摘要:
The crosslinked copolymer containing 75 to 99.9% by weight of recurring units of a pyridyl, quinolyl, isoquinolyl or pyrazinyl compound containing a polymerizable olefinic group, 0.1 to 25% by weight of units of a crosslinking agent and 0 to 25% by a weight of units of a polymerizable organosilicon and/or organoboron compound and, based on 100% by weight of the sum of the abovementioned units, 5 to 350% by weight of units of an N-vinyl-amide, is prepared by bead polymerization and used as a sorbent for acid substances from their aqueous solutions.
摘要:
Substances producing an undesired odor and taste can be removed from microbial protein materials if these materials are treated with aqueous solutions which contain a phosphate and/or a hydrophilic low molecular weight aliphatic compound which contains at least two functional groups from the series comprising hydroxy, formyl, keto and carboxy. Preferred aliphatic extraction auxiliaries are flavoring acids, sugars and polyols, and phosphates are orthophosphates and diphosphates. The extraction can also be carried out in association with reducing the nucleic acid content of defatted cell aggregates.
摘要:
A process for reducing the content of lipids and nucleic acids in a microbial cell mass to be used for food and feeding purposes, which comprises treating the cell mass with ammonia or ammonium hydroxide and with isopropanol or an organic solvent of the formulaR.sub.1 --(CH.sub.2).sub.n --OR.sub.2wherein either R.sub.1 and R.sub.2 are hydrogen, and n stands for one, two or three, or R.sub.1 is hydroxy, R.sub.2 is hydrogen, methyl or ethyl and n stands for two or three, and, after separation of the liquid, washing the residue with water, separating the aqueous phase and drying the residue.
摘要:
A cofactor having an aromatic or benzylic amino group is converted into an isothiocyanate by reaction with a compound such as thiophosgene and the isothiocyanate of the cofactor is attached to a polymer which is preferably water-soluble. When the polymer has amino groups, a thiourea bridge is formed between the polymer and cofactor and a polymer having hydroxyl groups results in a thiocarbamate bridge. The polymer may be a copolymer of vinylamine or vinylmethylamine and vinylmethylacetamide, partially alkylamine-substituted .alpha., .beta.-poly-(2-hydroxyethyl)-D,L-aspartamide, polyethyleneimine or carbohydrate. The cofactor bound to a polymer and an enzyme are contained in microcapsules or in a membrane to form an enzyme reactor.
摘要:
A process for the preparation of a mixture of sucrose oxidation products which contains a salt of sucrosetricarboxylic acid and which is obtained by reaction of sucrose with oxygen in an aqueous medium in the presence of a platinum metal/active carbon catalyst at elevated temperatures and neutralization of the reaction product to convert into the salt form, which comprises the reaction being carried out discontinuously, the starting materials being heated stepwise over the course of several hours from room temperature up to 60.degree. to 95.degree. C. and then the reaction product being isolated where appropriate.The oxidation products obtained in this way have, in particular, improved washing properties.
摘要:
Streptazoline is reacted with naphthoquinones in a Diels-Alder reaction, and the adduct is then oxidized. The resulting compounds have cytotoxic activity, in particular against leukemia cells, and have an antimicrobial action and act against protozoa.
摘要:
A process for the single-stage preparation of glycosyl fluorides by dissolving saccharides in liquid hydrogen fluoride and evaporating the hydrogen fluoride, wherein the resulting glycosyl fluoride is isolated in such a way that, when the evaporation of the hydrogen fluoride is started at a relatively high temperature, in general at -20.degree. to +20.degree. C., the evaporation is effected at a high evaporation rate or, when a low evaporation rate is used at the start of the evaporation, a sufficiently low temperature is set, in general -80.degree. C. to -30.degree. C.
摘要:
Polysaccharides built up from anhydroglucose are obtained when glucose or carbohydrates containing glucose as the monomer structural unit are condensed with polyhydric alcohols in hydrogen fluoride. The products may be used as water binding agents and water retaining agents, especially for dietetic foodstuffs.
摘要:
A process for the manufacture of glycosides which comprises reacting a protected hexopyranosyl fluoride with an aglycon or a silyl ether thereof in the presence of a metal fluoride of group IV or V of the periodic table, said metal having an atomic number of at least 22 and being present in the fluoride in a higher, stable and non-oxidizing or weekly oxidizing stage.
摘要:
In the process for the preparation of 4-benzyl aspartate starting from dibenzyl aspartate and/or its salts only one benzyl group is selectively removed by catalytic hydrogenation. By setting up appropriate reaction conditions elimination takes place mainly of the benzyl group on the C.sub.1 atom of the compound. The desired product can be isolated from the reaction mixture by precipitation.