公开(公告)号：US20150217222A1

公开(公告)日：2015-08-06

申请号：US14421949

申请日：2013-08-16

Applicant: SU HOLDING AB ,  BIOKOL LILLIESTRALE & CO KB

Inventor： Niklas Hedin ,  Malte Lilliestrale ,  Hao Wenming ,  Eva Bjorkman

IPC: B01D53/04 ,  B01J20/30 ,  B01J20/20 ,  B01J20/28 ,  B01D15/08 ,  B01J20/06

CPC classification number: B01D53/04 ,  B01D15/08 ,  B01D2253/102 ,  B01D2253/30 ,  B01D2259/40088 ,  B01J8/0085 ,  B01J8/009 ,  B01J8/025 ,  B01J20/06 ,  B01J20/20 ,  B01J20/28007 ,  B01J20/28009 ,  B01J20/28026 ,  B01J20/28057 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28069 ,  B01J20/28073 ,  B01J20/3078 ,  B01J20/3085 ,  B01J20/3416 ,  B01J20/3441 ,  B01J2208/00168 ,  B01J2208/00407 ,  B01J2208/00415 ,  B01J2208/00522 ,  B01J2220/4825 ,  B01J2220/4843 ,  B01J2220/485 ,  B82Y30/00 ,  C01B32/336 ,  H01F1/0063 ,  Y02C10/08

Abstract: A process for preparing magnetic activated carbons including the steps of a) treating an aqueous solution having a biomass hydrothermally at autogenic pressure at a temperature 180 and 250° C., under acidic conditions in the presence of iron ions, to obtain a precursor product, b) activating the precursor product obtained in step a) by mixing an activating agent at elevated temperatures between 550 and 850° C., for a period up to 9 h. The disclosure also relates to magnetic activated carbon prepared according to the process and use of the carbon for separation and storage of gases and purification of liquids. A method for separation of particles from a liquid and/or a gas, and method for regenerating magnetic activated carbon by heating using an oscillating electromagnetic field are also disclosed.

Abstract translation: 一种制备磁性活性炭的方法，包括以下步骤：a）在铁离子存在下，在酸性条件下，在温度为180℃和250℃的自生压力下，以水热法处理生物质水溶液，得到前体产物， b）通过在550和850℃之间的升高的温度下将活化剂混合达9小时来活化步骤a）中获得的前体产物。 本公开还涉及根据用于分离和储存气体的碳的方法和用途制备的磁性活性炭和液体的净化。 还公开了一种用于从液体和/或气体中分离颗粒的方法，以及通过使用振荡电磁场加热来再生磁性活性炭的方法。

公开(公告)号：US20140171709A1

公开(公告)日：2014-06-19

申请号：US14103322

申请日：2013-12-11

Applicant: BASF SE

Inventor： Gerhard Olbert ,  Carlos Tellaeche Herranz ,  Norbert Asprion ,  Alexander Weck ,  Ellen Dahlhoff

IPC: C07C5/48

CPC classification number: C07C5/48 ,  B01J8/0453 ,  B01J8/0492 ,  B01J8/0496 ,  B01J19/2485 ,  B01J2208/00168 ,  B01J2208/00176 ,  B01J2208/00221 ,  B01J2208/0053 ,  B01J2219/2409 ,  B01J2219/2411 ,  B01J2219/2414 ,  B01J2219/2419 ,  B01J2219/2443 ,  C07C11/167 ,  C07C11/06 ,  C07C11/09 ,  C07C11/08 ,  C07C15/46

Abstract: A reactor for gas-phase dehydrogenation of a hydrocarbon-comprising stream with an oxygen-comprising stream over a monolithic heterogeneous catalyst. Catalytically active zone(s) comprising monoliths packed next to one another and/or above one another and a mixing zone having fixed internals upstream of each catalytically active zone. Feed line(s) for the hydrocarbon-comprising gas stream to be dehydrogenated at the lower end of the reactor. Independently regulable feed line(s), which supply distributor(s), for the oxygen-comprising gas stream into each of the mixing zones and discharge line(s) for the reaction gas mixture of the autothermal gas-phase dehydrogenation at the upper end of the reactor. The interior wall of the reactor is provided with insulation. The catalytically active zone(s) is accessible from the outside of the reactor via manhole(s). The catalytically active zone(s), mixing zone, independently regulable feed line(s), and distributor(s), may be designed as one component which can individually be mounted and removed.

Abstract translation: 一种用于在含整个非均相催化剂上的含氧物流将含烃物流气相脱氢的反应器。 催化活性区包括彼此相邻和/或彼此重叠的整料，以及在每个催化活性区上游具有固定内部的混合区。 用于含烃气流的进料管线在反应器的下端被脱氢。 将供应分配器的独立可调节的进料管线用于含氧气流进入每个混合区和排出管线，用于上端的自热气相脱氢反应气体混合物 的反应器。 反应器的内壁设有绝缘体。 催化活性区可通过人孔从反应器的外部进入。 催化活性区域，混合区域，独立调节的进料管线和分配器可以被设计为可单独安装和移除的一个组件。

公开(公告)号：US08597583B2

公开(公告)日：2013-12-03

申请号：US12705056

申请日：2010-02-12

Applicant: Haruyuki Nakanishi ,  Norihiko Nakamura ,  Hidekazu Arikawa ,  Susumu Hikazudani ,  Sadao Araki ,  Chikashi Inazumi

Inventor： Haruyuki Nakanishi ,  Norihiko Nakamura ,  Hidekazu Arikawa ,  Susumu Hikazudani ,  Sadao Araki ,  Chikashi Inazumi

IPC: C01C1/00 ,  B01J19/00 ,  B01J8/00 ,  C01B21/00 ,  C01C1/04

CPC classification number: C01C1/0405 ,  B01J7/02 ,  B01J8/009 ,  B01J8/0423 ,  B01J8/0496 ,  B01J2208/00168 ,  C01B3/025 ,  C01B3/061 ,  C01B3/08 ,  C01B13/0251 ,  C01B2210/0046 ,  C01C1/0417 ,  Y02E60/36 ,  Y02P20/52

Abstract: An ammonia synthesis apparatus includes: a first gas channel; a second gas channel disposed outside the first gas channel; a third gas channel disposed outside the second gas channel; an air supply unit that supplies air to the second or third gas channel; a water supply unit that supplies water to the first gas channel; and a heat supply unit that supplies heat to the first gas channel. A metal or a metal oxide that reduces water to produce hydrogen is placed in the first gas channel. An ammonia synthesis catalyst is placed in the second gas channel located downstream of the downstream end portion of the first gas channel. The second and third gas channels are at least partially partitioned by an oxygen permeation membrane, or a nitrogen permeation membrane, so that oxygen is supplied to the third gas channel, and nitrogen is supplied to the second gas channel.

Abstract translation: 氨合成装置包括：第一气体通道; 设置在第一气体通道外侧的第二气体通道; 设置在所述第二气体通道外侧的第三气体通道; 空气供应单元，其向第二或第三气体通道供应空气; 供水单元，其向第一气体通道供水; 以及向第一气体通道供热的供热单元。 减少水以产生氢的金属或金属氧化物被放置在第一气体通道中。 氨合成催化剂被放置在位于第一气体通道的下游端部下游的第二气体通道中。 第二和第三气体通道至少部分地被氧气渗透膜或氮气渗透膜分隔开，使得向第三气体通道供应氧气，并且向第二气体通道供应氮气。

公开(公告)号：US20120141366A1

公开(公告)日：2012-06-07

申请号：US13143352

申请日：2009-01-07

Applicant: Peter Forsberg ,  Björn Häggendal ,  Anders Eriksson ,  Louise De Verdier

Inventor： Peter Forsberg ,  Björn Häggendal ,  Anders Eriksson ,  Louise De Verdier

IPC: C01B3/24 ,  B01J19/00

CPC classification number: C01B3/363 ,  B01J8/0438 ,  B01J8/0492 ,  B01J8/0496 ,  B01J2208/00168 ,  B01J2208/00212 ,  B01J2208/00362 ,  B01J2208/0053 ,  B01J2208/00646 ,  B01J2208/00716 ,  C01B3/382 ,  C01B3/48 ,  C01B2203/0244 ,  C01B2203/0288 ,  C01B2203/04 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/0485 ,  C01B2203/066 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1294 ,  C01B2203/147 ,  C01B2203/1604 ,  H01M8/0618 ,  H01M8/0631 ,  H01M2008/1095 ,  Y02E60/50

Abstract: A fuel processor for generating hydrogen rich gas or cleaned hydrogen rich gas from hydrocarbon fuel includes an inner housing and an outer housing defining a mantel space between them, wherein at least one fuel reformer unit for reforming hydrocarbon fuel to a hydrogen rich gas and optionally a gas-cleaning unit for cleaning the hydrogen rich gas from unwanted by-products are arranged in the inner housing. The fuel processor further includes a processor inlet for introducing hydrocarbon fuel into the inner housing and a processor outlet for releasing cleaned hydrogen rich gas from the inner housing. The outer housing further includes a fluid inlet for introducing a heat transporting fluid into the mantel space. The inner housing includes at least one opening for providing a fluid-connection between the inner housing and the mantel space. A method for operating such a fuel processor is also provided.

Abstract translation: 用于从烃燃料产生富氢气体或净化的富氢气体的燃料处理器包括内壳体和限定其间的壁架空间的外壳体，其中至少一个用于将烃燃料重整为富氢气体的燃料重整单元， 用于从不需要的副产物清洗富氢气体的气体清洁单元布置在内壳体中。 燃料处理器还包括用于将烃燃料引入内壳体的处理器入口和用于从内壳体释放净化的富氢气体的处理器出口。 外壳还包括用于将热输送流体引入壁架空间的流体入口。 内壳体包括用于在内壳体和壁架空间之间提供流体连接的至少一个开口。 还提供了一种用于操作这种燃料处理器的方法。

公开(公告)号：US08119299B2

公开(公告)日：2012-02-21

申请号：US10954679

申请日：2004-09-30

Applicant: Hongqiao (Bruce) Sun ,  W. Spencer Wheat ,  Vesna R. Mirkovic ,  Daniel G. Casey

Inventor： Hongqiao (Bruce) Sun ,  W. Spencer Wheat ,  Vesna R. Mirkovic ,  Daniel G. Casey

IPC: H01M8/04

CPC classification number: B01J8/0285 ,  B01J8/0496 ,  B01J2208/00141 ,  B01J2208/00168 ,  B01J2208/0053 ,  B01J2219/00083 ,  B01J2219/00087 ,  C01B3/382 ,  C01B3/48 ,  C01B3/56 ,  C01B2203/0244 ,  C01B2203/0283 ,  C01B2203/042 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/0485 ,  C01B2203/066 ,  C01B2203/0844 ,  C01B2203/0883 ,  C01B2203/146 ,  H01M8/0612 ,  H01M8/0668 ,  H01M2008/1095 ,  Y02P20/129

Abstract: A coolant subsystem for use in a fuel processor and a method for its operation are disclosed. In accordance with a first aspect, the coolant subsystem is separate from the feed to the processor reactor and is capable of circulating a coolant through the processor reactor. In accordance with a second aspect, the constituent elements of the fuel processor are housed in a cabinet, and the coolant subsystem is capable of cooling both the processor reactor and the interior of the cabinet. In various alternatives, the fuel processor can be employed to reform a fuel for a fuel cell power plant and/or may be used to provide thermal control for unrelated mechanical systems.

Abstract translation: 公开了一种用于燃料处理器的冷却剂子系统及其操作方法。 根据第一方面，冷却剂子系统与供给到处理器反应器的进料分离，并且能够使冷却剂循环通过处理器反应器。 根据第二方面，燃料处理器的组成元件容纳在机柜中，并且冷却剂子系统能够冷却处理器反应器和机柜的内部。 在各种替代方案中，燃料处理器可用于改造用于燃料电池发电厂的燃料和/或可用于为不相关的机械系统提供热控制。

公开(公告)号：US08097216B2

公开(公告)日：2012-01-17

申请号：US12898069

申请日：2010-10-05

Applicant: James H. Beech, Jr. ,  Nicolas P. Coute ,  Jeffrey S. Smith ,  Michael Peter Nicoletti

Inventor： James H. Beech, Jr. ,  Nicolas P. Coute ,  Jeffrey S. Smith ,  Michael Peter Nicoletti

IPC: B01J8/18 ,  F27B15/08

CPC classification number: C10G3/62 ,  B01J8/0055 ,  B01J8/1809 ,  B01J8/28 ,  B01J8/34 ,  B01J2208/00168 ,  B01J2208/00495 ,  B01J2208/00752 ,  B01J2208/00761 ,  B01J2208/0084 ,  B01J2208/00884 ,  C10G3/49 ,  C10G3/57 ,  C10G11/18 ,  C10G2400/20 ,  Y02P30/20

Abstract: A process and apparatus for fluidizing a population of catalyst particles having a low catalyst fines content includes a fluidized bed reactor which includes a plurality of catalyst particles in the reactor wherein the catalyst particles having a d2 value of greater than about 40 microns. The catalyst particles are contacted with a fluidizing medium under conditions to fluidize the particles, the reactor includes a continuous reaction zone and separation zone and the fluidized of the catalyst particles are situated within the reaction and both the reaction zone and the separation zone include obstructing members which obstruct the flow of particles such that the catalyst particles can be maintained at an axial gas Peclet number from about 10 to about 20.

Abstract translation: 用于流化具有低催化剂细粉含量的催化剂颗粒群的方法和设备包括流化床反应器，其在反应器中包括多个催化剂颗粒，其中催化剂颗粒的d2值大于约40微米。 催化剂颗粒在流化颗粒的条件下与流化介质接触，反应器包括连续反应区和分离区，催化剂颗粒的流化位于反应中，反应区和分离区都包括阻挡构件 这阻碍了颗粒的流动，使得催化剂颗粒可以保持在约10至约20的轴向气体佩克莱数。

公开(公告)号：US07931870B2

公开(公告)日：2011-04-26

申请号：US12104055

申请日：2008-04-16

Applicant: Kazumasa Takada ,  Norihiko Toyonaga

Inventor： Kazumasa Takada ,  Norihiko Toyonaga

IPC: B32B27/04

CPC classification number: C01B3/384 ,  B01J8/025 ,  B01J8/0278 ,  B01J8/0285 ,  B01J2208/00061 ,  B01J2208/00168 ,  B01J2208/00309 ,  B01J2208/00504 ,  B01J2208/0053 ,  B01J2208/00601 ,  B01J2219/002 ,  B01J2219/00211 ,  B01J2219/00231 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/0816 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1619 ,  C01B2203/1685 ,  C01B2203/1695 ,  H01M8/0618 ,  H01M8/0662 ,  Y02P20/128

Abstract: A controller for a reformer that: changes the supply quantity of at least either one of combustible gas and combustion oxidizing gas supplied to a combustion section; detects a change which is caused in the combustion state of the combustion section as a result of a change of the supply quantity; and checks the combustion state which arose at the combustion section before the change based on the previously detected detection result. Thus, a gone-out state of the combustion section can be reliably judged with a low cost device, and the combustion state of the combustion section in the reformer of a fuel cell system can be adjusted to an optimum combustion state.

Abstract translation: 一种重整器的控制器，其特征在于：改变供给至燃烧部的可燃气体和燃烧氧化气体中的至少一方的供给量; 检测由于供给量的变化导致燃烧部的燃烧状态引起的变化; 并基于先前检测到的检测结果来检查在变化之前在燃烧部分产生的燃烧状态。 因此，能够以低成本的装置可靠地判断燃烧部的熄灭状态，能够将燃料电池系统的重整器中的燃烧部的燃烧状态调整为最佳燃烧状态。

公开(公告)号：US07727509B2

公开(公告)日：2010-06-01

申请号：US10499227

申请日：2002-12-16

Applicant: Peter Edward James Abbott ,  Bernard John Crewdson ,  Martin Fowles

Inventor： Peter Edward James Abbott ,  Bernard John Crewdson ,  Martin Fowles

IPC: C01B3/24

CPC classification number: B01J19/002 ,  B01J8/0496 ,  B01J8/067 ,  B01J19/02 ,  B01J2208/00168 ,  B01J2208/00212 ,  B01J2208/00707 ,  B01J2219/00006 ,  B01J2219/00272 ,  B01J2219/0204 ,  B01J2219/0236 ,  C01B3/382 ,  C01B3/384 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0844 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/1235 ,  C01B2203/127 ,  C01B2203/141 ,  C23F11/02 ,  Y02P20/128

Abstract: A method for reducing the interaction between carbon monoxide present in a heat exchange medium and metals on the shell side of heat exchange reformer apparatus used for reforming of hydrocarbons by treatment of the shell-side of said apparatus with an effective amount of at least one passivation compound containing at least one element selected from phosphorus, tin, antimony, arsenic, lead, bismuth, copper, germanium, silver or gold is described. Where volatile compounds are formed by the passivation compound, the method further comprises compound recovery to prevent contamination and deactivation of subsequent process steps. The method reduces side reactions, provides improved reformer tube lifetime and allows tubes to be treated in-situ without the need for process shutdown.

Abstract translation: 一种用于通过用有效量的至少一种钝化处理所述装置的壳侧来减少在热交换介质中存在的一氧化碳与用于重整烃的热交换重整装置的壳侧上的金属之间的相互作用的方法 描述了含有选自磷，锡，锑，砷，铅，铋，铜，锗，银或金中的至少一种元素的化合物。 当通过钝化化合物形成挥发性化合物时，该方法还包括化合物回收以防止后续工艺步骤的污染和失活。 该方法减少了副反应，提供了改进的重整器管寿命，并允许管原位处理，而不需要过程关闭。

公开(公告)号：US20090304573A1

公开(公告)日：2009-12-10

申请号：US12499417

申请日：2009-07-08

Applicant: Aurel Wolf ,  Leslaw Mleczko ,  Stephan Schubert ,  Oliver Felix-Karl Schlüter

Inventor： Aurel Wolf ,  Leslaw Mleczko ,  Stephan Schubert ,  Oliver Felix-Karl Schlüter

IPC: C01B7/04 ,  B01J8/04

CPC classification number: C01B7/04 ,  B01J8/0453 ,  B01J8/0457 ,  B01J8/0496 ,  B01J23/462 ,  B01J27/13 ,  B01J2208/00168 ,  B01J2208/00176 ,  B01J2208/00274 ,  B01J2219/0004

Abstract: The present invention provides a process for producing chlorine by the catalytic gas phase oxidation of hydrogen chloride with oxygen, wherein the reaction is performed on at least two catalyst beds under adiabatic conditions, as well as a reactor system for performing the process.

Abstract translation: 本发明提供了通过氯气与氧气的催化气相氧化来生产氯的方法，其中反应在绝热条件下在至少两个催化剂床上进行，以及用于进行该方法的反应器系统。

公开(公告)号：US20070274901A1

公开(公告)日：2007-11-29

申请号：US11752676

申请日：2007-05-23

Applicant: Aurel Wolf ,  Leslaw Mleczko ,  Stephan Schubert ,  Oliver Schluter

Inventor： Aurel Wolf ,  Leslaw Mleczko ,  Stephan Schubert ,  Oliver Schluter

IPC: C01B7/04 ,  B01J8/04

CPC classification number: C01B7/04 ,  B01J8/0453 ,  B01J8/0457 ,  B01J8/0496 ,  B01J23/462 ,  B01J27/13 ,  B01J2208/00168 ,  B01J2208/00176 ,  B01J2208/00274 ,  B01J2219/0004

Abstract: The present invention provides a process for producing chlorine by the catalytic gas phase oxidation of hydrogen chloride with oxygen, wherein the reaction is performed on at least two catalyst beds under adiabatic conditions, as well as a reactor system for performing the process.

Abstract translation: 本发明提供了通过氯气与氧气的催化气相氧化来生产氯的方法，其中反应在绝热条件下在至少两个催化剂床上进行，以及用于进行该方法的反应器系统。