公开(公告)号：US09611081B2

公开(公告)日：2017-04-04

申请号：US13263806

申请日：2010-04-09

Applicant: Ronald James Valus ,  Mark Rule ,  Andrew Stuart Overend ,  Christine Leeming ,  Steven Burgess Tattum ,  James Stuart Leeming

Inventor： Ronald James Valus ,  Mark Rule ,  Andrew Stuart Overend ,  Christine Leeming ,  Steven Burgess Tattum

IPC: B65D81/24 ,  B23P11/00 ,  B65D51/24 ,  B65D51/00 ,  B65D81/26

CPC classification number: B65D51/244 ,  B65D51/00 ,  B65D81/267 ,  Y10T29/49826

Abstract: A closure 40 for a container body includes a liner 46 which incorporates a hydrogen generating device comprising a hydride which generates hydrogen on contact with moisture. The liner may be an interference fit within the body 42. The liner 46 and other liners described may include control means for controlling passage of moisture to the hydrogen generating means and/or sealing means for sealing the closure to a container. In use, with the closure secured to a container, water vapor passes into liner 46 and contacts the hydride which generates hydrogen. A reaction between hydrogen and oxygen which has passed into the container takes place, catalysed by a catalyst, and water is produced. Thus, oxygen is scavenged.

公开(公告)号：US08906299B2

公开(公告)日：2014-12-09

申请号：US12524402

申请日：2008-01-24

Applicant: Mark Rule ,  Ronald J. Valus ,  Steven Burgess Tattum

Inventor： Mark Rule ,  Ronald J. Valus ,  Steven Burgess Tattum

IPC: B65D51/24 ,  C08K3/10 ,  C01B3/06 ,  C08K5/098 ,  A23L3/3436 ,  C08K3/00

CPC classification number: B65D81/26 ,  A23L3/3436 ,  B65D51/244 ,  B65D81/266 ,  C01B3/065 ,  C08K3/014 ,  C08K3/10 ,  C08K5/098 ,  Y02E60/362

Abstract: A container (22) includes a shell (24) made from a polymer, for example PET, and incorporating a catalyst, for example a palladium catalyst. A closure (40) incorporates a plug which includes a source of hydrogen, for example a hydride. In use, with container (22) including a beverage and closure (40) in position, the headspace in the container will be saturated with water vapor. This vapor contacts the hydride associated with plug (42) and as a result the hydride produces molecular hydrogen which migrates into the polymer matrix of shell (24) and combines with oxygen which may have entered the container through its permeable walls. A reaction between the hydrogen and oxygen takes place, catalyzed by the catalyst, and water is produced. Thus, oxygen which may ingress the container is scavenged and the contents of the container are protected from oxidation.

Abstract translation: 容器（22）包括由聚合物例如PET制成的壳体（24），并且加入催化剂，例如钯催化剂。 封闭件（40）包括包括氢源（例如氢化物）的塞子。 在使用时，将包括饮料和封闭物（40）的容器（22）置于适当位置，容器中的顶部空间将被水蒸气饱和。 该蒸汽接触与塞子（42）相关联的氢化物，结果氢化物产生迁移到壳体（24）的聚合物基质中的分子氢并与可能通过其可渗透壁进入容器的氧气结合。 发生氢和氧之间的反应，由催化剂催化，产生水。 因此，可能进入容器的氧气被清除，容器的内容物被保护免受氧化。

公开(公告)号：US20080107850A1

公开(公告)日：2008-05-08

申请号：US11971278

申请日：2008-01-09

Applicant: Mark Rule

Inventor： Mark Rule

IPC: B32B1/08 ,  C08K5/524

CPC classification number: C08K5/524 ,  Y10T428/1352

Abstract: Methods to minimize aldehyde content of a polymer are provided. An effective amount of an additive that contains a P-H functionality is incorporated into the polymer in the presence of an acidic of basic catalyst compositions are also provided.

Abstract translation: 提供了使聚合物的醛含量最小化的方法。 还提供了在碱性催化剂组合物的酸性存在下将有效量的含有P-H官能团的添加剂并入聚合物中。

公开(公告)号：US07041350B1

公开(公告)日：2006-05-09

申请号：US10233332

申请日：2002-08-30

Applicant: Mark Rule ,  Yu Shi

Inventor： Mark Rule ,  Yu Shi

IPC: B29D22/00 ,  C08G20/00

CPC classification number: C08G63/88 ,  C08K3/08 ,  C08K5/5419 ,  C08K5/56 ,  C08K5/57 ,  Y10T428/1352 ,  Y10T428/1397 ,  Y10T428/249921 ,  C08L67/00

Abstract: A polyester composition with reduced acetaldehyde concentration comprising polyester, at least one hydrogenation catalyst, and at least one source of reactive hydrogen. A method for making the polyester composition is also disclosed along with polyester articles made with the polyester composition. Suitable articles include containers such as bottles. A packaged beverage comprising a container made with the polyester composition is disclosed.

Abstract translation: 具有降低的乙醛浓度的聚酯组合物包含聚酯，至少一种氢化催化剂和至少一种反应性氢源。 还公开了制备聚酯组合物的方法以及用聚酯组合物制成的聚酯制品。 合适的制品包括诸如瓶子的容器。 公开了一种包含由聚酯组合物制成的容器的包装饮料。

公开(公告)号：US20050014929A1

公开(公告)日：2005-01-20

申请号：US10621636

申请日：2003-07-17

Applicant: Mark Rule

Inventor： Mark Rule

IPC: C08G63/183 ,  C08K3/22 ,  C08G63/02

CPC classification number: C08K3/22 ,  C08G63/183 ,  Y10S220/906 ,  Y10T428/1352

Abstract: A method to decrease an aldehyde content of a polyester. The method comprises incorporating an effective amount of an additive that is capable of catalyzing a hydride-transfer reaction between an organic donor molecule and an aldehyde in the polyester.

公开(公告)号：US06279505B1

公开(公告)日：2001-08-28

申请号：US09380904

申请日：1999-09-10

Applicant: George Plester ,  Horst Ehrich ,  Mark Rule ,  Herbert Pickel ,  Heinz Humele

Inventor： George Plester ,  Horst Ehrich ,  Mark Rule ,  Herbert Pickel ,  Heinz Humele

IPC: C23C1600

CPC classification number: C23C14/10 ,  B29B17/0026 ,  B29K2709/08 ,  B29K2995/0067 ,  B29L2031/7158 ,  Y02W30/62

Abstract: A coated plastic container provides for low permeability to gases and vapors. A method and system for coating plastic containers includes applying a thin inorganic oxide layer to the external surface of the containers with plasma-assisted vacuum vapor deposition. For example, the coating can include silica which is bonded to the external surface of the container. This coating is flexible and be can be applied regardless of the container's internal pressure or lack thereof. The coating firmly adheres to the container and possess an enhanced gas barrier effect after pressurization even when the coating is scratched, fractured, flexed and/or stretched. Moreover, this gas barrier enhancement will be substantially unaffected by filling of the container. A method of recycling coated plastic containers and a method and system for packaging a beverage using the coated containers are also disclosed.

Abstract translation: 涂覆的塑料容器提供对气体和蒸气的低渗透性。 用于涂覆塑料容器的方法和系统包括使用等离子体辅助真空气相沉积将薄的无机氧化物层施加到容器的外表面。 例如，涂层可以包括结合到容器外表面的二氧化硅。 该涂层是柔性的，并且可以施加，而不管容器的内部压力或其不足。 即使当涂层被刮伤，断裂，弯曲和/或拉伸时，涂层牢固地粘附到容器上并且在加压之后具有增强的阻气效果。 此外，这种阻气增强将基本上不会通过填充容器而受到影响。 还公开了一种回收涂覆的塑料容器的方法和用于使用涂覆的容器包装饮料的方法和系统。

公开(公告)号：US5855942A

公开(公告)日：1999-01-05

申请号：US951514

申请日：1997-10-16

Applicant: Mark Rule

Inventor： Mark Rule

IPC: A23L2/00 ,  A23L2/40 ,  A23L2/54 ,  B01F1/00 ,  C12H1/14 ,  B65B55/00 ,  C12G1/06

CPC classification number: A23L2/40 ,  A23L2/54 ,  C12H1/14

Abstract: A method and composition for enhancing retention of carbon dioxide in carbonated bottled beverages indicates the addition of a carbonic acid ester such as propylene carbonate, 1,3-butylene carbonate, diethyl carbonate, neopentylene carbonate and propylene carbonate or mixtures thereof. The carbonic acid ester in the aqueous medium of the beverage undergoes slow hydrolysis thereby releasing CO.sub.2 to maintain the CO.sub.2 level in the container.

Abstract translation: 用于增强碳酸瓶装饮料中二氧化碳保留的方法和组合物表明加入碳酸酯如碳酸亚丙酯，碳酸1,3-丁二酯，碳酸二乙酯，碳酸亚碳酸酯和碳酸亚丙酯或它们的混合物。 饮料的水性介质中的碳酸酯经历缓慢的水解，从而释放CO 2以保持容器中的CO 2水平。

公开(公告)号：US5338886A

公开(公告)日：1994-08-16

申请号：US61468

申请日：1993-05-17

Applicant: Mark Rule ,  James T. Tanner, III

Inventor： Mark Rule ,  James T. Tanner, III

IPC: B01J23/755 ,  C07B61/00 ,  C07C319/02 ,  C07C321/26 ,  C07D207/48 ,  C07D209/04 ,  C07D333/46

CPC classification number: C07C319/02

Abstract: Disclosed is a process for preparation of an aromatic thiol corresponding to the structureA-(SH)nwhereinA is a substituted or unsubstituted aromatic radical and n is 1, 2, 3, 4, 5 or 6 comprising contacting at a temperature of at least 80.degree. C. an aromatic halide corresponding to the structureA-XmwhereinA is the same as above, X is bromine oriodine and n is 1, 2, 3, 4, 5, or 6with thiourea in the presence of nickel metal.

Abstract translation: 公开了一种制备对应于结构A-（SH）n的芳族硫醇的方法，其中A是取代或未取代的芳族基团，n是1,2,3,4,5或6，包括在 对应于结构A-Xm的芳族卤化物，其中A与上述相同，X为溴或碘，n为1,2,3,4,5或6与硫脲在镍存在下反应 金属。

公开(公告)号：US5104965A

公开(公告)日：1992-04-14

申请号：US658812

申请日：1991-02-22

Applicant: Waylon L. Jenkins ,  Gerry F. Rhodes ,  Mark Rule

Inventor： Waylon L. Jenkins ,  Gerry F. Rhodes ,  Mark Rule

IPC: C08G63/88

CPC classification number: C08G63/88

Abstract: A process for preparing a crystalline poly(ethylene terephthalate) having an inherent viscosity of at least 0.5 comprising(A) preparing an admixture of molten poly(ethylene terephthalate) and a zeolite, and(B) cooling the admixture at a rate less than about 300 degrees C. per minute to a temperature less than about 80 degrees C.

Abstract translation: 一种制备特性粘度至少为0.5的结晶聚（对苯二甲酸乙二醇酯）的方法，包括（A）制备熔融聚（对苯二甲酸乙二醇酯）和沸石的混合物，和（B）以小于约 每分钟300摄氏度至低于约80摄氏度的温度。

公开(公告)号：US4977236A

公开(公告)日：1990-12-11

申请号：US449289

申请日：1989-12-05

Applicant: David R. Fagerburg ,  Joseph J. Watkins ,  Paul B. Lawrence ,  Mark Rule

Inventor： David R. Fagerburg ,  Joseph J. Watkins ,  Paul B. Lawrence ,  Mark Rule

IPC: C08G75/02 ,  C08G75/06

CPC classification number: C08G75/0227 ,  C08G75/0231 ,  C08G75/0263 ,  C08G75/0268

Abstract: A process for preparation of a copoly(arylene sulfide) corresponding to the structure ##STR1## wherein A is a divalent substituted or unsubstituted aromatic radical, T is a monovalent aromatic radical, x is in the range of 0.5 to 0.001 and n is an integer from 1 to 100.