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    Process for the preparation of a catalyst useful for liquid-liquid sweetening LPG and light petroleum distillates
    11.
    发明授权
    Process for the preparation of a catalyst useful for liquid-liquid sweetening LPG and light petroleum distillates 有权
    制备可用于液 - 液增甜液化石油气和轻质石油馏分的催化剂的方法

    公开(公告)号：US06740619B1

    公开(公告)日：2004-05-25

    申请号：US09804994

    申请日：2001-03-13

    Applicant: Bir Sain ,  Som Nath Puri ,  Gautam Das ,  Bhagwati Prasad Balodi ,  Sunil Kumar ,  Anil Kumar ,  Virendra Kumar Kapoor ,  Virendra Kumar Bhatia ,  Turuga Sundara Rama Prasada Rao ,  Gur Pratap Rai

    Inventor： Bir Sain ,  Som Nath Puri ,  Gautam Das ,  Bhagwati Prasad Balodi ,  Sunil Kumar ,  Anil Kumar ,  Virendra Kumar Kapoor ,  Virendra Kumar Bhatia ,  Turuga Sundara Rama Prasada Rao ,  Gur Pratap Rai

    IPC: B01J3100

    CPC classification number: C10G27/10 ,  B01J31/183 ,  B01J2531/025 ,  B01J2531/56 ,  B01J2531/62 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07D487/22 ,  C09B47/26

    Abstract: The present invention relates to a process for the preparation of metal phthalocyanine sulphonamide [MPc(SO2NHR)x] catalyst useful for sweetening of LPG and light petroleum distillates which comprises reacting a metal phthalocyanine with chlorosulphonic acid at 90-150° C. for 1-5 hrs. cooling the reaction mixture adding 1-7 parts of a chloride reagent heating the said mixture at 60-80° C. from 0.5-3 hrs. to obtain the metal phthalocyanine sulphonyl chloride, isolating it by adding the reaction mixture in ice cold water, reacting the isolated metal phthalocyanine sulphonyl chloride with an amine of general formula H2NR where R is selected from hydrogen, aryl, alkyl and cycloalkyl in an aqueous or non-aqueous medium or a mixture thereof at a temperature in the range −4 to 15° C. and at a pH ranging between 7-9 in the presence of an acid binding agent to obtain the described metal phthalocyanine sulphonamide catalyst wherein the chloride reagent used is selected from the group consisting of thionyl chloride, phosphorus trichloride and phosphorus pentachloride, the binding agent used is selected from the group consisting of sodium bicarbonate, sodium carbonate, sodium hydroxide and tertiary organic bases selected from pyridine triethyl amine and piperidine and the catalyst metal phthalocyanine sulphonamide is selected from the group consisting of cobalt, manganese, nickel, iron vanadium phthalocyanine sulfonamide most preferably cobalt phthalocyanine sulphonamide.

    Abstract translation: 本发明涉及一种制备金属酞菁磺酰胺[MPc（SO2NHR）x]催化剂的方法，该催化剂可用于使LPG和轻质石油馏出物变甜，其包括使金属酞菁与氯磺酸在90-150℃下反应1- 5小时 冷却反应混合物，加入1-7份氯仿试剂，在60-80℃下加热所述混合物0.5-3小时。 以获得金属酞菁磺酰氯，通过将反应混合物加入冰冷的水中分离，将分离的金属酞菁磺酰氯与通式为H2NR的胺反应，其中R选自氢，芳基，烷基和环烷基，在水或 非水性介质或其混合物，在酸性粘合剂存在下，温度范围为-4至15℃，pH范围为7-9，得到所述金属酞菁磺酰胺催化剂，其中氯化试剂 所用的结合剂选自亚硫酰氯，三氯化磷和五氯化磷，所用粘合剂选自碳酸氢钠，碳酸钠，氢氧化钠和选自吡啶三乙胺和哌啶的叔有机碱，催化剂 金属酞菁磺胺选自钴，锰，镍，铁钒等 酞菁磺酰胺最优选钴酞菁磺酰胺。

    Magnesium dichloride-alcohol adducts
    13.
    发明授权
    Magnesium dichloride-alcohol adducts 有权
    二氯化镁 - 醇加合物

    公开(公告)号：US06686307B2

    公开(公告)日：2004-02-03

    申请号：US09993512

    申请日：2001-11-05

    Applicant: Mario Sacchetti ,  Gabriele Govoni ,  Anna Fait

    Inventor： Mario Sacchetti ,  Gabriele Govoni ,  Anna Fait

    IPC: B01J3100

    CPC classification number: B01J27/138 ,  B01J31/0201 ,  C08F10/00 ,  C08F110/06 ,  C08F4/6545 ,  C08F2500/18 ,  C08F2500/20 ,  C08F4/6543 ,  C08F4/022

    Abstract: The present invention relates to MgCl2.mROH.nH2O adducts, where R is a C1-C10 alkyl, 2≦m≦4.2, 0≦n≦0.7, characterized by an X-ray diffraction spectrum in which, in the range of 2&thgr; diffraction angles between 5° and 15°, the three main diffraction lines are present at diffraction angles 2&thgr; of 8.8±0.2°, 9.4±0.2° and 9.8±0.2°, the most intense diffraction lines being the one at 2&thgr;=8.8±0.2°, the intensity of the other two diffraction lines being at least 0.2 times the intensity of the most intense diffraction line. Catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity and stereospecificity with respect to the catalysts prepared from the adducts of the prior art.

    Abstract translation: 本发明涉及MgCl 2·mROH·nH 2 O加合物，其中R是C 1 -C 10烷基，2 <= m <= 4.2,0 <= n <0.7，其特征在于X射线衍射光谱，其中在 2θ衍射角在5°和15°之间的范围内，三条主要的衍射线分别以8.8±0.2°，9.4±0.2°和9.8±0.2°的衍射角2θ处存在，最强的衍射线为2θ= 8.8±0.2°，其他两条衍射线的强度是最强衍射线强度的0.2倍。由本发明的加合物得到的催化剂成分能够提供用于烯烃聚合的催化剂，其特征在于增强的 相对于由现有技术的加合物制备的催化剂的活性和立体定向性。

    Catalyst system and its use in a polymerization process
    16.
    发明授权
    Catalyst system and its use in a polymerization process 失效
    催化剂体系及其在聚合过程中的应用

    公开(公告)号：US06632770B2

    公开(公告)日：2003-10-14

    申请号：US09747821

    申请日：2000-12-22

    Applicant: Matthew W. Holtcamp

    Inventor： Matthew W. Holtcamp

    IPC: B01J3100

    CPC classification number: C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/65908 ,  C08F210/14

    Abstract: The invention provides new polymerization catalyst activator compositions including a non-coordinating or ionizing activator having a siloxane moiety. The invention also provides a new supported catalyst activator composition and method of making the composition. In one embodiment, the activator composition having a siloxane moiety represented by the formulae: [L—H]+[MQn]−O(SiR2O)x[MQn]−[L—H]+ or [L—H]+[MQn]−O(SiR2O)xR wherein L is an neutral Lewis base; [L—H]+ is a Bronsted acid or Lewis acid; n is 3 or 4; x is a positive integer; [MQn]− is a non-coordinating anion, wherein Q is independently selected from the group consisting of a hydride, a dialkylamido, a halide, an alkoxide, an aryloxide, a hydrocarbyl, a substituted hydrocarbyl, a halocarbyl, a substituted halocarbyl, a halosubstituted-hydrocarbyl radical and combinations thereof, M is an element selected from Group 13 of the Periodic Table of the Elements; and each R is independently selected from the group consisting of a hydrogen, a hydroxyl group, an alkyl, and combinations thereof.

    Abstract translation: 本发明提供新的聚合催化剂活化剂组合物，其包括具有硅氧烷部分的非配位或电离活化剂。 本发明还提供一种新的负载催化剂活化剂组合物和制备该组合物的方法。 在一个实施方案中，具有由下式表示的硅氧烷部分的活化剂组合物：其中L为中性路易斯碱;其中L为中性路易斯碱; [LH] HIL + PDAT>是布朗斯台德酸或路易斯酸; n是3或4; x是正整数; [MQ n ] < - 是非配位阴离子，其中Q独立地选自氢化物，二烷基酰氨基，卤化物，醇盐，芳氧基，烃基，取代的 烃基，卤代烃基，取代的卤代烃基，卤代烃基及其组合。元素选自元素周期表第13族元素; 每个R独立地选自氢，羟基，烷基和它们的组合。

    Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors
    18.
    发明授权
    Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors 有权
    由廉价和空气稳定的前体原位产生的高活性复分解催化剂

    公开(公告)号：US06610626B2

    公开(公告)日：2003-08-26

    申请号：US09948115

    申请日：2001-09-05

    Applicant: Robert H. Grubbs ,  Janis Louie ,  John P. Morgan ,  Jason L. Moore

    Inventor： Robert H. Grubbs ,  Janis Louie ,  John P. Morgan ,  Jason L. Moore

    IPC: B01J3100

    CPC classification number: B01J31/2295 ,  B01J23/462 ,  B01J23/466 ,  B01J31/2265 ,  B01J31/2273 ,  B01J2231/14 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07C6/04 ,  C07C6/06 ,  C07C2531/22 ,  C07F15/002 ,  C07F15/0046 ,  C08G61/06

    Abstract: The invention provides a process for the in-situ generation of a metathesis active catalyst of the formula: comprising contacting an NHC carbene with a dimer of the formula [(arene)MX1X]2 and an alkyne of the formula RC≡CR1 or wherein M is ruthenium or osmium; X and X1 are the same or different and are each independently an anionic ligand; NHC is any N-heterocyclic carbene ligand; R, R1 and R2 are each independently hydrogen or a substituted or unsubstituted substituent selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl; and R3 is OH. Preferably, the NHC is an s-IMES or IMES carbene ligand; the arene is preferably p-cymene and the alkyne is preferably acetylene. The invention further provides a process for ROMP and RCM reactions using the metathesis active catalysts.

    Abstract translation: 本发明提供了一种用于原位产生下式的复分解活性催化剂的方法：包括使NHC卡宾与式[（芳烃）MX1X] 2的二聚体和式RC = CR1或其中M是钌的咔啉接触 或锇; X和X 1相同或不同，各自独立地为阴离子配体; NHC为任何N-杂环卡宾配体; R 1，R 2和R 2各自独立地为氢或取代或未取代的取代基，所述取代基选自C1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，芳基，C 1 -C 20羧酸酯，C 1 -C 20烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，芳氧基，C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基， C20烷基磺酰基和C1-C20烷基亚磺酰基; 并且R 3是OH。优选地，NHC是s-IMES或IMES卡宾配体; 芳烃优选为对甲基异丙基苯并且炔优选为乙炔。 本发明还提供使用复分解活性催化剂的ROMP和RCM反应的方法。

    Polymerization catalysts, their production and use
    19.
    发明授权
    Polymerization catalysts, their production and use 失效
    聚合催化剂，其生产和使用

    公开(公告)号：US06608000B1

    公开(公告)日：2003-08-19

    申请号：US09661414

    申请日：2000-09-13

    Applicant: Robert Lee Bamberger ,  Moses Olukayode Jejelowo

    Inventor： Robert Lee Bamberger ,  Moses Olukayode Jejelowo

    IPC: B01J3100

    CPC classification number: C08L23/0815 ,  C08F4/63904 ,  C08F4/63908 ,  C08F4/63912 ,  C08F4/63916 ,  C08F4/6392 ,  C08F4/63922 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F210/16 ,  C08L2314/06 ,  Y10S526/901 ,  Y10S526/943 ,  C08F4/65925 ,  C08F210/08 ,  C08F2500/03 ,  C08F2500/11 ,  C08F2500/12 ,  C08F2500/06 ,  C08F2500/26 ,  C08F210/14 ,  C08F4/63925 ,  C08F2500/04 ,  C08F2500/17 ,  C08F2500/10

    Abstract: The invention generally relates to a metallocene-based, olefin polymerization catalyst system. The easily processible polymer product has a broad molecular weight distribution, a high molecular weight, and a narrow composition distribution. The catalyst system comprises a first component with a Group-4-6 metal bonded to cyclopentadienyl-containing rings having at least two substituents bonded to the rings in the same position; a second component comprising a Group-4-6 metal bonded to cyclopentadienyl-containing rings having at least two substituents bonded to the rings; and a third component comprising a Group-4-6 metal bonded to cyclopentadienyl-containing rings where one of the rings is substituted identically to the first component and another is substituted identically to the second component. When the substituents of the first and second components are the same, they are bonded to the first component rings at positions different from the bonding positions of the second component rings.

    Abstract translation: 本发明一般涉及基于金属茂的烯烃聚合催化剂体系。 容易加工的聚合物产物具有宽的分子量分布，高分子量和窄的组成分布。 该催化剂体系包括具有4-6族金属的第一组分与具有至少两个与相同位置的环结合的取代基的含环戊二烯基的环键合; 第二组分包含键合至含环戊二烯基的环的4-6族金属，所述环具有至少两个与所述环结合的取代基; 以及包含与含环戊二烯基的环键合的4-6族金属的第三组分，其中一个环与第一组分相同地取代，另一个与第二组分相同地被取代。 当第一和第二组分的取代基相同时，它们在与第二组分环的键合位置不同的位置处与第一组分环结合。

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