公开(公告)号：US10287450B2

公开(公告)日：2019-05-14

申请号：US15830245

申请日：2017-12-04

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Andrew Swartz

IPC: C08L33/08 ,  C09D143/02 ,  C09D7/40 ,  C09D125/14 ,  C09D133/08 ,  C09D133/12 ,  C08F265/06 ,  C09D151/00 ,  C08F2/22 ,  C08F212/08 ,  C08F220/14 ,  C08F220/18 ,  C08K3/22 ,  B82Y30/00 ,  C08F12/30

Abstract: The present invention relates to a composition comprising 1) an aqueous dispersion of polymer particles having a core-shell morphology wherein the core protuberates from the shell and comprises less than 0.09 structural units of a phosphorus acid monomer, based on the weight of the core; and 2) pigment particles with a refractive index in the range of from 2.0 and 3.0, wherein the pigment volume concentration of the pigment particles is at least 11. The composition of the present invention is useful for improving block resistance in coatings applications.

公开(公告)号：US10119018B2

公开(公告)日：2018-11-06

申请号：US15338530

申请日：2016-10-31

Applicant: Rohm and Haas Company

Inventor： Kebede Beshah ,  James C. Bohling ,  Pu Luo

IPC: C08L31/04 ,  C08F218/08 ,  C09D131/04

Abstract: The present invention relates to a process for preparing an aqueous dispersion of a vinyl acetate polymer comprising the step of polymerizing vinyl acetate under emulsion polymerization conditions in the presence of a chain transfer agent which is a hypophosphite salt or X—R1—SH, where R1 is a C1-C4 alkyl group and X is sulfonate, hydroxyl, sulfate, phosphate, phosphonate, carboxylic acid or a salt thereof, or C1-C3-alkyl carboxylate. The process provides a way of lowering the viscosity of the vinyl acetate polymer at a given solids content.

公开(公告)号：US09745492B2

公开(公告)日：2017-08-29

申请号：US15262566

申请日：2016-09-12

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Jihui Guo ,  Kevin J. Henderson ,  Ericka Lynn Killian ,  John J. Rabasco ,  Daniel A. Saucy ,  Jordan Stracke

IPC: C08K9/00 ,  C09D133/12 ,  C09D5/00

CPC classification number: C09D133/12 ,  C09D5/00

Abstract: The present invention relates to a composition comprising an aqueous dispersion of an associative thickener having a hydrophobic portion with a calculated log P in the range of from 2.7 to 4.8; and composite particles comprising phosphorus acid functionalized polymer particles adsorbed to the surfaces of TiO2 particles. The composition of the present invention provides formulators with flexibility in their use of low and mid shear rate thickeners to balance paint performance properties.

公开(公告)号：US20170081547A1

公开(公告)日：2017-03-23

申请号：US15262566

申请日：2016-09-12

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Jihui Guo ,  Kevin J. Henderson ,  Ericka Lynn Killian ,  John J. Rabasco ,  Daniel A. Saucy ,  Jordan Stracke

IPC: C09D133/12

CPC classification number: C09D133/12 ,  C09D5/00

Abstract: The present invention relates to a composition comprising an aqueous dispersion of an associative thickener having a hydrophobic portion with a calculated log P in the range of from 2.7 to 4.8; and composite particles comprising phosphorus acid functionalized polymer particles adsorbed to the surfaces of TiO2 particles. The composition of the present invention provides formulators with flexibility in their use of low and mid shear rate thickeners to balance paint performance properties.

公开(公告)号：US20170081529A1

公开(公告)日：2017-03-23

申请号：US15264659

申请日：2016-09-14

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Jihui Guo ,  Kevin J. Henderson ,  Ericka Lynn Killian ,  John J. Rabasco ,  Daniel A. Saucy ,  Jordan Stracke

IPC: C09D7/00 ,  C09D133/08 ,  C09D133/12 ,  C09D7/12

CPC classification number: C09D7/002 ,  C08G18/227 ,  C08G18/2825 ,  C08G18/4812 ,  C08G18/4833 ,  C08G18/73 ,  C08G18/758 ,  C08K9/04 ,  C08K9/08 ,  C08K2003/2241 ,  C08L75/04 ,  C09D5/024 ,  C09D5/028 ,  C09D7/40 ,  C09D7/43 ,  C09D7/44 ,  C09D7/62 ,  C09D133/08 ,  C09D133/12 ,  C09D143/02 ,  C09D151/003 ,  C09D151/06

Abstract: The present invention relates to a composition comprising an aqueous dispersion of an associative thickener having a hydrophobic portion with a calculated log P in the range of from 2.7 to 5.0; and composite particles comprising phosphorus acid functionalized polymer particles adsorbed to the surfaces of TiO2 particles; wherein the phosphorus acid functionalized polymer particles have a core-shell morphology wherein the core protuberates from the shell. The composition of the present invention provides formulators with flexibility in their use of low and mid shear rate thickeners to balance paint performance properties.

公开(公告)号：US20160280904A1

公开(公告)日：2016-09-29

申请号：US15075244

申请日：2016-03-21

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Wei Gao ,  Ericka Lynn Killian ,  Yogesh Tiwary

IPC: C08L33/12 ,  C08L33/08

CPC classification number: C08L33/12 ,  C08F265/06 ,  C08F2220/1825 ,  C08L33/08 ,  C08L43/02 ,  C08L2205/02 ,  C08L2207/53 ,  C09D151/003 ,  C08F220/06 ,  C08F220/14 ,  C08F220/40 ,  C08F230/02 ,  C08F220/36 ,  C08L51/003

Abstract: The present invention relates to a composition comprising a bimorphological aqueous dispersion of first and second polymer particles, wherein the first polymer particles comprise a shell and a phosphorus acid functionalized protuberating core, and the second polymer particles do not comprise a protuberating core. The composition is useful for pigmented coatings formulations.

Abstract translation: 本发明涉及包含第一和第二聚合物颗粒的双曲线性水分散体的组合物，其中所述第一聚合物颗粒包含壳和磷酸官能化的突起芯，并且所述第二聚合物颗粒不包含突起芯。 该组合物可用于着色涂料制剂。

公开(公告)号：US20160152817A1

公开(公告)日：2016-06-02

申请号：US15019444

申请日：2016-02-09

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Yogesh Tiwary

IPC: C08L51/00

CPC classification number: C08L51/003 ,  C08F2/001 ,  C08F2/24 ,  C08F265/04 ,  C08K3/22 ,  C08K2003/2241 ,  C08L33/04 ,  C08L33/08 ,  C08L2201/54 ,  C09D133/14 ,  C09D143/02 ,  C08F220/18 ,  C08F212/08 ,  C08F220/06 ,  C08F212/14 ,  C08F230/08

Abstract: The present invention relates to a stable aqueous dispersion of polymer particles with structural units of a) a phosphorus acid monomer or a salt thereof; b) a carboxylic acid monomer or a sulfur acid monomer or a salt thereof or a combination thereof; c) a multiethylenically unsaturated monomer; and d) an acrylate monomer, wherein the polymer particles have a solids content in the range of 30 to 50 percent and a particle size of from 40 nm and 100 nm.

Abstract translation: 本发明涉及具有以下结构单元的聚合物颗粒的稳定水分散体：a）一种磷酸单体或其盐; b）羧酸单体或硫酸单体或其盐或其组合; c）多烯属不饱和单体; 和d）丙烯酸酯单体，其中聚合物颗粒的固体含量范围为30-50％，粒度为40nm和100nm。

公开(公告)号：US20150073134A1

公开(公告)日：2015-03-12

申请号：US14479113

申请日：2014-09-05

Applicant: The Regents of the University of California ,  Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Joseph Jankolovits ,  Alexander S. Katz ,  Oz M. Gazit ,  James C. Bohling ,  John A. Roper, III

IPC: C08B37/00

CPC classification number: C08B37/0024 ,  B01J20/3204 ,  B01J20/3272 ,  B01J20/3274 ,  B01J20/3278 ,  B01J20/3289 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/04 ,  C08B11/20 ,  C09C1/3054 ,  C09C1/3072 ,  C09C1/3081 ,  C09C1/309 ,  C09C1/3661 ,  C09C1/3676 ,  C09C1/3684 ,  C09C1/3692 ,  C09C1/407 ,  C09C3/10 ,  C09D101/28 ,  C09D105/00

Abstract: The present invention is a multilayered composite comprising porous metal oxide particles that are covalently bonded by way of inorganic ether groups to one or more sites of a first polyhydroxyl-functionalized polymer. This first polymer is in turn covalently bonded by way of inorganic ether groups to one or more sites of a second polyhydroxyl-functionalized polymer. The multilayered composites can be prepared by contacting porous inorganic-oxide particles with a sufficient amount of OH-reactive crosslinking agent to form metal oxide particles imbibed with the crosslinking agent, and then contacting the inorganic-oxide particles with a solution of polyhydroxyl-functionalized polymer under reactive conditions.

Abstract translation: 本发明是一种多层复合材料，其包含多孔金属氧化物颗粒，其通过无机醚基团与第一多羟基官能化聚合物的一个或多个位点共价键合。 该第一聚合物又通过无机醚基团共价键合到第二多羟基官能化聚合物的一个或多个位点。 多层复合材料可以通过使多孔无机氧化物颗粒与足够量的OH-反应性交联剂接触以形成吸附有交联剂的金属氧化物颗粒，然后使无机氧化物颗粒与多羟基官能化聚合物 在反应条件下。

公开(公告)号：US20140221560A1

公开(公告)日：2014-08-07

申请号：US14169504

申请日：2014-01-31

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Beth Cooper ,  Wei Gao ,  Linus W. Linder ,  Alvin M. Maurice

IPC: C09D133/10

CPC classification number: C09D133/10 ,  C08F220/14 ,  C09D133/14 ,  C08F220/06 ,  C08F230/02 ,  C08F2220/1825 ,  C08F2220/283

Abstract: The present invention relates to a process comprising contacting methyl methacrylate or styrene; a C1-C10-alkyl acrylate; and a polymerizable carboxylic acid monomer with a stable aqueous dispersion of first polymer particles, under emulsion polymerization conditions, to form a stable aqueous dispersion of second polymer particles. The first polymer particles have a Tg in the range of from −30° C. to 30° C., and the monomers have a calculated Tg in the range of 50° C. to 120° C. The present invention also relates to the dispersion of second polymer particles, which is useful as a binder to improve freeze-thaw stability in a coatings formulation.

Abstract translation: 本发明涉及一种使甲基丙烯酸甲酯或苯乙烯接触的方法; 丙烯酸C1-C10烷基酯; 和具有稳定的第一聚合物颗粒的水分散体的可聚合羧酸单体，在乳液聚合条件下，形成稳定的第二聚合物颗粒的水分散体。 第一聚合物颗粒的Tg在-30℃至30℃的范围内，单体的计算Tg在50℃至120℃的范围内。本发明还涉及 第二聚合物颗粒的分散体，其可用作粘合剂以改善涂料配方中的冻融稳定性。

公开(公告)号：US12018167B2

公开(公告)日：2024-06-25

申请号：US17764677

申请日：2020-10-07

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Philip R. Harsh ,  Patrick E. Hartnett ,  Partha S. Majumdar ,  Qing Zhang

IPC: C09D133/08 ,  C08K5/5445 ,  C09D5/02 ,  C09D5/16 ,  C09D7/40 ,  C09D7/42

CPC classification number: C09D133/08 ,  C09D5/022 ,  C09D5/1637 ,  C09D5/1668 ,  C09D7/42 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D7/70 ,  C08K5/5445

Abstract: The present invention relates to a composition comprising an aqueous dispersion of a) polymer particles having a z-average particle size in the range of from 50 nm to 500 nm; b) anion exchange resin particles having a D50 median particle size in the range of from 0.1 μm to 50 μm; and c) polymeric organic microspheres having a D50 median particle size in the range of from 1 μm to 20 μm, wherein the weight-to-weight ratio of polymer particles to microspheres is in the range of from 0.5:1 to 20:1. The composition of the present invention is useful for paint compositions that form matte finishes with an excellent balance of stain blocking and stain removal properties.