PROCESS FOR REDUCING EMISSIONS OF VOLATILE ORGANIC COMPOUNDS FROM THE KETONIZATION OF CARBOXYLIC ACIDS
    25.
    发明申请
    PROCESS FOR REDUCING EMISSIONS OF VOLATILE ORGANIC COMPOUNDS FROM THE KETONIZATION OF CARBOXYLIC ACIDS 有权
    减少挥发性有机化合物从羧酸的酮化反应的方法

    公开(公告)号:US20130310608A1

    公开(公告)日:2013-11-21

    申请号:US13474837

    申请日:2012-05-18

    IPC分类号: C07C45/41 C07C49/08

    CPC分类号: C07C45/48 C07C49/08

    摘要: Disclosed is a process for reducing the emission of volatile organic compounds that are produced during the ketonization of carboxylic acids to ketones. The ketonization of carboxylic acids produces a gaseous by-product stream containing carbon dioxide and volatile organic compounds. This gaseous by-product stream can be fed to a direct-fired furnace used to heat the ketonization reaction feed streams where the volatile organic compounds are destroyed by combustion in the furnace. The carbon dioxide stream further acts as a diluent for the fuel to the furnace.

    摘要翻译: 公开了一种减少在将羧酸酮化成酮时产生的挥发性有机化合物的排放的方法。 羧酸的酮化产生含有二氧化碳和挥发性有机化合物的气态副产物流。 这种气态副产物流可以进料到用于加热酮化反应进料流的直接燃烧炉,其中挥发性有机化合物通过在炉中燃烧而被破坏。 二氧化碳流还充当用于燃料的炉的稀释剂。

    PROCESS FOR THE SEPARATION AND PURIFICATION OF A MIXED DIOL STREAM
    29.
    发明申请
    PROCESS FOR THE SEPARATION AND PURIFICATION OF A MIXED DIOL STREAM 有权
    混合二醇流的分离和纯化方法

    公开(公告)号:US20120184783A1

    公开(公告)日:2012-07-19

    申请号:US13431308

    申请日:2012-03-27

    IPC分类号: C07C29/86

    摘要: Disclosed is a process for the purification of a mixed diol stream. The mixed diol stream comprising two-, three-, and four-carbon diols is separated into component diols by extraction with a hydrophobic solvent mixture. The diols recovered in the extractant may be removed from the extractant stream by back extraction with water or by distillation with an azeotrope-forming agent present, preferably an azeotroping agent already present in the extractant mixture.

    摘要翻译: 公开了一种纯化混合二醇流的方法。 包含二,三和四碳二醇的混合二醇料流通过用疏水溶剂混合物萃取分离成组分二醇。 在萃取剂中回收的二醇可以通过用水反萃取或用存在的共沸物形成剂,优选已经存在于萃取剂混合物中的共沸剂进行蒸馏,从萃取剂流中除去。