摘要:
High-temperature furnace (10) for processing carbon-containing material in an inner zone (8) at a high-temperature. The furnace (10) comprises an in-feed side (20) for continuously feeding said carbon-containing material into said inner zone (8) and an output side (30) where a Syngas is provided. The infeed side (20) comprises an infeed section (23) providing for an atmosphere being essentially oxygen-free. There is gas inlet (22.1) at the infeed section (23) which is connected to the output side (30) for feeding some of said Syngas into said infeed section (23).
摘要:
The present invention has been designed to provide a solution to problems with conventional gasifiers which operate by having fuel introduced at one end of a gasification retort and gas and residues removed from the other end. This frequently results in powdered char residues being ejected with the gas, causing increased gas clean-up requirements. The present invention provides a solution to this problem by removing the gas from the retort at the fuel inlet end via the fuel feed apparatus which is preferably a combined ram and scroll feed providing a supply of fuel under anaerobic conditions.
摘要:
A system involving a two-step gasification of a carbonaceous source to produce bulk hydrogen that avoids the early formation of CO2 and obviates the traditional water gas shift (WGSR) step, carbochlorination of a metallic ore the production of metals found in the ore that utilizes carbon monoxide as an oxygen sink, rather than the traditional coke, and carbon oxides management that eliminates major impediments to emission-neutral power generation and the reduction of major metals. The gasification uses a rotary kiln reactor and gas-gas cyclonic separation process to separate synthesis gas into purified hydrogen and purified carbon monoxide. Purified bulk carbon monoxide issued in metallurgical reduction, and purified bulk hydrogen as fuel for an emission-neutral hydrogen combined cycle (HCC) turbine power generation station. The carbochlorination is integrated with: a) the concurrent separation and purification of all metal-chlorides (metchlors) and capture of CO2 for passage to the carbon oxides management system; b) the direct reduction of metchlors to nanoscale metallurgical powders and/or to dendritically-shaped particles, including metchlor reduction for the ultrahigh-performance semiconductor metals of the III-V group; and, c) the reforming of metal-oxides with improved crystalline structure from metchlors. The carbon oxides management collects, stores and directs to points of usage, carbon oxides that arise in various processes of the integrated system, and captures carbon monoxide for process enhancement and economic uses and captures carbon dioxide as a process intermediate and for economic uses.
摘要:
A port assembly for controlling the delivery of gases into the horizontal rotating reactor such as kiln gasifier is disclosed for introducing reactant gases. The port assembly comprises a cylindrical conduit is divided into noncommunicating four or more sections extending through the entire length of the kiln and supported by the stationary end plates of the rotating kiln gasifier. Each section of the conduit communicates with external supply of the reactant gases and each supply of reactant gases is independently controlled in terms of the composition and quantity. Each section of the port assembly communicates with the interior of the kiln gasifier through the plurality of nozzles are confined in the lower part of the conduit. The number and the size of the nozzles in individual section of the conduit is based on the desired flow of gases and available pressure for the supply of the reactant gases.
摘要:
The process and system of the invention converts carbonaceous feedstock such as coal, hydrocarbon oil, natural gas, petroleum coke, oil shale, carbonaceous-containing waste oil, carbonaceous-containing medical waste, carbonaceous-containing hazardous waste, carbonaceous-containing medical waste, and mixtures thereof into electrical energy without the production of unwanted greenhouse emissions. The process and system uses a combination of a gasifier, e.g., a kiln, operating in the exit range of at least 700null to about 1600null C. (1300-2900null F.) to convert the carbonaceous feedstock and a greenhouse gas stream into a synthesis gas comprising mostly carbon monoxide and hydrogen without the need for expensive catalysts and or high pressure operations. One portion of the synthesis gas from the gasifier becomes electrochemically oxidized in an electricity-producing fuel cell into an exit gas comprising carbon dioxide and water. The latter is recycled back to the gasifier after a portion of water is condensed out. The second portion of the synthesis gas from the gasifier is converted into useful hydrocarbon products.
摘要:
The present invention relates to an apparatus and method for separating and processing solid waste, often but not necessarily from municipalities (and so will be generically referred to herein as municipal solid waste or “MSW”), into useful products, and for reducing biohazards and putrid odors derived from MSW. The MSW is loaded into an elongated, generally cylindrically shaped rotating pressure vessel and is subjected to heat and pressure by the application of steam in specified amounts to break down the organic portion of the MSW into a cellulose feedstock, or a de-manufactured paper product, of uniform particle size and density. This product is then easily separable from other constituents of MSW, such as glass, aluminum and other metals, and plastics. The recyclables are recovered and sold in the market. The waste water from the process is reduced by processing through a water vamping apparatus. The apparatus and process disclosed herein, unlike any in the prior art, allows for an economically and technically viable industrial process and environmental solution, which have the potential to replace current landfill technology.
摘要:
The invention relates to a method for processing waste or biomass material into valuable products such as, for example, combustible gases, which is characterized in that(a) the waste or biomass material is subjected to a pyrolysis at a temperature of 350-650.degree. C., advantageously 450-550.degree. C.;(b) the gas released in the course of the pyrolysis is subjected--without condensation--to a cracking treatment at a temperature of 1100-1600.degree. C., advantageously 1200-1400.degree. C., under the influence of oxygen-rich gas introduced from outside and possibly of steam;(c) the residue liberated in the course of the pyrolysis is gasified under a pressure of 0.5-1.5 bar, advantageously 0.8-1.2 bar, at a temperature of 1200-1700.degree. C., advantageously 1400-1600.degree. C., and is volatilized or, as the case may be, fused under reducing conditions;(d) the fused slag or metal concentrate obtained under stage (c) is discharged or, as the case may be, recovered;(e) the product gases obtained in the course of stages (b) and (c) are combined or not combined and then subjected to gas cleaning.
摘要:
A method of destructively distilling an organic material in particulate form wherein the particulates are introduced through an inlet into one end of an inner rotating kiln ganged to and coaxial with an outer rotating kiln. The inner and outer kilns define a cylindrical annular space with the inlet being positioned in registry with the axis of rotation of the ganged kilns. During operation, the temperature of the wall of the inner rotary kiln at the inlet is not less than about 500.degree. C. to heat the particulate material to a temperature in the range of from about 200.degree. C. to about 900.degree. C. in a pyrolyzing atmosphere to reduce the particulate material as it moves from the one end toward the other end. The reduced particulates including char are transferred to the annular space between the inner and the outer rotating kilns near the other end of the inner rotating kiln and moved longitudinally in the annular space from near the other end toward the one end in the presence of oxygen to combust the char at an elevated temperature to produce a waste material including ash. Also, heat is provided which is transferred to the inner kiln. The waste material including ash leaves the outer rotating kiln near the one end and the pyrolysis vapor leaves through the particulate material inlet.
摘要:
A waste disposal and energy recovery system and method uses sub-stoichiometric combustion to gasify waste fuels into high temperature synthetic gas. The system minimizes the amount of flue gas exiting to the atmosphere. The high temperature synthetic gas is then combusted in a gas burner. The burner can be closely coupled to a heat recovery unit to facilitate radiative heat transfer. Some flue gas can be recirculated to maintain low combustion temperatures in both the kiln and the burner. Sub-stoichiometric combustion is accomplished in the rotary kiln in a counterflow configuration.
摘要:
A rotary fluid bed gasifier which comprises: a rotatable drum having a circumferentially extending wall which is permeable to gases; a means for feeding a fluidizing gas through the wall into the drum; a bed of particles which, at least when the gasifier is in use, is supported on an internal face of the wall and is fluidized by the fluidizing gas; an outlet means for receiving a carbonaceous material from outside the gasifier and delivering the carbonaceous material to the drum; a means for introducing steam into the drum; a de-NO.sub.x boiler having a quench zone and a nitrogen fixing zone; a means for introducing secondary air disposed between the quench zone and the nitrogen fixing zone; and a means for introducing tertiary air disposed between the de-NO.sub.x boiler and a main boiler or furnace.