CURABLE LOW SULFUR LIQUID RUBBER COMPOSITIONS
    271.
    发明申请

    公开(公告)号:US20200339786A1

    公开(公告)日:2020-10-29

    申请号:US16393493

    申请日:2019-04-24

    Abstract: A curable low sulfur liquid rubber composition including at least one polymer which contains, in polymerized form, at least one monomer having a carbon chain of four and a peroxide system which includes at least one organic peroxide and at least one coagent. The polymer has a vinyl content of 1% to 90% and a number average molecular weight of 800 g/mol to 70,000 g/mol. The curable low sulfur liquid rubber composition has a sulfur content of 0 to 1%, by weight, and is curable at a temperature of 100° C. to 190° C.

    Methods of catalyst activation
    274.
    发明授权

    公开(公告)号:US10647796B2

    公开(公告)日:2020-05-12

    申请号:US16270699

    申请日:2019-02-08

    Abstract: A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types.

    Farnesene-based macromonomers and methods of making and using the same

    公开(公告)号:US10544241B2

    公开(公告)日:2020-01-28

    申请号:US15266330

    申请日:2016-09-15

    Abstract: A macromonomer precursor is provided that includes a polymeric chain derived from farnesene and a single functional terminal end. The functional terminal end may include a hydroxyl group, an amino group, an epoxy group, an isocyanato group, or a carboxylic acid group. The terminal end of the macromonomer precursor may then be reacted with a (meth)acrylate to form a macromonomer having a (meth)acrylate functionalized terminal end that may be (co)polymerized with radically polymerizable monomers, such as alkyl(meth)acrylate monomers. Alternatively, a copolymer may be obtained by first deriving a poly(meth)acrylate from (meth)acrylate monomers having reactive groups that would allow the macromonomer precursors to be grafted onto the poly(meth)acrylate in a second step. The resulting copolymer may be incorporated as an additive in various formulations, such as a lubricant, a hydraulic fluid, a cosmetic composition, and an adhesive composition.

    Ziegler-natta catalysts doped with non-Group IV metal chlorides

    公开(公告)号:US10294311B2

    公开(公告)日:2019-05-21

    申请号:US15918075

    申请日:2018-03-12

    Abstract: A process may include contacting ethylene monomer with Ziegler-Natta catalyst to form polyethylene. The Ziegler-Natta catalyst may be formed by contacting an alkyl magnesium compound with an alcohol and a metal reagent to form a blend, and contacting the blend with a first agent to form a solution of reaction product “A”. The solution of reaction product “A” may be contacted with a second agent to form a solid reaction product “B”, and the solid reaction product “B” may be contacted with a third agent to form a solid reaction product “C”. The solid reaction product “C” may be contacted with a fourth agent to form a solid reaction product “D”, and the solid reaction product “D” may be contacted with a fifth agent to form a catalyst component.

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