Abstract:
The present disclosure is directed at a compression device for compressing a stack to prevent leaks and at an apparatus including the stack and the compression device. The stack includes a pair of rigid end plates located at opposing ends of the stack, a plurality of membrane bounded compartments layered between one of the rigid end plates and the other of the rigid end plates and fluid manifolds extending through the membrane bound compartments. The compression device is fixedly coupled to opposing ends of the pair of rigid end plates and includes compression members movable to compress one of the rigid end plates towards the other of the rigid end plates. The compression members are positioned to apply force to the stack in the vicinity of the fluid manifolds.
Abstract:
Described herein are a method and system for desalinating saltwater using concentration difference energy. A “five stream” dialytic stack is described that can be used to desalinate saltwater at a relatively high recovery ratio. The dialytic stack may include, for example, one or more drive cells having a paired concentrate and a diluent-c chamber in ionic communication with a product chamber that is adjacent to an anion and a cation discharge chamber each filled with diluent-p. The drive cell applies a drive voltage across the product chamber, and when the drive voltage exceeds a desalination voltage of the product chamber, the saltwater in the product chamber is desalinated. The diluent-p may be at a lower ionic concentration than the diluent-c, which may be at a lower concentration than the concentrate. The relatively high concentrations of the concentrate and the diluent-c facilitate a relatively high recovery ratio, while the relatively low concentration of the diluent-p facilitates a relatively low desalination voltage. The dialytic stack may accept brine discharged from a first desalination plant and may use this brine as a source of the concentrate, diluent-c, or diluent-p. Alternatively, the dialytic stack may accept the brine as saltwater to be desalinated, and may then output desalinated brine back to the first desalination plant for further desalination. Processing the brine in the dialytic stack may decrease its volume, decreasing costs associated with treating or otherwise disposing of the brine.
Abstract:
A method and apparatus for desalinating saltwater using concentration difference energy is disclosed. In order to desalinate saltwater that is contained within a product chamber, a drive cell is used to generate a drive voltage. The product chamber has a desalination voltage such that when a sufficient voltage is applied to the product chamber, anions and cations migrate out of the product chamber, thereby desalinating the water. The sufficient voltage, which includes the drive voltage and which is equal to or greater than the desalination voltage, is applied to the product chamber, consequently effecting desalination. Beneficially, concentration difference energy can be generated using a concentrated solution, which can be generated using, for example, solar energy.
Abstract:
A method for filtering suspended solids from a feed fluid involves filtering the feed fluid by pumping the feed fluid through a first retentate channel of a first cross-flow membrane unit and through a second retentate channel of a second cross-flow membrane unit that is connected in parallel with the first membrane unit. The retentate exiting the units after filtering is pumped through a suspended solids concentrating path. While the filtering is being performed by both membrane units, at least one of the membrane units may be cleaned by performing a forward flush on it in which a portion of the retentate from at least one of the first and the second retentate channels is drawn into a forward flushing path. The forward flushing path is fluidly connected to the retentate channel of the membrane unit that is being forward flushed.
Abstract:
Methods, systems, and techniques for desalinating a saltwater using a humidifier unit. The humidifier unit has a housing, which has a carrier gas inlet and a saltwater inlet. The humidifier unit also includes a packing, within the housing, having a surface with a critical surface tension of less than 25 mN/m according to the Zisman method. The packing is arranged to facilitate a saltwater that enters the housing through the saltwater inlet and a carrier gas that enters the housing through the carrier gas inlet to contact each other. The contact facilitates evaporation of the saltwater, which produces salt solids on at least a surface of the packing, a humidified gas and a concentrated brine.
Abstract:
Systems, processes, and techniques for treating a saltwater contaminated with volatile compounds. The saltwater is evaporated, resulting in a gas composed of water vapor and gaseous volatile compounds. This gas is then condensed into a condensate contaminated with the volatile compounds. The contaminated condensate is biologically treated to remove those volatile compounds, producing a purified water. Latent heat released by the condensing is used to evaporate the purified water into the atmosphere in an energy efficient manner. The contaminated saltwater is accordingly evaporatively disposed of without creating an issue regarding how to manage substantial liquid water byproduct, and without emitting substantial amounts of the volatile compounds into the atmosphere.
Abstract:
A process and system for removing ammonia from an aqueous ammonia solution. A first aqueous solution and the ammonia solution are flowed respectively through a first and a second separation chamber of a bipolar membrane electrodialysis (“BPMED”) stack. The first separation chamber is bounded on an anodic side by a cation exchange membrane and the second separation chamber is bounded on a cathodic side by the cation exchange membrane and on an anodic side by a bipolar membrane. The bipolar membrane has an anion-permeable layer and a cation-permeable layer respectively oriented to face the stack's anode and cathode. While the solutions are flowing through the stack a voltage is applied across the stack that causes the bipolar membrane to dissociate water into protons and hydroxide ions. The protons migrate into the second separation chamber and react there with ammonia to form ammonium ions that migrate to the first separation chamber.
Abstract:
A process for preparing an acrylamide-based crosslinking monomer comprising reacting in the presence of a catalyst an isocyanate compound containing at least two isocyanate groups with one of acrylic acid or methacrylic acid. These acrylamide-based crosslinking monomers are used in the preparation of coating compositions, adhesive compositions curable by applying thermal or radiation energy, and in the preparation of cation or anion exchange membranes.
Abstract:
A monovalent ion permselective ion exchange membrane comprising a base layer consisting of an ion exchange membrane, and a monovalent ion permselective layer affixed to the surface of the base layer. The monovalent ion permselective layer is formed by coating and polymerizing a polymerizable solution onto the base ion exchange membrane layer. The polymerizable solution comprises: (i) of an ionic monomer having one or more ethylenic groups selected from (meth)acryloxy groups, (meth)acryl-amido groups, and vinylbenzyl groups, (ii) a hydrophobic crosslinking monomer having two or more ethylenic groups selected from (meth)acryloxy groups, (meth)acrylamido groups, and vinylbenzyl groups, (iii) a free radical initiator, in (iv) a solvent medium. The monovalent ion permselective ion exchange membranes include monovalent cation permselective ion exchange membranes and monovalent anion permselective ion exchange membranes. Also disclosed are processes for preparing the monovalent ion permselective ion exchange membranes.
Abstract:
The present disclosure is directed at an apparatus, method and plant for desalinating saltwater and contaminated saltwater. The apparatus comprises a stack and a manifolding assembly. The stack comprises a product chamber, a first and second concentrate chamber, an anion exchange membrane forming a boundary between the first concentrate chamber and the product chamber and a cation exchange membrane forming a boundary between the second concentrate chamber and the product chamber. The manifolding assembly comprises product and concentrate manifolding fluidly coupled to the product and concentrate chambers respectively, to convey a saltwater being desalinated to and away from the product chamber, and a concentrate to and away from the concentrate chambers. The stack may include a diluent chamber and adjacent anion or cation exchange membranes between the product chamber, diluent chamber and concentrate chamber to respectively convey anions or cations across multiple chambers. The stack may also contain a rinse chamber bounded by an anion exchange membrane to guard the stack electrodes from scaling cations. A cleaning system for cleaning the stack is also disclosed.