ZINC-CONTAINING ZEOLITE WITH IFR FRAMEWORK TOPOLOGY
    25.
    发明申请
    ZINC-CONTAINING ZEOLITE WITH IFR FRAMEWORK TOPOLOGY 有权
    含有ZINC的ZEOLITE与IFR框架拓扑

    公开(公告)号:US20070292343A1

    公开(公告)日:2007-12-20

    申请号:US11759849

    申请日:2007-06-07

    申请人: Cong-Yan Chen

    发明人: Cong-Yan Chen

    IPC分类号: C01B39/00 C01B39/02 C01B39/04

    摘要: A process is disclosed for preparing a zinc-containing molecular sieve having IFR framework topology and having zinc atoms in its crystal framework, said process comprising: (a) preparing an aqueous mixture containing sources of silicon oxide, zinc oxide, an alkali metal, and an N-benzyl-1,4-diazabicyclo[2.2.2]octane cation having an anionic counterion which is not detrimental to the formation of the molecular sieve; and (b) maintaining the aqueous mixture under conditions sufficient to form crystals of the molecular sieves

    摘要翻译: 公开了一种制备具有IFR骨架拓扑并在其晶体框架中具有锌原子的含锌分子筛的方法,所述方法包括:(a)制备含有氧化硅,氧化锌,碱金属和 具有不影响分子筛形成的阴离子抗衡离子的N-苄基-1,4-二氮杂双环[2.2.2]辛烷阳离子; 和(b)在足以形成分子筛晶体的条件下保持含水混合物

    Method for heteroatom lattice substitution in large and extra-large pore borosilicate zeolites
    29.
    发明授权
    Method for heteroatom lattice substitution in large and extra-large pore borosilicate zeolites 有权
    大孔和超大孔硼硅酸盐沸石中杂原子晶格取代的方法

    公开(公告)号:US06468501B1

    公开(公告)日:2002-10-22

    申请号:US09662119

    申请日:2000-09-14

    IPC分类号: C01B3906

    CPC分类号: B01J29/86 C01B39/026

    摘要: The present invention provides a method for preparing a zeolite having lattice substituted heteroatoms. The method includes: (a) contacting a calcined borosilicate zeolite with an acid, thereby producing an at least partially deboronated zeolite; and (b) contacting the at least partially deboronated zeolite with a salt-containing aqueous solution comprising one or more salts selected from the group consisting of aluminum salt, gallium salt, and iron salt, thereby producing a silicate or borosilicate zeolite having a lattice comprising aluminum atoms; gallium atoms, iron atoms or a combination thereof. Step (b) is conducted at a pH of about 3.5 or less. Preferably, step (a), step (b) or both are conducted at a temperature of from about ambient temperature to about 300° C., preferably, under stirring/tumbling.

    摘要翻译: 本发明提供了制备具有晶格取代的杂原子的沸石的方法。 该方法包括:(a)使焙烧的硼硅酸盐沸石与酸接触,从而产生至少部分脱硼的沸石; 和(b)使所述至少部分脱硼的沸石与含有选自铝盐,镓盐和铁盐的一种或多种盐的含盐水溶液接触,从而制备具有晶格的硅酸盐或硼硅酸盐沸石, 铝原子; 镓原子,铁原子或其组合。 步骤(b)在约3.5或更低的pH下进行。 优选地,步骤(a),步骤(b)或两者都在约环境温度至约300℃的温度下进行,优选在搅拌/翻转下进行。

    Zeolite Me-UTD-1
    30.
    发明授权
    Zeolite Me-UTD-1 失效
    沸石Me-UTD-1

    公开(公告)号:US6103215A

    公开(公告)日:2000-08-15

    申请号:US870615

    申请日:1997-06-06

    摘要: An aluminosilicate zeolite is disclosed which has a silica/alumina mole ratio of about 500 or less and pores with at least one cross-sectional dimension greater than 7.5 Angstroms. Also disclosed is a zeolite comprising a first oxide selected from the group consisting of silicon oxide, germanium oxide and mixtures thereof and a second oxide selected from the group consisting of aluminum oxide, gallium oxide, iron oxide, indium oxide and mixtures of aluminum oxide, boron oxide, gallium oxide, iron oxide, indium oxide, titanium oxide, and vanadium oxide, the zeolite having, after calcination, the X-ray diffraction lines of Table I, and having a mole ratio of the first oxide to the second oxide of about 500 or less. The zeolites are useful in catalysts for hydrocarbon conversion reactions.

    摘要翻译: 公开了一种铝硅酸盐沸石,其具有约500或更小的二氧化硅/氧化铝摩尔比和具有至少一个横截面尺寸大于7.5埃的孔。 还公开了一种沸石,其包含选自氧化硅,氧化锗及其混合物的第一氧化物和选自氧化铝,氧化镓,氧化铁,氧化铟和氧化铝的混合物的第二氧化物, 氧化硼,氧化铜,氧化铁,氧化铟,氧化钛和氧化钒,沸石在煅烧后具有表Ⅰ的X射线衍射线,并且具有第一氧化物与第二氧化物的摩尔比 约500以下。 沸石可用于烃转化反应的催化剂。