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21.发明申请公开(公告)号：US20110129735A1
公开(公告)日：2011-06-02
申请号：US12956667
申请日：2010-11-30
Applicant: Mai Yokoi , Yuu Takanashi , Masahide Miyake , Yasuyuki Kusumoto , Shigeki Matsuta , Shinnosuke Ichikawa
Inventor： Mai Yokoi , Yuu Takanashi , Masahide Miyake , Yasuyuki Kusumoto , Shigeki Matsuta , Shinnosuke Ichikawa
IPC: H01M4/485
CPC classification number: H01M4/485
Abstract: A method of manufacturing an active material for a non-aqueous electrolyte battery, the active material containing a lithium-containing vanadium oxide, is provided. The active material for a non-aqueous electrolyte battery is washed with water or an acidic aqueous solution. By dissolving pentavalent vanadium, which is toxic, in water or an acidic aqueous solution, the pentavalent vanadium can be removed from the active material.
Abstract translation: 提供一种制造非水电解质电池用活性物质的方法，含有含锂的氧化钒的活性物质。 用水或酸性水溶液洗涤非水电解质电池的活性物质。 通过将有毒的五价钒溶解在水或酸性水溶液中，可以从活性物质中除去五价钒。
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22.发明授权公开(公告)号：US07592099B2
公开(公告)日：2009-09-22
申请号：US10878965
申请日：2004-06-29
Applicant: Noriyuki Tamura , Yoshio Kato , Shigeki Matsuta , Maruo Kamino
Inventor： Noriyuki Tamura , Yoshio Kato , Shigeki Matsuta , Maruo Kamino
CPC classification number: H01M4/70 , H01M4/0438 , H01M4/0445 , H01M4/0452 , H01M4/134 , H01M4/362 , H01M4/387 , H01M4/40 , H01M4/405 , H01M4/661 , H01M10/052
Abstract: An electrode for a lithium secondary battery includes a thin film of an active material having a first phase that reacts with Li dominantly and a second phase that reacts less readily with Li than the first phase and exists at least before initial-cycle charging and after discharging in each cycle following the initial cycle. A surface of the current collector has an arithmetical mean roughness Ra of 0.1 μm or greater. A surface of the thin film has irregularities formed corresponding to the irregularities of the current collector surface. By the charging and discharging in the initial cycle and thereafter, gaps form along the thin-film thickness on lines connecting valleys in the thin-film surface irregularities and valleys in the current-collector surface irregularities, and the thin film is divided into columnar or insular structures by the gaps.
Abstract translation: 用于锂二次电池的电极包括具有与Li主要反应的第一相的活性材料的薄膜和与第一相不太容易与Li反应的第二相，并且至少在初始循环充电之前和放电后存在 在初始周期后的每个周期。 集电体的表面的算术平均粗糙度Ra为0.1μm以上。 薄膜的表面具有对应于集电体表面的凹凸形成的凹凸。 通过在初始循环中的充放电，此后，在与集电体表面凹凸不平的薄膜表面凹凸和谷中的谷连接的线上沿着薄膜厚度形成间隙，并将薄膜分为柱状或 岛屿上的空隙结构。
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23.发明申请METHOD FOR PRODUCING POSITIVE ELECTRODE FOR NON-AQUEOUS ELECTROLYTE SECONDARY CELL AND METHOD FOR PRODUCING NON-AQUEOUS ELECTROLYTE SECONDARY CELL 失效用于生产非水电解质二次电池的正电极的方法和用于生产非水电解质二次电池的方法公开(公告)号：US20090119908A1
公开(公告)日：2009-05-14
申请号：US12268706
申请日：2008-11-11
Applicant: Katsutoshi TAKEDA , Yoshio KATO , Shingo TODE , Masanori MAEKAWA , Shigeki MATSUTA
Inventor： Katsutoshi TAKEDA , Yoshio KATO , Shingo TODE , Masanori MAEKAWA , Shigeki MATSUTA
CPC classification number: C23C8/16 , C01G51/42 , C01G53/42 , C01G53/44 , C01P2002/52 , C01P2002/88 , C01P2006/40 , H01M4/131 , H01M4/525 , H01M10/052 , Y10T29/49108 , Y10T29/49115
Abstract: A method for producing with a high yield a high performance non-aqueous electrolyte secondary cell with a reduced cost is provided. The method includes the steps of: a baking step of baking a positive electrode active material precursor containing a lithium source and a nickel source in order to render the positive electrode active material precursor a lithium nickel composite oxide; a measuring step of measuring the amount of carbon dioxide gas occurring when the lithium nickel composite oxide is heated to 200° C. or higher and 1500° C. or lower in an inactive gas atmosphere; a selecting step of selecting a lithium nickel composite oxide satisfying the following formulas: y
Abstract translation: 提供了一种以高产率生产低成本的高性能非水电解质二次电池的方法。 该方法包括以下步骤：烘焙包含锂源和镍源的正极活性物质前体以使正极活性物质前体成为锂镍复合氧化物的烘烤步骤; 测量在惰性气体气氛中将锂镍复合氧化物加热至200℃以上且1500℃以下时发生的二氧化碳气体量的测定步骤; 选择满足下列公式的锂镍复合氧化物的选择步骤：<？in-line-formula description =“In-line formula”end =“lead”？> y <（0.27x-51）/ 1000000（200 < = x <400）公式1 <？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？ > y <57/1000000（400 <= x <= 1500）公式2 <？in-line-formula description =“In-line Formulas”end =“tail”？>其中x是加热温度（°C） 在测量步骤中，y是在测量步骤中测量的每1g所述锂镍复合氧化物的二氧化碳气体量（摩尔/ g） 以及通过使用主要由选择步骤中选择的锂镍复合氧化物的正极活性物质来完成正极的正极完成步骤。
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24.发明申请Method of producing active material for lithium secondary battery, method of producing electrode for lithium secondary battery, method of producing lithium secondary battery, and method of monitoring quality of active material for lithium secondary battery 有权锂二次电池用活性物质的制造方法，锂二次电池用电极的制造方法，锂二次电池的制造方法以及锂二次电池的活性物质的监测方法公开(公告)号：US20080222881A1
公开(公告)日：2008-09-18
申请号：US12071880
申请日：2008-02-27
Applicant: Denis Yau Wai Yu , Kazunori Donoue , Toshikazu Yoshida , Tetsuo Kadohata , Tetsuyuki Murata , Shigeki Matsuta
Inventor： Denis Yau Wai Yu , Kazunori Donoue , Toshikazu Yoshida , Tetsuo Kadohata , Tetsuyuki Murata , Shigeki Matsuta
CPC classification number: H01M4/04 , C01B25/45 , H01M4/5825 , H01M10/0525 , Y10T29/49108
Abstract: A method of producing an active material for a lithium secondary battery, by which impurities causing problems in synthesizing an active material for a lithium secondary battery, including a lithium transition metal oxyanion compound are removed efficiently and enhancement of an energy density is realized, is provided. By cleaning the active material for a lithium secondary battery, including a lithium transition metal oxyanion compound, with a pH buffer solution, for example, it is possible to efficiently remove just only impurities such as Li3PO4 or Li2CO3, or a substance, other than LiFePO4, in which the valence of Fe is bivalent such as FeSO4, FeO or Fe3(PO4)2 without dissolving Fe of LiFePO4.
Abstract translation: 提供一种生产用于锂二次电池的活性材料的方法，其中提供了有效地除去包含锂过渡金属氧阴离子化合物的锂二次电池的活性材料合成的问题的杂质并实现能量密度的提高 。 通过例如利用pH缓冲溶液清洗包含锂过渡金属氧阴离子化合物的锂二次电池的活性材料，可以仅仅有效地除去诸如Li 3 PO 3的杂质， 或者其中Fe的化合价为Fe 3+ 3以下的物质，或者LiFePO 4以外的物质，其中Fe的价数为 二价如FeSO 4，FeO或Fe 3（PO 4）2，而不溶解LiFePO的Fe 4 。
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25.发明授权公开(公告)号：US07241533B1
公开(公告)日：2007-07-10
申请号：US10111075
申请日：2000-10-20
Applicant: Hiroaki Ikeda , Masahisa Fujimoto , Shin Fujitani , Kenji Asaoka , Shigeki Matsuta , Yoichi Domoto , Ryuji Ohshita , Masaki Shima , Hiromasa Yagi , Hisaki Tarui , Hiroshi Kurokawa , Yoshio Kato , Hiroshi Nakajima , Toshikazu Yoshida
Inventor： Hiroaki Ikeda , Masahisa Fujimoto , Shin Fujitani , Kenji Asaoka , Shigeki Matsuta , Yoichi Domoto , Ryuji Ohshita , Masaki Shima , Hiromasa Yagi , Hisaki Tarui , Hiroshi Kurokawa , Yoshio Kato , Hiroshi Nakajima , Toshikazu Yoshida
CPC classification number: H01M4/661 , H01M2/0207 , H01M4/04 , H01M4/131 , H01M4/134 , H01M4/1395 , H01M4/366 , H01M4/38 , H01M4/386 , H01M4/40 , H01M4/405 , H01M4/485 , H01M4/525 , H01M4/58 , H01M4/667 , H01M4/70 , H01M6/40 , H01M10/052 , H01M10/0587 , H01M10/44 , H01M2010/4292
Abstract: An electrode for a rechargeable lithium battery characterized in that thin films of active material capable of lithium storage and release, i.e., microcrystalline or amorphous silicone thin films are deposited on opposite faces of a plate-form current collector.
Abstract translation: 一种用于可再充电锂电池的电极，其特征在于，在板形集电器的相对面上沉积能够储存和释放锂的活性材料的薄膜，即微晶或非晶硅薄膜。
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Patent Agency Ranking
公开(公告)号：US20060222944A1
公开(公告)日：2006-10-05
申请号：US11385836
申请日：2006-03-22
Applicant: Hidekazu Yamamoto , Keiji Saisho , Yoshio Kato , Shigeki Matsuta
Inventor： Hidekazu Yamamoto , Keiji Saisho , Yoshio Kato , Shigeki Matsuta
CPC classification number: H01M10/052 , H01M2/16 , H01M2/1673 , H01M2/1686 , H01M4/0426 , H01M4/13 , H01M4/131 , H01M4/134 , H01M4/1391 , H01M4/1395 , H01M4/386 , H01M4/62 , H01M10/0567
Abstract: Disclosed is a nonaqueous electrolyte secondary battery which has a negative electrode containing silicon as a negative active material, a positive electrode containing a positive active material, a nonaqueous electrolyte and a separator. Characteristically, an additive which retards oxidation of silicon during operation of the battery is contained either in an interior or surface portion of the positive electrode, or in an interior or surface portion of the negative electrode, or in an interior or surface portion of the separator.
Abstract translation: 公开了一种非水电解质二次电池，其具有含有硅作为负极活性物质的负极，含有正极活性物质的正极，非水电解质和隔膜。 特征在于，在电池操作期间阻止硅的氧化的添加剂包含在正极的内部或表面部分中，或者包含在负极的内部或表面部分中，或者包含在隔板的内部或表面部分中 。
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公开(公告)号：US06579917B1
公开(公告)日：2003-06-17
申请号：US09511365
申请日：2000-02-23
Applicant: Yoshiaki Noguchi , Katsuhiro Shibata , Shigeki Matsuta
Inventor： Yoshiaki Noguchi , Katsuhiro Shibata , Shigeki Matsuta
IPC: B29C3508
CPC classification number: G03F7/0037 , B29C64/135 , B29K2995/0073 , B33Y40/00 , C08L75/16
Abstract: A surface treatment agent for a model according to this invention can improve finish of a surface treatment for a model and can shorten time necessary for finish. The surface treatment agent is used for filling stair-steppings on a model surface, mainly comprising base resin which is cured by physical action and microparticles which have good wettability to the base resin and have a particle diameter equal to or smaller than the stair-stepping.
Abstract translation: 根据本发明的用于模型的表面处理剂可以改善模型的表面处理的光洁度并且可以缩短整理所需的时间。 表面处理剂用于在模型表面上填充楼梯步进，主要包括通过物理作用固化的基础树脂和对基础树脂具有良好润湿性并且具有等于或小于阶梯步长的粒径的微粒 。
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28.发明授权公开(公告)号：US08852769B2
公开(公告)日：2014-10-07
申请号：US13279452
申请日：2011-10-24
Applicant: Masahiro Iyori , Hirofusa Tanaka , Naoki Terada , Seiji Omura , Yasuhiro Yamauchi , Toshiyuki Nohma , Masahide Miyake , Yasuyuki Kusumoto , Shigeki Matsuta , Toyoki Fujihara , Takeshi Yoshida
Inventor： Masahiro Iyori , Hirofusa Tanaka , Naoki Terada , Seiji Omura , Yasuhiro Yamauchi , Toshiyuki Nohma , Masahide Miyake , Yasuyuki Kusumoto , Shigeki Matsuta , Toyoki Fujihara , Takeshi Yoshida
IPC: H01M2/00 , H01M2/26 , H01M10/42 , H01M10/04 , H01M2/34 , H01M10/052 , H01M10/0587
CPC classification number: H01M2/263 , H01M2/345 , H01M10/0431 , H01M10/052 , H01M10/0587 , H01M10/4235 , H01M2200/20 , Y02E60/12 , Y02T10/7011 , Y10T29/49108 , Y10T29/49115
Abstract: A nonaqueous secondary battery includes a current cutoff mechanism that cuts off a current in a short period of time in response to a rise in pressure inside a battery outer body in at least one of a conductive path through which a current is taken out from a positive electrode plate to outside of the battery and a conductive path through which a current is taken out from a negative electrode plate to outside of the battery. At least one type selected from an oligomer containing a cyclohexyl group and a phenyl group, a modified product of the oligomer containing a cyclohexyl group and a phenyl group, a polymer containing a cyclohexyl group and a phenyl group, and a modified product of the polymer containing a cyclohexyl group and a phenyl group is present on the surface of the positive electrode plate.
Abstract translation: 非水二次电池包括电流切断机构，该电流切断机构响应于电池外体中的至少一个导电路径中的压力升高而在短时间内截止电流，电流从正极 电极板到电池外部，以及导电路径，电流从负极板取出到电池外部。 选自包含环己基和苯基的低聚物中的至少一种，包含环己基和苯基的低聚物的改性产物，含有环己基和苯基的聚合物，以及聚合物的改性产物 含有环己基和苯基存在于正极板的表面上。
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29.发明授权公开(公告)号：US08388703B2
公开(公告)日：2013-03-05
申请号：US13469747
申请日：2012-05-11
Applicant: Katsutoshi Takeda , Yoshio Kato , Shingo Tode , Masanori Maekawa , Shigeki Matsuta
Inventor： Katsutoshi Takeda , Yoshio Kato , Shingo Tode , Masanori Maekawa , Shigeki Matsuta
IPC: H01M4/525
CPC classification number: C23C8/16 , C01G51/42 , C01G53/42 , C01G53/44 , C01P2002/52 , C01P2002/88 , C01P2006/40 , H01M4/131 , H01M4/525 , H01M10/052 , Y10T29/49108 , Y10T29/49115
Abstract: A method for producing a non-aqueous electrolyte secondary cell by preparing a positive electrode by applying a positive electrode mixture onto a positive electrode core material, the mixture containing a positive electrode active material mainly made of a lithium nickel composite oxide and a binding agent containing polyvinylidene fluoride; measuring the amount of carbon dioxide gas generated when a layer of the positive electrode mixture is removed out of the positive electrode and the layer is heated to 200° C. or higher and 400° C. or lower in an inactive gas atmosphere; selecting a positive electrode satisfying the following formulas: y
Abstract translation: 一种通过在正极芯材上涂布正极合剂制备正极来制造非水电解质二次电池的方法，该混合物含有主要由锂镍复合氧化物制成的正极活性物质和含有 聚偏氟乙烯; 测量当正极混合物层从正极中除去并且在惰性气体气氛中将层加热至200℃以上且400℃以下时产生的二氧化碳气体的量; 选择满足以下公式的正极：y <（0.27x-51）/ 1000000（200＆nlE; x <400）式1 y <57/1000000（400＆nlE; x＆nlE; 1500）式2其中x是加热温度 C.），y是测量每1g镍镍复合氧化物的二氧化碳气体量（摩尔/ g）; 并通过使用所选择的正极制备非水电解质二次电池。
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30.发明申请NONAQUEOUS ELECTROLYTE SECONDARY BATTERY INCLUDING A NEGATIVE ELECTRODE CONTAINING SILICON AND AN ADDITIVE WHICH RETARDS OXIDATION OF SILICON DURING BATTERY OPERATION 审中-公开非电解电解质二次电池，其中包含含有硅的负极和在电池运行期间返回硅氧化的添加剂公开(公告)号：US20130004837A1
公开(公告)日：2013-01-03
申请号：US13607186
申请日：2012-09-07
Applicant: Hidekazu YAMAMOTO , Keiji SAISHO , Yoshio KATO , Shigeki MATSUTA
Inventor： Hidekazu YAMAMOTO , Keiji SAISHO , Yoshio KATO , Shigeki MATSUTA
IPC: H01M4/62 , H01M10/056
CPC classification number: H01M10/052 , H01M2/16 , H01M2/1673 , H01M2/1686 , H01M4/0426 , H01M4/13 , H01M4/131 , H01M4/134 , H01M4/1391 , H01M4/1395 , H01M4/386 , H01M4/62 , H01M10/0567
Abstract: Disclosed is a nonaqueous electrolyte secondary battery which has a negative electrode containing silicon as a negative active material, a positive electrode containing a positive active material, a nonaqueous electrolyte and a separator. Characteristically, an additive which retards oxidation of silicon during operation of the battery is contained either in an interior or surface portion of the positive electrode, in an interior or surface portion of the negative electrode, or in an interior or surface portion of the separator.
Abstract translation: 公开了一种非水电解质二次电池，其具有含有硅作为负极活性物质的负极，含有正极活性物质的正极，非水电解质和隔膜。 特征在于，在电池操作期间阻止硅的氧化的添加剂包含在正极的内部或表面部分，负极的内部或表面部分中，或者包含在隔板的内部或表面部分中。
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