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公开(公告)号：US08415512B2
公开(公告)日：2013-04-09
申请号：US12904030
申请日：2010-10-13
申请人： Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Rreed , Michael F. Doherty
发明人： Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Rreed , Michael F. Doherty
CPC分类号： C07C1/30 , C07C17/10 , C07C29/124 , C07C29/58 , C07C45/27 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/06 , C07C2523/42 , C07C2523/745 , C07C2523/75 , C07C2523/80 , C07C2527/128 , C07C2527/133 , C07D301/26 , Y02P20/582 , C07C19/075 , C07C19/043 , C07C19/07 , C07C47/06 , C07C41/01 , C07C43/04 , C07C31/02
摘要： Improvements in previously disclosed methods of and apparatuses for converting alkanes, alkenes, and aromatics to olefins, alcohols, ethers, and aldehydes includes: safety improvements, use of alternative feedstocks, process simplification, improvements to the halogenation step, improvements to the reproportionation step, improvements to the solid oxide reaction, improvements to solid oxide regeneration, improvements in separations, maintenance, start-up, shut-down, and materials of construction.
摘要翻译： 将烷烃，烯烃和芳族化合物转化为烯烃，醇，醚和醛的先前公开的方法和装置的改进包括：安全性改进，替代原料的使用，工艺简化，改进卤化步骤，改善重复步骤， 固体氧化物反应的改进，固体氧化物再生的改进，分离改进，维护，启动，停机和施工材料。
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公开(公告)号：US20100121119A1
公开(公告)日：2010-05-13
申请号：US12692831
申请日：2010-01-25
申请人： Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Breed , Michael F. Doherty
发明人： Jeffrey H. Sherman , Eric W. McFarland , Michael J. Weiss , Ivan Marc Lorkovic , Leroy E. Laverman , Shouli Sun , Dieter J. Schaefer , Galen D. Stucky , Peter C. Ford , Philip Grosso , Ashley W. Breed , Michael F. Doherty
IPC分类号： C07C17/013
CPC分类号： C07C1/30 , C07C17/10 , C07C29/124 , C07C29/58 , C07C45/27 , C07C2521/02 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/06 , C07C2523/42 , C07C2523/745 , C07C2523/75 , C07C2523/80 , C07C2527/128 , C07C2527/133 , C07D301/26 , Y02P20/582 , C07C19/075 , C07C19/043 , C07C19/07 , C07C47/06 , C07C41/01 , C07C43/04 , C07C31/02
摘要： Improvements in previously disclosed methods of and apparatuses for converting alkanes, alkenes, and aromatics to olefins, alcohols, ethers, and aldehydes includes: safety improvements, use of alternative feedstocks, process simplification, improvements to the halogenation step, improvements to the reproportionation step, improvements to the solid oxide reaction, improvements to solid oxide regeneration, improvements in separations, maintenance, start-up, shut-down, and materials of construction.
摘要翻译： 将烷烃，烯烃和芳族化合物转化为烯烃，醇，醚和醛的先前公开的方法和装置的改进包括：安全性改进，替代原料的使用，工艺简化，改进卤化步骤，改性步骤， 固体氧化物反应的改进，固体氧化物再生的改进，分离改进，维护，启动，停机和施工材料。
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公开(公告)号：US07662274B2
公开(公告)日：2010-02-16
申请号：US11852434
申请日：2007-09-10
IPC分类号： C10M175/02
CPC分类号： C10G19/00 , C10G19/04 , C10M175/00 , C10M175/0016 , C10M175/0033
摘要： In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.
摘要翻译： 在除去酸性化合物，着色剂和多环芳香烃，以及从废油馏出物中除去或转化含有杂原子的烃的方法中，使用相转移催化剂来促进无机或有机碱转移到油馏分的底物上。 将无机或有机碱，选自包括季铵盐，多元醇醚和冠醚的相转移催化剂和使用的油馏分混合加热。 此后，通过蒸馏从废油馏分中除去污染物。
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公开(公告)号：US06486368B1
公开(公告)日：2002-11-26
申请号：US10054004
申请日：2002-01-24
IPC分类号： C07C2700
CPC分类号： C07D301/26 , C07C17/10 , C07C29/124 , C07C41/01 , C07C45/27 , Y02P20/125 , C07C19/075 , C07C47/06 , C07C31/04 , C07C43/06 , C07C43/043
摘要： Alcohols, ethers, and olefins are manufactured from alkanes by mixing an alkane and bromine in a reactor to form alkyl bromide and hydrogen bromide. The alkyl bromide only or the alkyl bromide and the hydrogen bromide are directed into contact with metal oxide to form an alcohol and/or an ether, or an olefin and metal bromide. The metal bromide is oxidized to form original metal oxide and bromine, both of which are recycled.
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公开(公告)号：US06444131B1
公开(公告)日：2002-09-03
申请号：US09619009
申请日：2000-07-19
申请人： Jeffrey H. Sherman
发明人： Jeffrey H. Sherman
IPC分类号： C02F172
CPC分类号： C02F1/78 , B01F3/04539 , B01F5/045 , B01F2003/04297 , B01F2003/04319 , B01F2003/0439 , B01F2003/04695 , B01F2003/04858 , B01F2003/04879 , C02F1/72 , C02F1/722 , C02F1/725 , C02F1/74 , C02F1/76 , C02F1/763 , C02F2201/782 , Y02W10/37 , Y10S210/908
摘要： In a method of removing organic and biological contaminants from a liquid, an oxidizing gas is formed into sub-micron size bubbles which are dispersed into an initially contaminated liquid, after which the treated liquid is recovered. The oxidizing gas is preferably selected from a group including ozone and chlorine dioxide and is utilized immediately upon its manufacture. An oxidizing liquid may be employed in conjunction with the oxidizing gas. The method may be practiced repeatedly. A base may be added to the contaminated liquid to raise the pH thereof.
摘要翻译： 在从液体中除去有机和生物污染物的方法中，氧化气体形成亚微米级的气泡，其分散在初始污染的液体中，之后回收处理过的液体。 氧化气体优选选自包括臭氧和二氧化氯的组，并且在其制造时立即使用。 可以与氧化气体一起使用氧化液体。 该方法可以重复实施。 碱可以加入污染的液体中以提高其pH。
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公开(公告)号：US06398948B1
公开(公告)日：2002-06-04
申请号：US09664195
申请日：2000-09-18
IPC分类号： C10M17500
CPC分类号： C10G19/00 , C10G19/04 , C10M175/00 , C10M175/0016 , C10M175/0033
摘要： In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.
摘要翻译： 在除去酸性化合物，着色剂和多环芳香烃，以及从废油馏出物中除去或转化含有杂原子的烃的方法中，使用相转移催化剂来促进无机或有机碱转移到油馏分的底物上。 将无机或有机碱，选自包括季铵盐，多元醇醚和冠醚的相转移催化剂和使用的油馏分混合并加热。 此后，通过蒸馏从废油馏分中除去污染物。
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公开(公告)号：US06319394B2
公开(公告)日：2001-11-20
申请号：US09754680
申请日：2001-01-04
申请人： Jeffrey H. Sherman , Richard T. Taylor , Amanda L. Hofacker , James W. Hershberger , Garrett M. Conn , William A. Gorman
发明人： Jeffrey H. Sherman , Richard T. Taylor , Amanda L. Hofacker , James W. Hershberger , Garrett M. Conn , William A. Gorman
IPC分类号： C10M17500
CPC分类号： B01D3/146 , B01D3/34 , C10G19/04 , C10M175/00 , C10M175/0016 , C10M175/0033
摘要： In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.
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公开(公告)号：US06179999B2
公开(公告)日：2001-01-30
申请号：US09418448
申请日：1999-10-15
IPC分类号： C10M7500
CPC分类号： C10G19/00 , C10G19/04 , C10M175/00 , C10M175/0016 , C10M175/0033
摘要： In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.
摘要翻译： 在除去酸性化合物，着色剂和多环芳香烃，以及从废油馏出物中除去或转化含有杂原子的烃的方法中，使用相转移催化剂来促进无机或有机碱转移到油馏分的底物上。 将无机或有机碱，选自包括季铵盐，多元醇醚和冠醚的相转移催化剂和使用的油馏分混合并加热。 此后，通过蒸馏从废油馏分中除去污染物。
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公开(公告)号：US07847139B2
公开(公告)日：2010-12-07
申请号：US12217311
申请日：2008-07-02
IPC分类号： C07C1/00
CPC分类号： C07C1/26 , C07C2521/10 , C07C2523/02 , C07C2529/18 , C07C2529/40 , Y10S585/935 , Y10S585/943
摘要： A method of synthesizing hydrocarbons from smaller hydrocarbons includes the steps of hydrocarbon halogenation, simultaneous oligomerization and hydrogen halide neutralization, and product recovery, with a metal-oxygen cataloreactant used to facilitate carbon-carbon coupling. Treatment with air or oxygen liberates halogen and regenerates the cataloreactant.
摘要翻译： 从较小的烃合成烃的方法包括烃卤化，同时低聚和卤化氢中和以及用于促进碳 - 碳偶联的金属 - 氧催化反应物的产物回收步骤。 用空气或氧气处理释放卤素并再生催化反应物。
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公开(公告)号：US20080269534A1
公开(公告)日：2008-10-30
申请号：US12217311
申请日：2008-07-02
IPC分类号： C07C2/00
CPC分类号： C07C1/26 , C07C2521/10 , C07C2523/02 , C07C2529/18 , C07C2529/40 , Y10S585/935 , Y10S585/943
摘要： A method of synthesizing hydrocarbons from smaller hydrocarbons includes the steps of hydrocarbon halogenation, simultaneous oligomerization and hydrogen halide neutralization, and product recovery, with a metal-oxygen cataloreactant used to facilitate carbon-carbon coupling. Treatment with air or oxygen liberates halogen and regenerates the cataloreactant.
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