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    Treatment to improve the durability of a hydrodechlorination catalyst and catalyst
    11.
    发明授权
    Treatment to improve the durability of a hydrodechlorination catalyst and catalyst 失效
    处理以提高加氢脱氯催化剂和催化剂的耐久性

    公开(公告)号：US5721189A

    公开(公告)日：1998-02-24

    申请号：US755759

    申请日：1996-11-21

    申请人： Zongchao Zhang

    发明人： Zongchao Zhang

    IPC分类号： B01J23/58 ,  B01J27/13 ,  B01J37/22 ,  B01J37/24 ,  C07C17/23 ,  C07C1/00

    CPC分类号： C07C17/23 ,  B01J23/58 ,  B01J27/13 ,  B01J37/22 ,  B01J37/24 ,  Y10S502/503 ,  Y10S502/504

    摘要： The durability of a supported noble metal hydrodechlorination catalyst can be improved by (1) treating the supported catalyst, which comprises support and catalytic noble metal, with a non-elemental halide compound, which is not a mineral acid (such as an alkali metal halide, an ammonium halide, an alkaline earth metal halide, and/or a halogenated hydrocarbon); and (2) then using the treated catalyst in a hydrodechlorination reaction. Suitable treatment compounds include ammonium chloride, lithium chloride, or a chlorinated hydrocarbon. The treated catalyst is a novel composition of matter comprising at least one platinum group metal supported by an oxidic support wherein the metal, which is in the zero valent state, predominantly resides adjacent the surface of the support and is predominantly visible under a microscope having a resolution of about 5 .ANG..

    摘要翻译： 负载型贵金属加氢脱氯催化剂的耐久性可以通过（1）用不含无机酸（例如碱金属卤化物）的非元素卤化物处理负载催化剂（包括载体和催化剂贵金属）来改善 ，卤化铵，碱土金属卤化物和/或卤代烃）; 和（2）然后在加氢脱氯反应中使用经处理的催化剂。 合适的处理化合物包括氯化铵，氯化锂或氯化烃。 经处理的催化剂是包含至少一种由氧化载体负载的铂族金属的新物质组合物，其中处于零价态的金属主要位于载体表面附近，并且主要在具有 分辨率约5 ANGSTROM。

    Method for producing hydrogen peroxide
    14.
    发明授权
    Method for producing hydrogen peroxide 失效
    生产过氧化氢的方法

    公开(公告)号：US5180573A

    公开(公告)日：1993-01-19

    申请号：US811035

    申请日：1991-12-20

    申请人： Yasushi Hiramatsu ,  Yukio Ishiuchi ,  Hiromitsu Nagashima

    发明人： Yasushi Hiramatsu ,  Yukio Ishiuchi ,  Hiromitsu Nagashima

    IPC分类号： B01J31/28 ,  B01J23/40 ,  B01J31/08 ,  B01J37/22 ,  C01B15/029

    CPC分类号： B01J37/22 ,  B01J23/40 ,  B01J31/08 ,  C01B15/029

    摘要： This invention provides a method for high efficiency, high concentration production of hydrogen peroxide wherein oxygen and hydrogen are reacted in the reaction medium in the presence of a catalyst comprising a metallic or carrier supported platinum group metal catalyst onto which an organic halogen compound which is insoluble in water, which compound excludes compounds which contain no halogen other than fluorine, has been adsorbed or a platinum group metal catalyst supported on a carrier in which a halogenated organic compound, which compound excludes compounds that contain no halogen other than fluorine, has been adsorbed to the carrier prior to supporting the platinum group metal. Since it is not necessary for halogen ions to be present in the reaction medium as it was in the prior art, the problems of deterioration due to the dissolution of the catalyst and of corrosion of the structural materials of the reaction vessel are alleviated.

    Regeneration of noble metal catalysts used in hydrodehalogenation of halogen-substituted hydrocarbons containing fluorine and at least one other halogen
    16.
    发明授权
    Regeneration of noble metal catalysts used in hydrodehalogenation of halogen-substituted hydrocarbons containing fluorine and at least one other halogen 失效
    在含有氟化物和至少一种其他卤素的氢取代的烃类的氢化反应中使用的贵金属催化剂的再生

    公开(公告)号：US5057470A

    公开(公告)日：1991-10-15

    申请号：US526720

    申请日：1990-05-22

    申请人： Carl S. Kellner

    发明人： Carl S. Kellner

    IPC分类号： B01J23/40 ,  B01J23/96 ,  B01J27/28 ,  B01J27/32 ,  B01J37/22 ,  B01J38/42 ,  C07B61/00 ,  C07C17/00 ,  C07C17/23 ,  C07C19/08 ,  C07C51/377

    CPC分类号： C07C51/377 ,  B01J23/96 ,  B01J27/32 ,  B01J38/42 ,  C07C17/23 ,  Y02P20/584

    摘要： A process is disclosed for the treatment of a new or deactivated supported metal catalyst containing noble metal to prepare said catalyst for use in the hydrodehalogenation of a compound having the formula C.sub.n H.sub.m F.sub.p X.sub.q, where each X is independently selected from Cl and Br, wherein n is an integer from 1 to 6, m is an integer from 0 to 12, p is an integer from 1 to 13, and q is an integer from 1 to 13, and wherein m+p+q equals 2n+2 for saturated compounds which are acyclic, m+p+q equals 2n for saturated compounds which are cyclic and for olefinic compounds which are acyclic, and m+p+q equals 2n-2 for olefinic compounds which are cyclic, comprising the step of contacting said catalyst with an atmosphere comprising chlorine gas at a temperature from about 100.degree. C. to 400.degree. C. for a time sufficient to improve the catalytic activity thereof for said hydrodehalogenation. A process is also disclosed for catalytic hydrodehalogenation characterized by using a supported metal catalyst containing noble metal which has been so contacted with an atmosphere comprising chlorine.

    摘要翻译： 公开了一种用于处理含有贵金属的新的或失活的负载金属催化剂以制备用于具有式C n H m F p X q的化合物的加氢脱卤的所述催化剂的方法，其中每个X独立地选自Cl和Br，其中n为 1〜6的整数，m为0〜12的整数，p为1〜13的整数，q为1〜13的整数，m + p + q等于2n + 2，饱和化合物为 对环状的饱和化合物和环状的烯属化合物，m + p + q等于2n，对于环状烯烃化合物，m + p + q等于2n-2，包括使所述催化剂与气氛接触的步骤 包括在约100℃至400℃的温度下的氯气持续足以改善其对所述加氢脱卤的催化活性的时间。 还公开了一种用于催化加氢脱卤的方法，其特征在于使用含有贵金属的负载金属催化剂，其已经与包含氯的气氛接触。

    Virgin catalyst treatment
    17.
    发明授权
    Virgin catalyst treatment 失效
    维生素催化剂处理

    公开(公告)号：US4806512A

    公开(公告)日：1989-02-21

    申请号：US50875

    申请日：1987-05-18

    申请人： Frank J. Elvin

    发明人： Frank J. Elvin

    IPC分类号： B01J37/06 ,  B01J37/22 ,  C10G11/05 ,  B01J29/06 ,  B01J37/28

    CPC分类号： B01J37/06 ,  B01J37/22 ,  C10G11/05

    摘要： A process for treating a virgin catalyst useful to promote hydrocarbon conversion, e.g., cracking at hydrocarbon conversion, e.g., cracking, conditions comprising:(a) contacting the virgin catalyst with a liquid reductive wash medium; and(b) contacting the reductively washed virgin catalyst with a liquid oxidative wash medium, thereby producing a washed virgin catalyst with at least one improved catalytic property.

    摘要翻译： 一种处理可用于促进烃转化的原始催化剂的方法，例如在烃转化，例如裂化的条件下开裂，包括：（a）使原始催化剂与液体还原洗涤介质接触; 和（b）将还原性洗涤的原始催化剂与液体氧化洗涤介质接触，从而产生具有至少一种改进的催化性能的洗涤的原始催化剂。

    Regeneration method for gravity-flowing deactivated catalyst particles
    18.
    发明授权
    Regeneration method for gravity-flowing deactivated catalyst particles 失效
    重力流失活催化剂颗粒的再生方法

    公开(公告)号：US4094817A

    公开(公告)日：1978-06-13

    申请号：US806886

    申请日：1977-06-15

    申请人： Robert K. Olson ,  Lester F. Smith

    发明人： Robert K. Olson ,  Lester F. Smith

    IPC分类号： B01J23/94 ,  B01J23/96 ,  B01J37/22 ,  C10G35/12 ,  B01J21/20 ,  C10G35/08

    CPC分类号： B01J8/12 ,  B01J23/94 ,  B01J23/96 ,  B01J37/22 ,  C10G35/12

    摘要： A continuous method for regenerating deactivated catalyst particles in a regeneration zone through which the particles are downwardly movable by way of gravity-flow. Particles are initially introduced into an upper carbon-burning/halogenation section wherein they are contacted by a first air stream and a halogen, or halogen-containing compound. Therefrom, the catalyst particles flow into a lower drying section, wherein they are contacted with a dry second air stream.

    摘要翻译： 用于在再生区再生失活的催化剂颗粒的连续方法，通过该再生区域，颗粒可以通过重力流向下移动。 颗粒最初被引入上碳燃烧/卤化部分，其中它们与第一气流和卤素或含卤素的化合物接触。 由此，催化剂颗粒流入下部干燥部分，其中它们与干燥的第二气流接触。

    Hydrocracking of hydrocarbons over tri-metallic catalyst
    20.
    发明授权
    Hydrocracking of hydrocarbons over tri-metallic catalyst 失效
    碳氢化合物在三金属催化剂上的加氢裂化

    公开(公告)号：US4070270A

    公开(公告)日：1978-01-24

    申请号：US776041

    申请日：1977-03-09

    申请人： Richard E. Rausch

    发明人： Richard E. Rausch

    IPC分类号： B01J21/12 ,  B01J23/62 ,  B01J29/12 ,  B01J37/22 ,  C10G35/09 ,  C10G45/10 ,  C10G45/40 ,  C10G47/14 ,  C10G49/06 ,  C10G13/06 ,  B01J27/06

    CPC分类号： C10G49/06 ,  B01J21/12 ,  B01J23/626 ,  B01J29/12 ,  B01J37/22 ,  C10G35/09 ,  C10G45/10 ,  C10G45/40 ,  C10G47/14 ,  C10G2400/08 ,  Y10S585/94

    摘要： A process for hydrotreating (hydroprocessing) hydrocarbons and mixtures of hydrocarbons utilizing a catalytic composite of a porous carrier material, a platinum or palladium component, a rhodium component and a tin component, in which process there is effected a chemical consumption of hydrogen. A specific example of one such catalyst is a composite of a crystalline aluminosilicate, a platinum component, a rhodium component and a tin component, for utilization in a hydrocracking process. Other hydrocarbon hydroprocesses are directed toward the hydrogenation of aromatic nuclei, the ring-opening of cyclic hydrocarbons, desulfurization, denitrification, hydrogenation, etc.

    摘要翻译： 利用多孔载体材料，铂或钯组分，铑组分和锡组分的催化复合物对碳氢化合物和烃混合物进行加氢处理（加氢处理）的方法，其中进行氢的化学消耗。 一种这样的催化剂的具体实例是结晶硅铝酸盐，铂组分，铑组分和锡组分的复合物，用于加氢裂化过程。 其他烃类加氢工艺涉及芳烃氢化，环状烃开环，脱硫，脱氮，氢化等。