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    Method for obtaining coating compositions having reduced VOC
    202.
    发明授权
    Method for obtaining coating compositions having reduced VOC 有权
    获得具有降低的VOC的涂料组合物的方法

    公开(公告)号：US07321013B2

    公开(公告)日：2008-01-22

    申请号：US10866596

    申请日：2004-06-11

    Applicant: Walter H. Ohrbom ,  Marvin L. Green ,  Gregory G. Menovcik

    Inventor： Walter H. Ohrbom ,  Marvin L. Green ,  Gregory G. Menovcik

    IPC: C08L67/00 ,  C08G18/00

    CPC classification number: C09D201/02 ,  C08F8/00 ,  C08F2800/20 ,  C08G18/4072 ,  C08G18/4233 ,  C08G18/6229 ,  C08G18/6254 ,  C08G18/672 ,  C08G18/8175 ,  C08G2190/00 ,  C09D5/02 ,  C09D133/14 ,  C09D167/00 ,  C09D175/04 ,  C09D201/00 ,  C09D201/025 ,  C08F220/20

    Abstract: Disclosed is a method of making reduced VOC polymers and coating compositions containing such polymers. Provided is a mixture (I) comprising a reactant mixture (a) of polymerizable components and a nonvolatile solvent (bnv) that (i) is not a crystalline solid at 25° C., (ii) is nonvolatile, (iii) comprises at least one functional group (F1) and (iv) is a fluid solid. Reactant mixture (a) is polymerized to provide a polymer (a′). The at least one functional group (F1) of nonvolatile solvent (bnv) is reacted with one or more reactants (e) to obtain a nonvolatile solvent (b′nv) comprising at least two functional groups (F2). Obtained is a mixture (II) comprising polymer (a′) in nonvolatile solvent (b′nv) comprising at least two functional groups (F2). The at least one functional group (F1) is substantially nonreactive: (1) with the components of reactive mixture (a), (2) under the polymerization conditions which polymerize reactant mixture (a), and (3) with polymer (a′).

    Abstract translation: 公开了一种制备含有这种聚合物的VOC聚合物和涂料组合物的方法。 提供了包含可聚合组分的反应物混合物（a）和不挥发性溶剂（b）的混合物（I），（i）在25℃下不是结晶固体，（ii） 是非挥发性的，（iii）包含至少一个官能团（F 1 H 1）和（iv）是流体固体。 将反应物混合物（a）聚合以提供聚合物（a'）。 非挥发性溶剂（b）的至少一个官能团（F 1 N 1）与一种或多种反应物（e）反应，得到非挥发性溶剂（b' 包括至少两个官能团（F 2 N 2）。 获得的包含聚合物（a'）在包含至少两个官能团（F 2 N 2）的非挥发性溶剂（b'Nv））中的混合物（II）。 至少一个官能团（F 1 H 1）基本上是非反应性的：（1）在聚合反应混合物（a）的聚合条件下与反应混合物（a），（2）的组分反应，和 （3）与聚合物（a'）。

    Method of providing cured coating films free of popping defects
    203.
    发明授权
    Method of providing cured coating films free of popping defects 有权
    提供没有突出缺陷的固化涂膜的方法

    公开(公告)号：US07205029B2

    公开(公告)日：2007-04-17

    申请号：US10261888

    申请日：2002-09-30

    Applicant: Walter H. Ohrbom ,  Sergio E. Balatan ,  David J. Law ,  Robert D. Weise

    Inventor： Walter H. Ohrbom ,  Sergio E. Balatan ,  David J. Law ,  Robert D. Weise

    IPC: B05D3/00

    CPC classification number: C09D201/00 ,  C08F212/14 ,  C08K5/205 ,  C09D5/002 ,  C09D5/033 ,  C09D7/63 ,  C09D133/08 ,  C09D201/02 ,  C08L2666/28 ,  C08L2666/36

    Abstract: A method for providing cured coating films free of popping defects. The method requires the application to a substrate of at least 2.0 mils/50.8 microns of a uncured curable coating composition comprising an anti-popping component (a), a film-forming component (b), and a crosslinking component (c), wherein anti-popping component (a) has from 12 to 72 carbon atoms, is substantially free of any heteroatoms, is not a crystalline solid at room temperature and comprises a mixture of two or more structures selected from the group consisting of aliphatic structures for anti-popping component (a), aromatic-containing structures for anti-popping component (a), cycloaliphatic-containing structures for anti-popping component (a), and mixtures thereof, at least one of the two or more structures being a cycloaliphatic-containing structure or an aromatic-containing structure. The coated uncured substrate is cured to provide a cured film free of popping defects with an average film build of at least 2.0 mils/50.8 microns.

    Abstract translation: 提供没有突出缺陷的固化涂膜的方法。 该方法需要施用至少2.0密耳/ 50.8微米的包含抗爆组分（a），成膜组分（b）和交联组分（c）的未固化的可固化涂料组合物的基材，其中 抗突起组分（a）具有12至72个碳原子，基本上不含任何杂原子，在室温下不是结晶固体，并且包含两种或更多种选自以下的结构的混合物：脂肪族结构， 弹性组分（a），用于抗爆组分（a）的含芳族化合物的结构，用于抗爆组分（a）的含脂环族的结构及其混合物，所述两种或多种结构中的至少一种是含脂环族的 结构或含芳族结构。 固化涂覆的未固化基底以提供没有突出缺陷的固化膜，其平均膜构成为至少2.0密耳/ 50.8微米。

    Method for polymeric surface modification
    206.
    发明申请
    Method for polymeric surface modification 审中-公开
    聚合物表面改性方法

    公开(公告)号：US20060088716A1

    公开(公告)日：2006-04-27

    申请号：US11289422

    申请日：2005-11-30

    Applicant: Kenneth Wynne

    Inventor： Kenneth Wynne

    IPC: B32B27/40

    CPC classification number: C08J3/005 ,  C08G18/3218 ,  C08G18/4854 ,  C08G18/6674 ,  C08G18/833 ,  C08J2375/04 ,  C09D201/02 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/3158 ,  Y10T428/31583 ,  A01N25/10 ,  A01N43/50 ,  A01N35/02 ,  A01N33/12 ,  C08L2666/14

    Abstract: Polymers, and particularly conventional commodity bulk polymers, are modified to have a surface activity of interest using a surface modifying polymer that includes a moiety that favors migration to the surface of the bulk polymer together with a moiety provides the activity of interest (e.g., biocidal, wettability modifying (hydrophobic or hydrophilic), resistance to radiant energy, providing a functional group for functionalizing the surface, etc.). The surface modifying polymer is combined with the bulk polymer, and, due to the presence of the moiety that favors migration, concentrates primarily on the surface of the bulk polymer such that the moiety that provides the activity of interest is located primarily on the surface of the bulk polymeric article which is produced.

    Abstract translation: 使用表面改性聚合物改性聚合物，特别是常规的商品本体聚合物以具有感兴趣的表面活性，所述表面改性聚合物包括有利于与本体聚合物的表面迁移的部分以及部分提供感兴趣的活性（例如，杀生物剂 ，润湿性改性（疏水性或亲水性），耐辐射能，提供功能性表面官能团等）。 表面改性聚合物与本体聚合物组合，并且由于存在有利于迁移的部分，主要集中在本体聚合物的表面上，使得提供感兴趣的活性的部分主要位于 生产的散装聚合物制品。

    Method for polymeric surface modification
    207.
    发明申请
    Method for polymeric surface modification 失效
    聚合物表面改性方法

    公开(公告)号：US20050084683A1

    公开(公告)日：2005-04-21

    申请号：US10882238

    申请日：2004-07-02

    Applicant: Kenneth Wynne

    Inventor： Kenneth Wynne

    IPC: B05D1/36 ,  B32B27/40 ,  C08L20060101

    CPC classification number: C08J3/005 ,  C08G18/3218 ,  C08G18/4854 ,  C08G18/6674 ,  C08G18/833 ,  C08J2375/04 ,  C09D201/02 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/3158 ,  Y10T428/31583 ,  A01N25/10 ,  A01N43/50 ,  A01N35/02 ,  A01N33/12 ,  C08L2666/14

    Abstract: Polymers, and particularly conventional commodity bulk polymers, are modified to have a surface activity of interest using a surface modifying polymer that includes a moiety that favors migration to the surface of the bulk polymer together with a moiety provides the activity of interest (e.g., biocidal, wettability modifying (hydrophobic or hydrophilic), resistance to radiant energy, providing a functional group for functionalizing the surface, etc.). The surface modifying polymer is combined with the bulk polymer, and, due to the presence of the moiety that favors migration, concentrates primarily on the surface of the bulk polymer such that the moiety that provides the activity of interest is located primarily on the surface of the bulk polymeric article which is produced.

    Abstract translation: 使用表面改性聚合物改性聚合物，特别是常规的商品本体聚合物以具有感兴趣的表面活性，所述表面改性聚合物包括有利于与本体聚合物的表面迁移的部分以及部分提供感兴趣的活性（例如，杀生物剂 ，润湿性改性（疏水性或亲水性），耐辐射能，提供功能性表面官能团等）。 表面改性聚合物与本体聚合物组合，并且由于存在有利于迁移的部分，主要集中在本体聚合物的表面上，使得提供感兴趣的活性的部分主要位于 生产的散装聚合物制品。

    Method for improving environmental durability of materials
    209.
    发明申请
    Method for improving environmental durability of materials 失效
    提高材料耐候性的方法

    公开(公告)号：US20040225028A1

    公开(公告)日：2004-11-11

    申请号：US10866607

    申请日：2004-06-11

    Inventor： Walter H. Ohrbom ,  Marvin L. Green ,  Gregory G. Menovcik

    IPC: C08J003/28

    CPC classification number: C08F4/28 ,  C08F2/06 ,  C08F2/52 ,  C08F2/56 ,  C08F4/04 ,  C09D175/04 ,  C09D201/02 ,  C09D201/025 ,  C08L2666/16

    Abstract: Disclosed is a method of making an environmentally durable material, the method requiring providing a material comprising at least one functional group Fc, and subjecting the material to a free radical source such that substantially all functional groups Fc are eliminated but the material is not polymerized. In one embodiment, the functional group Fc is at least one of a nonaromatic carbon-carbon double bond, a hydrogen atom alpha to an aromatic ring, a hydrogen atom alpha to a carbon-carbon double bond, or a hydrogen atom attached to a tertiary substituted carbon. In another embodiment, functional group Fc is present in the material as a contaminant. In one exemplary embodiment, the material comprises from 0.05 to less than 15% by weight of functional group Fc, based on the total weight of the material.

    Abstract translation: 公开了一种制备环境耐久材料的方法，该方法需要提供包含至少一个官能团Fc的材料，并使材料经受自由基源，使得基本上所有的官能团Fc都被去除，但是材料没有聚合。 在一个实施方案中，官能团Fc是非芳族碳 - 碳双键，芳族环中的α，氢原子，碳 - 碳双键的氢原子或连接到第三个碳原子上的氢原子中的至少一个 取代碳。 在另一个实施方案中，官能团Fc作为污染物存在于材料中。 在一个示例性实施方案中，基于材料的总重量，该材料包含0.05至小于15重量％的官能团Fc。

    Waterborne coating compositions containing monomeric difunctional compounds
    210.
    发明申请
    Waterborne coating compositions containing monomeric difunctional compounds 失效
    含有单体双官能化合物的水性涂料组合物

    公开(公告)号：US20040063850A1

    公开(公告)日：2004-04-01

    申请号：US10261428

    申请日：2002-09-30

    Applicant: BASF CORPORATION

    Inventor： Walter H. Ohrbom ,  Sergio E. Balatan ,  David J. Law ,  Robert D. Weise

    IPC: C08K003/00

    CPC classification number: C09D5/02 ,  C09D133/14 ,  C09D201/00 ,  C09D201/02 ,  C09D201/025

    Abstract: The invention provides curable waterborne coating compositions comprising an aqueous dispersion (A) comprising an organic binder component (A1) comprising at least 5% by weight of a reactive component (a), based on the total weight of organic binder component (A1), and at least one crosslinking component (B). The reactive component (a) is substantially free of any heteratoms and is a not a crystalline solid at room temperature and comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups. The curable waterborne coating compositions of the invention show significantly improved pop resistance while also providing improved chip resistance, weathering resistance, flexibility, and/or scratch & mar resistance.

    Abstract translation: 本发明提供可固化的水性涂料组合物，其包含基于有机粘合剂组分（A1）的总重量的包含至少5重量％的反应性组分（a）的有机粘合剂组分（A1）的水性分散体（A） 和至少一种交联组分（B）。 反应性组分（a）基本上不含任何杂原子，并且在室温下不是结晶固体，并且包含（i）12至72个碳原子，和（ii）至少两个官能团。 本发明的可固化水性涂料组合物显示出显着改善的弹性阻力，同时还提供改善的耐碎屑性，耐候性，柔韧性和/或抗划痕性。

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