公开(公告)号：US20100116714A1

公开(公告)日：2010-05-13

申请号：US12269366

申请日：2008-11-12

Applicant: Mark P. Lapinski ,  Richard R. Rosin ,  Marc R. Schreier

Inventor： Mark P. Lapinski ,  Richard R. Rosin ,  Marc R. Schreier

IPC: C10G35/06

CPC classification number: C10G35/06 ,  B01J23/08 ,  B01J27/13 ,  B01J27/32 ,  B01J38/02 ,  B01J38/10 ,  B01J38/44 ,  B01J38/48 ,  B01J38/60 ,  C10G35/085 ,  C10G2300/1044 ,  C10G2300/70

Abstract: One exemplary embodiment can be a process for facilitating adding a promoter metal to at least one catalyst particle in situ in a catalytic naphtha reforming unit. The process can include introducing a compound comprising the promoter metal to the catalyst naphtha reforming unit and adding an effective amount of the promoter metal from the compound comprising the promoter metal to the catalyst particle under conditions to effect such addition and improve a conversion of a hydrocarbon feed.

Abstract translation: 一个示例性实施方案可以是促进助催化剂金属在催化石脑油重整单元中原位加入至少一种催化剂颗粒的方法。 该方法可以包括将催化剂石脑油重整单元引入包含助催化剂金属的化合物，并且在实施这种添加的条件下将有效量的助催化剂金属从包含促进剂金属的化合物加入催化剂颗粒中，并改善烃的转化率 饲料。

公开(公告)号：US07687049B2

公开(公告)日：2010-03-30

申请号：US12177851

申请日：2008-07-22

Applicant: Mark P. Lapinski ,  Richard R. Rosin

Inventor： Mark P. Lapinski ,  Richard R. Rosin

IPC: B01D53/94 ,  C01D3/06

CPC classification number: B01D53/864 ,  B01D53/02 ,  B01D2251/202 ,  B01D2253/108 ,  B01D2255/1026 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2256/16 ,  B01D2256/24 ,  B01D2257/502 ,  B01J23/96 ,  B01J38/10 ,  C10G35/06

Abstract: One exemplary embodiment can be a process for lowering an amount of carbon monoxide in a stream rich in hydrogen. The process can include passing the stream rich in hydrogen through a carbon monoxide removal zone to produce a product stream having no more than about 10 vppm carbon monoxide and communicating the product stream to a reduction zone receiving a catalyst comprising unreduced metal species.

Abstract translation: 一个示例性实施方案可以是用于降低富含氢气的一氧化碳的量的方法。 该方法可以包括使富含氢的物流通过一氧化碳去除区，以产生具有不超过约10vppm一氧化碳的产物流，并将产物流连通至含有未还原金属物质的催化剂的还原区。

公开(公告)号：US20100018899A1

公开(公告)日：2010-01-28

申请号：US12179524

申请日：2008-07-24

Applicant: Steven L. Krupa ,  Mark P. Lapinski ,  Clayton C. Sadler

Inventor： Steven L. Krupa ,  Mark P. Lapinski ,  Clayton C. Sadler

IPC: C10G35/00

CPC classification number: C10G35/04

Abstract: One exemplary embodiment can be a process for producing a reformate by combining a stream having an effective amount of isopentane and a stream having an effective amount of naphtha for reforming. Generally, the naphtha has not less than about 95%, by weight, of one or more compounds having a boiling point of about 38—about 260° C. as determined by ASTM D86-07. The process may include introducing the combined stream to a reforming reaction zone. The combined stream can have an isopentane:naphtha mass ratio of about 0.10:1.00—about 1.00:1.00.

Abstract translation: 一个示例性实施方案可以是通过将具有有效量的异戊烷的物流和具有有效量的石脑油的物流混合以重整来生产重整产品的方法。 通常，根据ASTM D86-07测定，石脑油具有不小于约95重量％的一种或多种沸点为约38-约260℃的化合物。 该方法可以包括将组合的流引入重整反应区。 合并的流可以具有约0.10:1.00-约1.00:1.00的异戊烷：石脑油质量比。

公开(公告)号：US07410565B1

公开(公告)日：2008-08-12

申请号：US11015156

申请日：2004-12-17

Applicant: Mark P. Lapinski ,  Leon Yuan ,  Mark D. Moser

Inventor： Mark P. Lapinski ,  Leon Yuan ,  Mark D. Moser

IPC: C10G35/04

CPC classification number: C10G35/085

Abstract: The chloride retention of an alumina catalyst over the course of operation and regeneration can be controlled and stabilized by incorporating a small amount of a component selected from the group including phosphorus, boron, titanium, silicon, and zirconium. Steam treatments have been used to simulate commercial hydrothermal stability and a small amount of the stabilizer component has been discovered which balances chloride retention. Moreover, in a multi-catalyst hydrocarbon conversion process, such as the two-step reforming of naphtha, it has been discovered that proper selection of a catalyst having lower chloride retention in combination with another catalyst having higher chloride retention results in a process with increased yield and/or higher octane gasoline.

Abstract translation: 通过加入少量选自磷，硼，钛，硅和锆的组分，可以控制和稳定氧化铝催化剂在操作和再生过程中的氯化物保留。 已经使用蒸汽处理来模拟商业水热稳定性，并且已经发现少量的稳定剂组分平衡氯化物保留。 此外，在诸如石脑油两步重整的多催化剂烃转化方法中，已经发现，适当选择具有较低氯化物保留性的催化剂与另外具有较高氯化物保留性的催化剂结合使催化剂具有增加的过程 产率和/或更高辛烷值的汽油。

公开(公告)号：US09266091B2

公开(公告)日：2016-02-23

申请号：US13547335

申请日：2012-07-12

Applicant: Manuela Serban ,  Colleen K. Costello ,  Mark P. Lapinski

Inventor： Manuela Serban ,  Colleen K. Costello ,  Mark P. Lapinski

IPC: B01J23/58 ,  C10G35/09 ,  B01J37/18 ,  B01J21/04 ,  B01J23/62 ,  B01J27/10 ,  B01J35/08 ,  B01J37/00 ,  B01J37/02 ,  B01J27/13 ,  B01J27/135 ,  B01J27/138

CPC classification number: B01J23/58 ,  B01J21/04 ,  B01J23/626 ,  B01J27/10 ,  B01J27/13 ,  B01J27/135 ,  B01J27/138 ,  B01J35/08 ,  B01J37/0072 ,  B01J37/0201 ,  B01J37/18 ,  C10G35/09

Abstract: One exemplary embodiment can be a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, at least two alkali metals or at least two alkaline earth metals, or mixtures of alkali metals and alkaline earth metals and a support.

Abstract translation: 一个示例性实施方案可以是用于石脑油的催化重整的催化剂。 催化剂可以具有包括铂，钯，铑，钌，锇和铱中的一种或多种的贵金属，至少两种碱金属或至少两种碱土金属，或碱金属和碱土金属的混合物和载体 。

公开(公告)号：US09023298B2

公开(公告)日：2015-05-05

申请号：US13440527

申请日：2012-04-05

Applicant: Mark D. Moser ,  Clayton C. Sadler ,  Mark P. Lapinski ,  Kurt M. VandenBussche

Inventor： Mark D. Moser ,  Clayton C. Sadler ,  Mark P. Lapinski ,  Kurt M. VandenBussche

IPC: B01J8/00 ,  B01J8/04 ,  B01J19/00 ,  B01J19/24 ,  C01B3/00 ,  C01B3/02 ,  C01B3/22 ,  C01B3/24 ,  C01B3/26 ,  C01B3/32 ,  C01B3/34 ,  C01B3/38

CPC classification number: C01B3/26 ,  B01J8/008 ,  B01J8/0415 ,  B01J8/0492 ,  B01J8/0496 ,  B01J2208/00194 ,  B01J2208/0053 ,  B01J2219/024 ,  C01B2203/0277

Abstract: An apparatus for reforming a hydrocarbon stream is presented. The apparatus involves changing the design of reformers and associated equipment to allow for increasing the processing temperatures in the reformers and heaters. The reformers are operated under different conditions to utilize advantages in the equilibriums, but require modifications to prevent increasing thermal cracking and to prevent increases in coking.

Abstract translation: 提出了一种用于重整烃流的装置。 该设备包括改变重整器和相关设备的设计，以允许提高重整器和加热器中的加工温度。 改造者在不同条件下运行，以利用平衡中的优点，但需要进行修改以防止增加热裂解并防止焦化增加。

公开(公告)号：US08845884B2

公开(公告)日：2014-09-30

申请号：US13417203

申请日：2012-03-10

Applicant: Gregory J. Gajda ,  Mary Jo Wier ,  Mark P. Lapinski ,  David A. Wegerer ,  Kurt M. VandenBussche ,  Mark D. Moser

Inventor： Gregory J. Gajda ,  Mary Jo Wier ,  Mark P. Lapinski ,  David A. Wegerer ,  Kurt M. VandenBussche ,  Mark D. Moser

IPC: C10G35/04 ,  C10G59/06 ,  C10G35/06 ,  C10G35/085

CPC classification number: C10G35/04 ,  C10G35/06 ,  C10G35/065 ,  C10G35/085 ,  C10G59/06 ,  C10G2300/1044 ,  C10G2400/30

Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.

公开(公告)号：US20130256194A1

公开(公告)日：2013-10-03

申请号：US13547335

申请日：2012-07-12

Applicant: Manuela Serban ,  Colleen K. Costello ,  Mark P. Lapinski

Inventor： Manuela Serban ,  Colleen K. Costello ,  Mark P. Lapinski

IPC: B01J27/13 ,  B01J23/58 ,  C10G35/09

CPC classification number: B01J23/58 ,  B01J21/04 ,  B01J23/626 ,  B01J27/10 ,  B01J27/13 ,  B01J27/135 ,  B01J27/138 ,  B01J35/08 ,  B01J37/0072 ,  B01J37/0201 ,  B01J37/18 ,  C10G35/09

Abstract: One exemplary embodiment can be a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, at least two alkali metals or at least two alkaline earth metals, or mixtures of alkali metals and alkaline earth metals and a support.

Abstract translation: 一个示例性实施方案可以是用于石脑油的催化重整的催化剂。 催化剂可以具有包括铂，钯，铑，钌，锇和铱中的一种或多种的贵金属，至少两种碱金属或至少两种碱土金属，或碱金属和碱土金属的混合物和载体 。

公开(公告)号：US20120277500A1

公开(公告)日：2012-11-01

申请号：US13440487

申请日：2012-04-05

Applicant: Mark D. Moser ,  Clayton C. Sadler ,  Mark P. Lapinski ,  Kurt M. VandenBussche

Inventor： Mark D. Moser ,  Clayton C. Sadler ,  Mark P. Lapinski ,  Kurt M. VandenBussche

IPC: C07C2/00

CPC classification number: C10G35/04 ,  C07C4/06 ,  C10G35/06 ,  C10G61/04 ,  C10G2300/1044 ,  C10G2300/4018 ,  C10G2400/30 ,  Y02P20/584 ,  C07C15/02 ,  C07C15/067

Abstract: A process for reforming a hydrocarbon stream is presented. The process involves increasing the processing temperatures in the reformers. The reformers are operated under different conditions to utilize advantages in the equilibriums, but require modifications to prevent increasing thermal cracking and to prevent increases in coking. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.

Abstract translation: 提出了一种重整烃流的方法。 该方法涉及提高改性剂中的加工温度。 改造者在不同条件下运行，以利用平衡中的优点，但需要进行修改以防止增加热裂解并防止焦化增加。 该方法利用普通的催化剂和用于回收生成的所需芳族化合物的常见的下游方法。

公开(公告)号：US20110152589A1

公开(公告)日：2011-06-23

申请号：US12701187

申请日：2010-02-05

Applicant: Manuela Serban ,  Mark P. Lapinski ,  Mark D. Moser

Inventor： Manuela Serban ,  Mark P. Lapinski ,  Mark D. Moser

IPC: C07C7/12 ,  C07C4/00

CPC classification number: C10G25/003 ,  C10G61/06 ,  C10G2300/1044 ,  C10G2300/1096 ,  C10G2300/301 ,  C10G2300/305 ,  C10G2300/4018 ,  C10G2400/02

Abstract: An exemplary embodiment can be a process for removing one or more polynuclear aromatics from at least one reformate stream from a reforming zone. The PNAs may be removed using an adsorption zone. The adsorption zone can include first and second vessels each vessel containing an activated carbon adsorbent. Generally, the process includes passing the at least a portion of an effluent of the reforming zone through the first vessel containing a first activated carbon adsorbent wherein the first activated carbon adsorbent comprises iron.

Abstract translation: 示例性实施方案可以是从重整区从至少一种重整产物流中除去一种或多种多核芳烃的方法。 可以使用吸附区去除PNA。 吸附区可以包括第一和第二容器，每个容器含有活性炭吸附剂。 通常，该方法包括使重整区的流出物的至少一部分通过包含第一活性炭吸附剂的第一容器，其中第一活性炭吸附剂包含铁。