Abstract:
An electrochemical apparatus includes an electrolyte, where the electrolyte includes a carboxylate compound and fluoroethylene carbonate (FEC). Based on a total weight of the electrolyte, percentages of the carboxylate compound and FEC are w1 and w2 respectively, where 5%≤w1≤60%, 2%≤w2≤12%, and 2≤w1/w2≤20. The electrochemical apparatus delivers excellent fast charging performance and high-temperature interval cycle performance.
Abstract:
The present invention relates to an industrially usable process for preparing alkali metal and alkaline earth metal tricyanomethanides in particularly high purity.
Abstract:
The present invention provides an ionic compound which: can exert excellent basic performance such as excellent electrochemical stability including an excellent ionic conductivity; is excellent in pH stability; and can suitably find use in a variety of applications, and an electrolyte material, an electrolytic solution, and an electrolytic capacitor each containing the ionic compound. Anionic compound of the present invention has an anion represented by a general formula (1) and a cation represented by a general formula (2): where X represents an element selected from B, C, N, O, Al, Si, P, S, As, and Se, M1 and M2 represent linking groups, Q represents a monovalent element or organic group, a represents an integer of 1 or more, and b, c, d, and e each represent an integer of 0 or more; Rs-LH⊕ (2) where L represents an element selected from C, Si, N, P, S, and O, R represents a monovalent element, functional group, or organic group, and s represents an integer of 2, 3, or 4.
Abstract:
The invention relates to a continuous process, carried out in two steps, for the cyanoalkylation of compounds having one or more NH functions by reaction thereof with carbonyl compounds and hydrocyanic acid, in which the first step is carried out without pressure at a temperature which is below the boiling point of the reaction mixture.
Abstract:
A process for electrochemically coupling anions of organic radicals to form multifunctional compounds having the general formula ##STR1## in which R.sub.1 and R.sub.2 are independently selected from --CN, CO.sub.2 Et, --R .sub.4 CH.sub.2 Et, --CO.sub.2 R.sub.4, and --COCH.sub.3 ; R.sub.3 is Br, H, or Et, and R.sub.4 is C.sub.1-12 alkyl; and the novel compounds per se.
Abstract:
An electrolyte, including: a compound of Formula I, and at least one of a compound of Formula II or a compound of Formula III,
R1, R2, R3 and R4 are each independently selected from hydrogen, fluoro, substituted or unsubstituted C1-C10 alkyl, substituted or unsubstituted C2-C10 alkenyl, substituted or unsubstituted C2-C10 alkynyl, substituted or unsubstituted C6-C12 aryl, substituted or unsubstituted C1-C10 alkoxy, or substituted or unsubstituted C6-C12 aryloxy, wherein when substituted, the substituent is fluoro, cyano or C1-C10 alkyl; and a, d and f are each independently selected from an integer from 1 to 5, and b, c, e, g, h and i are each independently selected from an integer from 0 to 5.
Abstract:
A lubricant, which includes an ionic liquid including a conjugate base and a conjugate acid including 2 or more cations in a molecule of the conjugate acid, wherein the conjugate acid includes a monovalent group including a straight-chain hydrocarbon group having 6 or more carbon atoms, and an acid that is a source of the conjugate base has a pKa in acetonitrile of 10 or less.
Abstract:
An ionic compound is provided that has an anion represented by a: formula (1) and a cation represented by a formula (2): where X is an element selected from the group consisting of B, C, N, O, Al, Si, P, S, As, and Se, M1 and M2 are identical or different, and represent linking groups, and, when multiple M1s or multiple M2s are present, they may be identical or different, Q represents a monovalent element or organic group, a represents an integer of 1 or more, and b, c, d, and a each represent an integer of 0 or more; and RS-LH⊕(2) where L is an element selected from the group consisting of C, Si, N, P, S, and 0, R represents a monovalent element, functional group, or organic group, and s represents an integer of 2 to 4.
Abstract:
Hydrolyzed nitrilotriacetonitrile compositions are disclosed prepared by a method characterized by a one-shot addition of an amount of nitrilotriacetonitrile to a solution containing an acid catalyst, where the reaction is complete in a time period of less than an hour. The method is also characterized by adjusting the pH of the reaction mixture to a pH of at least 8. The method is also characterized by oxidatively removing free cyanide to a desired low level through the addition of an oxidizing agent the produces environmentally benign by-products to the crude hydrolyzed NTAN to form hydrolyzed NTAN compositions having minimized, negligible, or substantially no free cyanide levels.
Abstract:
Hydrolyzed nitrilotriacetonitrile compositions are disclosed prepared by a method characterized by a one-shot addition of an amount of nitrilotriacetonitrile to a solution containing an acid catalyst, where the reaction is complete in a time period of less than an hour. The method is also characterized by adjusting the pH of the reaction mixture to a pH of at least 8. The method is also characterized by oxidatively removing free cyanide to a desired low level through the addition of an oxidizing agent the produces environmentally benign by-products to the crude hydrolyzed NTAN to form hydrolyzed NTAN compositions having minimized, negligible, or substantially no free cyanide levels.