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公开(公告)号：US20240116837A1
公开(公告)日：2024-04-11
申请号：US18544924
申请日：2023-12-19
发明人： David Sellinger , Robert Choi , Quo-Chen Yeh , Alok Srivastava , Kristine E. Hamilton , Michael A. Radzicki
CPC分类号： C07C2/38 , B01J19/0013 , C07C7/04 , C07C13/61 , B01J2219/00051 , C07C2603/68
摘要： A system and a process for dimerizing cyclopentadiene (CPD) including producing a C6+C7 rich bottoms stream and a C5 rich side draw from a debutanizer, where the C5 rich side draw and at least a portion of the C6+C7 rich bottoms stream are directed to a dimerizer where the CPD is thermally dimerized to dicyclopentadiene (DCPD). DCPD is more stable than CPD and thus safer to handle.
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公开(公告)号：US20190118169A1
公开(公告)日：2019-04-25
申请号：US16221316
申请日：2018-12-14
申请人： UOP LLC
发明人： Timur V. Voskoboynikov , Alakananda Bhattacharyya , Nikolay Y. Adonin , Mariya N. Timofeeva , Sergey A. Prikhodko , Valentin N. Parmon
IPC分类号： B01J31/08 , B01J31/30 , B01J41/13 , B01J41/14 , B01J41/10 , B01J41/16 , B01J47/016 , C07C2/38 , C07C5/09
CPC分类号： B01J31/08 , B01J23/72 , B01J27/128 , B01J27/13 , B01J27/236 , B01J31/30 , B01J41/10 , B01J41/13 , B01J41/14 , B01J41/16 , B01J47/016 , B01J2231/20 , C07C2/38 , C07C5/09 , C07C11/167 , C07C11/28 , C07C2531/08
摘要： A catalyst and a process for using the catalyst are presented. The catalyst is a heterogeneous catalyst and includes active metal halides bonded to functional groups. The functional groups are bonded to a polymeric backbone to form the structure supporting the catalyst. The catalyst is useful for the dimerization of acetylene to convert the acetylene to a larger hydrocarbon, and in particular to dimerize acetylene to vinylacetylene.
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公开(公告)号：US08993804B2
公开(公告)日：2015-03-31
申请号：US13791410
申请日：2013-03-08
发明人： Wei Zhang , Jyothish Kuthanapillil , Qi Wang
IPC分类号： C07C211/00 , C07C215/50 , B01J31/22 , C07C41/30 , C07C45/72 , C07D333/08 , C07D213/127 , C07D487/22 , C07C37/48 , C07B37/00 , C07C6/02 , C07F7/00 , C07C17/269 , C07F11/00 , C07C215/76 , C07C215/90 , C07D333/18
CPC分类号： B01J31/2265 , B01J31/1608 , B01J31/1805 , B01J31/223 , B01J31/2295 , B01J2231/546 , B01J2531/0247 , B01J2531/58 , B01J2531/64 , B01J2531/66 , B01J2531/74 , B01J2540/40 , B01J2540/62 , C07B37/00 , C07C2/38 , C07C6/02 , C07C17/269 , C07C37/48 , C07C41/30 , C07C45/72 , C07C201/12 , C07C215/50 , C07C215/76 , C07C215/90 , C07D213/127 , C07D321/00 , C07D333/08 , C07D333/18 , C07D487/22 , C07F7/00 , C07F11/00 , C07C43/215 , C07C17/26 , C07C25/24 , C07C47/548 , C07C11/22 , C07C39/21
摘要： The invention relates to highly active and selective catalysts for alkyne metathesis. In one aspect, the invention includes a multidentate organic ligand wherein one substrate-binding site of the metal center is blocked. In another aspect, the invention includes N-quaternized or silane-based multidentate organic ligands, capable of binding to metals. In yet another aspect, the invention includes N-quaternized or silane-based multidentate catalysts. The catalysts of the invention show high robustness, strong resistance to small alkyne polymerization and significantly enhanced catalytic activity compared to their corresponding non-quaternized or non-silane-based multidentate catalyst analogs.
摘要翻译： 本发明涉及用于炔烃复分解的高活性和选择性催化剂。 一方面，本发明包括多金属有机配体，其中金属中心的一个底物结合位点被阻断。 另一方面，本发明包括能与金属结合的N-季铵化或硅烷基多齿有机配体。 另一方面，本发明包括N-季铵化或硅烷基多齿催化剂。 与其相应的非季铵化或非硅烷基多齿催化剂类似物相比，本发明的催化剂显示出高稳定性，对小炔炔聚合的强耐受性和显着增强的催化活性。
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公开(公告)号：US20140058128A1
公开(公告)日：2014-02-27
申请号：US13915130
申请日：2013-06-11
申请人： UOP LLC
IPC分类号： B01J19/10 , C07C309/28 , C07C5/08
CPC分类号： B01J19/10 , B01J3/08 , B01J19/26 , B01J2219/00006 , B01J2219/0004 , B01J2219/00123 , C07C2/06 , C07C2/38 , C07C2/64 , C07C2/78 , C07C5/08 , C07C5/09 , C07C67/04 , C07C67/055 , C07C303/04 , C07C309/28 , C10G50/00 , C10G2300/1025 , C10G2400/24 , C07C11/24 , C07C11/04 , C07C11/08 , C07C11/22 , C07C9/00 , C07C15/107 , C07C309/31
摘要： Methods and systems are provided for converting methane in a feed stream to acetylene. The hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream is further processed to generate larger hydrocarbons in a second reactor. The reactor effluent stream can be processed before the second reactor to remove waste products such as carbon monoxide and nitrogen in the reactor effluent stream.
摘要翻译： 提供了将进料流中的甲烷转化为乙炔的方法和系统。 将烃流引入超音速反应器中并热解以将至少一部分甲烷转化为乙炔。 在第二反应器中进一步处理反应器流出物流以产生较大的烃。 可以在第二反应器之前处理反应器流出物流以除去反应器流出物流中的废物，例如一氧化碳和氮。
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公开(公告)号：US3305598A
公开(公告)日：1967-02-21
申请号：US21300562
申请日：1962-07-27
申请人： MONSANTO CO
发明人： FRANZ RAYMOND A , MOORE RICHARD N
CPC分类号： C07C2/38 , C07C2/08 , C07C2/20 , C07C2/26 , C07C2527/02 , C07C2527/08 , C07C2531/02
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公开(公告)号：US3268596A
公开(公告)日：1966-08-23
申请号：US30548863
申请日：1963-08-29
申请人： KNAPSACK AG
发明人： KURT SENNEWALD , WILHELM VOGT , HANS WEIDEN , PETER KOMISCHKE
IPC分类号： C07C2/38
CPC分类号： C07C2/38 , C07C2527/10 , C07C2527/122 , C07C11/30
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18.发明授权New catalyst system for linear and cyclic polymerization of mono substituted acetylenes 失效用于单取代乙炔的直链和环状聚合的新型催化剂体系
公开(公告)号：US3098843A
公开(公告)日：1963-07-23
申请号：US3210360
申请日：1960-05-27
申请人： AMERICAN CYANAMID CO
发明人： LUTTINGER LIONEL B
CPC分类号： C08F38/00 , B01J31/1805 , B01J31/1895 , B01J31/24 , B01J31/2404 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C2/38 , C07C2/48 , C07C2531/22 , C07C2531/24 , C08F4/26
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19.发明授权Polymerizing substituted acetylenes using nickel-carbonyl complex catalysts 失效使用镍 - 羰基络合物催化剂聚合取代的乙炔
公开(公告)号：US3051694A
公开(公告)日：1962-08-28
申请号：US3210260
申请日：1960-05-27
申请人： AMERICAN CYANAMID CO
CPC分类号： B01J31/1845 , B01J31/06 , B01J31/24 , B01J31/2409 , B01J2231/12 , B01J2531/847 , C07C2/38 , C07C2531/24 , C08F4/80
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20.发明授权Process for making acetylenic compounds by contacting alkyl acetylenes with oxygen and a copper salt 失效通过使烷基乙炔与氧和铜盐接触来制备炔属化合物的方法
公开(公告)号：US2952718A
公开(公告)日：1960-09-13
申请号：US73244158
申请日：1958-05-02
申请人： DU PONT
发明人： CHARLES KAUER JAMES
IPC分类号： C07C2/38
CPC分类号： C07C2/38 , C07C2527/122
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