公开(公告)号：US11855098B2

公开(公告)日：2023-12-26

申请号：US17986379

申请日：2022-11-14

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Cheng-Yen Tsai ,  Ming-Chi Huang ,  Zoe Chen ,  Wei-Chin Lee ,  Cheng-Lung Hung ,  Da-Yuan Lee ,  Weng Chang ,  Ching-Hwanq Su

IPC: H01L29/66 ,  H01L29/51 ,  H01L29/78 ,  H01L27/092 ,  H01L21/324 ,  H01L29/08 ,  H01L21/768 ,  H01L21/28 ,  H01L21/8238 ,  H01L21/02 ,  H01L29/10 ,  H01L21/321 ,  H01L21/027 ,  H01L29/49

CPC classification number: H01L27/0924 ,  H01L21/0228 ,  H01L21/0271 ,  H01L21/02318 ,  H01L21/02321 ,  H01L21/28088 ,  H01L21/324 ,  H01L21/3212 ,  H01L21/76829 ,  H01L21/823821 ,  H01L21/823857 ,  H01L21/823864 ,  H01L21/823871 ,  H01L29/0847 ,  H01L29/1033 ,  H01L29/517 ,  H01L29/6681 ,  H01L29/66545 ,  H01L29/66553 ,  H01L29/7851 ,  H01L27/092 ,  H01L29/4966 ,  H01L29/513 ,  H01L29/7848

Abstract: In an embodiment, a method includes: forming a gate dielectric layer on an interface layer; forming a doping layer on the gate dielectric layer, the doping layer including a dipole-inducing element; annealing the doping layer to drive the dipole-inducing element through the gate dielectric layer to a first side of the gate dielectric layer adjacent the interface layer; removing the doping layer; forming a sacrificial layer on the gate dielectric layer, a material of the sacrificial layer reacting with residual dipole-inducing elements at a second side of the gate dielectric layer adjacent the sacrificial layer; removing the sacrificial layer; forming a capping layer on the gate dielectric layer; and forming a gate electrode layer on the capping layer.

公开(公告)号：US11322411B2

公开(公告)日：2022-05-03

申请号：US16686408

申请日：2019-11-18

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Cheng-Yen Tsai ,  Chung-Chiang Wu ,  Tai-Wei Hwang ,  Hung-Chin Chung ,  Wei-Chin Lee ,  Da-Yuan Lee ,  Ching-Hwanq Su ,  Yin-Chuan Chuang ,  Kuan-Ting Liu

IPC: H01L21/8234 ,  H01L27/088 ,  H01L21/02 ,  H01L29/51

Abstract: Embodiments disclosed herein relate to a pre-deposition treatment of materials utilized in metal gates of different transistors on a semiconductor substrate. In an embodiment, a method includes exposing a first metal-containing layer of a first device and a second metal-containing layer of a second device to a reactant to form respective monolayers on the first and second metal-containing layers. The first and second devices are on a substrate. The first device includes a first gate structure including the first metal-containing layer. The second device includes a second gate structure including the second metal-containing layer different from the second metal-containing layer. The monolayers on the first and second metal-containing layers are exposed to an oxidant to provide a hydroxyl group (—OH) terminated surface for the monolayers. Thereafter, a third metal-containing layer is formed on the —OH terminated surfaces of the monolayers on the first and second metal-containing layers.

公开(公告)号：US20200083114A1

公开(公告)日：2020-03-12

申请号：US16684765

申请日：2019-11-15

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Zoe Chen ,  Ching-Hwanq Su ,  Cheng-Lung Hung ,  Cheng-Yen Tsai ,  Da-Yuan Lee ,  Hsin-Yi Lee ,  Weng Chang ,  Wei-Chin Lee

IPC: H01L21/8238 ,  H01L27/092 ,  H01L29/10

Abstract: Generally, the present disclosure provides example embodiments relating to tuning threshold voltages in transistor devices and the transistor devices formed thereby. Various examples implementing various mechanisms for tuning threshold voltages are described. In an example method, a gate dielectric layer is deposited over an active area in a device region of a substrate. A dipole layer is deposited over the gate dielectric layer in the device region. A dipole dopant species is diffused from the dipole layer into the gate dielectric layer in the device region.

公开(公告)号：US12142531B2

公开(公告)日：2024-11-12

申请号：US17661576

申请日：2022-05-02

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Cheng-Yen Tsai ,  Chung-Chiang Wu ,  Tai-Wei Hwang ,  Hung-Chin Chung ,  Wei-Chin Lee ,  Da-Yuan Lee ,  Ching-Hwanq Su ,  Yin-Chuan Chuang ,  Kuan-Ting Liu

IPC: H01L21/8234 ,  H01L21/02 ,  H01L27/088 ,  H01L29/51

Abstract: Embodiments disclosed herein relate to a pre-deposition treatment of materials utilized in metal gates of different transistors on a semiconductor substrate. In an embodiment, a method includes exposing a first metal-containing layer of a first device and a second metal-containing layer of a second device to a reactant to form respective monolayers on the first and second metal-containing layers. The first and second devices are on a substrate. The first device includes a first gate structure including the first metal-containing layer. The second device includes a second gate structure including the second metal-containing layer different from the second metal-containing layer. The monolayers on the first and second metal-containing layers are exposed to an oxidant to provide a hydroxyl group (—OH) terminated surface for the monolayers. Thereafter, a third metal-containing layer is formed on the —OH terminated surfaces of the monolayers on the first and second metal-containing layers.

公开(公告)号：US20230231037A1

公开(公告)日：2023-07-20

申请号：US18123596

申请日：2023-03-20

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Chih-Hsiang Fan ,  Tsung-Han Shen ,  Jia-Ming Lin ,  Wei-Chin Lee ,  Hsien-Ming Lee ,  Chi On Chui

IPC: H01L29/66 ,  H01L21/02 ,  H01L29/78 ,  H01L21/8234

CPC classification number: H01L29/6681 ,  H01L21/02274 ,  H01L21/823431 ,  H01L29/6656 ,  H01L29/7851 ,  H01L29/66545

Abstract: A method of forming a semiconductor device includes: forming a dummy gate over a fin, where the fin protrudes above a substrate; surrounding the dummy gate with a dielectric material; and replacing the dummy gate with a replacement gate structure, where replacing the dummy gate includes: forming a gate trench in the dielectric material, where forming the gate trench includes removing the dummy gate; forming a metal-gate stack in the gate trench, where forming the metal-gate stack includes forming a gate dielectric layer, a first work function layer, and a gap-filling material sequentially in the gate trench; and enlarging a volume of the gap-filling material in the gate trench.

公开(公告)号：US11502080B2

公开(公告)日：2022-11-15

申请号：US17120921

申请日：2020-12-14

Applicant: Taiwan Semiconductor Manufacturing Co. Ltd.

Inventor： Cheng-Yen Tsai ,  Ming-Chi Huang ,  Zoe Chen ,  Wei-Chin Lee ,  Cheng-Lung Hung ,  Da-Yuan Lee ,  Weng Chang ,  Ching-Hwanq Su

IPC: H01L27/092 ,  H01L29/66 ,  H01L29/51 ,  H01L29/78 ,  H01L29/08 ,  H01L29/10 ,  H01L29/49 ,  H01L21/324 ,  H01L21/768 ,  H01L21/28 ,  H01L21/8238 ,  H01L21/02 ,  H01L21/321 ,  H01L21/027

Abstract: In an embodiment, a method includes: forming a gate dielectric layer on an interface layer; forming a doping layer on the gate dielectric layer, the doping layer including a dipole-inducing element; annealing the doping layer to drive the dipole-inducing element through the gate dielectric layer to a first side of the gate dielectric layer adjacent the interface layer; removing the doping layer; forming a sacrificial layer on the gate dielectric layer, a material of the sacrificial layer reacting with residual dipole-inducing elements at a second side of the gate dielectric layer adjacent the sacrificial layer; removing the sacrificial layer; forming a capping layer on the gate dielectric layer; and forming a gate electrode layer on the capping layer.

公开(公告)号：US20220262685A1

公开(公告)日：2022-08-18

申请号：US17661576

申请日：2022-05-02

Applicant: Taiwan Semiconductor Manufacturing Co. Ltd.

Inventor： Cheng-Yen Tsai ,  Chung-Chiang Wu ,  Tai-Wei Hwang ,  Hung-Chin Chung ,  Wei-Chin Lee ,  Da-Yuan Lee ,  Ching-Hwanq Su ,  Yin-Chuan Chuang ,  Kuan-Ting Liu

IPC: H01L21/8234 ,  H01L27/088 ,  H01L21/02 ,  H01L29/51

Abstract: Embodiments disclosed herein relate to a pre-deposition treatment of materials utilized in metal gates of different transistors on a semiconductor substrate. In an embodiment, a method includes exposing a first metal-containing layer of a first device and a second metal-containing layer of a second device to a reactant to form respective monolayers on the first and second metal-containing layers. The first and second devices are on a substrate. The first device includes a first gate structure including the first metal-containing layer. The second device includes a second gate structure including the second metal-containing layer different from the second metal-containing layer. The monolayers on the first and second metal-containing layers are exposed to an oxidant to provide a hydroxyl group (—OH) terminated surface for the monolayers. Thereafter, a third metal-containing layer is formed on the —OH terminated surfaces of the monolayers on the first and second metal-containing layers.

公开(公告)号：US11121041B2

公开(公告)日：2021-09-14

申请号：US16684765

申请日：2019-11-15

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Zoe Chen ,  Ching-Hwanq Su ,  Cheng-Lung Hung ,  Cheng-Yen Tsai ,  Da-Yuan Lee ,  Hsin-Yi Lee ,  Weng Chang ,  Wei-Chin Lee

IPC: H01L21/8238 ,  H01L27/092 ,  H01L29/10

Abstract: Generally, the present disclosure provides example embodiments relating to tuning threshold voltages in transistor devices and the transistor devices formed thereby. Various examples implementing various mechanisms for tuning threshold voltages are described. In an example method, a gate dielectric layer is deposited over an active area in a device region of a substrate. A dipole layer is deposited over the gate dielectric layer in the device region. A dipole dopant species is diffused from the dipole layer into the gate dielectric layer in the device region.

公开(公告)号：US20210098301A1

公开(公告)日：2021-04-01

申请号：US17120499

申请日：2020-12-14

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Chung-Chiang Wu ,  Hsin-Han Tsai ,  Wei-Chin Lee ,  Chia-Ching Lee ,  Hung-Chin Chung ,  Cheng-Lung Hung ,  Da-Yuan Lee

IPC: H01L21/8234 ,  H01L21/3213 ,  H01L29/49 ,  H01L27/088 ,  H01L21/28 ,  H01L29/66 ,  H01L27/092 ,  H01L21/8238 ,  H01L29/40

Abstract: Semiconductor devices and methods of manufacturing semiconductor devices with differing threshold voltages are provided. In embodiments the threshold voltages of individual semiconductor devices are tuned through the removal and placement of differing materials within each of the individual gate stacks within a replacement gate process, whereby the removal and placement helps keep the overall process window for a fill material large enough to allow for a complete fill.

公开(公告)号：US20200321252A1

公开(公告)日：2020-10-08

申请号：US16907570

申请日：2020-06-22

Applicant: Taiwan Semiconductor Manufacturing Co., Ltd.

Inventor： Chung-Chiang Wu ,  Wei-Chin Lee ,  Shih-Hang Chiu ,  Chia-Ching Lee ,  Hsueh Wen Tsau ,  Cheng-Yen Tsai ,  Cheng-Lung Hung ,  Da-Yuan Lee ,  Ching-Hwanq Su

IPC: H01L21/8234 ,  H01L27/088 ,  H01L29/78

Abstract: Semiconductor device structures having gate structures with tunable threshold voltages are provided. Various geometries of device structure can be varied to tune the threshold voltages. In some examples, distances from tops of fins to tops of gate structures can be varied to tune threshold voltages. In some examples, distances from outermost sidewalls of gate structures to respective nearest sidewalls of nearest fins to the respective outermost sidewalls (which respective gate structure overlies the nearest fin) can be varied to tune threshold voltages.