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    Coated monolith substrate and monolith catalysts
    12.
    发明申请
    Coated monolith substrate and monolith catalysts 审中-公开
    涂层整料基板和整体催化剂

    公开(公告)号：US20030036477A1

    公开(公告)日：2003-02-20

    申请号：US10002250

    申请日：2001-10-26

    Inventor： Andrew Francis Nordquist ,  Frederick Carl Wilhelm ,  Francis Joseph Waller ,  Reinaldo Mario Machado

    IPC: B01J023/00 ,  B01J021/04 ,  B01J021/18

    CPC classification number: C07C209/36 ,  B01J21/18 ,  B01J23/44 ,  B01J35/04 ,  B01J35/10 ,  B01J35/1014 ,  B01J37/0219 ,  B01J37/084 ,  C07C211/46

    Abstract: The present invention relates to monolith catalysts comprising a catalytic metal deposited onto a coated monolith substrate comprising a wash coat applied to a monolith substrate wherein the monolith catalysts have a surface area ranging from 0.1 to 25 m2/gram as measured by adsorption of N2 or Kr using the BET method. The invention also relates to the coated monolith substrates used in such monolith catalysts. The monolith catalysts of the present invention are particularly suited toward use in hydrogenation processes which employ an immiscible mixture of an organic reactant in water.

    Abstract translation: 本发明涉及包含沉积在涂覆的整料基材上的催化金属的整料催化剂，其包括施加到整料基材上的洗涤涂层，其中整料催化剂的表面积范围为0.1-25m 2 / g，通过吸附N2或Kr 使用BET方法。 本发明还涉及在这种整体催化剂中使用的涂覆的整料基板。 本发明的整体催化剂特别适用于使用有机反应物在水中的不混溶混合物的氢化方法。

    Thermally stable alumina particulates
    13.
    发明申请
    Thermally stable alumina particulates 有权
    热稳定的氧化铝颗粒

    公开(公告)号：US20020192150A1

    公开(公告)日：2002-12-19

    申请号：US09825473

    申请日：2001-04-03

    Inventor： Michael V. Glazov ,  John W. Novak JR. ,  Alexey Vertegel

    IPC: B01J021/04

    CPC classification number: B01D53/945 ,  B01J21/04 ,  B01J23/10 ,  B01J37/32 ,  C01F7/02 ,  C01F7/34 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2006/13 ,  C01P2006/17 ,  Y02T10/22

    Abstract: Thermally stable transitional alumina particulates retaining high specific surface area after calcination at 1000null C. suitable for the use as catalysts or catalysts supports are produced by treating an aqueous solution containing Al3null and optionally a doping amount of La3null (e.g., 0.3 mol. %) with an anion-exchange resin to give a stable hydroxide sol followed by freeze drying of the sol and further thermal dehydration. The resultant stabilized transitional alumina retains high specific surface area at 1000null C., and additionally stabilization is achieved at very low levels of added La.

    Abstract translation: 通过处理含有Al 3+的水溶液和任选的掺杂量的La 3+（例如，0.3mol％）来制备适于用作催化剂或催化剂载体的在1000℃煅烧后保持高比表面积的热稳定的过渡氧化铝颗粒， 用阴离子交换树脂提供稳定的氢氧化物溶胶，然后冷冻干燥溶胶和进一步的热脱水。 所得到的稳定的过渡氧化铝在1000℃下保持高比表面积，并且另外在非常低的添加La水平下实现稳定化。

    Honeycomb body made of material with improved radial pressure resistance
    14.
    发明申请
    Honeycomb body made of material with improved radial pressure resistance 有权
    蜂窝体由材料制成，具有改善的径向压力阻力

    公开(公告)号：US20020004454A1

    公开(公告)日：2002-01-10

    申请号：US09852151

    申请日：2001-05-10

    Inventor： Rainer Domesle ,  Thomas Kreuzer ,  Egbert Lox

    IPC: B01J023/02 ,  B01J021/04

    CPC classification number: B01J37/0215 ,  B01J35/04 ,  Y10T29/49345 ,  Y10T428/24149 ,  Y10T428/2982 ,  Y10T428/2991

    Abstract: A honeycomb body made from a ceramic material with improved radial pressure resistance that is of cylindrical shape and features a first and a second end face and a cylindrical shell and that is traversed from one end face to the other by axially parallel channels formed by channel walls and distributed across the cross section of the honeycomb body in a regular grid pattern, in which design an outer marginal zone of the honeycomb body, the thickness of which amounts to several channel diameters, encloses a central area. The increase in radial pressure resistance of the honeycomb body is achieved by reinforcing the ceramic material of the cylindrical shell and of the channel walls in the outer marginal zone of the honeycomb body by depositing on or in it one or several inorganic substances for the purpose of increasing its mechanical stability.

    Abstract translation: 一种由陶瓷材料制成的蜂窝体，其具有圆柱形形状的具有改进的径向耐压性，并且具有第一和第二端面和圆柱形壳体，并且通过由通道壁形成的轴向平行通道从一个端面横向延伸到另一个端面 并且以规则的格栅图案分布在蜂窝体的横截面上，其中设计为蜂窝体的外边缘区域，其厚度相当于几个通道直径，包围中心区域。 蜂窝体的径向耐压性的增加是通过在蜂窝体的外边缘区域中加载陶瓷材料和蜂窝体的外边缘区域中的通道壁来实现的，其中一个或几个无机物质用于 增加其机械稳定性。

    Freeze dry process for the preparation of a high surface area and high pore volume catalyst
    16.
    发明申请
    Freeze dry process for the preparation of a high surface area and high pore volume catalyst 审中-公开
    冷冻干法制备高表面积和高孔体积催化剂

    公开(公告)号：US20040235657A1

    公开(公告)日：2004-11-25

    申请号：US10442773

    申请日：2003-05-21

    Applicant: FINA Technology, Inc.

    Inventor： Xin Xiao ,  James R. Butler

    IPC: B01J021/04

    CPC classification number: B01J21/066 ,  B01J23/30 ,  B01J23/8892 ,  B01J27/053 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/20 ,  B01J37/32 ,  C10G35/06 ,  C10G45/60

    Abstract: The present invention provides a process for the preparation of a catalyst having a high surface area and pore volume. The process includes freeze drying an intermediary of the catalyst. The present invention further includes a catalyst prepared by a process that includes the freeze drying step. The present invention also includes a catalyst having a high acidity, as indicated by having an ammonium desorption peak at greater than about 500null C. The prevent invention further includes a method of manufacturing isomerized organic compounds using the catalyst.

    Abstract translation: 本发明提供了制备具有高表面积和孔体积的催化剂的方法。 该方法包括冷冻干燥催化剂的中间体。 本发明还包括通过包括冷冻干燥步骤的方法制备的催化剂。 本发明还包括具有高酸度的催化剂，如通过在大于约500℃具有铵解吸峰所表明的。本发明还包括使用该催化剂制备异构化有机化合物的方法。

    Monolith coating apparatus and method therefor
    17.
    发明申请
    Monolith coating apparatus and method therefor 有权
    Monolith涂层设备及其方法

    公开(公告)号：US20040023799A1

    公开(公告)日：2004-02-05

    申请号：US10628543

    申请日：2003-07-28

    Inventor： Dirk Aderhold ,  Alan George Haynes ,  Michael Leonard William Spencer ,  Duncan John William Winterborn

    IPC: B01J021/04

    CPC classification number: B01J37/0215 ,  B01J35/04 ,  B05D3/0493 ,  B05D7/22

    Abstract: Apparatus for coating a support such as a monolithic catalyst support (5) comprises a dispenser (1) for dispensing a predetermined quantity of coating liquid, a containment (2) for the liquid and a source of vacuum (8, 9) which can be actuated to draw the entire quantity of coating liquid into the support (5). The apparatus and method are particularly useful for coating car catalysts without wastage and with increased design options.

    Abstract translation: 用于涂覆诸如整体式催化剂载体（5）的载体的装置包括用于分配预定量的涂布液体的分配器（1），用于液体的容器（2）和真空源（8,9），其可以是 致动以将整个量的涂布液体吸入支撑件（5）中。 该设备和方法对于不浪费涂层汽车催化剂和增加的设计选择特别有用。

    Titania-coated honeycomb catalyst matrix for UV-photocatalytic oxidation of organic pollutants, and process for making
    18.
    发明申请
    Titania-coated honeycomb catalyst matrix for UV-photocatalytic oxidation of organic pollutants, and process for making 审中-公开

    公开(公告)号：US20030203816A1

    公开(公告)日：2003-10-30

    申请号：US10431210

    申请日：2003-05-07

    Inventor： Joseph J. Sangiovanni ,  Zissis A. Dardas

    IPC: B01J021/04 ,  B01J023/02

    CPC classification number: B01J21/063 ,  B01D2255/802 ,  B01D2257/708 ,  B01J35/002 ,  B01J35/004 ,  B01J35/04 ,  B01J37/0226 ,  B01J37/036 ,  Y10T428/12743 ,  Y10T428/12806 ,  Y10T428/31678 ,  Y10T428/31685

    Abstract: A titania-coated honeycomb catalyst matrix is provided for the ultraviolet-photocatalytic oxidation of organic pollutants in a flowing fluid. A honeycomb-shaped skeletal structure (12) has a thin, lightweight substrate (18) of metal or ceramic, typically an aluminum alloy, and a surface coating (20) of photocatalyst, such as titania. The photocatalyst (20) is bonded to the substrate (18) via a thin oxide layer (18null) on the substrate. The oxide layer (18null) may be grown on the substrate. The photocatalyst coating (20) is made by mixing (30) titania powder in a TiO2 sol-gel to form a titania slurry. The substrate with oxide layer is coated (30) with the titania slurry and then heat treated (31). The photocatalyst coating (20) is typically applied to substrate sheets (40, 60, 62) preformed for assembly into a honeycomb-shaped skeletal structure (12) having an array of parallel cells (46, 46null). The coated sheets (40) may have troughs (42) and crests (42), and be stacked (34) with intermediate parting sheets (48). Alternatively, the coated sheets (60, 62) may be notched (64) and interfitted in nulleggcratenull fashion. The honeycomb-shaped structure (12) is housed in a frame (50), and one or more stabilizer members (52) fastened to the frame serve to limit displacement of the structure as may be caused by the flowing fluid (14).

    Thermally stable catalysts for methane combustion
    19.
    发明申请
    Thermally stable catalysts for methane combustion 失效
    用于甲烷燃烧的热稳定催化剂

    公开(公告)号：US20030176278A1

    公开(公告)日：2003-09-18

    申请号：US10382132

    申请日：2003-03-05

    Inventor： David Wickham ,  Ronald Cook

    IPC: B01J021/04

    CPC classification number: C01G55/002 ,  B01J21/04 ,  B01J23/002 ,  B01J23/34 ,  B01J35/1009 ,  B01J37/30 ,  B01J2523/00 ,  C01F7/021 ,  C01F17/0025 ,  C01G45/006 ,  C01P2002/50 ,  C01P2006/13 ,  F23C13/08 ,  B01J2523/24 ,  B01J2523/3706 ,  B01J2523/72 ,  B01J2523/31 ,  B01J2523/824

    Abstract: The present invention provides metal-exchanged hexaaluminate catalysts that exhibit good catalytic activity and/or stability at high temperatures for extended periods with retention of activity as combustion catalysts, and more generally as oxidation catalysts, that make them eminently suitable for use in methane combustion, particularly for use in natural gas fired gas turbines. The hexaaluminate catalysts of this invention are of particular interest for methane combustion processes for minimization of the generation of undesired levels (less than about 10 ppm) of NOx species. Metal exchanged hexaaluminate oxidation catalysts are also useful for oxidation of volatile organic compounds (VOC), particularly hydrocarbons. Metal exchanged hexaaluminate oxidation catalysts are further useful for partial oxidation, particularly at high temperatures, of reduced species, particularly hydrocarbons (alkanes and alkenes).

    Abstract translation: 本发明提供了金属交换的六铝酸盐催化剂，其在高温下长时间显示出良好的催化活性和/或稳定性，同时保留作为燃烧催化剂的活性，更一般地，其作为氧化催化剂，使其非常适合用于甲烷燃烧， 特别适用于天然气燃气轮机。 本发明的六铝酸盐催化剂对于最小化NOx物质的不期望水平（小于约10ppm）的产生的甲烷燃烧过程是特别有意义的。 金属交换的六铝酸盐氧化催化剂也可用于挥发性有机化合物（VOC），特别是烃的氧化。 金属交换的六铝酸盐氧化催化剂还可用于部分氧化，特别是在高温下的还原物质，特别是烃（烷烃和烯烃）。

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