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公开(公告)号：US20140037523A1
公开(公告)日：2014-02-06
申请号：US13966382
申请日：2013-08-14
申请人： Todd Howard Ballinger , Philip Gerald Blakeman , Guy Richard Chandler , Hai-Ying Chen , Julian Peter Cox , Joseph M. Fedeyko , Alexander Nicholas Michael Green , Paul Richard Phillips , Stuart David Reid , Erich Conlan Weigert , James Alexander Wylie
发明人： Todd Howard Ballinger , Philip Gerald Blakeman , Guy Richard Chandler , Hai-Ying Chen , Julian Peter Cox , Joseph M. Fedeyko , Alexander Nicholas Michael Green , Paul Richard Phillips , Stuart David Reid , Erich Conlan Weigert , James Alexander Wylie
CPC分类号： B01J29/763 , B01D53/565 , B01D53/8621 , B01D53/9413 , B01D53/9418 , B01D53/9422 , B01D2251/2062 , B01D2251/2067 , B01D2255/2065 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9202 , B01D2258/012 , B01J29/7065 , B01J35/023 , B01J37/0009 , B01J37/0215 , B01J37/0246 , B01J2229/186 , B01J2229/42
摘要： A catalyst composition is provided having a zeolite material of a CHA crystal structure and a silica to alumina mole ratio (SAR) of about 10 to about 25 and preferably having a mean crystal size of at least 1.0 microns; and a non-aluminum base metal (M), wherein said zeolite material contains said base metal in a base metal to aluminum ratio (M:Al) of about 0.10 to about 0.24.
摘要翻译： 提供一种催化剂组合物，其具有CHA晶体结构的沸石材料和约10至约25的二氧化硅与氧化铝的摩尔比（SAR），优选具有至少1.0微米的平均晶体尺寸; 和非铝贱金属（M），其中所述沸石材料含有基本金属与铝的比例（M:Al）为约0.10至约0.24的所述贱金属。
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公开(公告)号：US20140079616A1
公开(公告)日：2014-03-20
申请号：US14110565
申请日：2012-01-23
CPC分类号： B01J29/85 , B01D53/58 , B01D53/9436 , B01D53/945 , B01D53/9477 , B01D2255/1021 , B01D2255/20761 , B01D2255/50 , B01D2255/9022 , B01J29/072 , B01J29/076 , B01J29/763 , B01J37/0244 , B01J37/0246 , F01N3/101 , Y02T10/22
摘要： A system for reducing ammonia (NH3) emissions includes (a) a first component comprising a first substrate containing a three-way catalyst, wherein the first component is disposed upstream of a second component comprising a second substrate containing an ammonia oxidation catalyst, wherein said ammonia oxidation catalyst comprises a small pore molecular sieve supporting at least one transition metal; and (b) an oxygen-containing gas input disposed between the components. For example, a CHA Framework Type small pore molecular sieve may be used. A method for reducing NH3 emission includes introducing an oxygen-containing gas into a gas stream to produce an oxygenated gas stream; and exposing the oxygenated gas stream to an NH3 oxidation catalyst to selectively oxidize at least a portion of the NH3 to N2. The method may further include the step of exposing a rich burn exhaust gas to a three-way catalyst to produce the gas stream comprising NH3.
摘要翻译： 用于还原氨（NH 3）排放的系统包括（a）第一组分，其包含含有三元催化剂的第一基质，其中所述第一组分设置在包含含有氨氧化催化剂的第二底物的第二组分的上游，其中所述 氨氧化催化剂包括支撑至少一种过渡金属的小孔分子筛; 和（b）设置在所述部件之间的含氧气体输入。 例如，可以使用CHA框架型小孔分子筛。 减少NH 3排放的方法包括将含氧气体引入气流中以产生氧化气流; 并将氧化的气流暴露于NH 3氧化催化剂以选择性地将至少一部分NH 3氧化成N 2。 该方法还可以包括将富燃烧废气暴露于三元催化剂以产生包含NH 3的气流的步骤。
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13.发明授权公开(公告)号：US08101146B2
公开(公告)日：2012-01-24
申请号：US13083154
申请日：2011-04-08
CPC分类号： B01J29/85 , B01D53/9436 , B01D53/945 , B01D53/9477 , B01D2255/1021 , B01D2255/20761 , B01D2255/50 , B01D2255/9022 , B01J23/42 , B01J29/072 , B01J29/076 , B01J29/763 , B01J35/0006 , B01J37/0244 , B01J37/0246 , Y02A50/2346 , Y02T10/22
摘要： A system for reducing ammonia (NH3) emissions includes (a) a first component comprising a first substrate containing a three-way catalyst, wherein the first component is disposed upstream of a second component comprising a second substrate containing an ammonia oxidation catalyst, wherein said ammonia oxidation catalyst comprises a small pore molecular sieve supporting at least one transition metal; and (b) an oxygen-containing gas input disposed between the components. For example, a CHA Framework Type small pore molecular sieve may be used. A method for reducing NH3 emission includes introducing an oxygen-containing gas into a gas stream to produce an oxygenated gas stream; and exposing the oxygenated gas stream to an NH3 oxidation catalyst to selectively oxidize at least a portion of the NH3 to N2.
摘要翻译： 用于还原氨（NH 3）排放的系统包括（a）第一组分，其包含含有三元催化剂的第一基质，其中所述第一组分设置在包含含有氨氧化催化剂的第二底物的第二组分的上游，其中所述 氨氧化催化剂包括支撑至少一种过渡金属的小孔分子筛; 和（b）设置在所述部件之间的含氧气体输入。 例如，可以使用CHA框架型小孔分子筛。 减少NH 3排放的方法包括将含氧气体引入气流中以产生氧化气流; 并将氧化的气流暴露于NH 3氧化催化剂以选择性地将至少一部分NH 3氧化成N 2。
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公开(公告)号：US08535629B2
公开(公告)日：2013-09-17
申请号：US13310216
申请日：2011-12-02
申请人： Todd Howard Ballinger , Philip Gerald Blakeman , Guy Richard Chandler , Hai-Ying Chen , Julian Peter Cox , Joseph M. Fedeyko , Alexander Nicholas Michael Green , Paul Richard Phillips , Stuart David Reid , Erich C. Weigert , James Alexander Wylie
发明人： Todd Howard Ballinger , Philip Gerald Blakeman , Guy Richard Chandler , Hai-Ying Chen , Julian Peter Cox , Joseph M. Fedeyko , Alexander Nicholas Michael Green , Paul Richard Phillips , Stuart David Reid , Erich C. Weigert , James Alexander Wylie
CPC分类号： B01J29/763 , B01D53/565 , B01D53/8621 , B01D53/9413 , B01D53/9418 , B01D53/9422 , B01D2251/2062 , B01D2251/2067 , B01D2255/2065 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9202 , B01D2258/012 , B01J29/7065 , B01J35/023 , B01J37/0009 , B01J37/0215 , B01J37/0246 , B01J2229/186 , B01J2229/42
摘要： Provided is a catalyst comprising (a) a zeolite material having a mean crystal size of at least about 0.5 μm, having a CHA framework that contains silicon and aluminum, and having a silica-to-alumina mole ratio (SAR) of about 10 to about 25; and (b) an extra-framework promoter metal (M) disposed in said zeolite material as free and/or exchanged metal, wherein the extra-framework promoter metal is copper, iron, and mixtures thereof, and is present in a promoter metal-to-aluminum atomic ratio (M:Al) of about 0.10 to about 0.24 based on the framework aluminum; and optionally comprising (c) at least about 1 weight percent of cerium in said zeolite material, based on the total weight of the zeolite, wherein said cerium is present in a form selected from exchanged cerium ions, monomeric ceria, oligomeric ceria, and combinations thereof, provided that said oligomeric ceria has a particle size of less than 5 μm.
摘要翻译： 提供了一种催化剂，其包括（a）具有至少约0.5μm的平均晶体尺寸的沸石材料，具有含有硅和铝的CHA骨架，并且具有约10至20的二氧化硅与氧化铝的摩尔比（SAR） 约25; 和（b）作为游离和/或交换的金属配置在所述沸石材料中的外框架助催化剂金属（M），其中所述外骨架助催化剂金属是铜，铁及其混合物，并且存在于助催化剂金属 - 铝原子比（M：Al）为约0.10至约0.24; 并且任选地包含（c）所述沸石材料中至少约1重量％的铈，基于沸石的总重量，其中所述铈以选自交换的铈离子，单体二氧化铈，低聚二氧化铈和组合的形式存在 条件是所述低聚二氧化铈具有小于5μm的粒度。
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公开(公告)号：US20120201731A1
公开(公告)日：2012-08-09
申请号：US13310216
申请日：2011-12-02
申请人： Todd Howard Ballinger , Philip Gerald Blakeman , Guy Richard Chandler , Hai-Ying Chen , Julian Peter Cox , Joseph M. Fedeyko , Alexander Nicholas Michael Green , Paul Richard Phillips , Stuart David Reid , Erich C. Weigert , James Alexander Wylie
发明人： Todd Howard Ballinger , Philip Gerald Blakeman , Guy Richard Chandler , Hai-Ying Chen , Julian Peter Cox , Joseph M. Fedeyko , Alexander Nicholas Michael Green , Paul Richard Phillips , Stuart David Reid , Erich C. Weigert , James Alexander Wylie
CPC分类号： B01J29/763 , B01D53/565 , B01D53/8621 , B01D53/9413 , B01D53/9418 , B01D53/9422 , B01D2251/2062 , B01D2251/2067 , B01D2255/2065 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9202 , B01D2258/012 , B01J29/7065 , B01J35/023 , B01J37/0009 , B01J37/0215 , B01J37/0246 , B01J2229/186 , B01J2229/42
摘要： Provided is a catalyst comprising (a) a zeolite material having a mean crystal size of at least about 0.5 μm, having a CHA framework that contains silicon and aluminum, and having a silica-to-alumina mole ratio (SAR) of about 10 to about 25; and (b) an extra-framework promoter metal (M) disposed in said zeolite material as free and/or exchanged metal, wherein the extra-framework promoter metal is copper, iron, and mixtures thereof, and is present in a promoter metal-to-aluminum atomic ratio (M:Al) of about 0.10 to about 0.24 based on the framework aluminum; and optionally comprising (c) at least about 1 weight percent of cerium in said zeolite material, based on the total weight of the zeolite, wherein said cerium is present in a form selected from exchanged cerium ions, monomeric ceria, oligomeric ceria, and combinations thereof, provided that said oligomeric ceria has a particle size of less than 5 μm.
摘要翻译： 提供了一种催化剂，其包含（a）平均晶体尺寸为至少约0.5μm的沸石材料，具有包含硅和铝的CHA骨架，并且具有约10至20的二氧化硅与氧化铝的摩尔比（SAR） 约25; 和（b）作为游离和/或交换的金属配置在所述沸石材料中的外框架助催化剂金属（M），其中所述外骨架助催化剂金属是铜，铁及其混合物，并且存在于助催化剂金属 - 铝原子比（M：Al）为约0.10至约0.24; 并且任选地包含（c）所述沸石材料中至少约1重量％的铈，基于沸石的总重量，其中所述铈以选自交换的铈离子，单体二氧化铈，低聚二氧化铈和组合的形式存在 只要所述低聚二氧化铈的粒度小于5μm即可。
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公开(公告)号：US20110182791A1
公开(公告)日：2011-07-28
申请号：US13083154
申请日：2011-04-08
CPC分类号： B01J29/85 , B01D53/9436 , B01D53/945 , B01D53/9477 , B01D2255/1021 , B01D2255/20761 , B01D2255/50 , B01D2255/9022 , B01J23/42 , B01J29/072 , B01J29/076 , B01J29/763 , B01J35/0006 , B01J37/0244 , B01J37/0246 , Y02A50/2346 , Y02T10/22
摘要： A system for reducing ammonia (NH3) emissions includes (a) a first component comprising a first substrate containing a three-way catalyst, wherein the first component is disposed upstream of a second component comprising a second substrate containing an ammonia oxidation catalyst, wherein said ammonia oxidation catalyst comprises a small pore molecular sieve supporting at least one transition metal; and (b) an oxygen-containing gas input disposed between the components. For example, a CHA Framework Type small pore molecular sieve may be used. A method for reducing NH3 emission includes introducing an oxygen-containing gas into a gas stream to produce an oxygenated gas stream; and exposing the oxygenated gas stream to an NH3 oxidation catalyst to selectively oxidize at least a portion of the NH3 to N2. The method may further include the step of exposing a rich burn exhaust gas to a three-way catalyst to produce the gas stream comprising NH3.
摘要翻译： 用于还原氨（NH 3）排放的系统包括（a）第一组分，其包含含有三元催化剂的第一基质，其中所述第一组分设置在包含含有氨氧化催化剂的第二底物的第二组分的上游，其中所述 氨氧化催化剂包括支撑至少一种过渡金属的小孔分子筛; 和（b）设置在所述部件之间的含氧气体输入。 例如，可以使用CHA框架型小孔分子筛。 减少NH 3排放的方法包括将含氧气体引入气流中以产生氧化气流; 并将氧化的气流暴露于NH 3氧化催化剂以选择性地将至少一部分NH 3氧化成N 2。 该方法还可以包括将富燃烧废气暴露于三元催化剂以产生包含NH 3的气流的步骤。
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17.发明申请BASE METAL CATALYSTS FOR THE OXIDATION OF CARBON MONOXIDE AND VOLATILE ORGANIC COMPOUNDS 审中-公开一氧化碳和挥发性有机化合物氧化的基础金属催化剂公开(公告)号：US20100266473A1
公开(公告)日：2010-10-21
申请号：US12427375
申请日：2009-04-21
摘要： A method for oxidizing carbon monoxide (CO) and volatile organic compounds (VOCS) comprises contacting a gas containing water vapor and said CO and VOCs with a catalyst composition comprising at least one base metal promoter and at least one base metal catalyst supported on an oxide support material comprising one or more of alumina, silica, zirconia, ceria, and titania, wherein the VOCs comprise one or more of methyl acetate, methane, methyl bromide, benzene, methanol, methyl ethyl ketone, butane, and butene.
摘要翻译： 氧化一氧化碳（CO）和挥发性有机化合物（VOCS）的方法包括使含有水蒸汽和所述CO和VOC的气体与包含至少一种贱金属助催化剂和至少一种负载在氧化物上的贱金属催化剂的催化剂组合物接触 包含氧化铝，二氧化硅，氧化锆，二氧化铈和二氧化钛中的一种或多种的载体材料，其中VOC包括一种或多种乙酸甲酯，甲烷，甲基溴，苯，甲醇，甲基乙基酮，丁烷和丁烯。
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18.发明授权公开(公告)号：US10792647B2
公开(公告)日：2020-10-06
申请号：US12427375
申请日：2009-04-21
IPC分类号： B01D53/44 , B01D53/62 , B01J21/08 , B01J23/10 , B01J23/889 , B01D53/86 , B01J35/04 , B01J23/00
摘要： A method for oxidizing carbon monoxide (CO) and volatile organic compounds (VOCS) comprises contacting a gas containing water vapor and said CO and VOCs with a catalyst composition comprising at least one base metal promoter and at least one base metal catalyst supported on an oxide support material comprising one or more of alumina, silica, zirconia, ceria, and titania, wherein the VOCs comprise one or more of methyl acetate, methane, methyl bromide, benzene, methanol, methyl ethyl ketone, butane, and butene.
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公开(公告)号：US09878316B2
公开(公告)日：2018-01-30
申请号：US14991272
申请日：2016-01-08
申请人： John L. Casci , Hai-Ying Chen , Joseph Michael Fedeyko , Jillian Elaine Collier , Raj Rao Rajaram , David Thompsett , Robert P. Hodgkins
发明人： John L. Casci , Hai-Ying Chen , Joseph Michael Fedeyko , Jillian Elaine Collier , Raj Rao Rajaram , David Thompsett , Robert P. Hodgkins
IPC分类号： C01B39/54 , B01J29/85 , B01J29/76 , C01B39/10 , B01J37/28 , B01D53/94 , B01J29/70 , C01B39/04 , B01D53/86 , B01J29/88 , B01J35/04 , B01J37/02
CPC分类号： B01J29/763 , B01D53/8628 , B01D53/9418 , B01D2251/2062 , B01D2251/2067 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/707 , B01J29/7015 , B01J29/85 , B01J29/88 , B01J35/04 , B01J37/0246 , B01J37/28 , B01J2229/183 , B01J2229/186 , C01B39/04 , C01B39/10 , C01B39/54 , Y02T10/24
摘要： A catalyst washcoat is provided having a molecular sieve with a CHA crystal structure; about 0.5 to about 5.0 mol % phosphorus; and SiO2 and Al2O3 in a mole ratio of about 5 to about 40. The washcoat includes one or more promoters or stabilizers, and may be applied to a monolith substrate to produce a catalytically active article.
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公开(公告)号：US09358525B2
公开(公告)日：2016-06-07
申请号：US12630344
申请日：2009-12-03
IPC分类号： B01J23/58 , B01D53/30 , B01D53/94 , B01J23/656 , B01J23/96 , B01J37/02 , G01N27/12 , G01N33/00
CPC分类号： B01J23/58 , B01D53/30 , B01D53/9422 , B01D2255/102 , B01D2255/2022 , B01D2255/2061 , B01D2255/2063 , B01D2255/2066 , B01D2255/2068 , B01D2255/2073 , B01D2255/2092 , B01D2255/91 , B01J23/6562 , B01J23/96 , B01J37/0215 , G01N27/125 , G01N33/0037 , Y02A50/245
摘要： A NOx storage material comprises a support, a potassium salt impregnated on the support, the potassium impregnated on the support is promoted with a platinum group metal, and wherein the NOx storage material has an electrical property which changes based on the amount of NOx loading on the NOx storage material. An apparatus for direct NOx measurement includes a sensor coated with the NOx storage material. A method of determining NOx flux in a NOx containing gas comprises exposing the gas to the apparatus and converting a signal developed by the apparatus to a signal representative of the NOx flux.
摘要翻译： NOx储存材料包括载体，浸渍在载体上的钾盐，用铂族金属促进浸渍在载体上的钾，并且其中所述NOx储存材料具有基于NOx负载量变化的电性能 NOx储存材料。 用于直接NOx测量的装置包括涂覆有NOx储存材料的传感器。 确定含NOx的气体中的NOx通量的方法包括将气体暴露于设备并将由该装置产生的信号转换为代表NOx通量的信号。
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