公开(公告)号：US09505674B2

公开(公告)日：2016-11-29

申请号：US14647728

申请日：2013-11-08

申请人： ExxonMobil Chemical Patents Inc.

发明人： Paul Hamilton

IPC分类号： C07C2/02 ,  C08F210/00 ,  C07C2/08 ,  C10G3/00 ,  C07C7/10

CPC分类号： C07C2/08 ,  C07C7/10 ,  C10G3/00 ,  Y02P30/20 ,  C07C11/02 ,  C07C11/06

摘要： Embodiments disclosed herein relate to a process for the oligomerization of olefins, the process including at least one olefin feedstream that includes ammonia and contacting the at least one olefin feedstream with a liquid including alkaline water to remove at least a portion of the ammonia to produce at least one treated olefin feedstream and subsequently contacting the at least one treated olefin feedstream with a catalyst under oligomerization conditions to produce an oligomer product. In several embodiments disclosed herein, the at least one olefin feedstream includes one or more C3-C15 olefins, preferably, C3-C5 olefins, any isomer thereof, one or more paraffins having the same or different carbon number as the olefins, and mixtures thereof.

摘要翻译： 本文公开的实施方案涉及烯烃低聚的方法，所述方法包括至少一种包含氨的烯烃进料流，并使至少一种烯烃进料流与包含碱性水的液体接触以除去至少一部分氨以在 至少一种经处理的烯烃进料流，随后在低聚条件下使至少一种经处理的烯烃进料流与催化剂接触以产生低聚物产物。 在本文公开的几个实施方案中，至少一种烯烃进料流包括一种或多种C 3 -C 15烯烃，优选C 3 -C 5烯烃，其任何异构体，一种或多种具有与烯烃相同或不同碳数的链烷烃，及其混合物 。

公开(公告)号：US09481745B2

公开(公告)日：2016-11-01

申请号：US14917549

申请日：2014-09-08

申请人： BASELL POLIOLEFINE ITALIA S.R.L.

发明人： Alessandro Mignogna ,  Reynald Chevalier ,  Giampiero Morini ,  Martin Schneider

IPC分类号： C08F4/00 ,  C08F4/52 ,  C08F210/00 ,  C07C205/00 ,  C08F110/06 ,  C07C271/12

CPC分类号： C08F110/06 ,  C07C271/12 ,  C08F4/651 ,  C08F2500/12

摘要： The present technology relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the general formula (I): where R1 is selected from C1-C15 hydrocarbon groups, the R2 groups are equal to or different from each other, are hydrogen, or the R1 groups can be fused together to form one or more cycles and A is a bivalent bridging group. The catalyst components of the present disclosure exhibit high activity and stereospecificity in the polymerization of olefins.

公开(公告)号：US09428595B2

公开(公告)日：2016-08-30

申请号：US14127802

申请日：2012-06-21

申请人： Sean W. Ewart ,  Teresa P. Karjala ,  Sarat Munjal ,  Mehmet Demirors

发明人： Sean W. Ewart ,  Teresa P. Karjala ,  Sarat Munjal ,  Mehmet Demirors

IPC分类号： C08F4/44 ,  C08F2/00 ,  C08F4/12 ,  C08F210/00 ,  C08F4/52 ,  C08F10/02 ,  C08F4/38

CPC分类号： C08F4/52 ,  C08F4/38 ,  C08F10/02 ,  C08F210/16 ,  C08L23/04 ,  C08F2/38 ,  C08F4/34 ,  C08L23/14 ,  C08L23/08 ,  C08F210/06 ,  C08F2500/08 ,  C08F2500/12 ,  C08F4/54

摘要： The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene in the presence of at least one free-radical agent, and in the presence of a “metal alkyl-containing compound” selected from the group consisting of the following: i) at least one “Group II metal alkyl-containing compound,” ii) at least one “Group III metal alkyl-containing compound,” or iii) a combination of i) and ii). The invention also provides a composition comprising at least one ethylene-based polymer, prepared from a free-radical polymerization, and wherein the ethylene-based polymer has the following property: y>0.28567x−0.00032, wherein y=vinyl/1000C, as determined by 1H NMR, and x=mol % polymerized α-olefin, as determined by 13C NMR.

摘要翻译： 本发明提供一种形成乙烯基聚合物的方法，所述方法包括在至少一种自由基试剂存在下使乙烯聚合，并在“含金属烷基化合物”存在下，选自 以下：i）至少一种“II族金属烷基化合物”，ii）至少一种“III族金属烷基化合物”，或iii）i）和ii）的组合。 本发明还提供一种包含至少一种由自由基聚合制备的乙烯基聚合物的组合物，其中乙烯类聚合物具有以下性质：y> 0.28567x-0.00032，其中y =乙烯基/ 1000℃，为 通过1 H NMR测定，x =聚合的α-烯烃的摩尔％，通过13 C NMR测定。

公开(公告)号：US09371404B2

公开(公告)日：2016-06-21

申请号：US14614631

申请日：2015-02-05

申请人： Ineos USA, LLC

发明人： Gregory Dudish ,  Ernest Chan

IPC分类号： B01J19/00 ,  C08F2/00 ,  C08F210/00 ,  C08F2/01 ,  C08F110/06 ,  C08F2/34 ,  B01J19/24

CPC分类号： C08F2/01 ,  B01J19/0006 ,  B01J19/0033 ,  B01J19/24 ,  B01J2219/00069 ,  B01J2219/00164 ,  B01J2219/00186 ,  B01J2219/002 ,  B01J2219/00218 ,  B01J2219/00231 ,  B01J2219/24 ,  C08F2/34 ,  C08F110/06

摘要： A gas-phase polyolefin reactor system for rapidly transitioning from one polyolefin product to another is disclosed. The reactor system comprises a control valve, a high-flow valve, a polyolefin reactor, a flow meter, a totalizer and an empirical model. During a transition, the empirical model predicts a required amount based upon an initial concentration and a selected ending concentration, the flow meter measures a flow rate, the totalizer determines a totalized amount when the flow rate of the first stream reaches the required amount based upon the measured flow rate and outputs the totalized amount to the empirical model, and the empirical model compares the required amount to the totalized amount and determines a transition endpoint. A method of rapidly transitioning the reactor system from one polyolefin product to another is also disclosed.

公开(公告)号：US09308514B2

公开(公告)日：2016-04-12

申请号：US14543369

申请日：2014-11-17

申请人： TOTAL RESEARCH & TECHNOLOGY FELUY

发明人： Frank Timmermans ,  Wouter Ooms ,  Daan Dewachter ,  Louis Fouarge

IPC分类号： C08F2/00 ,  C08F210/00 ,  B63H1/26 ,  F03B3/12 ,  B01J19/18 ,  C08F10/02 ,  C08F110/02 ,  F04D3/00 ,  F04D29/18

CPC分类号： B01J19/1875 ,  B01J19/1837 ,  C08F10/02 ,  C08F110/02 ,  F04D3/00 ,  F04D29/181 ,  C08F2/14 ,  C08F2/01 ,  C08F2500/05 ,  C08F2500/24

摘要： The present invention relates the use of a pump in a loop reactor for the production of polyethylene, as well as a reactor comprising such pump and methods for producing polyolefin by means of such reactor. The pump according to the invention is characterized in that it is an axial flow impeller circulation pump, wherein the impeller comprises 6 blades and wherein the pump is fixed on a spring supported frame. Use of the pump according to the present invention allows for preparation of homogeneous polyethylene products that meet high quality standards from the complicated ethylene polymerization mixtures while at the same time being produced with low energy consumption.

公开(公告)号：US09243136B2

公开(公告)日：2016-01-26

申请号：US13509256

申请日：2010-11-03

申请人： Ulf Nilsson ,  Annika Smedberg ,  Alfred Campus

发明人： Ulf Nilsson ,  Annika Smedberg ,  Alfred Campus

IPC分类号： B05D5/12 ,  C08F210/00 ,  C08F110/02 ,  C08L23/06 ,  C08F6/00 ,  C08F210/02 ,  H01B3/44 ,  C08K3/04 ,  C08K5/00 ,  C08K5/01 ,  C08K5/14

摘要： A cable comprising a semiconductive layer and an insulation layer with improved DC electrical properties is provided.

公开(公告)号：US09212277B2

公开(公告)日：2015-12-15

申请号：US13509256

申请日：2010-11-03

申请人： Ulf Nilsson ,  Annika Smedberg ,  Alfred Campus

发明人： Ulf Nilsson ,  Annika Smedberg ,  Alfred Campus

IPC分类号： B05D5/12 ,  C08F210/00 ,  C08F110/02 ,  C08L23/06 ,  C08F6/00 ,  C08F210/02 ,  H01B3/44 ,  C08K3/04 ,  C08K5/00 ,  C08K5/01 ,  C08K5/14

摘要： A cable comprising a semiconductive layer and an insulation layer with improved DC electrical properties is provided.

公开(公告)号：US09138713B2

公开(公告)日：2015-09-22

申请号：US14310546

申请日：2014-06-20

申请人： ExxonMobil Chemical Patents Inc.

发明人： Yu Feng Wang

IPC分类号： B01J19/18 ,  C08F210/00 ,  B01J19/00 ,  C08F210/06

CPC分类号： B01J19/0053 ,  C08F210/06 ,  C08F10/00 ,  C08F2/001 ,  C08F2/06 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/17 ,  C08F210/08 ,  C08F210/18 ,  C08F236/20 ,  C08F2500/25

摘要： The present invention relates to a process of forming a polymer, the process comprising polymerizing olefin monomers to form a reaction mixture, treating the reaction mixture to form a first polymer-rich phase, treating the first polymer-rich phase to form a second polymer-rich phase, and devolatilizing the second polymer-rich phase, the process further comprising at least one step of adjusting the temperature of a first and/or the second polymer-rich phase before the devolatilization. The present invention also relates to a plant that is useful for the process provided above.

摘要翻译： 本发明涉及形成聚合物的方法，该方法包括聚合烯烃单体以形成反应混合物，处理该反应混合物以形成第一富聚合物相，处理第一富聚合物相以形成第二聚合物 - 富分相，以及使第二富聚合物相脱挥发分，该方法还包括在脱挥发分之前调节第一和/或第二富聚合物相的温度的至少一个步骤。 本发明还涉及一种可用于上述方法的植物。

公开(公告)号：US09126878B1

公开(公告)日：2015-09-08

申请号：US14449443

申请日：2014-08-01

申请人： Chevron Phillips Chemical Company LP

发明人： Lei Ji ,  Ai-Fu Chang

IPC分类号： C08F2/00 ,  C08F210/00 ,  C07C7/13 ,  B01D53/04 ,  C07C7/00 ,  C08F110/02

CPC分类号： B01D53/0462 ,  B01D53/0407 ,  B01D2253/102 ,  B01D2253/108 ,  B01D2253/116 ,  B01D2253/204 ,  B01D2256/24 ,  B01D2257/7022 ,  B01D2259/40043 ,  B01J8/085 ,  B01J8/087 ,  B01J19/00 ,  B01J2208/00212 ,  B01J2208/00274 ,  B01J2219/0004 ,  B01J2219/00837 ,  B01J2219/00842 ,  C07C7/12 ,  C07C7/13 ,  C08F110/02 ,  Y02P20/582 ,  C08F10/02 ,  C08F2/01 ,  C08F210/16 ,  C08F210/14 ,  C08F2/14 ,  C07C11/04

摘要： A process for component separation in a polymer production system, comprising (a) separating a polymerization product stream into a gas stream and a polymer stream, (b) contacting the polymer stream with a purge gas to yield a purged polymer and a spent purge gas comprising purge gas, ethylene, and ethane, (c) contacting the spent purge gas with a temperature swing adsorber contactor (TSAC) to yield a loaded TSAC, wherein at least a portion of the ethylene is adsorbed by the TSAC at a first temperature to yield TSAC-adsorbed ethylene, wherein a portion of the ethane is adsorbed by the TSAC at the first temperature to yield TSAC-adsorbed ethane, (d) heating the loaded TSAC to a second temperature to yield a regenerated TSAC, and (e) contacting the regenerated TSAC with a sweeping gas stream to yield a recovered adsorbed gas stream comprising sweeping gas, recovered ethylene and recovered ethane.

摘要翻译： 一种聚合物生产系统中组分分离的方法，包括（a）将聚合产物流分离成气流和聚合物流，（b）使聚合物流与净化气体接触以产生吹扫的聚合物和废净化气体 包括吹扫气体，乙烯和乙烷，（c）将废净化气体与变温吸附器接触器（TSAC）接触以产生负载的TSAC，其中至少一部分乙烯在第一温度下被TSAC吸附至 产生TSAC吸附的乙烯，其中一部分乙烷在第一温度下被TSAC吸附以产生TSAC吸附的乙烷，（d）将负载的TSAC加热至第二温度以产生再生的TSAC，和（e）接触 再生的具有清扫气流的TSAC以产生包含扫气，回收的乙烯和回收的乙烷的回收的吸附气流。

公开(公告)号：US09114374B2

公开(公告)日：2015-08-25

申请号：US14377273

申请日：2013-02-28

申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

发明人： Masakazu Sumida ,  Kazuhiro Yamazaki

IPC分类号： B01J10/00 ,  C08F2/00 ,  C08F210/00 ,  B01J19/18 ,  C08F2/01 ,  B01J19/00 ,  C08F120/10

CPC分类号： B01J19/1862 ,  B01J19/0013 ,  B01J19/0046 ,  B01J2219/00006 ,  B01J2219/00033 ,  B01J2219/0004 ,  B01J2219/0006 ,  B01J2219/00063 ,  B01J2219/00085 ,  B01J2219/00094 ,  B01J2219/002 ,  B01J2219/00204 ,  B01J2219/00231 ,  B01J2219/00736 ,  C08F2/01 ,  C08F120/10 ,  Y02P20/582

摘要： Continuous polymerization apparatus including a first reactor of a complete mixing type and a second reactor of a complete mixing type (10, 20). Each of the reactors (10, 20) is provided with a supply port (11a, 21a), an effluent port (11b, 21b), and a temperature detecting means (T) for detecting a temperature in the reactor, wherein the supply port (11a) of the first reactor (10) is connected to the supply sources (1, 3) of a raw material monomer and a polymerization initiator, and the effluent port (11b) of the first reactor is connected through a connection line (15) to the supply port (21a) of the second reactor (20). Connection line (15) is combined with a secondary line (15′) for supplying a raw material monomer at a combining part (M) located between the effluent port (11b) of the first reactor (10) and the supply port (21a) of the second reactor (20).

摘要翻译： 连续聚合装置包括完全混合型的第一反应器和完全混合型的第二反应器（10,20）。 每个反应器（10,20）设置有用于检测反应器中的温度的供应口（11a，21a），流出口（11b，21b）和温度检测装置（T），其中供给口 第一反应器（10）的出口（11a）与原料单体和聚合引发剂的供给源（1,3）连接，第一反应器的流出口（11b）通过连接管线 ）到第二反应器（20）的供给口（21a）。 连接管线（15）与位于第一反应器（10）的排出口（11b）和供给口（21a）之间的组合部分（M）处供给原料单体的二次管线（15'）组合， 的第二反应器（20）。