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    Hydrogen regeneration of coke-selectivated crystalline aluminosilicate catalyst
    2.
    发明授权
    Hydrogen regeneration of coke-selectivated crystalline aluminosilicate catalyst 失效
    焦炭选择性结晶硅铝酸盐催化剂的氢再生

    公开(公告)号：US4358395A

    公开(公告)日：1982-11-09

    申请号：US941606

    申请日：1978-09-11

    申请人： Werner O. Haag ,  David H. Olson ,  Paul G. Rodewald

    发明人： Werner O. Haag ,  David H. Olson ,  Paul G. Rodewald

    IPC分类号： B01J29/90 ,  B01J38/10 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C2/66 ,  C07C5/27 ,  C07C6/12 ,  C07C15/02 ,  C07C15/08 ,  C07C67/00 ,  B01J29/38 ,  C07C1/24 ,  C07C5/22

    CPC分类号： C07C6/123 ,  B01J29/90 ,  C07C1/20 ,  C07C2/66 ,  C07C5/2708 ,  B01J2229/123 ,  B01J38/10 ,  C07C2529/40 ,  Y02P20/584

    摘要： A method is provided for regeneration of a catalyst comprising a crystalline aluminosilicate zeolite characterized by a silica to alumina mole ratio of at least about 12, a constraint index, as hereinafter defined, within the approximate range of 1 to 12, which catalyst has undergone controlled precoking by exposing the same to a thermally decomposable organic compound at a temperature in excess of the decomposition temperature of said compound but less than about 1200.degree. F., at a hydrogen to organic compound mole ratio of between 0 and 1 to deposit at least about 1 weight percent coke thereon, such precoked catalyst having been deactivated by formation of a carbonaceous deposit thereon as a result of use of the same in catalytically converting an organic charge under conditions less severe, i.e., at a lower temperature and/or a higher hydrogen concentration than those employed during said precoking which comprises contacting the aged catalyst with an atmosphere comprising hydrogen at a temperature between about 800.degree. F. and about 1200.degree. F. and a pressure between about 0 and about 2000 psig for a period of time sufficient to at least partially restore the activity of the catalyst.

    摘要翻译： 提供了一种用于再生包含结晶硅铝酸盐沸石的催化剂的方法，其特征在于二氧化硅与氧化铝的摩尔比为至少约12，下文定义的约束指数在约12至约12的范围内，该催化剂已被控制 通过在超过所述化合物的分解温度但小于约1200°F的温度下将其暴露于可热分解的有机化合物中，在氢与有机化合物的摩尔比为0至1之间进行沉淀，以沉积至少约 其中焦炭重量为1％，这种预制催化剂已经通过在其上形成碳质沉积物而失活，其结果是在不太严格的条件下即在较低温度和/或较高的氢气条件下催化转化有机电荷 浓度高于在所述预处理中使用的浓度，其包括使老化的催化剂与包含氢气的气氛接触 约800°F至约1200°F之间的温度和约0至约2000psig的压力持续足以至少部分恢复催化剂活性的时间。

    Conversion of biological material to liquid fuels
    3.
    发明授权
    Conversion of biological material to liquid fuels 失效
    将生物材料转化为液体燃料

    公开(公告)号：US4300009A

    公开(公告)日：1981-11-10

    申请号：US150109

    申请日：1980-05-15

    申请人： Werner O. Haag ,  Paul G. Rodewald ,  Paul B. Weisz

    发明人： Werner O. Haag ,  Paul G. Rodewald ,  Paul B. Weisz

    IPC分类号： C07C1/00 ,  C10G3/00 ,  C07C11/20

    CPC分类号： C07C1/00 ,  C10G3/49 ,  C10G3/50 ,  C07C2529/08 ,  C07C2529/40 ,  C07C2529/70 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  Y02P30/20

    摘要： Living plants and animals synthesize and often accumulate a wide variety of organic materials having a molecular weight greater than 150. These include different chemical types such as natural hydrocarbons including rubbery substances, natural resins, and natural glycerides such as oils and fats. These substances, formed in the anabolic process, are collectively called "anabolites".This invention provides a process for catalytically converting certain anabolites to liquid hydrocarbons useful for the manufacture of fuels such as gasoline and chemicals such as para-xylene. Crystalline aluminosilicate zeolites having an effective pore size of greater than about 5 Angstrom units are useful catalysts.

    摘要翻译： 活的植物和动物合成并经常积聚分子量大于150的各种各样的有机材料。它们包括不同的化学类型，例如包括橡胶状物质的天然烃，天然树脂和天然甘油酯如油和脂肪。 在合成代谢过程中形成的这些物质统称为“代谢物”。 本发明提供了将某些合成代谢物催化转化成液体烃的方法，所述液体烃可用于制造燃料如汽油和化学品如对二甲苯。 具有大于约5埃单位的有效孔径的结晶硅铝酸盐沸石是有用的催化剂。

    Selective disproportionation of toluene
    6.
    发明授权
    Selective disproportionation of toluene 失效
    甲苯的选择性歧化

    公开(公告)号：US4097543A

    公开(公告)日：1978-06-27

    申请号：US760893

    申请日：1977-01-21

    申请人： Werner O. Haag ,  David H. Olson

    发明人： Werner O. Haag ,  David H. Olson

    IPC分类号： B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C07C3/62

    CPC分类号： B01J29/40 ,  B01J2229/12 ,  B01J2229/26 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70

    摘要： A catalytic process is provided for the selective production of para-xylene by disproportionation of toluene in the presence of a catalyst comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12 and a constraint index within the approximate range of 1 to 12, which catalyst has undergone controlled precoking, i.e. selectivation, by exposing the same to a thermally decomposable organic compound at a temperature in excess of the decomposition temperature of said compound, generally greater than 1000.degree. F., but less than about 1200.degree. F., at a hydrogen to organic compound mole ratio between 0 and 1 to deposit at least about 2 weight percent coke thereon and thereafter contacting toluene with the resulting coke-containing catalyst under disproportionation conditions including a temperature between about 800.degree. F. and 1025.degree. F., and preferably between about 825.degree. F. and 1000.degree. F., at a hydrogen to toluene mole ratio greater than 1 and up to about 10 and recovering a product mixture containing para-xylene in an amount greater than the thermodynamic equilibrium concentration thereof in the total xylenes produced.

    摘要翻译： 提供了一种催化方法，用于通过在包含二氧化硅与氧化铝比为至少约12的结晶硅铝酸盐沸石的催化剂存在下甲苯的歧化来选择性生产对二甲苯，约束指数在约1至 如图12所示，该催化剂经过可控制的预炼，即选择性，通过在超过所述化合物的分解温度的温度下将其暴露于可热分解的有机化合物，通常大于1000°F，但小于约1200°F 在氢与有机化合物的摩尔比为0和1之间沉积至少约2重量％的焦炭，然后在包括温度在约800°至1025°之间的歧化条件下将甲苯与所得的含焦炭催化剂接触。 F，优选在约825°F至1000°F之间，氢气与甲苯的摩尔比大于1， p至约10，并回收含有大于其产生的总二甲苯中的热力学平衡浓度的含对二甲苯的产物混合物。

    Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
    7.
    发明授权
    Alkylation in presence of thermally modified crystalline aluminosilicate catalyst 失效
    在热改性结晶硅铝酸盐催化剂存在下烷基化

    公开(公告)号：US4016218A

    公开(公告)日：1977-04-05

    申请号：US582025

    申请日：1975-05-29

    申请人： Werner O. Haag ,  David H. Olson

    发明人： Werner O. Haag ,  David H. Olson

    IPC分类号： B01J29/00 ,  B01J29/40 ,  C07B61/00 ,  C07C1/00 ,  C07C2/66 ,  C07C15/02 ,  C07C67/00 ,  C07C3/52

    CPC分类号： B01J29/40 ,  C07C2/66 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/40 ,  B01J2229/42 ,  C07C2521/04 ,  C07C2529/40 ,  Y10S585/906

    摘要： Process for the alkylation of aromatic hydrocarbons by contacting same with an olefin alkylating agent in a reaction zone maintained under conditions such that said alkylation is accomplished in the presence of a catalyst comprising a crystalline aluminosilicate zeolite, said zeolite having a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12, said catalyst having been modified by prior thermal treatment to reduce the activity thereof, as determined by an alpha value, as described herein, to less than about 250 and preferably within the range of less than about 200 but greater than 10.

    摘要翻译： 芳族烃的烷基化方法是通过在反应区中与烯烃烷基化试剂接触而进行的，所述反应区保持在使得所述烷基化在包含结晶硅铝酸盐沸石的催化剂存在下完成的条件下，所述沸石的二氧化硅与氧化铝的比例为 至少约12和约1到12的约束指数，所述催化剂已经通过先前的热处理进行了修饰，以将其活性降低，如本文所述的α值确定为小于 约250，优选在小于约200但大于10的范围内。

    Xylene isomerization
    8.
    发明授权
    Xylene isomerization 失效
    二甲苯异构化

    公开(公告)号：US4159282A

    公开(公告)日：1979-06-26

    申请号：US913999

    申请日：1978-06-09

    申请人： David H. Olson ,  Werner O. Haag

    发明人： David H. Olson ,  Werner O. Haag

    IPC分类号： B01J29/00 ,  B01J29/40 ,  C07B61/00 ,  C07C1/00 ,  C07C5/27 ,  C07C15/08 ,  C07C67/00 ,  C07C5/24

    CPC分类号： C07C5/2775 ,  Y02P20/52

    摘要： A catalytic process is provided for isomerizing an isomerization feed containing an aromatic C.sub.8 mixture of ethylbenzene and xylene in which the para-xylene content is less than equilibrium which comprises contacting said feed, under conversion conditions, with a catalyst comprising a crystalline aluminosilicate zeolite having a crystal size of at least about 1 micron, a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12 to yield an isomerization product characterized by a reduced ethylbenzene content and an enhanced para-xylene content.

    摘要翻译： {PG，1提供了异构化异构化进料异构化的异构化原料，该异构化进料含有芳族C {HD 8 {乙基苯和二甲苯的混合物，其中对二甲苯含量小于平衡，其包括在转化条件下将所述进料与 催化剂，其包含晶体尺寸为至少约1微米，二氧化硅与氧化铝之比为至少约12的结晶硅铝酸盐沸石和约1至12的约束指数，以产生异构化产物 其特征在于乙苯含量降低和对二甲苯含量增加。

    Alkylation/transalkylation in presence of crystalline aluminosilicate catalyst
    9.
    发明授权
    Alkylation/transalkylation in presence of crystalline aluminosilicate catalyst 失效
    在结晶硅铝酸盐催化剂存在下进行烷基化/烷基转移

    公开(公告)号：US4070407A

    公开(公告)日：1978-01-24

    申请号：US580864

    申请日：1975-05-27

    申请人： Werner O. Haag ,  David H. Olson

    发明人： Werner O. Haag ,  David H. Olson

    IPC分类号： B01J29/65 ,  C07C2/66 ,  C07C2/86 ,  C07C6/12 ,  C07C3/52 ,  C07C3/62

    CPC分类号： C07C2/864 ,  B01J29/65 ,  C07C2/66 ,  C07C6/123 ,  C07C6/126 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2529/06

    摘要： A process is provided for alkylation or transalkylation of aromatic hydrocarbons by contacting same with an alkylating or transalkylating agent in a reaction zone maintained under alkylation/transalkylation effective conditions and in the presence of a catalyst comprising a crystalline aluminosilicate zeolite characterized by a unique X-ray diffraction pattern, said catalyst under said conditions being capable of affording a high and selective yield of desired alkylaromatic product while maintaining excellent aging properties.

    摘要翻译： 提供了通过在烷基化/烷基转移反应有效条件下保持的反应区中与烷基化或烷基转移剂接触，并且在包含结晶硅铝酸盐沸石的催化剂存在下，芳族烃的烷基化或烷基转移的方法，其特征在于独特的X射线 所述催化剂在所述条件下能够提供所需烷基芳族化合物的高选择性产率，同时保持优异的老化性能。

    Selective production of para dialkyl substituted benzenes
    10.
    发明授权
    Selective production of para dialkyl substituted benzenes 失效
    选择性生产PARA二烷基取代的苯乙烯

    公开(公告)号：US4117026A

    公开(公告)日：1978-09-26

    申请号：US841073

    申请日：1977-10-11

    申请人： Werner O. Haag ,  David H. Olson

    发明人： Werner O. Haag ,  David H. Olson

    IPC分类号： B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C07C3/52 ,  C07C3/62

    CPC分类号： B01J29/40 ,  B01J2229/12 ,  B01J2229/26 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70 ,  C07C2529/40 ,  C07C2529/65 ,  C07C2529/70

    摘要： A catalytic process is provided for the selective production of para dialkyl substituted benzenes containing alkyl groups of 1 to 4 carbon atoms, typified by para-xylene, by contacting, under conversion conditions, a hydrocarbon precursor selected from the group consisting of mono alkyl-substituted benzenes having 1-4 carbon atoms in the alkyl substituent, e.g., toluene, ethyl benzene, propyl benzene, or butyl benzene; a C.sub.2 -C.sub.15 olefin and a C.sub.3 -C.sub.60 paraffin, or mixtures thereof including mixtures of benzene with at least one of the aforementioned olefins or paraffins with a zeolite-containing catalyst characterized by a xylene sorption capacity greater than 1 gram/100 grams of zeolite and an ortho xylene sorption time for 30 percent of said capacity of greater than 10 minutes, said sorption capacity and sorption time being measured at 120.degree. C and a xylene pressure of 4.5 .+-.0.8 mm. of mercury, said catalyst comprising a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12 and recovering from the resulting product mixture, a para dialkyl substituted benzene in an amount greater than the thermodynamic equilibrium concentration thereof in total dialkyl substituted benzenes produced.