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43 条记录 (耗时 0.034 秒)

    Amine organoborane complex polymerization initiators and polymerizable compositions
    21.
    发明授权
    Amine organoborane complex polymerization initiators and polymerizable compositions 失效
    胺有机硼烷络合物聚合引发剂和可聚合组合物

    公开(公告)号：US06713578B2

    公开(公告)日：2004-03-30

    申请号：US09881985

    申请日：2001-06-15

    申请人： Mark F. Sonnenschein ,  Steven P. Webb ,  Nelson G. Rondan

    发明人： Mark F. Sonnenschein ,  Steven P. Webb ,  Nelson G. Rondan

    IPC分类号： C08F452

    CPC分类号： C08F4/52 ,  C07F5/027 ,  C09J4/06 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31909 ,  C08F265/06

    摘要： A method of bonding two or more substrates together which comprises I. contacting the components of the composition comprising a) an organoborane/amine complex wherein the amine is selected from the group of amines having an amidine structural component; aliphatic heterocycles having at least one nitrogen in the heterocyclic ring; an alicyclic compound having bound to the ring a substituent having an amine moiety; primary amines which in addition to a primary amine have one or more hydrogen bond accepting groups of an ether, polyether, thioether or halogen wherein there is an alkylene chain of at least two carbon atoms between the primary amine and the hydrogen bond accepting group, and conjugated imines; b) one or more of monomers, oligomers or polymers having olefinic unsaturation; and, c) optionally an effective amount of a compound which causes the complex to disassociate or heating the composition to a temperature at which the complex dissassociates; II. contacting the adhesive composition with the two or more substrates; III. positioning the two or more substrates such that the adhesive composition is located between them; and IV. allowing the adhesive to cure so as to bind the two or more substrates together.

    摘要翻译： 将两个或更多个基板结合在一起的方法，其包括I。 使包含a）有机硼烷/胺络合物的组合物的组分接触，其中胺选自具有脒结构组分的胺类; 在杂环中具有至少一个氮的脂族杂环; 与环结合的具有胺部分的取代基的脂环化合物; 除伯胺之外的伯胺具有一个或多个醚，聚醚，硫醚或卤素的氢键接受基团，其中在伯胺和氢键接受基团之间存在至少两个碳原子的亚烷基链，以及 共轭亚胺; b）一种或多种具有烯属不饱和键的单体，低聚物或聚合物; 和c）任选地有效量的使复合物将组合物解离或加热至复合物不凝结的温度的化合物; II。 使粘合剂组合物与两种或更多种基材接触; III。 定位两个或更多个基板，使得粘合剂组合物位于它们之间; 和IV。 使粘合剂固化，从而将两个或多个基底结合在一起。

    Blends of polysulfone with diaryl fluorene carbonate polymer
    22.
    发明授权
    Blends of polysulfone with diaryl fluorene carbonate polymer 失效
    聚砜与二芳基芴碳酸酯聚合物的共混物

    公开(公告)号：US5633331A

    公开(公告)日：1997-05-27

    申请号：US641984

    申请日：1996-05-02

    申请人： Kevin L. Nichols ,  Paul J. Moses ,  Mark F. Sonnenschein ,  Deborah E. Plaver

    发明人： Kevin L. Nichols ,  Paul J. Moses ,  Mark F. Sonnenschein ,  Deborah E. Plaver

    IPC分类号： C08L69/00 ,  C08L81/06

    CPC分类号： C08L69/00 ,  C08L81/06

    摘要： Polymer blend compositions are prepared having excellent combinations of optical properties, physical properties and hydrolytic stability comprising, in admixture, (a) a diaryl fluorene carbonate polymer and (b) a polysulfone. Preferably, the diaryl carbonate polymer is a copolycarbonate of bisphenol A with bis(hydroxyphenyl) fluorene, preferably 9,9-bis(4-hydroxyphenyl) fluorene. Optionally, the blend compositions also comprise a second non-fluorene carbonate polymer (c). Preferably, the polysulfone is a bisphenol A polysulfone or a polyether poly sulfone. In preferred aspects of this invention, the polysulfone and diaryl carbonate polymer components are selected to provide a transparent blend composition.

    摘要翻译： 制备具有优异的光学性质，物理性质和水解稳定性组合的聚合物共混组合物，其包含（a）二芳基芴碳酸酯聚合物和（b）聚砜。 优选地，碳酸二芳酯聚合物是双酚A与双（羟基苯基）芴的共聚碳酸酯，优选9,9-双（4-羟基苯基）芴。 任选地，共混组合物还包含第二非芴碳酸酯聚合物（c）。 优选地，聚砜是双酚A聚砜或聚醚聚砜。 在本发明的优选方面，选择聚砜和碳酸二芳酯聚合物组分以提供透明的共混组合物。

    Process of three dimensional lithography in amorphous polymers
    24.
    发明授权
    Process of three dimensional lithography in amorphous polymers 失效
    无定形聚合物三维光刻工艺

    公开(公告)号：US5043251A

    公开(公告)日：1991-08-27

    申请号：US442815

    申请日：1989-11-29

    申请人： Mark F. Sonnenschein ,  Charles M. Roland

    发明人： Mark F. Sonnenschein ,  Charles M. Roland

    IPC分类号： G03F7/039 ,  G03F7/20 ,  G11B7/244 ,  G11B7/26

    CPC分类号： G11B7/245 ,  G03F7/039 ,  G03F7/20 ,  G11B7/26 ,  Y10S430/145 ,  Y10S430/146

    摘要： A process of three dimensional lithography in amorphous polymers to form an instantaneous, permanent image in the polymer by the steps of providing an undoped, non-crystalline layer or film of a polymer having a stable amorphous state under human operating conditions. The film is preferably poly(ethyleneterphthalate) (PET), poly(aryl-ether-ether-ketone) (PEEK), poly(chloro-trifluoroethylene) (Kel-F.RTM.), poly(carbonate) (ie LEXAN 9032.RTM.), poly(sulfone), poly(methylmethacrylate(PMMA, or LUCITE.RTM.), a poly(cyanurate) such as bisphenol A dicyanate, or an epoxy (eg. Epon 820.RTM.). The film can be either self supporting or mounted on a substrate. The film is then covered (and optionally contacted) with a mask which serves to block the radiation from impinging on where no marking is desired. If the mask is in actual contact with the film, it is capable of also acting as a heat sink. Next, the film is exposed through the mask to radiation of sufficient intensity to cause ablation of the exposed areas imparting a distinct, three-dimensional impression in the film. The film may then, for example, be processed by metalization and coating with a protective layer to form a finished product of an optical data storage disk.

    摘要翻译： 在无定形聚合物中的三维平版印刷方法，通过在人类操作条件下提供具有稳定非晶状态的聚合物的未掺杂的非结晶层或膜的步骤，在聚合物中形成瞬时，永久的图像。 该膜优选为聚（邻苯二甲酸乙二醇酯）（PET），聚（芳基醚 - 醚 - 酮）（PEEK），聚（氯 - 三氟乙烯）（Kel-F TM），聚（碳酸酯）（即LEXAN 9032 TM） 聚（砜），聚甲基丙烯酸甲酯（PMMA或LUCITE TM），聚（氰尿酸酯）如双酚A二氰酸酯或环氧树脂（例如Epon 820 TM），该膜可以是自支撑的或安装在基材上 然后将膜覆盖（并任选地接触）与掩模，该掩模用于阻挡辐射照射到不需要标记的地方，如果掩模实际上与膜接触，则其也能够用作散热片 接下来，通过掩模将膜暴露于足够强度的辐射下，使曝光区域的消融在膜中赋予明显的三维印象，然后可以例如通过金属化和涂覆 保护层以形成光学数据存储盘的成品。

    Amine organoborane complex polymerization initiators and polymerizable compositions
    29.
    发明授权
    Amine organoborane complex polymerization initiators and polymerizable compositions 失效
    胺有机硼烷络合物聚合引发剂和可聚合组合物

    公开(公告)号：US06806330B1

    公开(公告)日：2004-10-19

    申请号：US09466321

    申请日：1999-12-17

    申请人： Mark F. Sonnenschein ,  Steven P. Webb ,  Nelson G. Rondan

    发明人： Mark F. Sonnenschein ,  Steven P. Webb ,  Nelson G. Rondan

    IPC分类号： C08F452

    CPC分类号： C08F4/52 ,  C07F5/027 ,  C09J4/06 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31909 ,  C08F265/06

    摘要： The invention is an amine-organoborane complex wherein the organoborane is a trialkyl borane and the amine is an amine having an amidine structural component; an aliphatic heterocycle having at least one nitrogen in the heterocyclic ring wherein the heterocyclic compound may also contain one or more nitrogen atoms, oxygen atoms, sulfur atoms, or double bonds in the heterocycle; a primary amine which in addition has one or more hydrogen bond accepting groups wherein there is at least two carbon atoms, preferably three, between the primary amine and the hydrogen bond accepting group, such that due to inter- or intramolecular interactions within the complex the strength of the B—N bond is increased; or a conjugated imine. Preferred hydrogen bond accepting groups include the following: a secondary amine, a tertiary amine, an ether, a halogen, a polyether group or a polyamine group. The complexes of the invention are used in polymerizable compositions, adhesive compositions and coatings compositions containing compounds having moieties which polymerize under free radical polymerization conditions.

    摘要翻译： 本发明是胺有机硼烷络合物，其中有机硼烷是三烷基硼烷，胺是具有脒结构成分的胺; 在杂环中具有至少一个氮的脂族杂环，杂环化合物还可以在杂环中含有一个或多个氮原子，氧原子，硫原子或双键; 伯胺还具有一个或多个氢键接受基团，其中在伯胺和氢键接受基团之间存在至少两个碳原子，优选三个，使得由于络合物内的分子间或分子内相互作用 国债的实力增加; 或共轭亚胺。 优选的氢键接受基团包括：仲胺，叔胺，醚，卤素，聚醚基团或多胺基团。本发明的络合物用于可聚合组合物，粘合剂组合物和包含化合物的涂料组合物中， 在自由基聚合条件下聚合的部分。

    Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components
    30.
    发明授权
    Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components 失效
    胺有机硼烷络合物引发含有硅氧烷可聚合组分的可聚合组合物

    公开(公告)号：US06777512B1

    公开(公告)日：2004-08-17

    申请号：US10377440

    申请日：2003-02-28

    申请人： Mark F. Sonnenschein ,  Steven P. Webb ,  Benjamin L. Wendt ,  Daniel R. Harrington

    发明人： Mark F. Sonnenschein ,  Steven P. Webb ,  Benjamin L. Wendt ,  Daniel R. Harrington

    IPC分类号： C08F452

    CPC分类号： C08L83/04 ,  C08G77/00 ,  C08G77/045 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/20 ,  C08K5/55 ,  C09J4/00 ,  C08L83/00

    摘要： In one embodiment the invention is a polymerizable composition comprising a) an organoborane amine complex; b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization; c) one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization; and d) a catalyst for the polymerization of the one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization. This composition may further comprise a compound which causes the organoborane amine complex to disassociate. In a preferred embodiment, the two part composition further comprises a compound which is reactive with both the b) one or more of monomers, oligomers or polymers having olefinic unsaturation which is capable of polymerization by free radical polymerization; and the c) one or more compounds, oligomers or prepolymers having a siloxane backbone and reactive moieties capable of polymerization. This composition can be polymerized by contacting the two parts of the composition. In another embodiment the invention is an organoborane amine complex comprising an alkyl borane having ligands which are alkyl, cycloalkyl or both and an amino siloxane.

    摘要翻译： 在一个实施方案中，本发明是一种可聚合组合物，其包含a）有机硼烷胺络合物; b）一种或多种能够通过自由基聚合聚合的具有烯属不饱和键的单体，低聚物或聚合物; c）一种或多种具有硅氧烷主链和能聚合的反应性部分的化合物，低聚物或预聚物; 和d）用于聚合具有硅氧烷骨架的一种或多种化合物，低聚物或预聚物和能聚合的反应性部分的催化剂。 该组合物还可以包含使有机硼烷胺络合物脱离的化合物。 在优选的实施方案中，两部分组合物还包含与b）一种或多种具有烯属不饱和键的能够通过自由基聚合聚合的单体，低聚物或聚合物反应的化合物; 和c）一种或多种具有硅氧烷主链和能聚合的反应性部分的化合物，低聚物或预聚物。 该组合物可以通过使组合物的两个部分接触来聚合。 在另一个实施方案中，本发明是一种有机硼烷胺络合物，其包含具有烷基，环烷基或两者的氨基硅氧烷的配体的烷基硼烷。