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公开(公告)号：US08071655B2
公开(公告)日：2011-12-06
申请号：US11721923
申请日：2005-11-17
CPC分类号： B01J21/12 , B01J23/005 , B01J23/462 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8913 , B01J29/405 , B01J29/7049 , B01J29/7088 , B01J29/7092 , B01J29/90 , B01J37/08 , C10G2/332 , Y10S502/524
摘要： A catalyst applicable to the synthesis gas conversions especially E-T slurry processes, said catalyst comprising: a) a support containing at least a first aluminate element of mixed spinel structure of formula MxM′(1−x)Al2O4/Al2O3.SiO2, x ranging between and excluding 0 and 1, or of simple spinel structure of formula MAl2O4/Al2O3.SiO2, said support being calcined in an at least partly oxidizing atmosphere, at a temperature ranging between 850° C. and 900° C., and b) an active phase deposited on said support, which contains one or more group VIII metals, selected from among cobalt, nickel, ruthenium or iron. Said catalyst is used in a fixed bed or suspended in a three-phase reactor for hydrocarbon synthesis from a CO, H2 mixture.
摘要翻译： 一种适用于合成气转化尤其是ET淤浆法的催化剂，所述催化剂包括：a）至少含有式M x M'（1-x）Al 2 O 4 / Al 2 O 3 -SiO 2的混合尖晶石结构的第一铝酸盐元素的载体， 并且不包括0和1，或者简单的尖晶石结构式为MA1204 / Al2O3.SiO2，所述载体在至少部分氧化的气氛中在850℃和900℃之间的温度下煅烧，和b） 活性相沉积在所述载体上，其含有一种或多种选自钴，镍，钌或铁的第VIII族金属。 所述催化剂用于固定床或悬浮在三相反应器中，用于从CO，H 2混合物合成碳氢化合物。
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公开(公告)号：US20100029792A1
公开(公告)日：2010-02-04
申请号：US11721923
申请日：2005-11-17
CPC分类号： B01J21/12 , B01J23/005 , B01J23/462 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/8913 , B01J29/405 , B01J29/7049 , B01J29/7088 , B01J29/7092 , B01J29/90 , B01J37/08 , C10G2/332 , Y10S502/524
摘要： The invention relates to a catalyst which can be applied to a method for converting synthesis gas, said catalyst comprising: a) a support made of a solid solution containing at least one first aluminate element with a mixed spinel structure of formula MxM′(1-X)AI2O4/AI203.SiO2, x ranging from 0 to 1 being excluded, or a simple spinel structure of formula MAI2O4/AI2O3 SiO2, wherein the support is calcinated in an at least partially oxidizing atmosphere at a temperature ranging from 850° C. to 900° C., b) an active phase which is deposited on the support which contains one or several metals of group VIII, selected from amongst cobalt, nickel, ruthenium or iron. The catalyst is used in a fixed bed or in a suspension in a triphasic reactor for the synthesis of hydrocarbons from a CO, H2 mixture.
摘要翻译： 本发明涉及可用于转化合成气的方法的催化剂，所述催化剂包括：a）由含有至少一种第一铝酸盐元素与具有式MxM'（1- X）Al 2 O 4 / Al 2 O 3·Si 2 O 2，排除0至1的x，或式MAI 2 O 4 / Al 2 O 3 SiO 2的简单尖晶石结构，其中载体在至少部分氧化气氛中在850℃的温度下煅烧。 至900℃，b）沉积在载体上的活性相，其含有一种或几种选自钴，镍，钌或铁的VIII族金属。 该催化剂用于固定床或三相反应器中用于从CO，H 2混合物合成烃的悬浮液中。
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3.发明授权公开(公告)号：US07198712B2
公开(公告)日：2007-04-03
申请号：US10462809
申请日：2003-06-17
CPC分类号： C10G21/12 , C10G29/205
摘要： For desulfurization and, if necessary, for denitrification of hydrocarbon fractions the hydrocarbon mixture is brought into contact with a non-aqueous ionic liquid of general formula Q+A−, wherein Q+ is a ammonium, phosphonium or sulfonium cation, that contains at least one alkylating agent of the formula RX−, making it possible to form ionic sulfur-containing derivatives (and, if necessary, nitrogen-containing derivatives) that have a preferred solubility in the ionic liquid; and the ionic liquid is separated from the hydrocarbon mixture that is low in sulfur and nitrogen by decanting.
摘要翻译： 对于脱硫，如果需要，使烃馏分脱氮，使烃混合物与通式为Q +的非水离子液体接触，其中Q 含有至少一种式RX的烷基化剂的铵，鏻或锍阳离子，使得可以形成离子含硫衍生物（和， 如果需要，含氮衍生物）在离子液体中具有优选的溶解度; 离子液体通过倾析从硫和氮低的烃混合物中分离出来。
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4.发明申请SPHERICAL MATERIAL BASED ON HETEROPOLYANIONS TRAPPED IN A MESOSTRUCTURED OXIDE MATRIX AND USE THEREOF AS CATALYST IN HYDROCARBON REFINING PROCESSES 审中-公开基于在结构化氧化物基质中捕获的异黄酮的球形材料及其作为烃类精炼工艺中的催化剂的用途公开(公告)号：US20140005031A1
公开(公告)日：2014-01-02
申请号：US13995508
申请日：2011-12-15
申请人： Alexandra Chaumonnot , Clement Sanchez , Cedric Boissiere , Frederic Colbeau-Justin , Karin Marchand , Elodie Devers , Audrey Bonduelle , Denis Uzio , Antoine Daudin , Bertrand Guichard , Denis Uzio , Antoine Daudin
发明人： Alexandra Chaumonnot , Clement Sanchez , Cedric Boissiere , Frederic Colbeau-Justin , Karin Marchand , Elodie Devers , Audrey Bonduelle , Denis Uzio , Antoine Daudin , Bertrand Guichard , Denis Uzio , Antoine Daudin
IPC分类号： B01J27/199 , B01J27/19 , B01J27/188 , B01J23/882
CPC分类号： B01J27/199 , B01J23/882 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/0333 , B01J29/0341 , B01J29/041 , B01J29/044 , B01J29/045 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/0045 , B01J37/033 , B01J37/10 , B01J37/20 , C01B37/00 , C01B37/005 , C01B37/02 , C01B39/04 , C01B39/06 , C10G3/45 , C10G3/46 , C10G3/48 , C10G3/49 , C10G3/50 , C10G45/06 , C10G47/12 , C10G2300/1011 , C10G2300/104 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/301 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10L1/04 , C10L1/06 , C10L1/08 , Y02P30/10 , Y02P30/20
摘要： Inorganic material having at least two elementary spherical particles, each of said spherical metallic particles: a polyoxometallate with formula (XxMmOyHh)q−, where H is hydrogen, O is oxygen, X is phosphorus, silicon, boron, nickel or cobalt and M is one or more vanadium, niobium, tantalum, molybdenum, tungsten, iron, copper, zinc, cobalt and nickel, x is 0, 1, 2 or 4, m is 5, 6, 7, 8, 9, 10, 11, 12 or 18, y is 17 to 72, h is 0 to 12 and q is 1 to 20.
摘要翻译： 具有至少两个基本球形颗粒的无机材料，每个所述球形金属颗粒：具有式（XxMmOyHh）q-的多金属氧酸盐，其中H是氢，O是氧，X是磷，硅，硼，镍或钴，M是 一种或多种钒，铌，钽，钼，钨，铁，铜，锌，钴和镍，x为0,1,2或4，m为5,6,7,8,9,10,11,12 或18，y为17〜72，h为0〜12，q为1〜20。
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5.发明授权公开(公告)号：US07374667B2
公开(公告)日：2008-05-20
申请号：US10095293
申请日：2002-03-12
申请人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard , David B Arnett , Mike Grayson , Donald E Zeek , Carl Snider
发明人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard , David B Arnett , Mike Grayson , Donald E Zeek , Carl Snider
CPC分类号： C10G67/08 , C10G2400/02
摘要： For the production of gasoline with a low sulfur content, a process comprises at least one stage for transformation of sulfur-containing compounds consisting of an alkylation or adsorption of sulfur-containing compounds and/or an increasing of the weight of light sulfur-containing compounds, at least one stage for treatment in the presence of an acid catalyst and at least one desulfurization treatment of at least a portion of the gasoline. The process can also optionally comprise at least one stage for selective hydrogenation of diolefins and optionally at least one fractionation of the gasoline that is obtained into at least two fractions: light gasoline and heavy gasoline.
摘要翻译： 为了生产硫含量低的汽油，一种方法包括至少一个阶段，用于转化由含硫化合物的烷基化或吸附组成的含硫化合物和/或轻质含硫化合物的重量的增加 ，在酸催化剂存在下处理的至少一个阶段和至少一部分汽油的至少一个脱硫处理。 该方法还可以任选地包含至少一个阶段，用于二烯烃的选择性氢化和任选的至少一种汽油的分馏，其被获得至少两个馏分：轻汽油和重汽油。
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6.发明授权Process for hydrodesulphurizing cuts containing sulphur containing compounds and olefins in the presence of a supported catalyst comprising group VIII and VIB elements 有权在含有VIII族和VIB族元素的负载催化剂存在下，含硫化合物和烯烃的加氢脱硫馏分的方法公开(公告)号：US07306714B2
公开(公告)日：2007-12-11
申请号：US10449714
申请日：2003-06-02
申请人： Denis Uzio , Stephane Cremer , Carine Petit-Clair , Nathalie Marchal-George , Christophe Bouchy , Florent Picard
发明人： Denis Uzio , Stephane Cremer , Carine Petit-Clair , Nathalie Marchal-George , Christophe Bouchy , Florent Picard
IPC分类号： C10G45/04
CPC分类号： C10G45/08
摘要： A process for hydrodesulphurizing gasoline cuts is carried out in the presence of a catalyst comprising at least one group VIII element, at least one group VIB element, and a support with a specific surface area of less than about 200 m2/g, wherein the density of the group VIB elements per unit surface area of the support is in the range 4×10−4 to 36×10−4 g of group VIB element oxides per m2 of the support.
摘要翻译： 加氢脱硫汽油馏分的方法是在包含至少一种VIII族元素，至少一种VIB族元素和比表面积小于约200m 2 / g的载体的催化剂的存在下进行的， SUP> / g，其中载体每单位表面积的组VIB元素的密度在4×10 -4至36×10 -4 V族VIB元素 氧化物/ m 2的载体。
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7.发明授权Process for recovering hydrogen in a gaseous hydrocarbon effluent by chemical reaction 有权通过化学反应回收气态烃流出物中的氢气的方法公开(公告)号：US07081558B2
公开(公告)日：2006-07-25
申请号：US10680417
申请日：2003-10-08
CPC分类号： C01B3/38 , C01B3/52 , C01B3/58 , C01B2203/0415 , C01B2203/0435 , C01B2203/048 , C01B2203/0485 , C01B2203/0495 , C01B2203/147 , C10G45/00 , C10G69/08
摘要： Process for recovery of hydrogen in an effluent that is rich in hydrocarbons and that also contains hydrogen and a light olefin fraction, whereby said process comprises: a stage a) in which said effluent is brought into contact with at least one reagent that can react with said olefins to form with them a complex or a molecule; a stage c) in which the effluent that is obtained from stage a) is brought into contact with a composition that comprises at least one unsaturated compound in the presence of a suitable catalyst under hydrogenation conditions of at least a portion of said unsaturated compound by at least a portion of the hydrogen that is present in said effluent; a stage d) in which a reaction for dehydrogenation of hydrocarbons that are present in the effluent that is obtained from stage c) is carried out.
摘要翻译： 在富含烃并且还含有氢和轻质烯烃馏分的流出物中回收氢气的方法，其中所述方法包括：a）使所述流出物与至少一种可与 所述烯烃与它们形成复合物或分子; 阶段c），其中从阶段a）获得的流出物与包含至少一种不饱和化合物的组合物在合适的催化剂存在下在至少部分所述不饱和化合物的氢化条件下与在 所述流出物中存在的至少一部分氢; 阶段d），其中进行从阶段c）获得的流出物中存在的烃的脱氢反应。
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公开(公告)号：US06602821B2
公开(公告)日：2003-08-05
申请号：US09780610
申请日：2001-02-12
申请人： Carine Petit-Clair , Blaise Didillon , Denis Uzio
发明人： Carine Petit-Clair , Blaise Didillon , Denis Uzio
IPC分类号： B01J2358
CPC分类号： B01J35/023 , B01J23/40 , B01J23/683 , B01J23/74 , B01J35/0013 , B01J37/0211
摘要： The present invention relates to a catalyst which can be used in a process involving a conversion reaction for organic compounds, containing at least one support and at least one metal, and characterized in that it has particles of an average size greater than approximately 1 nm, and more than 80% of particles, the size of which is comprised in the range D±(D.0.2) where D represents the average size of the particles. It also relates to the process for preparing this catalyst which consists of preparing a colloidal suspension, in aqueous phase, of the metal oxide or metals to be supported, then depositing this suspension on a support, and optionally reducing the oxide thus supported.
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9.发明授权公开(公告)号：US07932205B2
公开(公告)日：2011-04-26
申请号：US11638351
申请日：2006-12-14
CPC分类号： B01J37/0211 , B01J21/04 , B01J23/50 , B01J23/62 , B01J23/622 , B01J23/626 , B01J23/892 , B01J23/8926 , B01J35/0013 , B01J35/006 , B01J35/008 , B01J37/0213 , C10G45/34 , C10G2300/1088 , C10G2300/4018 , C10G2400/20
摘要： The invention relates to a process for the preparation of a catalyst comprising: a) The preparation of a colloidal oxide suspension of a first metal M1 that consists in the neutralization of a basic solution by an acidic mineral solution that contains the precursor of the metal M1, b) Bringing into contact the precursor of the promoter M2, either directly in its crystallized form or after dissolution in aqueous phase, with the colloidal suspension that is obtained in stage a), c) Bringing into contact the colloidal suspension that is obtained in stage b) with the substrate, d) Drying at a temperature of between 30° C. and 200° C., under a flow of air. The invention also relates to a process for the treatment of an olefinic fraction that uses the catalyst prepared [by] said preparation process.
摘要翻译： 本发明涉及一种制备催化剂的方法，包括：a）第一金属M1的胶体氧化物悬浮液的制备，其包括通过含有金属M1前体的酸性矿物溶液中和碱性溶液 b）使步骤a）中获得的胶体悬浮液与促进剂M2的前体直接接触，其结晶形式或溶解于水相中，c）使得所得到的胶体悬浮液接触 阶段b）与基材，d）在空气流下在30℃和200℃之间的温度下干燥。 本发明还涉及一种处理使用由所述制备方法制备的催化剂的烯烃级分的方法。
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10.发明申请CATALYST PREPARED BY IMPREGNATION OF AN AQUEOUS SOLUTION CONTAINING OXY(HYDROXIDE) PARTICLES OF A CATION IN INTERACTION WITH A MOLECULAR SPECIES OF A GROUP VIII METAL 审中-公开包含含有氧化物（羟基）的颗粒的水溶液与通过VIII族金属的分子物质相互作用的水溶液制备的催化剂公开(公告)号：US20080154074A1
公开(公告)日：2008-06-26
申请号：US11953272
申请日：2007-12-10
申请人： Cecile Thomazeau , Denis Uzio , Catherine Verdon , Lars Fischer
发明人： Cecile Thomazeau , Denis Uzio , Catherine Verdon , Lars Fischer
CPC分类号： B01J23/58 , B01J21/04 , B01J23/54 , B01J23/63 , B01J23/76 , B01J35/0013 , B01J35/008 , B01J37/0211 , B01J37/0213 , C07C5/3337 , C07C2523/58 , C07C2523/63 , C10G45/40 , C07C11/08
摘要： The invention concerns a process for preparing a catalyst precursor comprising the following steps: 1)a) preparing a colloidal solution A with a defined pH containing oxy(hydroxide) particles of a cation Mz+ selected from the group constituted by cations from columns IIA, IIIA, IIIB, IVB and IVA of the periodic table; or 1)b) using a commercial aqueous colloidal solution (solution A) with a defined pH containing oxy(hydroxide) particles of a cation Mz+ selected from the group constituted by cations from columns IIA, IIIA, IIIB, IVB and IVA of the periodic table; 2) adding in an aqueous solution B containing a precursor salt of a group VIII metal with a concentration of 0.001 to 1 mole/litre, the precursor salt of the metal being soluble under the pH conditions used in step 1. The invention also concerns the catalyst obtained from a catalyst precursor and its application in selective hydrogenation.
摘要翻译： 本发明涉及一种制备催化剂前体的方法，其包括以下步骤：1）a）制备胶体溶液A，其中所述胶体溶液A具有含有选自以下基团的阳离子M z（z）的氧（氢氧化物）颗粒的定义的pH 由周期表的列IIA，IIIA，IIIB，IVB和IVA的阳离子构成; 或1）b）使用具有规定的pH的市售含水胶体溶液（溶液A），其含有选自由IIA，IIIA，IIIA，IIIA族中的阳离子构成的组的阳离子M z z + 周期表IIIB，IVB和IVA; 2）在含有浓度为0.001〜1摩尔/升的Ⅷ族金属的前体盐的水溶液B中加入，该金属的前体盐在步骤1中使用的pH条件下是可溶的。本发明还涉及 由催化剂前体获得的催化剂及其在选择性氢化中的应用。
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