enabling stable long-term operation of a fuel cell which uses hydrogen gas as a fuel and which is frequently and repeatedly started and stopped.

摘要翻译： 本发明提供一氧化碳转化用催化剂，其含有10〜90质量％的氧化铜成分，5〜50质量％的氧化锌成分和10〜50质量％的氧化铝成分， 比表面积为100〜300m2 / g，一氧化碳吸附量为20〜80mumol / g，氧化铜微晶直径为200以下，作为适用于全部一氧化碳转化的催化剂 为了能够使使用氢气作为燃料的燃料电池能够稳定地长期运行并且频繁且反复地开始和停止的目的，减少通过原料烃材料的重整获得的氢气中的一氧化碳。

公开(公告)号：US07556872B2

公开(公告)日：2009-07-07

申请号：US10526397

申请日：2003-08-26

申请人： Kozo Takatsu ,  Gakuji Takegoshi

发明人： Kozo Takatsu ,  Gakuji Takegoshi

IPC分类号： H01M8/04 ,  C01B3/22 ,  C01B3/26

CPC分类号： B01J20/103 ,  B01J20/041 ,  B01J20/06 ,  B01J20/08 ,  B01J20/28004 ,  B01J20/28057 ,  B01J20/3007 ,  B01J20/3071 ,  B01J20/3078 ,  B01J2220/42 ,  C01B3/38 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0844 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/127 ,  C01B2203/1294 ,  C01B2203/142 ,  C01B2203/146 ,  C01B2203/82 ,  C10G25/00 ,  C10G2300/1025 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1059 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/202 ,  C10G2300/207

摘要： The present invention provides an adsorbent for removing sulfur compounds, which adsorbent can effectively remove a variety of sulfur compounds contained in a hydrocarbon fuel to a low concentration even at room temperature; a process for effectively producing hydrogen that can be used in a fuel cell; and a fuel cell system employing hydrogen produced through the process.The adsorbent for removing a sulfur compound contained in a hydrocarbon fuel contains cerium oxide. The process for producing hydrogen that can be used in a fuel cell includes desulfurizing a hydrocarbon fuel through removal of a sulfur compound contained in the a hydrocarbon fuel by use of the aforementioned adsorbent and, subsequently, bringing the thus-desulfurized fuel into contact with a partial-oxidation reforming catalyst, an authothermal reforming catalyst, or a steam reforming catalyst. The fuel cell system employs hydrogen produced through the process.

摘要翻译： 本发明提供了用于除去硫化合物的吸附剂，即使在室温下，该吸附剂也能够有效地将烃类燃料中所含的各种硫化合物除去至低浓度; 用于有效生产可用于燃料电池中的氢的方法; 以及使用通过该方法生产的氢的燃料电池系统。 用于除去烃燃料中所含的硫化合物的吸附剂含有氧化铈。 可用于燃料电池的生产氢气的方法包括通过使用上述吸附剂除去烃燃料中所含的硫化合物来脱硫烃燃料，随后使如此脱硫的燃料与 部分氧化重整催化剂，自热重整催化剂或蒸汽重整催化剂。 燃料电池系统采用通过该方法生产的氢。