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11.发明申请公开(公告)号：US20150209767A1
公开(公告)日：2015-07-30
申请号：US14404774
申请日：2012-07-27
申请人： Xionghou Gao , Haitao Zhang , Di Li , Xueli Li , Hongchang Duan , Zhengguo Tan , Chaowei Liu , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang , Zhishuang Pan , Gengzhen Cao
发明人： Xionghou Gao , Haitao Zhang , Di Li , Xueli Li , Hongchang Duan , Zhengguo Tan , Chaowei Liu , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang , Zhishuang Pan , Gengzhen Cao
CPC分类号： B01J29/088 , B01J29/084 , B01J29/80 , B01J35/10 , B01J35/109 , B01J37/009 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/28 , B01J37/30 , B01J2229/18 , B01J2229/186 , B01J2229/40 , B01J2229/42 , C01B39/026 , C01B39/24 , C01B39/54
摘要： Provided is a phosphorus-containing ultrastable Y-type rare earth (RE) molecular sieve and the preparation method thereof. The method is: based on Na Y molecular sieve as a raw material, obtaining “one-exchange one-roast” RE-Na Y-type molecular sieve through the steps of exchanging with RE, pre-exchanging with dispersing, and the first calcination; and then performing ammonium salt exchange, phosphorus modification, and the second calcination on the “one-exchange one-roast” RE-Na Y-type molecular sieve, wherein the sequence of the RE exchange and the pre-exchange with dispersing is unlimited, and the sequence of the ammonium salt exchange and the phosphorus modification is unlimited as well. The obtained molecular sieve contains RE oxide 1-20 wt %, phosphorus 0.1-5 wt %, and sodium oxide no more than 1.2 wt %, and has a crystallization degree of 51-69% and a lattice parameter of 2.449-2.469 nm. Heavy oil conversion rate can be increased by using the molecular sieve as an active component in a catalytic cracking catalyst.
摘要翻译： 提供一种含磷超纯Y型稀土（RE）分子筛及其制备方法。 方法为：以Na Y分子筛为原料，通过与RE交换，分散预交换和第一次煅烧的步骤获得“一换一烘焙”RE-Na Y型分子筛 ; 然后在“一换一烘焙”RE-Na Y型分子筛上进行铵盐交换，磷改性和第二次煅烧，其中RE交换和分散预交换的顺序是无限的， 并且铵盐交换和磷改性的顺序也是无限的。 得到的分子筛含有1-20重量％的RE氧化物，0.1-5重量％的磷，不超过1.2重量％的氧化钠，结晶度为51-69％，晶格参数为2.449-2.469nm。 通过在催化裂化催化剂中使用分子筛作为活性组分可以提高重油转化率。
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12.发明授权公开(公告)号：US08876014B2
公开(公告)日：2014-11-04
申请号：US13642273
申请日：2011-04-18
申请人： Chenxi Zhang , Gang Sun , Yi Shen , Hui Zhao
发明人： Chenxi Zhang , Gang Sun , Yi Shen , Hui Zhao
摘要： The present invention relates to a polyurethane ballast layer, the method for preparing the same and a railway comprising the polyurethane ballast layer. The polyurethane ballast layer provided in this invention comprises a polyurethane-filled ballast layer and a polyurethane external protective layer, wherein the polyurethane-filled ballast layer comprises ballasts and polyurethane foam filled in the space among the ballasts. The polyurethane ballast layer provided in this invention can reduce the probability of ballast crashing, shifting and cracking under heavy load, and separate the ballast track from the outside environment to prevent rain, snow and wastes from entering into the internal space of the ballast track bed. Furthermore, the polyurethane ballast layer can keep the polyurethane foam filled in the ballasts layer away from water in the outside environment to avoid hydrolysis. The polyurethane ballast layer presented in this invention can be used in the railway ballast track bed to extend the track bed maintenance cycle, and save maintenance cost significantly.
摘要翻译： 本发明涉及聚氨酯压载层，其制备方法和包含聚氨酯压载层的铁路。 本发明提供的聚氨酯压载层包括聚氨酯填充的压载层和聚氨酯外部保护层，其中聚氨酯填充的压载层包括填充在镇流器之间的空间中的镇流器和聚氨酯泡沫。 本发明提供的聚氨酯压载层可以降低重载荷下的压载撞击，移动和开裂的可能性，并将镇流器与外部环境分开，以防止雨，雪和废物进入压载轨道床的内部空间 。 此外，聚氨酯压载层可以将填充在镇流器层中的聚氨酯泡沫保持在外部环境中的水中，以避免水解。 本发明中提出的聚氨酯压载层可用于铁路轨道车床，以延长轨道床维护周期，显着节省维护成本。
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13.发明授权Modified molecular sieve characterized by improved sodium-contamination-resisting activity and preparation method thereof 有权改进的分子筛，其特征在于改善耐钠耐污染活性及其制备方法公开(公告)号：US08545803B2
公开(公告)日：2013-10-01
申请号：US13505224
申请日：2009-12-01
申请人： Xionghou Gao , Dong Ji , Haitao Zhang , Hongchang Duan , Di Li , ZhengGuo Tan , Yi Su , Chenxi Zhang , Yi Wang , Yanqing Ma , Yanbo Sun
发明人： Xionghou Gao , Dong Ji , Haitao Zhang , Hongchang Duan , Di Li , ZhengGuo Tan , Yi Su , Chenxi Zhang , Yi Wang , Yanqing Ma , Yanbo Sun
CPC分类号： B01J29/40 , B01J29/06 , B01J37/10 , B01J37/28 , B01J2229/34 , B01J2229/40 , B01J2229/42 , C10G11/05 , C10G11/18
摘要： Modified molecular sieve characterized by improved sodium-resisting contamination activity and preparation method thereof are provided. The method comprises: adding molecular sieve in phosphorus-containing organic solution, and reacting for 10-200 minutes at temperature of 70-200° C. and pressure of 0.2-1.2 MPa, and then filtering, drying and calcining. The said modified molecular sieve contains 90-99 wt. % molecular sieve as dry basis and 1-10 wt. % phosphorus as oxide. The said method can improve the capability of sodium-resisting contamination effectively, and its technology is simple and fits the existing catalyst production apparatus and process. The said modified molecular sieve has high sodium-resisting contamination activity, and the model catalyst by sodium contamination has high activity retention.
摘要翻译： 提供了具有改善的耐钠污染活性的改性分子筛及其制备方法。 该方法包括：在含磷有机溶液中加入分子筛，在70-200℃的温度和0.2-1.2 MPa的压力下反应10-200分钟，然后过滤，干燥和煅烧。 所述改性分子筛含有90-99wt。 ％分子筛为干基，1-10重量％ 磷作为氧化物。 所述方法可以有效提高耐钠污染的能力，其技术简单，适合现有的催化剂生产设备和工艺。 所述改性分子筛具有较高的抗钠污染活性，而钠污染模型催化剂具有较高的活性保留性。
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14.发明申请公开(公告)号：US20120213695A1
公开(公告)日：2012-08-23
申请号：US13505224
申请日：2009-12-01
申请人： Xionghou Gao , Dong Ji , Haitao Zhang , Hongchang Duan , Di Li , ZhengGuo Tan , Yi Su , Chenxi Zhang , Yi Wang , Yanqing Ma , Yanbo Sun
发明人： Xionghou Gao , Dong Ji , Haitao Zhang , Hongchang Duan , Di Li , ZhengGuo Tan , Yi Su , Chenxi Zhang , Yi Wang , Yanqing Ma , Yanbo Sun
IPC分类号： C01B39/38
CPC分类号： B01J29/40 , B01J29/06 , B01J37/10 , B01J37/28 , B01J2229/34 , B01J2229/40 , B01J2229/42 , C10G11/05 , C10G11/18
摘要： Modified molecular sieve characterized by improved sodium-resisting contamination activity and preparation method thereof are provided. The method comprises: adding molecular sieve in phosphorus-containing organic solution, and reacting for 10-200 minutes at temperature of 70-200° C. and pressure of 0.2-1.2 MPa, and then filtering, drying and calcining. The said modified molecular sieve contains 90-99 wt. % molecular sieve as dry basis and 1-10 wt. % phosphorus as oxide. The said method can improve the capability of sodium-resisting contamination effectively, and its technology is simple and fits the existing catalyst production apparatus and process. The said modified molecular sieve has high sodium-resisting contamination activity, and the model catalyst by sodium contamination has high activity retention.
摘要翻译： 提供了具有改善的耐钠污染活性的改性分子筛及其制备方法。 该方法包括：在含磷有机溶液中加入分子筛，在70-200℃的温度和0.2-1.2 MPa的压力下反应10-200分钟，然后过滤，干燥和煅烧。 所述改性分子筛含有90-99wt。 ％分子筛为干基，1-10重量％ 磷作为氧化物。 所述方法可以有效提高耐钠污染的能力，其技术简单，适合现有的催化剂生产设备和工艺。 所述改性分子筛具有较高的抗钠污染活性，而钠污染模型催化剂具有较高的活性保留性。
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15.发明授权公开(公告)号：US09968915B2
公开(公告)日：2018-05-15
申请号：US14404774
申请日：2012-07-27
申请人： Xionghou Gao , Haitao Zhang , Di Li , Xueli Li , Hongchang Duan , Zhengguo Tan , Chaowei Liu , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang , Zhishuang Pan , Gengzhen Cao
发明人： Xionghou Gao , Haitao Zhang , Di Li , Xueli Li , Hongchang Duan , Zhengguo Tan , Chaowei Liu , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang , Zhishuang Pan , Gengzhen Cao
IPC分类号： B01J29/06 , B01J29/08 , B01J29/80 , B01J37/30 , B01J35/10 , C01B39/02 , B01J37/28 , C01B39/24 , C01B39/54 , B01J37/00 , B01J37/04 , B01J37/06 , B01J37/08
CPC分类号： B01J29/088 , B01J29/084 , B01J29/80 , B01J35/10 , B01J35/109 , B01J37/009 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/28 , B01J37/30 , B01J2229/18 , B01J2229/186 , B01J2229/40 , B01J2229/42 , C01B39/026 , C01B39/24 , C01B39/54
摘要： Provided is a phosphorus-containing ultrastable Y-type rare earth (RE) molecular sieve and the preparation method thereof. The method is: based on NaY molecular sieve as a raw material, obtaining “one-exchange one-roast” RE-Na Y-type molecular sieve through the steps of exchanging with RE, pre-exchanging with dispersing, and the first calcination; and then performing ammonium salt exchange, phosphorus modification, and the second calcination on the “one-exchange one-roast” RE-Na Y-type molecular sieve, wherein the sequence of the RE exchange and the pre-exchange with dispersing is unlimited, and the sequence of the ammonium salt exchange and the phosphorus modification is unlimited as well. The obtained molecular sieve contains RE oxide 1-20 wt %, phosphorus 0.1-5 wt %, and sodium oxide no more than 1.2 wt %, and has a crystallization degree of 51-69% and a lattice parameter of 2.449-2.469 nm. Heavy oil conversion rate can be increased by using the molecular sieve as an active component in a catalytic cracking catalyst.
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公开(公告)号：US09844772B2
公开(公告)日：2017-12-19
申请号：US14364536
申请日：2012-04-13
申请人： Xionghou Gao , Haitao Zhang , Zhengguo Tan , Di Li , Dong Ji , Hongchang Duan , Chenxi Zhang
发明人： Xionghou Gao , Haitao Zhang , Zhengguo Tan , Di Li , Dong Ji , Hongchang Duan , Chenxi Zhang
IPC分类号： B01J29/06 , B01J29/80 , C01B39/24 , C01B39/02 , B01J35/10 , B01J35/08 , B01J37/00 , B01J37/30 , B01J29/08 , B01J29/40 , B01J35/00 , B01J35/02
CPC分类号： B01J29/80 , B01J29/088 , B01J29/40 , B01J35/002 , B01J35/023 , B01J35/08 , B01J35/10 , B01J35/1085 , B01J35/109 , B01J37/0018 , B01J37/0045 , B01J37/30 , B01J2029/062 , B01J2229/186 , B01J2229/37 , B01J2229/40 , B01J2229/42 , C01B39/026 , C01B39/24
摘要： The present invention relates to a heavy oil catalytic cracking catalyst and preparation method thereof. The catalyst comprises 2 to 50% by weight of an ultra-stable rare earth type Y molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of rare earth oxide. The ultra-stable rare earth type Y molecular sieve is obtained as follows: the raw material, NaY molecular sieve, is subjected to a rare earth exchange and a dispersing pre-exchange, and the molecular sieve slurry is filtered, washed and subjected to a first calcination to produce a “one-exchange one-calcination” rare earth sodium Y molecular sieve, wherein the order of the rare earth exchange and the dispersing pre-exchange is not limited; and the “one-exchange one-calcination” rare earth sodium Y molecular sieve is further subjected to ammonium salt exchange for sodium reduction and a second calcination. The catalyst provided in the present invention is characteristic in its high heavy-oil-conversion capacity, a high total liquid yield and a high light oil yield.
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17.发明申请公开(公告)号：US20130140373A1
公开(公告)日：2013-06-06
申请号：US13642273
申请日：2011-04-18
申请人： Chenxi Zhang , Gang Sun , Yi Shen , Hui Zhao
发明人： Chenxi Zhang , Gang Sun , Yi Shen , Hui Zhao
摘要： The present invention relates to a polyurethane ballast layer, the method for preparing the same and a railway comprising the polyurethane ballast layer. The polyurethane ballast layer provided in this invention comprises a polyurethane-filled ballast layer and a polyurethane external protective layer, wherein the polyurethane-filled ballast layer comprises ballasts and polyurethane foam filled in the space among the ballasts. The polyurethane ballast layer provided in this invention can reduce the probability of ballast crashing, shifting and cracking under heavy load, and separate the ballast track from the outside environment to prevent rain, snow and wastes from entering into the internal space of the ballast track bed. Furthermore, the polyurethane ballast layer can keep the polyurethane foam filled in the ballasts layer away from water in the outside environment to avoid hydrolysis. The polyurethane ballast layer presented in this invention can be used in the railway ballast track bed to extend the track bed maintenance cycle, and save maintenance cost significantly.
摘要翻译： 本发明涉及聚氨酯压载层，其制备方法和包含聚氨酯压载层的铁路。 本发明提供的聚氨酯压载层包括聚氨酯填充的镇流器层和聚氨酯外部保护层，其中聚氨酯填充的压载层包括填充在镇流器之间的空间中的镇流器和聚氨酯泡沫。 本发明提供的聚氨酯压载层可以降低重载荷下的压载撞击，移动和开裂的可能性，并将镇流器与外部环境分开，以防止雨，雪和废物进入压载轨道床的内部空间 。 此外，聚氨酯压载层可以将填充在镇流器层中的聚氨酯泡沫保持在外部环境中的水中，以避免水解。 本发明中提出的聚氨酯压载层可用于铁路轨道车床，以延长轨道床维护周期，显着节省维护成本。
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公开(公告)号：US20080261022A1
公开(公告)日：2008-10-23
申请号：US11663815
申请日：2005-09-26
申请人： Chenxi Zhang , Jen-Chieh Lin , Chi-Kwong Chow , Xiang Wang
发明人： Chenxi Zhang , Jen-Chieh Lin , Chi-Kwong Chow , Xiang Wang
CPC分类号： C08G18/7657 , B29C44/0461 , B29C67/246 , B29K2075/00 , B29K2105/043 , B32B5/20 , B32B7/02 , B32B27/065 , B32B27/40 , B32B2266/0278 , B32B2266/08 , B32B2307/72 , C08G18/4804 , C08G2101/0008 , C08G2101/0025 , C08G2101/0033 , C08G2101/0058 , C08G2101/0066 , C08G2101/0083 , Y10T428/249976 , Y10T428/249977 , Y10T428/249987 , Y10T428/249991
摘要： A polyurethane composite is disclosed comprising rigid polyurethane and foamed thereupon a flexible integral skin (surface pore closed) polyurethane foam, wherein the rigid polyurethane having a density range of 600 kg/m3 to 1200 kg/m3, a Shore A hardness range of 90 to 99, a Shore D hardness range of 40 to 80, a tensile strength range of 10 MPa to 60 MPa, a flexural strength range of 20 MPa to 60 Mpa, a elastic flexural modulus range of 800 MPa to 2500 Mpa, an elongation rate at break of 10-100% and an elongation at break of 25-150%; wherein the flexible integral skin (surface pore closed) polyurethane foam having a density range of 60 kg/m3 to 200 kg/m3, a tensile strength of 60 kPa to 250 kPa, an elongation at break of 70-180%, a tearing strength of 130-220 N/m, a resilience of falling ball of 40-70%, IFD25% of 200-600 N and IFD65% of 600-1800 N.
摘要翻译： 公开了一种聚氨酯复合材料，其包含刚性聚氨酯并在其上发泡柔性整体表面（表面孔封闭）聚氨酯泡沫，其中密度范围为600kg / m 3至1200kg / 肖氏A硬度范围为90至99，肖氏D硬度范围为40至80，拉伸强度范围为10MPa至60MPa，弯曲强度范围为20MPa至60Mpa， 弹性挠曲模量范围为800MPa〜2500Mpa，断裂伸长率为10〜100％，断裂伸长率为25〜150％。 其中所述柔性整体表皮（表面孔封闭）聚氨酯泡沫的密度范围为60kg / m 3至200kg / m 3，拉伸强度为60kPa至 250kPa，断裂伸长率为70-180％，撕裂强度为130-220N / m，回弹力为40-70％，IFD25％为200-600N，IFD65％为600-1800N 。
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