公开(公告)号：US4508836A

公开(公告)日：1985-04-02

申请号：US472822

申请日：1983-03-07

Applicant: Werner O. Haag ,  David H. Olson ,  Paul G. Rodewald

Inventor： Werner O. Haag ,  David H. Olson ,  Paul G. Rodewald

IPC: B01J29/40 ,  B01J29/90 ,  B01J38/10 ,  C07C2/66 ,  C07C5/27 ,  C07C6/12 ,  B01J29/38 ,  C07C5/22

CPC classification number: C07C6/123 ,  B01J29/40 ,  B01J29/90 ,  C07C2/66 ,  C07C5/2708 ,  B01J2229/12 ,  B01J2229/34 ,  B01J38/10 ,  C07C2521/04 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P20/584

Abstract: In the process of converting an aromatic feedstock to an alkyl-substituted mono-nuclear aromatic product by contacting the feedstock with a coke-selectivated ZSM-5 type catalyst at elevated temperature under conversion process coking conditions to produce said alkyl-1-substituted mononuclear aromatic product selectively, the improvement which comprises:regenerating the process coked catalyst in contact with a non-oxidizing atmosphere comprising an effective amount of hydrogen at a temperature of about 800.degree. F. to 1200.degree. F. to restore activity of the catalyst while retaining selectivity. Advantageously, the conversion involves alkylation, disproportionation and/or isomerization to produce at least one lower alkyl or dialkyl benzene product.

Abstract translation: 在将芳族原料转化为烷基取代的单核芳香族产物的过程中，通过在转化工艺焦化条件下在升高的温度下使原料与焦炭选择性ZSM-5型催化剂接触以产生所述烷基-1-取代的单核芳族 产物选择性地，其改进包括：使工艺焦化催化剂与包含有效量氢的非氧化性气氛在约800-1200°F的温度下再生，以恢复催化剂的活性，同时保持选择性 。 有利地，转化涉及烷基化，歧化和/或异构化以产生至少一种低级烷基或二烷基苯产物。

公开(公告)号：US4477583A

公开(公告)日：1984-10-16

申请号：US502856

申请日：1983-06-09

Applicant: Paul G. Rodewald

Inventor： Paul G. Rodewald

IPC: B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J29/80 ,  B01J37/02 ,  B01J37/08 ,  C07B61/00 ,  C07C1/00 ,  C07C2/66 ,  C07C2/86 ,  C07C5/22 ,  C07C6/12 ,  C07C15/02 ,  C07C67/00 ,  B01J29/28

CPC classification number: C07C2/66 ,  B01J29/40 ,  B01J37/0219 ,  B01J37/082 ,  B01J37/086 ,  C07C2/864 ,  B01J2229/12 ,  B01J2229/32 ,  B01J29/65 ,  B01J29/70 ,  B01J29/80 ,  C07C2529/40 ,  Y02P20/52

Abstract: The present invention relates to a new method for preparing a composition comprised of a crystalline zeolite having deposited thereon a coating of silica which extensively covers and resides substantially exclusively on the external surface thereof, and to the composition so prepared.

Abstract translation: 本发明涉及一种制备组合物的新方法，该组合物由结晶沸石沉积在其上大体上完全覆盖并基本上仅存在于其外表面上的二氧化硅涂层，以及如此制备的组合物。

公开(公告)号：US4300009A

公开(公告)日：1981-11-10

申请号：US150109

申请日：1980-05-15

Applicant: Werner O. Haag ,  Paul G. Rodewald ,  Paul B. Weisz

Inventor： Werner O. Haag ,  Paul G. Rodewald ,  Paul B. Weisz

IPC: C07C1/00 ,  C10G3/00 ,  C07C11/20

CPC classification number: C07C1/00 ,  C10G3/49 ,  C10G3/50 ,  C07C2529/08 ,  C07C2529/40 ,  C07C2529/70 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  Y02P30/20

Abstract: Living plants and animals synthesize and often accumulate a wide variety of organic materials having a molecular weight greater than 150. These include different chemical types such as natural hydrocarbons including rubbery substances, natural resins, and natural glycerides such as oils and fats. These substances, formed in the anabolic process, are collectively called "anabolites".This invention provides a process for catalytically converting certain anabolites to liquid hydrocarbons useful for the manufacture of fuels such as gasoline and chemicals such as para-xylene. Crystalline aluminosilicate zeolites having an effective pore size of greater than about 5 Angstrom units are useful catalysts.

Abstract translation: 活的植物和动物合成并经常积聚分子量大于150的各种各样的有机材料。它们包括不同的化学类型，例如包括橡胶状物质的天然烃，天然树脂和天然甘油酯如油和脂肪。 在合成代谢过程中形成的这些物质统称为“代谢物”。 本发明提供了将某些合成代谢物催化转化成液体烃的方法，所述液体烃可用于制造燃料如汽油和化学品如对二甲苯。 具有大于约5埃单位的有效孔径的结晶硅铝酸盐沸石是有用的催化剂。

公开(公告)号：US4127616A

公开(公告)日：1978-11-28

申请号：US869732

申请日：1978-01-16

Applicant: Paul G. Rodewald

Inventor： Paul G. Rodewald

IPC: B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C07C2/00 ,  C07C2/66 ,  C07C2/76 ,  C07C2/86 ,  C07C4/00 ,  C07C5/41 ,  C07C3/52 ,  C07C3/62

CPC classification number: C07C4/00 ,  B01J29/40 ,  C07C2/00 ,  C07C2/66 ,  C07C2/76 ,  C07C2/864 ,  C07C5/41 ,  B01J2229/12 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70 ,  Y02P20/52

Abstract: A process is provided for the selective production of para dialkyl substituted benzenes wherein the alkyl group contains from 1 to 4 carbon atoms which comprises contacting, under conversion conditions, a hydrocarbon precursor selected from the group consisting of mono alkyl-substituted benzenes having 1-4 carbon atoms in the alkyl substituent and a mixture of said precursor or benzene with an alkylating agent containing from 1 to 4 carbon atoms with a catalyst comprising a porous crystalline aluminosilicate zeolite having deposited thereon a coating of silica which extensively covers and resides substantially exclusively on the external surface thereof, said zeolite being characterized by an activity, in terms of alpha value, of between about 2 and about 5000, a xylene sorption capacity greater than 1 gram/100 grams of zeolite and an ortho xylene sorption time for 30 percent of said capacity greater than 10 minutes, said sorption capacity and sorption time being measured at 120.degree. C and a pressure of 4.5 .+-. 0.8 mm. of mercury and recovering from the resulting product mixture, a para dialkyl substituted benzene in an amount greater than the thermodynamic equilibrium concentration thereof in the total dialkyl substituted benzenes produced.

Abstract translation: 提供了一种选择性生产对二烷基取代的苯的方法，其中烷基含有1至4个碳原子，其包括在转化条件下使烃前体选自下组的烃前体：单烷基取代的苯，其具有1-4个 烷基取代基中的碳原子和所述前体或苯与含有1至4个碳原子的烷基化剂的混合物与催化剂的混合物，所述催化剂包含多孔结晶硅铝酸盐沸石，其上沉积有二氧化硅涂层，其广泛地覆盖并基本上位于 所述沸石的特征在于α值在约2至约5000之间的活性，大于1克/ 100克沸石的二甲苯吸附容量和所述沸石的30％的邻二甲苯吸附时间 容量大于10分钟，所述吸附容量和吸附时间在120℃下测量 压力为4.5 +/- 0.8mm。 的汞并从所得到的产物混合物中回收，所产生的总二烷基取代的苯中的对二烷基取代的苯的量大于其热力学平衡浓度。

公开(公告)号：US4100219A

公开(公告)日：1978-07-11

申请号：US753748

申请日：1976-12-23

Applicant: Paul G. Rodewald

Inventor： Paul G. Rodewald

IPC: B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C07C1/20 ,  C07C1/24

CPC classification number: B01J29/40 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70

Abstract: A catalyst is provided, which is especially applicable for the selective production of C.sub.2 -C.sub.3 olefins, comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12, a constraint index, as hereinafter defined, within the approximate range of 1 to 12 and having contained within the interior crystalline structure thereof added amorphous silica in an amount of at least about 0.3 and preferably between about 0.5 and about 30 weight percent. The resultant catalyst is characterized by n-hexane sorption capacity at a temperature of 90.degree. C and a n-hexane partial pressure of 83 mm. of mercury which is at least 1 percent less than corresponding sorption capacity under identical conditions for the unmodified zeolite. Generally, the n-hexane sorption capacity for the described silica-modified zeolite, at the above specified conditions, is 5 to 60 percent less than that for the zeolite which has not undergone treatment to incorporate amorphous silica therein. The invention described herein also encompasses synthesis of the specified catalyst and use of the same in selectively converting lower monohydric alcohols and their ethers, especially methanol and dimethyl ether, to a hydrocarbon mixture rich in ethylene and propylene.

Abstract translation: 提供了一种催化剂，其特别适用于选择性生产C2-C3烯烃，其包含二氧化硅与氧化铝之比至少为约12的结晶硅铝酸盐沸石，约定指数如下所定义，在约1的范围内 至12，并且其内部结晶结构中含有至少约0.3，优选约0.5至约30重量％的量的无定形二氧化硅。 所得催化剂的特征在于在90℃的温度和83毫秒的正己烷分压下的正己烷吸附容量。 的汞在未改性沸石的相同条件下比相应的吸附容量小至少1％。 通常，在上述特定条件下，所述二氧化硅改性沸石的正己烷吸附容量比没有经过处理以在其中掺入无定形二氧化硅的沸石的正己烷吸附容量小5至60％。 本文所述的本发明还包括合成规定的催化剂及其在将低级一元醇及其醚，特别是甲醇和二甲醚选择性转化成富烯烃和丙烯的烃混合物时的用途。

公开(公告)号：US3944501A

公开(公告)日：1976-03-16

申请号：US406997

申请日：1973-10-16

Applicant: Darrell D. Whitehurst ,  Stephen A. Butter ,  Paul G. Rodewald

Inventor： Darrell D. Whitehurst ,  Stephen A. Butter ,  Paul G. Rodewald

IPC: B01J20/22 ,  C10G25/02 ,  B01J1/22 ,  B01D15/00 ,  C09K3/32

CPC classification number: B01J20/22 ,  C10G25/02

Abstract: A novel use for sorbents involving the selective removal of heavy metals from liquid streams has been discovered. More specifically it has been discovered that these sorbents selectively remove alkyl lead moieties from gasoline. The sorbents are comprised of metal halides (preferably tin tetrachloride or antimony pentachloride) bonded to a suitable substrate through at least one amine or alkyl halide functional group. The sorbents can be effectively regenerated.

Abstract translation: 已经发现了一种用于涉及从液体流中选择性去除重金属的吸附剂的新用途。 更具体地，已经发现这些吸附剂选择性地从汽油中除去烷基铅部分。 吸附剂由金属卤化物（优选四氯化锡或五氯化锑）组成，通过至少一种胺或烷基卤官能团与合适的底物结合。 吸附剂可以有效再生。

公开(公告)号：US5726114A

公开(公告)日：1998-03-10

申请号：US516435

申请日：1995-08-17

Applicant: Clarence D. Chang ,  John D. Lutner ,  Sharon B. McCullen ,  Paul G. Rodewald ,  David S. Shihabi

Inventor： Clarence D. Chang ,  John D. Lutner ,  Sharon B. McCullen ,  Paul G. Rodewald ,  David S. Shihabi

IPC: B01J29/40 ,  B01J31/02 ,  B01J37/08 ,  C07C6/12 ,  B01J29/06

CPC classification number: C07C6/123 ,  B01J29/40 ,  B01J37/086 ,  B01J2229/12 ,  B01J2229/32 ,  B01J2229/42 ,  C07C2529/00

Abstract: A method of preparing a modified catalytic molecular sieve for enhanced shape selective hydrocarbon conversions in which a catalytic molecular sieve is modified by being exposed to at least one ex situ selectivation sequence, each sequence including an impregnation of the molecular sieve with a selectivating agent in an aqueous emulsion and a subsequent calcination of the impregnated molecular sieve. The selectivating agent compositions for the ex situ selectivation method are also described, including the selectivating agents, the surfactants, and the aqueous components. Also, a method for moderate steaming of the ex situ selectivated molecular sieve. Also a method for in situ trim-selectivating the ex situ selectivated catalytic molecular sieve. Also described is the modified catalytic molecular sieve modified by this method. Also described is a process for shape selective hydrocarbon conversion comprising contacting a hydrocarbon feedstream under conversion conditions with the modified catalytic molecular sieve.

Abstract translation: 一种制备用于增强形状选择性烃转化的改性催化分子筛的方法，其中催化分子筛通过暴露于至少一种非原位选择活性序列来修饰，每个序列包括用选择性试剂浸渍分子筛 水性乳液，随后煅烧浸渍的分子筛。 还描述了用于异位选择方法的选择性试剂组合物，包括选择性试剂，表面活性剂和水性组分。 另外，用于非原位选择性分子筛的中等蒸度的方法。 还有一种用于原位选择活化的催化分子筛的原位选择方法。 还描述了通过该方法改性的改性催化分子筛。 还描述了一种用于形状选择性烃转化的方法，其包括在转化条件下使烃进料流与改性的催化分子筛接触。

公开(公告)号：US5349113A

公开(公告)日：1994-09-20

申请号：US22205

申请日：1993-02-25

Applicant: Clarence D. Chang ,  Paul G. Rodewald

Inventor： Clarence D. Chang ,  Paul G. Rodewald

IPC: B01J29/40 ,  B01J31/02 ,  C07C6/12 ,  C07C5/52

CPC classification number: C07C6/123 ,  B01J29/40 ,  B01J2229/12 ,  B01J2229/123 ,  B01J2229/32 ,  B01J2229/42

Abstract: A process for a shape selective hydrocarbon conversion such as toluene disproportionation involves contacting a reaction stream under conversion conditions with a catalytic molecular sieve which has been pre-selectivated and concurrently activated by contact with a substantially aqueous solution of an organosilicon compound. The invention also includes a method for concurrently preselectivating and activating a catalyst and the shape selectivated, activated catalyst which results from this method.

Abstract translation: 形成选择性碳氢化合物转化的方法如甲苯歧化过程包括使转化条件下的反应物流与催化分子筛接触，所述催化分子筛已经预选择并通过与基本上有机硅化合物的水溶液接触同时活化。 本发明还包括同时预选择和活化催化剂和由该方法产生的形状选择活化的催化剂的方法。

公开(公告)号：US5057640A

公开(公告)日：1991-10-15

申请号：US636857

申请日：1991-01-02

Applicant: Clarence D. Chang ,  Paul G. Rodewald

Inventor： Clarence D. Chang ,  Paul G. Rodewald

IPC: B01J29/06 ,  B01J29/40 ,  C07B61/00 ,  C07C2/12 ,  C07C11/02

CPC classification number: C07C2/12 ,  B01J29/40 ,  B01J2229/14 ,  B01J2229/32 ,  C07C2529/40 ,  Y02P20/52

Abstract: There is provided a process for oligomerizing propylene by contacting propylene with silica modified zeolites. The modification of the zeolite with silica results in a product which is enriched in hydrocarbons falling within the boiling range of jet fuel (330.degree.-480.degree. F.) and diesel fuel (480.degree.-650.degree. F.). The zeolite may be ZSM-5, which may be modified by sorbing methylhydrogensilicone into the pores of the zeolite followed by calcination to convert the sorbed methylhydrogensilicone into amorphous silica.

Abstract translation: 提供了通过使丙烯与二氧化硅改性沸石接触来使丙烯低聚的方法。 用二氧化硅改性沸石产生的一种富含烃类物质落入喷气燃料沸点范围（330°-480°F）和柴油（480°-650°F）的产物。 沸石可以是ZSM-5，其可以通过将甲基氢硅酮吸附到沸石的孔中，然后煅烧以将吸附的甲基氢硅氧烷转化成无定形二氧化硅来进行改性。

公开(公告)号：US5035818A

公开(公告)日：1991-07-30

申请号：US476082

申请日：1990-02-07

Applicant: Catherine S. H. Chen ,  Paul G. Rodewald

Inventor： Catherine S. H. Chen ,  Paul G. Rodewald

IPC: C07G99/00 ,  C10M105/68 ,  C10M105/72 ,  C10M133/16 ,  C10M135/10

CPC classification number: C07G17/004 ,  C10M105/68 ,  C10M105/72 ,  C10M133/16 ,  C10M135/10 ,  C10M2215/08 ,  C10M2219/044

Abstract: Oligomers produced from lower alkenes by acidic zeolite catalyzed oligomerization can be converted to useful lubricant additives or lubricants by amidation and sulfonation of olefinic bonds in the oligomers by reaction with nitriles in the presence of strong acid catalyst whereby oligomer derivatives containing amide groups and sulfonic acid groups are produced. The products so produced from C.sub.20 + olefins exhibit favorable qualities as lubricants. The discovery is particularly applicable to the amidation and sulfonation of oligomers produced from lower olefins such as propylene by oligomerization using a ZSM-5 catalyst which has been surface deactivated.

Abstract translation: 通过酸性沸石催化低聚产生的低级烯烃产生的低聚物可以通过在强酸催化剂存在下与腈反应而在低聚物中通过酰胺化和磺化烯烃键转化为有用的润滑剂添加剂或润滑剂，从而含有酰胺基和磺酸基的低聚物衍生物 被生产。 由C20 +烯烃生产的产品具有润滑油的优良品质。 该发现特别适用于使用已被表面去活化的ZSM-5催化剂通过低聚而由低级烯烃如丙烯生产的低聚物的酰胺化和磺化。