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公开(公告)号：US06334948B1
公开(公告)日：2002-01-01
申请号：US09443152
申请日：1999-11-18
申请人： Blaise Didillon , Denis Uzio , Jean-Luc Nocca , Jean Cosyns
发明人： Blaise Didillon , Denis Uzio , Jean-Luc Nocca , Jean Cosyns
IPC分类号： C10G4506
CPC分类号： C10G65/16
摘要： A process for producing a gasoline with a low sulphur content comprises: separating a sulphur-containing gasoline into a light fraction and a heavy fraction, hydrodesulphurising the light gasoline on a nickel-based catalyst, hydrodesulphurising the heavy fraction on a catalyst comprising at least one group VIII metal and/or at least one group VIB metal, and mixing the desulphurised fractions.
摘要翻译： 一种生产低硫含量的汽油的方法包括：将含硫汽油分离成轻馏分和重馏分，将轻汽油加氢脱硫在镍基催化剂上，对重馏分进行加氢脱硫，所述催化剂包含至少一种 VIII族金属和/或至少一种VIB族金属，并混合脱硫馏分。
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公开(公告)号：US06197721B1
公开(公告)日：2001-03-06
申请号：US09143113
申请日：1998-08-28
申请人： Blaise Didillon , Denis Uzio , Maryline Delage
发明人： Blaise Didillon , Denis Uzio , Maryline Delage
IPC分类号： B01J2340
CPC分类号： C10G45/46 , B01J23/40 , B01J23/58 , B01J35/002 , B01J35/1019 , B01J35/1047 , C10G45/34 , C10G69/06
摘要： A novel catalyst for transforming organic compounds is described. The catalyst is composed of a support selected from refractory oxides such as aluminas, silicas, silica-aluminas or magnesia, used alone or as a mixture, a group VIII metal such as palladium, associated or not associated with another metal, said catalyst being such that the volume of chemisorbed carbon monoxide is greater than or equal to 180 cm3 per gram of metal and has a programmed temperature reduction profile comprising a single hydrogen consumption peak.
摘要翻译： 描述了一种用于转化有机化合物的新型催化剂。 催化剂由选自耐火氧化物如氧化铝，二氧化硅，二氧化硅 - 氧化铝或氧化镁的载体组成，单独或作为混合物使用，与另一种金属缔合或不相关的第Ⅷ族金属如钯，所述催化剂为 化学吸附一氧化碳的体积大于或等于180cm 3 / g金属，并且具有包括单个氢消耗峰值的程序温度降低曲线。
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23.发明授权公开(公告)号：US08652321B2
公开(公告)日：2014-02-18
申请号：US12791492
申请日：2010-06-01
IPC分类号： C10G65/12
CPC分类号： C10G67/08 , C10G65/06 , C10G2400/02
摘要： Production of gasolines with low sulfur contents from a starting gasoline containing sulfur-containing compounds comprising a stage a) for selective hydrogenation of non-aromatic polyunsaturated compounds present in the starting gasoline, a stage b) for increasing the molecular weight of the light sulfur-containing products that are initially present in the gasoline that enters this stage, a stage c) for alkylation of at least a portion of the sulfur-containing compounds present in the product that originates from stage b), a stage d) for fractionation of the gasoline that originates from stage c) into at least two fractions, one fraction virtually lacking in sulfur-containing compounds, whereby the other contains a larger proportion of sulfur-containing compounds (heavy gasoline), a stage e) for catalytic treatment of the heavy gasoline for transformation of sulfur-containing compounds under conditions for the at least partial decomposition of hydrogenation of these sulfur-containing compounds.
摘要翻译： 从含有硫化合物的起始汽油中制备含硫低的汽油，包括a）用于选择氢化存在于起始汽油中的非芳族多不饱和化合物的步骤，b）用于提高轻质硫化物的分子量， 最初存在于进入该阶段的汽油中的含有产物，c）用于烷基化存在于产物中的步骤b）中的至少一部分含硫化合物的阶段d），用于分馏 起始于阶段c）的汽油至少有两个馏分，一个实际上不含硫化合物的馏分，另一个馏分含有较大比例的含硫化合物（重汽油），e）用于催化处理重质 用于在含硫化合物的至少部分分解氢化的条件下转化含硫化合物的汽油 化合物。
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公开(公告)号：US08071655B2
公开(公告)日：2011-12-06
申请号：US11721923
申请日：2005-11-17
CPC分类号： B01J21/12 , B01J23/005 , B01J23/462 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8913 , B01J29/405 , B01J29/7049 , B01J29/7088 , B01J29/7092 , B01J29/90 , B01J37/08 , C10G2/332 , Y10S502/524
摘要： A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM′(1−x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.
摘要翻译： 一种适用于合成气转化尤其是ET淤浆法的催化剂，所述催化剂包括：a）至少含有式M x M'（1-x）Al 2 O 4 / Al 2 O 3 -SiO 2的混合尖晶石结构的第一铝酸盐元素的载体， 并且不包括0和1，或者简单的尖晶石结构式为MA1204 / Al2O3.SiO2，所述载体在至少部分氧化的气氛中在850℃和900℃之间的温度下煅烧，和b） 活性相沉积在所述载体上，其含有一种或多种选自钴，镍，钌或铁的第VIII族金属。 所述催化剂用于固定床或悬浮在三相反应器中，用于从CO，H 2混合物合成碳氢化合物。
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公开(公告)号：US20100029792A1
公开(公告)日：2010-02-04
申请号：US11721923
申请日：2005-11-17
CPC分类号： B01J21/12 , B01J23/005 , B01J23/462 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8913 , B01J29/405 , B01J29/7049 , B01J29/7088 , B01J29/7092 , B01J29/90 , B01J37/08 , C10G2/332 , Y10S502/524
摘要： The invention relates to a catalyst which can be applied to a method for converting synthesis gas, said catalyst comprising: a) a support made of a solid solution containing at least one first aluminate element with a mixed spinel structure of formula MxM′(1-X)AI2O4/AI203.SiO2, x ranging from 0 to 1 being excluded, or a simple spinel structure of formula MAI2O4/AI2O3 SiO2, wherein the support is calcinated in an at least partially oxidizing atmosphere at a temperature ranging from 850° C. to 900° C., b) an active phase which is deposited on the support which contains one or several metals of group VIII, selected from amongst cobalt, nickel, ruthenium or iron. The catalyst is used in a fixed bed or in a suspension in a triphasic reactor for the synthesis of hydrocarbons from a CO, H2 mixture.
摘要翻译： 本发明涉及可用于转化合成气的方法的催化剂，所述催化剂包括：a）由含有至少一种第一铝酸盐元素与具有式MxM'（1- X）Al 2 O 4 / Al 2 O 3·Si 2 O 2，排除0至1的x，或式MAI 2 O 4 / Al 2 O 3 SiO 2的简单尖晶石结构，其中载体在至少部分氧化气氛中在850℃的温度下煅烧。 至900℃，b）沉积在载体上的活性相，其含有一种或几种选自钴，镍，钌或铁的VIII族金属。 该催化剂用于固定床或三相反应器中用于从CO，H 2混合物合成烃的悬浮液中。
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26.发明授权Method for selective hydrogenation of polyunsaturated compounds into monounsaturated compounds using a homogeneous catalyst 有权使用均相催化剂将多不饱和化合物选择性氢化成单不饱和化合物的方法公开(公告)号：US07612245B2
公开(公告)日：2009-11-03
申请号：US10519355
申请日：2003-06-16
申请人： Gerard Hillion , Laurent Savary , David Proriol , Christophe Gautreau , Denis Uzio , Helene Olivier-Bourbigou
发明人： Gerard Hillion , Laurent Savary , David Proriol , Christophe Gautreau , Denis Uzio , Helene Olivier-Bourbigou
CPC分类号： B01J35/10 , B01J31/0234 , B01J31/18 , B01J31/2204 , C10G45/34 , C10G45/36 , C10G45/40
摘要： A process for the selective hydrogenation of diolefinic compounds to mono-olefinic compounds uses a catalyst composition comprising at least one salt of a transition metal from groups IB, IIB, VB, VIB, VIIB and VIII of the periodic table, at least one ligand and at least one organometallic reducing agent, optionally in the presence of a non-aqueous ionic liquid selected from the group formed by liquid salts with general formula Q+A− (in which Q+ represents a quaternary ammonium and/or quaternary phosphonium and A− represents any anion which can form a liquid salt below 90° C.).
摘要翻译： 将二烯化合物选择性氢化成单烯烃化合物的方法使用包含至少一种元素周期表中IB，IIB，VB，VIB，VIIB和VIII族的过渡金属盐的至少一种盐的催化剂组合物，至少一种配体和 至少一种有机金属还原剂，任选地在选自由通式Q + A-的液体盐形成的基团（其中Q +表示季铵和/或季鏻和A-代表）的非水性离子液体存在下 任何可在90℃以下形成液态盐的阴离子）。
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27.发明申请Platinum-based, bimetallic catalyst, and a second group VIII metal used for the opening of cyclic compounds 失效铂金双金属催化剂和用于开环的化合物的第二族Ⅷ族金属公开(公告)号：US20080207437A1
公开(公告)日：2008-08-28
申请号：US11979637
申请日：2007-11-06
申请人： Gil Mabilon , Patrice Marecot , Denis Uzio , Catherine Especel , Florence Epron
发明人： Gil Mabilon , Patrice Marecot , Denis Uzio , Catherine Especel , Florence Epron
CPC分类号： B01J23/42 , B01J21/04 , B01J23/464 , B01J23/89 , B01J37/0205 , B01J37/06 , B01J37/16 , C07C5/31 , C07C2521/04 , C07C2523/42 , C07C2523/46 , C07C2527/13 , C10G45/62 , C07C9/14
摘要： A description is given of a catalyst comprising at least one porous support, at least some platinum, and at least a second group VIII metal which is different from platinum and iridium, said catalyst having been prepared in accordance with a process comprising a) impregnation of the support with at least one solution containing a platinum precursor, b) activation in a neutral or oxidising atmosphere, at a temperature of between 120 and 800° C., c) activation in a reducing medium, at a temperature of between 0 and 800° C., d1) impregnation with an aqueous solution and d2) treatment with at least one hydrogen donor compound, at a temperature of less than 200° C., e) the impregnation of the support, which has already been impregnated with the platinum, with at least one solution containing a precursor of said second group VIII metal, and f) activation in a neutral, reducing, or oxidising atmosphere, at a temperature of between 100 and 800° C.
摘要翻译： 给出了包含至少一种多孔载体，至少一些铂和至少一种与铂和铱不同的第Ⅷ族金属的催化剂的描述，所述催化剂是按照以下方法制备的：a）将 含有至少一种含有铂前体的溶液的载体，b）在中性或氧化性气氛中在120〜800℃的温度下活化，c）在还原介质中在0〜800℃的温度下进行活化 ℃），d1）用水溶液浸渍，和d2）在低于200℃的温度下用至少一种氢供体化合物处理，e）已经浸渍有铂的载体的浸渍 与至少一种含有所述第二族VIII族金属的前体的溶液，和f）在中性，还原性或氧化性气氛中在100至800℃的温度下活化。
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28.发明授权公开(公告)号：US07347931B2
公开(公告)日：2008-03-25
申请号：US10765840
申请日：2004-01-29
CPC分类号： B01J23/74 , B01J21/04 , B01J23/24 , B01J23/755 , B01J23/85 , B01J23/882 , B01J35/1019 , B01J35/1047 , B01J37/0203 , B01J37/084 , B01J37/20 , C10G45/08
摘要： The invention relates to a catalyst for the selective hydrodesulfurization of hydrocarbon-containing feedstocks that comprise sulfur-containing compounds and olefins. This catalyst comes in a sulfurized form and comprises a substrate that is selected from among the refractory oxides, at least one metal that is selected from the group that consists of the metals of groups VI and VII of the periodic table and carbon, whereby the carbon content is less than or equal to 2.8% by weight. The invention also relates to a method for the production of the catalyst that is described above, as well as a process that uses this catalyst for the selective hydrodesulfurization of hydrocarbon-containing feedstocks that contain sulfur-containing compounds and olefins.
摘要翻译： 本发明涉及包含含硫化合物和烯烃的含烃原料的选择性加氢脱硫催化剂。 该催化剂为硫化形式，并且包含选自耐火氧化物，至少一种选自由元素周期表第Ⅵ族和第Ⅶ族金属组成的组的金属和碳的底物，其中碳 含量小于或等于2.8重量％。 本发明还涉及上述催化剂的制备方法，以及使用该催化剂用于含有含硫化合物和烯烃的含烃原料的选择性加氢脱硫的方法。
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29.发明申请公开(公告)号：US20070191651A1
公开(公告)日：2007-08-16
申请号：US11638351
申请日：2006-12-14
CPC分类号： B01J37/0211 , B01J21/04 , B01J23/50 , B01J23/62 , B01J23/622 , B01J23/626 , B01J23/892 , B01J23/8926 , B01J35/0013 , B01J35/006 , B01J35/008 , B01J37/0213 , C10G45/34 , C10G2300/1088 , C10G2300/4018 , C10G2400/20
摘要： The invention relates to a process for the preparation of a catalyst comprising: a) The preparation of a colloidal oxide suspension of a first metal M1 that consists in the neutralization of a basic solution by an acidic mineral solution that contains the precursor of the metal M1, b) Bringing into contact the precursor of the promoter M2, either directly in its crystallized form or after dissolution in aqueous phase, with the colloidal suspension that is obtained in stage a), c) Bringing into contact the colloidal suspension that is obtained in stage b) with the substrate, d) Drying at a temperature of between 30° C. and 200° C., under a flow of air. The invention also relates to a process for the treatment of an olefinic fraction that uses the catalyst prepared [by] said preparation process.
摘要翻译： 本发明涉及一种制备催化剂的方法，包括：a）第一金属M1的胶体氧化物悬浮液的制备，其包括通过含有金属M1前体的酸性矿物溶液中和碱性溶液 b）使步骤a）中获得的胶体悬浮液与促进剂M2的前体直接接触，其结晶形式或溶解于水相中，c）使得所得到的胶体悬浮液接触 阶段b）与基材，d）在空气流下在30℃和200℃之间的温度下干燥。 本发明还涉及一种处理使用由所述制备方法制备的催化剂的烯烃级分的方法。
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30.发明授权公开(公告)号：US07052598B2
公开(公告)日：2006-05-30
申请号：US10095295
申请日：2002-03-12
CPC分类号： C10G65/06 , C10G2400/02
摘要： A process for the production of gasoline with a low sulfur content that comprises at least one selective hydrogenation of diolefins, optionally at least one stage for transformation, preferably to increase their weight, for light sulfur-containing compounds that are present in the gasoline, at least one fractionation of the gasoline that is obtained into at least two fractions: light gasoline and heavy gasoline, then optionally a stage for transformation, preferably for alkylation or adsorption, of sulfur-containing compounds and a desulfurization treatment in a stage of at least a portion of the heavy fraction.
摘要翻译： 一种生产低硫含量的汽油的方法，该方法包括至少一种二烯烃的选择性氢化，任选的至少一个转化阶段，优选增加其重量，用于存在于汽油中的轻质含硫化合物，在 将至少两种馏分中的汽油的至少一次分馏：轻质汽油和重质汽油，然后任选地用于转化，优选用于烷基化或吸附的含硫化合物和脱硫处理的阶段至少为 部分重部分。
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